CN110611014B - Cs (volatile organic Compounds)3Cu2I5Ultraviolet detector and film preparation method thereof - Google Patents
Cs (volatile organic Compounds)3Cu2I5Ultraviolet detector and film preparation method thereof Download PDFInfo
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- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000012855 volatile organic compound Substances 0.000 title claims description 5
- 238000004528 spin coating Methods 0.000 claims abstract description 22
- 239000002243 precursor Substances 0.000 claims abstract description 21
- 239000011521 glass Substances 0.000 claims abstract description 18
- 239000012296 anti-solvent Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 10
- 238000000137 annealing Methods 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims abstract description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Substances CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 23
- 239000000243 solution Substances 0.000 claims description 21
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 20
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- KXKVLQRXCPHEJC-UHFFFAOYSA-N methyl acetate Chemical compound COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000003599 detergent Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000009210 therapy by ultrasound Methods 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 abstract description 2
- 239000010949 copper Substances 0.000 description 26
- 239000010408 film Substances 0.000 description 26
- 239000010409 thin film Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 7
- 229910052736 halogen Inorganic materials 0.000 description 5
- 238000006862 quantum yield reaction Methods 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 4
- 231100000053 low toxicity Toxicity 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 238000002189 fluorescence spectrum Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004020 luminiscence type Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- AQOUTLFYXBBFQD-UHFFFAOYSA-N [Cs].[Cu].[I] Chemical compound [Cs].[Cu].[I] AQOUTLFYXBBFQD-UHFFFAOYSA-N 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 238000000089 atomic force micrograph Methods 0.000 description 1
- 238000004630 atomic force microscopy Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 1
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Abstract
The invention discloses a Cs3Cu2I5The ultraviolet detector and the film preparation method comprise the step of adopting a differential spin coating method to coat Cs3Cu2I5Coating the precursor solution on ITO glass, and dropwise adding an anti-solvent within the last 5 seconds of spin coating; the differential speed is firstly slow and then fast. The film preparation technology has the advantages of short annealing time, low annealing temperature, uniform and compact film, high transmittance and high fluorescence quantum efficiency which reaches 76.1 percent and is stable in the air, and the luminous efficiency is still maintained at 76 percent after the film is stored in the air for 2 months.
Description
Technical Field
The invention belongs to the technical field of lead-free perovskite thin films, particularly relates to morphology control and a preparation method of a blue-light lead-free perovskite thin film, and particularly relates to a Cs3Cu2I5A method for preparing a film.
Background
Lead-halogen perovskite is widely applied to the fields of solar cells, LED illumination, laser, photoelectric detection and the like due to the excellent photoelectric property of lead-halogen perovskite, and is considered to be a material with excellent prospect. Firstly, in the aspect of luminescence, most of the green light thin film materials with higher and stable luminescence efficiency in the pre-halogen perovskite are researched, and the blue light luminescence efficiency of the lead-halogen perovskite thin film materials is not high, so that the research on the blue light thin film materials is not much; secondly, the lead-halogen perovskite is unstable in air and is easy to decompose; finally, and most critically, lead-halo perovskites contain lead atoms that are harmful to both the environment and humans, thereby limiting their practical application. In recent years, more and more researchers have generated great interest in lead-free perovskites, for example, there are reports on adopting Bi, Cu, Sb and the like to replace Pb atoms, wherein the toxicity of transition metal Cu is the lowest, and cesium copper iodine has an ultra-wide forbidden bandwidth of-3.8 eV as a novel non-toxic perovskite material, has strong response to deep ultraviolet light, and is relatively stable in air. Therefore, the research on the cesium copper iodine-based deep ultraviolet detector has important research value. Thus becoming the best material for replacing Pb. Therefore, the preparation of the high-efficiency and high-stability low-toxicity blue light film has a great promotion effect on the preparation of blue light LEDs and blue light lasers.
