CN110615609B - Novel glass material - Google Patents
Novel glass material Download PDFInfo
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- CN110615609B CN110615609B CN201910639503.6A CN201910639503A CN110615609B CN 110615609 B CN110615609 B CN 110615609B CN 201910639503 A CN201910639503 A CN 201910639503A CN 110615609 B CN110615609 B CN 110615609B
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- 239000011521 glass Substances 0.000 title claims abstract description 90
- 239000000463 material Substances 0.000 title claims abstract description 13
- 239000006229 carbon black Substances 0.000 claims abstract description 57
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 30
- 239000000919 ceramic Substances 0.000 claims abstract description 20
- 239000002270 dispersing agent Substances 0.000 claims abstract description 19
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 8
- 235000019738 Limestone Nutrition 0.000 claims abstract description 8
- 239000006004 Quartz sand Substances 0.000 claims abstract description 8
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 8
- 150000001639 boron compounds Chemical class 0.000 claims abstract description 8
- 239000006028 limestone Substances 0.000 claims abstract description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 59
- 239000007788 liquid Substances 0.000 claims description 46
- 239000000243 solution Substances 0.000 claims description 37
- 239000011259 mixed solution Substances 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 239000002994 raw material Substances 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 9
- 238000003723 Smelting Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 6
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- PHEDXBVPIONUQT-UHFFFAOYSA-N Cocarcinogen A1 Natural products CCCCCCCCCCCCCC(=O)OC1C(C)C2(O)C3C=C(C)C(=O)C3(O)CC(CO)=CC2C2C1(OC(C)=O)C2(C)C PHEDXBVPIONUQT-UHFFFAOYSA-N 0.000 claims description 4
- 238000000137 annealing Methods 0.000 claims description 4
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 4
- 239000003258 bubble free glass Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 238000004806 packaging method and process Methods 0.000 claims description 4
- PHEDXBVPIONUQT-RGYGYFBISA-N phorbol 13-acetate 12-myristate Chemical compound C([C@]1(O)C(=O)C(C)=C[C@H]1[C@@]1(O)[C@H](C)[C@H]2OC(=O)CCCCCCCCCCCCC)C(CO)=C[C@H]1[C@H]1[C@]2(OC(C)=O)C1(C)C PHEDXBVPIONUQT-RGYGYFBISA-N 0.000 claims description 4
- 230000001376 precipitating effect Effects 0.000 claims description 4
- 239000013049 sediment Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 3
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 3
- 239000006060 molten glass Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 11
- 239000011248 coating agent Substances 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 6
- 230000032683 aging Effects 0.000 abstract description 5
- 239000011247 coating layer Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000005315 stained glass Substances 0.000 description 2
- 239000005341 toughened glass Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000005304 optical glass Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
- C03C4/085—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for ultraviolet absorbing glass
Abstract
The invention discloses a technical scheme that: the novel glass material is prepared from the following components in parts by weight: 70-80 parts of quartz sand, 5-8 parts of soda ash, 40-50 parts of carbon black, 6-8 parts of calcite, 7-10 parts of ceramic micro powder, 7-10 parts of iron oxide, 5-9 parts of limestone, 1-3 parts of boron compound, 2-5 parts of barium carbonate and 3-6 parts of dispersing agent. Make the glass of preparation directly possess sunshade, shading, anti ultraviolet's effect, directly replace the tradition glass surface coating light shield layer again, make the glass of preparation directly possess the effect of coating light shield layer, durability, ageing degree etc. can obtain promotion by a wide margin when outdoor use simultaneously, make glass can not yellow, drop and improve glass shading effect, through the mutually supporting debugging of carbon black, ceramic miropowder and iron oxide powder simultaneously, make the glass intensity of preparation be higher than ordinary glass's intensity.
Description
Technical Field
The invention relates to the technical field of glass manufacturing, in particular to a novel glass material.
Background
The glass is a non-crystal inorganic non-metal material, generally made up by using several inorganic minerals as main raw material and adding small quantity of auxiliary raw material, its main component is silicon dioxide and other oxides, and can be extensively used in building, and can be used for insulating wind and transmitting light, belonging to a mixture, and in addition, there are some coloured glasses which can be mixed with some metal oxides or salts and can display colour, and toughened glass made up by using physical or chemical method, and some transparent plastics are also called organic glass.
