CN110614820A - Bio-based electronic microwave oven heating packaging bag - Google Patents

Bio-based electronic microwave oven heating packaging bag Download PDF

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Publication number
CN110614820A
CN110614820A CN201910475722.5A CN201910475722A CN110614820A CN 110614820 A CN110614820 A CN 110614820A CN 201910475722 A CN201910475722 A CN 201910475722A CN 110614820 A CN110614820 A CN 110614820A
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China
Prior art keywords
layer
additive
resin
bio
degradation
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Withdrawn
Application number
CN201910475722.5A
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Chinese (zh)
Inventor
张建华
张磊
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Hengda Technology (tianjin) Co Ltd
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Hengda Technology (tianjin) Co Ltd
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Priority to CN201910475722.5A priority Critical patent/CN110614820A/en
Publication of CN110614820A publication Critical patent/CN110614820A/en
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00—Protecting plants
    • A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0256—Ground coverings
    • A01G13/0268—Mats or sheets, e.g. nets or fabrics
    • A01G13/0275—Films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/716—Degradable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/716—Degradable
    • B32B2307/7163—Biodegradable

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  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Wrappers (AREA)

Abstract

The invention belongs to the technical field of bio-based degradation, and particularly relates to a bio-based electronic microwave oven heating packaging bag which comprises a surface layer, a middle layer and an inner layer; the surface layer comprises a surface resin layer and a surface additive layer, the surface resin layer is oxygen-containing resin controllable degradation (YZSZ) resin, and the surface additive layer is PBAT bio-based controllable degradation (PBZJ) additive; the middle layer comprises a middle layer resin layer and a middle layer additive layer, the middle layer additive layer is positioned below the middle layer resin layer, the middle layer resin layer is modified bio-based polyester bonding (SHQ-GTIE) resin, and the middle layer additive layer is PVA bio-based controllable degradation (PVZJ) additive; the inner layer comprises an inner resin layer and an inner additive layer, the inner additive layer is positioned below the inner resin layer, the inner resin layer is modified polycaprolactone (SHQ-MCL) resin, and the inner additive layer is an oxidative biological controlled degradation (YHZJ) additive.