Disclosure of Invention
In order to solve the problems, the invention provides a method for preparing full-lead-free smooth and stable Cs by low-toxicity green anti-solvent assisted crystallization3Cu2I5The film prepared by the method is more uniform and compact, and the fluorescence quantum efficiency is higher and stable.
The technical scheme adopted by the invention is as follows:
cs (volatile organic Compounds)3Cu2I5The preparation method of the film adopts a differential spin coating method to coat Cs3Cu2I5Coating the precursor solution on ITO glass, and dropwise adding an anti-solvent within the last 5 seconds of spin coating; the differential speed is firstly slow and then fast.
Preferably, said Cs3Cu2I5The preparation method of the precursor solution is to dissolve CsI and CuI in a mixed solvent of DMF and DMSO.
Preferably, the dissolving mode is heating and stirring at 50-70 ℃ for 0.5-1.2 h.
Preferably, the mass-to-volume ratio of CsI, CuI, DMF and DMSO is 2g:1g:3-3.5ml:0.85-1.0 ml.
Preferably, the ITO glass is sequentially treated with detergent, deionized water, acetone, alcohol and isopropanol through ultrasonic treatment and UV ozone treatment.
Preferably, the ultrasonic time is 25-35min respectively; the UV ozone treatment time is 25-35 min.
Preferably, the differential speed spin coating is specifically:
1) mixing the Cs3Cu2I5Dripping precursor solution at the central position of the ITO glass;
2) in the center of the ITO glass, Cs is slowly spin-coated at the rotating speed of 800-3Cu2I5Precursor solutionLiquid for 10-20 s;
3) at the center of the ITO glass, the rotation speed of 3000 plus 5000r/min, Cs is quickly spin-coated3Cu2I5Precursor solution for 20-40 s;
4) 3) quickly dripping methyl acetate in the center of the ITO glass within the last 5s or 5s of spin coating; for the mixed solution, the total vapor pressure of the solution is equal to the sum of the vapor pressures of the individual partial solvents, and the total boiling point is lower than the lowest boiling solvent in the mixed solution. Therefore, the introduction of a solution having a high vapor pressure and a low boiling point as an anti-solvent helps accelerate the evaporation of DMF and DMSO in the perovskite precursor solution to accelerate the crystallization of perovskite and form a uniform and dense perovskite thin film. Compared with the common anti-solvent such as toluene, chlorobenzene, isopropanol and the like, the low-toxicity methyl acetate solution has higher vapor pressure (28.8kPa) and lower boiling point (56.9 ℃), so that the uniform and compact total lead-free Cs can be effectively prepared by dropwise adding methyl acetate as the anti-solvent in the spin coating3Cu2I5A perovskite thin film.
5) Heating the ITO glass prepared in the step 4) at the temperature of 50-70 ℃ for 0.5-1.5h, and cooling to obtain Cs3Cu2I5A film.
Preferably, said Cs3Cu2I5The volume ratio of the precursor solution to the methyl acetate is 2-3: 5.
The deep ultraviolet photoelectric detector of the film prepared based on the method.
The invention has the beneficial effects that:
1. the differential step spin coating method is adopted during spin coating, wherein the low-speed spin coating can enable the precursor solution to be flatly spread on the substrate according to a certain thickness, and the relatively high speed in the second stage is favorable for uniformly flatly spreading the film on the substrate and is favorable for evaporating the solvent in the solution;
2. methyl acetate is dripped into the last 5s of the spin coating to be used as an anti-solvent for accelerating the evaporation of perovskite precursor solution solvents dimethyl formamide (DMF) and dimethyl sulfoxide (DMSO);
3. the method has the advantages of short required annealing time, low annealing temperature, uniform and compact film and high transmittance;
4. the film prepared by the invention has high fluorescence quantum efficiency which reaches 76.1 percent and is stable in the air, and the luminous efficiency is still maintained at 76 percent after the film is stored in the air for 2 months.