Glass is used as an industrial material and widely applied to facilities such as buildings, the existing glass is mostly divided into different glass, toughened glass, curved glass, optical glass and the like, some glass on the buildings is mostly transparent, sunlight is directly irradiated in summer, ultraviolet rays and light sources are directly irradiated indoors through the glass, the temperature of an area of indoor furniture irradiated by the sunlight is increased, the furniture is discolored, and the local aging is caused, in order to increase the sun-shading effect of the glass, the glass is mostly coated on the surface of the glass in the modes of sun-shading glue or sun-shading film and the like, but the glass can only play a sun-shading effect within a limited time, the glass is irradiated by the sunlight for a long time, and in addition, the glass is mostly located outdoors, the weather such as rainwater, sand storm and the like is caused, the coating layer is directly acted on the glass, the coating layer is aged and yellowed, and falls off from the surface layer of the glass, so that the local sun-shading effect of the glass is deteriorated, the coating that ages further ftractures, and the coating receives the shining of sunshine to appear ageing, and the adhesion of part curing adhesive can't clear away on glass, further influences the quality and pleasing to the eye of glass, is unfavorable for glass's permanent use.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a novel glass material, and solves the problems of glass aging, formation of solidified spots on the surface of glass and poor sun-shading effect.
In order to achieve the purpose, the invention provides the following technical scheme: the novel glass material is prepared from the following components in parts by weight: 70-80 parts of quartz sand, 5-8 parts of soda ash, 40-50 parts of carbon black, 6-8 parts of calcite, 7-10 parts of ceramic micro powder, 7-10 parts of iron oxide, 5-9 parts of limestone, 1-3 parts of boron compound, 2-5 parts of barium carbonate and 3-6 parts of dispersing agent, and specifically comprises the following operation steps:
the method comprises the following steps: preparing a carbon black solution, dropwise adding a proper amount of organic solvent into a reaction kettle, slowly adding 40-50 parts of carbon black into the reaction kettle, raising the temperature in the reaction kettle to 60-80 ℃, completing adding of the carbon black within ten minutes, starting a stirring device to stir the carbon black solution for 5-10 minutes, adding 3-6 parts of a dispersing agent into the reaction kettle, completing dropping of the dispersing agent within 5-7 minutes, then starting the stirring device to stir the carbon black solution, keeping the temperature of the mixed solution at 60 ℃, observing the liquid level state of the mixed solution after 10-20 minutes, slowly dropwise adding 1-2 parts of the dispersing agent into the reaction kettle if the mixed solution contains a large amount of flocculent or sediment, then starting the stirring device again to stir for 5-10 minutes, observing the liquid level state of the mixed solution again after 10-20 minutes, and after the liquid level state is flat and has no large amount of flocculent objects, selecting 7-10 parts of ceramic micro powder into a reaction kettle, starting a stirring device to uniformly stir the ceramic micro powder and the mixed solution, adding 7-10 parts of ferric oxide into the reaction kettle after stirring for 5-10 minutes, starting the stirring device to uniformly stir the ferric oxide powder and the mixed solution, observing the liquid level state after stirring for 5-10 minutes, reducing the water content in the mixed solution to 15% -20%, keeping the mixed solution at 70 ℃ and precipitating for 0.5-1 hour;
step two: weighing 70-80 parts of quartz sand, 5-8 parts of soda ash, 6-8 parts of calcite, 5-9 parts of limestone, 1-3 parts of boron compound and 2-5 parts of barium carbonate, mixing and stirring uniformly as a glass preparation main raw material, then transporting the mixed raw materials into a smelting furnace by using a feeder, raising the temperature in the smelting furnace to 1200-1600 ℃, melting the mixed raw materials at high temperature, after the melted raw materials form uniform bubble-free glass liquid, putting the carbon black solution obtained in the first step into the glass liquid by using the feeder, starting a stirring device to completely mix the carbon black solution and the glass liquid, observing whether the carbon black solution and the glass liquid are mixed after 1-2 hours, starting the stirring device again if the carbon black solution is aggregated, till the carbon black solution and the glass liquid are completely melted together, and mixing the melted mixed glass liquid after the carbon black solution and the glass liquid, and (3) solidifying and molding the molten glass on a molding grinding tool, then annealing the molded glass, and finally packaging and warehousing the prepared glass.