Description

Bio-based electronic microwave oven heating packaging bag
Technical Field
The invention belongs to the technical field of bio-based degradation, and particularly relates to a bio-based electronic microwave oven heating packaging bag.
Background
With the rapid development of economy, people are increasingly seriously damaged to the environment, and particularly, non-degradable plastics are not easily degraded by soil microorganisms and are stored in the soil for a long time after being randomly thrown by people, so that the ecological environment is seriously polluted. Disposable tableware, disposable plastic products, agricultural mulching films and the like are difficult to recycle, and the traditional treatment method mainly comprises incineration and burying. A large amount of harmful gas is generated by burning, so that the environment is polluted; if buried, the polymer in the buried polymer cannot be decomposed by microorganisms in a short time, and the environment is polluted. The residual plastic film exists in the soil, which hinders the development of crop roots and the absorption of water and nutrients, so that the air permeability of the soil is reduced, and the yield of crops is reduced; after the residual plastic film is eaten in action, intestinal obstruction is caused and the patient dies; synthetic fiber fishing nets and fishing lines lost to or discarded in the ocean have caused considerable damage to marine life, and thus it is imperative to promote green consumption and enhance environmental protection.
In order to reduce white pollution and protect the ecological environment, people begin to research degradable plastics, the first-generation degradable plastics researched is degradable plastics, and a small part of degradable master batch or starch-based raw materials are added on the basis of the original raw materials, and the majority of the degradable plastics cannot be degraded and are not beneficial to the recovery and reconstruction of the plastics; the second generation of degraded plastics researched is bio-based controllable full-degradable plastics, biomass which is rich in resources and renewable is used as a raw material, the degradation process is green and clean, the benign cycle of a land and environment system is also facilitated to be constructed, and the method is an effective way for relieving the petroleum crisis and eliminating white pollution.
At present, the bio-based fully-degradable insect-proof mulching film applied in practice has the advantages of simple structure, incomplete degradation and poor implementation effect.
Disclosure of Invention
The invention provides a bio-based electronic microwave oven heating packaging bag, which aims to solve the problems of simple structure and incomplete degradation in the background technology.
The technical problem solved by the invention is realized by adopting the following technical scheme:
a biological-based electronic microwave oven heating packaging bag comprises a surface layer, a middle layer and an inner layer;
the surface layer comprises a surface resin layer and a surface additive layer, the surface additive layer is positioned below the surface resin layer, the surface resin layer is oxygen-containing resin controllable degradation (YZSZ) resin, and the surface additive layer is a PBAT bio-based controllable degradation (PBZJ) additive;
the middle layer comprises a middle layer resin layer and a middle layer additive layer, the middle layer additive layer is positioned below the middle layer resin layer, the middle layer resin layer is modified bio-based polyester bonding (SHQ-GTIE) resin, and the middle layer additive layer is PVA bio-based controllable degradation (PVZJ) additive;
the inner layer comprises an inner resin layer and an inner additive layer, the inner additive layer is positioned below the inner resin layer, the inner resin layer is modified polycaprolactone (SHQ-MCL) resin, and the inner additive layer is an oxidative biological controlled degradation (YHZJ) additive.
The thickness percentage of the surface layer is 20%, the thickness percentage of the middle layer is 60%, and the thickness percentage of the inner layer is 20%.
The thickness percentage of the surface resin layer is 85 percent, and the thickness percentage of the surface additive layer is 15 percent.
The thickness percentage of the middle layer resin layer is 90%, and the thickness percentage of the middle layer additive layer is 10%.
The thickness percentage of the inner resin layer is 95%, and the thickness percentage of the inner additive layer is 5%.
The PBAT bio-based controllable degradation (PBZJ) additive, the PVA bio-based controllable degradation (PVZJ) additive and the oxidative bio-controllable degradation (YHZJ) additive are all as follows: cobalt dithiocarbamate.
The invention has the beneficial effects that:
the mulching film prepared by the technical scheme can realize complete degradation, has ideal implementation effect,
the concrete component effects are as follows:
1 controlled degradation of oxygen-containing resins (YZSZ) resin: the degradable modified resin is added in the production process of the degradable plastic product, so that various non-degradable plastic products are changed into controllable and completely degradable plastic products, the degradable plastic products using the degradable modified resin can be degraded when being exposed to sunlight, high temperature or external force, and the degradation time and speed are controllable. In the production process of the degradable plastics, the triple controllable degradable resins are prepared by adopting a multi-layer co-extrusion molding process, and the degradable resins with different polarities are co-extruded into a molding chamber by utilizing a special process, so that the biodegradation of compost and the oxidative biodegradation are effectively combined together, and the degradation controllability and the complete degradability are really realized. The triple controllable degradable resin has no toxicity, can be contacted with edible substances, has strong processability, is compatible with most materials, has controllable degradability, can control the degradation time according to the required requirement, has 100 percent of environmental degradability, can be completely converted into water, carbon dioxide and organic substances, can not be harmful to the environment or soil, has high cost performance, and has lower cost compared with other degradation technologies. The triple controllable degradable resin is mainly used in garbage treating system, packing industry, agriculture, compost and plastic producing industry, and is suitable for producing various degradable plastic products, such as mulching film, drip irrigation belt, shopping bag, vest bag, garbage bag, express bag, snack box, etc.
2 modified bio-based polyester adhesive (SHQ-GTIE) resin: the bio-based polyester adhesive resin adopts special resin as a carrier and special auxiliary agent as a medium, and can be co-extruded and adhered with the bio-based polyester resin and polyolefin resin through modification. The modified bio-based polyester adhesive resin is a high molecular polymer, is a yellow white granular solid in appearance, is nontoxic, tasteless and pollution-free, is a degradable resin, and has the characteristics of good chemical stability, adhesiveness and the like. The modified bio-based polyester adhesive resin has two groups of hydrophilic group and hydrophobic group, so that the modified bio-based polyester adhesive resin can be adhered to petroleum-based resin and bio-based resin, and has good compatibility. The modified bio-based polyester adhesive resin is mainly used for adhesion of bio-based resin polyolefins or adhesion of petroleum-based resin polyolefins.
3 modified polycaprolactone (SHQ-MCL) resin: the polycaprolactone resin is a semi-crystalline polymer, colorless crystalline solid polyester with lower molecular weight has the defects of higher cost and poor compatibility with other degradable resin materials, the cost is reduced by modification, the compatibility with other resin materials is solved, the modified polycaprolactone resin has good thermoplasticity and molding processability, and the modified polycaprolactone resin can be prepared into fibers, sheets and the like by adopting methods such as extrusion, blow molding and injection molding. The modified polycaprolactone resin has the advantages of biodegradability, drug permeability, biocompatibility, easily-obtained raw materials and the like, is soft, convenient to process and excellent in performance, and can be used as a tissue engineering scaffold material. The modified polycaprolactone resin is applied to medical materials, coating materials, packaging materials, aquatic and forestry materials and the like, such as surgical sutures, orthopedic splints, dental impressions and the like, coatings, inks, hot melt adhesives, non-woven fabric adhesives, shoe materials and the like, medium blown films, laminated materials and the like, and hand models, organic colorants, powder coatings and the like in other fields.
4, adding a degradation additive in a raw material modification production process in a ratio to change various modified resins into modified resin raw materials with controllable degradation, and adding the degradation additive in a degradation product production process to change various non-degradable plastic products into controllable completely degradable plastic products; the degradation additive is added into the resin in the production process of the plastic product, production equipment and procedures do not need to be changed, the degradation plastic product added with the degradation additive can be degraded when being exposed to sunlight, high temperature or external force, and the degradation time and speed are controllable; the degradation additive is nontoxic, can be contacted with edible objects, has strong processability, can be compatible with most materials, can control the degradability, can control the degradation time according to the required requirements, has 100 percent of environmental degradability, can be completely converted into water, carbon dioxide and organic matters, can not be harmful to the environment or soil, has high cost performance, and has lower cost compared with other degradation technologies; the degradation additive is mainly used in garbage disposal system, packaging industry, agriculture, compost and plastic manufacturing industry, and is suitable for manufacturing various degradation plastic products, such as agricultural mulching films, drip irrigation belts, shopping bags, vest bags, garbage bags, express bags, snack boxes and the like.
Drawings
FIG. 1 is a schematic structural view of the present invention;
in the figure: 1-surface layer, 2-middle layer, 3-inner layer, 4-surface resin layer, 5-surface additive layer, 6-middle resin layer, 7-middle additive layer, 8-inner resin layer and 9-inner additive layer.
Detailed Description
A bio-based electronic microwave oven heating packaging bag comprises a surface layer 1, a middle layer 2 and an inner layer 3;
the surface layer 1 comprises a surface layer resin layer 4 and a surface layer additive layer 5, the surface layer additive layer 5 is positioned below the surface layer resin layer 4, the surface layer resin layer 4 is oxygen-containing resin controllable degradation (YZSZ) resin, and the surface layer additive layer 5 is PBAT bio-based controllable degradation (PBZJ) additive;
the middle layer 2 comprises a middle layer resin layer 6 and a middle layer additive layer 7, the middle layer additive layer 7 is positioned below the middle layer resin layer 6, the middle layer resin layer 6 is modified bio-based polyester bonding (SHQ-GTIE) resin, and the middle layer additive layer 7 is PVA bio-based controlled degradation (PVZJ) additive;
the inner layer 3 comprises an inner resin layer 8 and an inner additive layer 9, the inner additive layer 9 is positioned below the inner resin layer 8, the inner resin layer 8 is modified polycaprolactone (SHQ-MCL) resin, and the inner additive layer 9 is an oxidative biological controlled degradation (YHZJ) additive.
The thickness percentage of the surface layer 1 is 20%, the thickness percentage of the middle layer 2 is 60%, and the thickness percentage of the inner layer 3 is 20%.
The thickness percentage of the surface layer resin layer 4 is 85%, and the thickness percentage of the surface layer additive layer 5 is 15%.
The thickness percentage of the middle resin layer 6 is 90%, and the thickness percentage of the middle additive layer 7 is 10%.
The inner resin layer 8 had a thickness percentage of 95% and the inner additive layer 9 had a thickness percentage of 5%.
The PBAT bio-based controllable degradation (PBZJ) additive, the PVA bio-based controllable degradation (PVZJ) additive and the oxidative bio-controllable degradation (YHZJ) additive are all as follows: cobalt dithiocarbamate.