Preferably, the particle size of the carbon black particles is 5nm, the particle size of the ceramic micro powder is 5nm, the particle size of the iron oxide powder particles is 5nm, and the ratio of the carbon black, the ceramic micro powder and the iron oxide powder is 1:0.5: 0.5.
Preferably, the dispersant is one of diethylene glycol dimethyl ether, PMA or butyl acetate.
The beneficial effects are as follows:
this novel glass new material, through the combination of carbon black solution and glass liquid, make the glass of preparing directly possess the sunshade, the shading, anti ultraviolet's effect, directly replace the tradition glass surface coating light shield layer again, make the glass of preparation directly possess the effect of coating light shield layer, durability when outdoor use simultaneously, promotion by a wide margin can be obtained to ageing degree etc., make glass can not yellow, it improves glass shading effect to drop, simultaneously, through carbon black, the mutually supporting debugging of ceramic miropowder and iron oxide powder, make the glass intensity of preparation be higher than ordinary glass's intensity, the glass of preparation simultaneously possesses the absorption ultraviolet, the effect of shading, keep ornaments such as indoor furniture can long-time use, the glass of preparation simultaneously can adapt to with different operational environment.
Detailed Description
All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a technical scheme that: the novel glass material is prepared from the following components in parts by weight: 70-80 parts of quartz sand, 5-8 parts of soda ash, 40-50 parts of carbon black, 6-8 parts of calcite, 7-10 parts of ceramic micro powder, 7-10 parts of iron oxide, 5-9 parts of limestone, 1-3 parts of boron compound, 2-5 parts of barium carbonate and 3-6 parts of dispersing agent, and specifically comprises the following operation steps:
the method comprises the following steps: preparing a carbon black solution, dropwise adding a proper amount of organic solvent into a reaction kettle, slowly adding 40-50 parts of carbon black into the reaction kettle, raising the temperature in the reaction kettle to 60-80 ℃, completing adding of the carbon black within ten minutes, starting a stirring device to stir the carbon black solution for 5-10 minutes, adding 3-6 parts of a dispersing agent into the reaction kettle, completing dropping of the dispersing agent within 5-7 minutes, then starting the stirring device to stir the carbon black solution, keeping the temperature of the mixed solution at 60 ℃, observing the liquid level state of the mixed solution after 10-20 minutes, slowly dropwise adding 1-2 parts of the dispersing agent into the reaction kettle if the mixed solution contains a large amount of flocculent or sediment, then starting the stirring device again to stir for 5-10 minutes, observing the liquid level state of the mixed solution again after 10-20 minutes, and after the liquid level state is flat and has no large amount of flocculent objects, selecting 7-10 parts of ceramic micro powder into a reaction kettle, starting a stirring device to uniformly stir the ceramic micro powder and the mixed solution, adding 7-10 parts of ferric oxide into the reaction kettle after stirring for 5-10 minutes, starting the stirring device to uniformly stir the ferric oxide powder and the mixed solution, observing the liquid level state after stirring for 5-10 minutes, reducing the water content in the mixed solution to 15% -20%, keeping the mixed solution at 70 ℃ and precipitating for 0.5-1 hour;
step two: weighing 70-80 parts of quartz sand, 5-8 parts of soda ash, 6-8 parts of calcite, 5-9 parts of limestone, 1-3 parts of boron compound and 2-5 parts of barium carbonate, mixing and stirring uniformly as a glass preparation main raw material, then transporting the mixed raw materials into a smelting furnace by using a feeder, raising the temperature in the smelting furnace to 1200-1600 ℃, melting the mixed raw materials at high temperature, after the melted raw materials form uniform bubble-free glass liquid, putting the carbon black solution obtained in the first step into the glass liquid by using the feeder, starting a stirring device to completely mix the carbon black solution and the glass liquid, observing whether the carbon black solution and the glass liquid are mixed after 1-2 hours, starting the stirring device again if the carbon black solution is aggregated, till the carbon black solution and the glass liquid are completely melted together, and mixing the melted mixed glass liquid after the carbon black solution and the glass liquid, and (3) solidifying and molding the molten glass on a molding grinding tool, then annealing the molded glass, and finally packaging and warehousing the prepared glass.