The technical scheme adopts a binary process forming technology, which means that a forming process is added on the basis of unitary process forming (formula process), the unitary formula process only occupies 50% of technical content in the production process of a product, and the basic technical guarantee of the product can be perfected by the binary forming process, mainly embodying the thinning and thickening of the product, thinning and reinforcing, effectively reducing the cost and improving the market share.
The binary process forming technology comprises the following steps: a unitary formula process and a binary forming process.
The unitary formula process comprises the following steps:
1, a formula process of an oxygen-containing polyolefin controllable degradation material;
2, oxidizing the biological controllable degradation material formula process;
3PVA biological-based controllable degradation material formula process;
4PBAT bio-based controllable degradation material formula process;
5, a triple controllable degradation technology formula process;
6 fourfold controllable degradation technology formula process;
7 quintuple controllable degradation technology formula process;
8, a formula process of a sextuple controllable degradation technology;
9 three-layer water-retention type controllable degradation technology formula process.
The binary forming process comprises the following steps:
1, vacuum sizing forming process;
2, an intelligent weighing system forming process;
3, controlling materials between layers to intelligently control a forming process;
4, intelligently controlling a thickness forming process;
5 intelligently controlling the width forming process;
6, intelligent deviation rectifying and forming process;
7, a two-bubble forming process;
8, forming by a three-bubble method;
9, forming by a four-bubble method;
10 automatic rolling and forming process of intelligent manipulator.
The principle is as follows:
the bio-based controllable fully degradable plastics can be classified into starch, polyester and other types according to raw materials;
the starch is a natural high molecular material with rich sources and low price, the natural starch exists in a small particle state with a crystal structure inside, and the molecular structure of the natural starch has two types of straight chain and branched chain. The morphology and size of the starch granules and the ratio of amylose to amylopectin content vary from plant species to plant species. The grain size of the starch grains is 15-100 mu m. Amylose glucose is a chain compound having alpha-D-1, 4 glycosidic bonds and having a relative molecular mass of (20-200) x104. The connection mode of each glucose unit in the amylopectin is that besides alpha-D-1, 4 glycosidic bonds, alpha-D-1, 6 glycosidic bonds exist, and the relative molecular mass is (100-6. The properties of starch are related to the relative molecular mass of the starch, the length of the amylopectin, and the ratio of amylose to amylopectin. The high amylose starch is more suitable for the preparation of plastics and the resulting products have better mechanical properties. Natural starch has hydrogen bonds among molecules, has poor solubility, is hydrophilic but not easily soluble in water, and has a strong polar crystalline property. Because of the strong hydrogen bonding between macromolecules of natural starch, the natural starch is difficult to directly process and form. In order to improve the processing property, the method is generally realized by opening hydrogen bonds among starch chains to ensure that the starch loses crystallization. The operation method comprises two methods, one is heating starch solution with water content more than 90%, and the starch granule content is 60-70%oSwelling begins between C and reaches 90 DEG CoC, the starch particles begin to crack, and hydrogen bonds among high molecular chains are opened to generate gelatinization; and the other is heating in a closed state, plasticating and extruding the starch with the water content of less than 28 percent.
Polylactic acid (PLA), also known as polylactide, belongs to the family of polyesters, and has the structural formula (-O-CHCH 3-CO-) n.
The two most important polymerization methods of polylactic acid are the direct polymerization method and the ring-opening polymerization method. The direct polymerization process is typically a polycondensation reaction. The polylactic acid is obtained by heating and dehydration condensation reaction between lactic acid molecules by utilizing the activity of the lactic acid. The direct polymerization method has simple production process and low production cost, and does not need to separate reaction intermediates. However, polylactic acid has a low molecular weight, a wide molecular weight distribution, and poor properties. The lactide ring-opening polymerization method adopts a two-step method to produce polylactic acid. Firstly, lactic acid is subjected to dehydration cyclization to prepare lactide, and then refined lactide is subjected to ring-opening polymerization to prepare polylactic acid. The polylactic acid prepared by the ring-opening polymerization method has better physical and mechanical properties, and the production cost of the method is higher than that of a direct polymerization method.
The degradation of polylactic acid is divided into simple hydrolysis (acid-base catalysis) and enzymatic hydrolysis degradation. The main degradation mode of polylactic acid is bulk erosion. Hydrophobic polymers become low relative molecular weight, water soluble molecules and monomers by hydrolysis of labile bonds (C-O bonds) in the backbone and then are further degraded by enzymes into water and carbon dioxide. The degradation of polylactic acid is firstly the hydrolysis of the amorphous regions and secondly the crystalline regions. The hydrolysis reaction is accelerated by the presence of carboxyl groups. The polylactic acid has autocatalysis inside, and the internal degradation speed is higher than that of the surface. At the beginning of the degradation, the hydrolysis of the ester bonds in the matrix is isotropic. During the degradation process, the terminal carboxyl groups play a catalytic role in hydrolysis. As the degradation proceeds, the amount of terminal carboxyl groups increases and the degradation rate increases.
Although the embodiments of the present invention have been described in detail, the description is only a preferred embodiment of the present invention, and should not be considered as limiting the scope of the invention, and all equivalent changes and modifications made within the scope of the present invention should be covered by the claims of the present invention.