The particle size of the carbon black particles is 5nm, the particle size of the ceramic micro powder is 5nm, the particle size of the iron oxide powder particles is 5nm, and the ratio of the carbon black, the ceramic micro powder and the iron oxide powder is 1:0.5: 0.5.
Wherein the dispersant is diethylene glycol dimethyl ether or PMA, and the PMA is one of propylene glycol methyl ether acetate or butyl acetate.
Examples
A novel glass material specifically comprises the following operation steps:
the method comprises the following steps: preparing a carbon black solution, dropwise adding a proper amount of organic solvent into a reaction kettle, slowly adding 40 parts of carbon black into the reaction kettle, raising the temperature in the reaction kettle to 65 ℃, completing the adding of the carbon black within ten minutes, starting a stirring device to stir the carbon black solution for 5 minutes, adding 4 parts of a dispersing agent into the reaction kettle, completing the dropping of the dispersing agent within 7 minutes, then starting the stirring device to stir the carbon black solution, keeping the temperature of the mixed solution to 60 ℃, observing the liquid level state of the mixed solution after waiting for 15 minutes, slowly dropwise adding 2 parts of the dispersing agent into the reaction kettle if the mixed solution contains a large amount of floccules or sediments, then starting stirring equipment again for 5 minutes, after waiting for 10 minutes, observing the liquid level state of the mixed solution again, selecting 8 parts of ceramic micro powder into the reaction kettle after the liquid level state is calm and has no large amount of floccules, starting stirring equipment to uniformly stir the ceramic micro powder and the mixed solution, adding 8 parts of iron oxide into the reaction kettle after stirring for 5-10 minutes, starting the stirring equipment to uniformly stir the iron oxide powder and the mixed solution, observing the liquid level state after stirring for 5-10 minutes, reducing the water content in the mixed solution to 15%, keeping the mixed solution at 70 ℃ and precipitating for 1 hour;
step two: weighing 80 parts of quartz sand, 7 parts of soda ash, 7 parts of calcite, 8 parts of limestone, 1 part of boron compound and 2 parts of barium carbonate, mixing and uniformly stirring the materials serving as main glass preparation raw materials, conveying the mixed raw materials into a smelting furnace by using a feeder, raising the temperature in the smelting furnace to 1300 ℃, melting the mixed raw materials at high temperature, putting the carbon black solution obtained in the step I into glass liquid through the feeder after the molten raw materials form uniform bubble-free glass liquid, starting stirring equipment to completely mix the carbon black solution and the glass liquid, observing whether the carbon black solution and the glass liquid are mixed after 1 hour, starting the stirring equipment again if the carbon black solution is gathered together, till the carbon black solution and the glass liquid are completely melted together, after the carbon black solution and the glass liquid are mixed, putting the melted mixed glass liquid onto a forming grinding tool, and solidifying and forming the glass liquid, then annealing the formed glass, and finally packaging and warehousing the prepared glass.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (3)
1. A new glass material is characterized in that: the glass is prepared from the following components in parts by weight: 70-80 parts of quartz sand, 5-8 parts of soda ash, 40-50 parts of carbon black, 6-8 parts of calcite, 7-10 parts of ceramic micro powder, 7-10 parts of iron oxide, 5-9 parts of limestone, 1-3 parts of boron compound, 2-5 parts of barium carbonate and 3-6 parts of dispersing agent, and specifically comprises the following operation steps:
the method comprises the following steps: preparing a carbon black solution, dropwise adding a proper amount of organic solvent into a reaction kettle, slowly adding 40-50 parts of carbon black into the reaction kettle, raising the temperature in the reaction kettle to 60-80 ℃, completing adding of the carbon black within ten minutes, starting a stirring device to stir the carbon black solution for 5-10 minutes, adding 3-6 parts of a dispersing agent into the reaction kettle, completing dropping of the dispersing agent within 5-7 minutes, then starting the stirring device to stir the carbon black solution, keeping the temperature of the mixed solution at 60 ℃, observing the liquid level state of the mixed solution after 10-20 minutes, slowly dropwise adding 1-2 parts of the dispersing agent into the reaction kettle if the mixed solution contains a large amount of flocculent or sediment, then