Claims (6)

1. The utility model provides a biology base electron microwave oven heating wrapping bag which characterized in that:
comprises a surface layer, a middle layer and an inner layer;
the surface layer comprises a surface resin layer and a surface additive layer, the surface additive layer is positioned below the surface resin layer, the surface resin layer is oxygen-containing resin controllable degradation (YZSZ) resin, and the surface additive layer is a PBAT bio-based controllable degradation (PBZJ) additive;
the middle layer comprises a middle layer resin layer and a middle layer additive layer, the middle layer additive layer is positioned below the middle layer resin layer, the middle layer resin layer is modified bio-based polyester bonding (SHQ-GTIE) resin, and the middle layer additive layer is PVA bio-based controllable degradation (PVZJ) additive;
the inner layer comprises an inner resin layer and an inner additive layer, the inner additive layer is positioned below the inner resin layer, the inner resin layer is modified polycaprolactone (SHQ-MCL) resin, and the inner additive layer is an oxidative biological controlled degradation (YHZJ) additive.
2. The bio-based electronic microwave oven heating packaging bag of claim 1, wherein: the thickness percentage of the surface layer is 20%, the thickness percentage of the middle layer is 60%, and the thickness percentage of the inner layer is 20%.
3. The bio-based electronic microwave oven heating packaging bag of claim 1, wherein: the thickness percentage of the surface resin layer is 85 percent, and the thickness percentage of the surface additive layer is 15 percent.
4. The bio-based electronic microwave oven heating packaging bag of claim 1, wherein: the thickness percentage of the middle layer resin layer is 90%, and the thickness percentage of the middle layer additive layer is 10%.
5. The bio-based electronic microwave oven heating packaging bag of claim 1, wherein: the thickness percentage of the inner resin layer is 95%, and the thickness percentage of the inner additive layer is 5%.
6. The bio-based electronic microwave oven heating packaging bag of claim 1, wherein: the PBAT bio-based controllable degradation (PBZJ) additive, the PVA bio-based controllable degradation (PVZJ) additive and the oxidative bio-controllable degradation (YHZJ) additive are all as follows: cobalt dithiocarbamate.
CN201910475722.5A 2019-06-03 2019-06-03 Bio-based electronic microwave oven heating packaging bag Withdrawn CN110614820A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910475722.5A CN110614820A (en) 2019-06-03 2019-06-03 Bio-based electronic microwave oven heating packaging bag

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910475722.5A CN110614820A (en) 2019-06-03 2019-06-03 Bio-based electronic microwave oven heating packaging bag

Publications (1)

Publication Number Publication Date
CN110614820A true CN110614820A (en) 2019-12-27

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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Application publication date: 20191227