starting the stirring device again to stir for 5-10 minutes, observing the liquid level state of the mixed solution again after 10-20 minutes, and after the liquid level state is flat and has no large amount of flocculent objects, selecting 7-10 parts of ceramic micro powder into a reaction kettle, starting a stirring device to uniformly stir the ceramic micro powder and the mixed solution, adding 7-10 parts of ferric oxide into the reaction kettle after stirring for 5-10 minutes, starting the stirring device to uniformly stir the ferric oxide powder and the mixed solution, observing the liquid level state after stirring for 5-10 minutes, reducing the water content in the mixed solution to 15% -20%, keeping the mixed solution at 70 ℃ and precipitating for 0.5-1 hour;
step two: weighing 70-80 parts of quartz sand, 5-8 parts of soda ash, 6-8 parts of calcite, 5-9 parts of limestone, 1-3 parts of boron compound and 2-5 parts of barium carbonate, mixing and stirring uniformly as a glass preparation main raw material, then transporting the mixed raw materials into a smelting furnace by using a feeder, raising the temperature in the smelting furnace to 1200-1600 ℃, melting the mixed raw materials at high temperature, after the melted raw materials form uniform bubble-free glass liquid, putting the carbon black solution obtained in the first step into the glass liquid by using the feeder, starting a stirring device to completely mix the carbon black solution and the glass liquid, observing whether the carbon black solution and the glass liquid are mixed after 1-2 hours, starting the stirring device again if the carbon black solution is aggregated, till the carbon black solution and the glass liquid are completely melted together, and mixing the melted mixed glass liquid after the carbon black solution and the glass liquid, and (3) solidifying and molding the molten glass on a molding grinding tool, then annealing the molded glass, and finally packaging and warehousing the prepared glass.
2. A new material for glass according to claim 1, characterized in that: the particle size of the carbon black particles is 5nm, the particle size of the ceramic micro powder is 5nm, the particle size of the iron oxide powder particles is 5nm, and the ratio of the carbon black, the ceramic micro powder and the iron oxide powder is 1:0.5: 0.5.
3. A new material for glass according to claim 1, characterized in that: the dispersant is one of diethylene glycol dimethyl ether, PMA or butyl acetate.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910639503.6A CN110615609B (en) | 2019-07-16 | 2019-07-16 | Novel glass material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910639503.6A CN110615609B (en) | 2019-07-16 | 2019-07-16 | Novel glass material |
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| CN110615609A CN110615609A (en) | 2019-12-27 |
| CN110615609B true CN110615609B (en) | 2021-08-10 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116751488B (en) * | 2023-06-19 | 2024-02-02 | 广东吉美帮新材料有限公司 | Coating with efficient shading performance and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101696087A (en) * | 2009-11-12 | 2010-04-21 | 君达（凤县）环保资源无害化过程科技有限公司 | Black micro-crystalline glass plate made of gold ore tailings and manufacturing method thereof |
| CN108298814A (en) * | 2018-02-08 | 2018-07-20 | 合肥利裕泰玻璃制品有限公司 | A kind of novel building glass and preparation method thereof |
| CN108863060A (en) * | 2018-08-03 | 2018-11-23 | 吴秀华 | The cold-resistant imperial wind type glass of one kind and its manufacturing process |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080090034A1 (en) * | 2006-09-18 | 2008-04-17 | Harrison Daniel J | Colored glass frit |
| DE102012004138B3 (en) * | 2011-12-06 | 2012-09-27 | Ley & Co. Farbenwerke Wunsiedel KG | Use of a zinc oxide frit comprising zinc oxide, e.g. as a UV light-absorbing pigment for the application areas of thermoplastically moldable plastics and in the solvent borne coatings for alkyd resin paints and polyurethane resin coatings |
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2019
- 2019-07-16 CN CN201910639503.6A patent/CN110615609B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101696087A (en) * | 2009-11-12 | 2010-04-21 | 君达（凤县）环保资源无害化过程科技有限公司 | Black micro-crystalline glass plate made of gold ore tailings and manufacturing method thereof |
| CN108298814A (en) * | 2018-02-08 | 2018-07-20 | 合肥利裕泰玻璃制品有限公司 | A kind of novel building glass and preparation method thereof |
| CN108863060A (en) * | 2018-08-03 | 2018-11-23 | 吴秀华 | The cold-resistant imperial wind type glass of one kind and its manufacturing process |
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| CN110615609A (en) | 2019-12-27 |
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