5. The invention adopts an anti-solvent auxiliary crystallization method to prepare the full-lead-free low-toxicity green perovskite thin film and the deep ultraviolet photoelectric detector.
Drawings
FIG. 1 shows an embodiment of the present invention Cs3Cu2I5Scanning electron microscope pictures of the surface and the cross section of the film;
FIG. 2 shows an embodiment of the present invention Cs3Cu2I5Mapping pictures on the surface of the film;
FIG. 3 shows an embodiment of the present invention Cs3Cu2I5Film EDS pictures;
FIG. 4 shows an embodiment of the present invention Cs3Cu2I5Atomic force microscopy pictures of the thin film;
FIG. 5 shows an embodiment of the present invention Cs3Cu2I5An X-ray diffraction pattern of the film;
FIG. 6 shows an embodiment of the present invention Cs3Cu2I5A fluorescence spectrum and an absorption spectrum of the film;
FIG. 7 shows an embodiment of the present invention Cs3Cu2I5A fluorescence quantum yield map of the thin film;
FIG. 8 shows an embodiment of the present invention Cs3Cu2I5Fluorescence quantum yield stability plots for thin films (samples stored in air).
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1
This embodiment provides a method for producing Cs3Cu2I5The preparation method of the film comprises the following specific steps:
1) and mixing CsI: 469mg, CuI: 229mg of the precursor solution was dissolved in a mixed solvent of DMF and DMSO, wherein the DMF was 800. mu.L and the DMSO was 200. mu.L, and the precursor solution was completely dissolved by heating and stirring at 60 ℃ for 1 hour;
2) respectively ultrasonically cleaning ITO glass by using detergent, deionized water, acetone, alcohol and isopropanol for 30 minutes, and then treating by using UV ozone for 30 minutes for later use;
3) taking 60 mu L of precursor completely dissolved by a liquid transfer gun, dropping the precursor liquid at the center of the ITO glass, starting spin coating after the precursor liquid is completely spread, wherein the spin coating adopts step spin coating, the spin coating speed of the first stage is 1000 rpm, the spin coating time is 15 seconds, the spin coating speed of the second stage is 4000 rpm, the spin coating time is 30 seconds, in addition, 100 mu L of methyl acetate is quickly dropped at the center of the ITO as an anti-solvent for auxiliary crystallization in the last 5 seconds of the second stage, finally, the film is placed on a heating table at 60 ℃ for heating for 1 hour, after the heating is finished, the sample with the ultra-smooth film is cooled to room temperature and taken down, and the ultra-smooth Cs can be obtained3Cu2I5A film.
The prepared films were characterized as follows: FIG. 1(a) is an SEM topography of the surface of the film, the particle size is uniform and dense; FIG. 1(b) is a cross-sectional view of a thin film having a thickness of about 350 nm. FIG. 2 is a graph showing that the elements Cs, Cu and I are uniformly distributed on the surface of the film. FIG. 3EDS pictures, Cs, Cu, I are distributed on the surface of the film in a ratio close to 3:2: 5. FIG. 4 is an AFM image of a thin film that is uniform and dense with a root mean square roughness of 17.5 nm. FIG. 5 is an XRD pattern of the film, and the diffraction peak positions are matched with the PDF card No.45-0077, which proves that the film is Cs3Cu2I5A material. FIG. 6 is a UV-VIS absorption and fluorescence spectrum of a thin film having an absorption peak at 290nm and a fluorescence spectrum peak at 445 nm. FIG. 7 is a PLQY spectrum of a thin film with a fluorescence quantum yield of 76.1%. FIG. 8 shows the result of the quantum yield stability test of the fluorescence of the thin film, the sample is stored in the air and tested for 2 months at irregular intervals, and the quantum yield of the thin film is almost kept unchanged.
Finally, it is noted that the above-mentioned preferred embodiments illustrate rather than limit the invention, and that, although the invention has been described in detail with reference to the above-mentioned preferred embodiments, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the scope of the invention as defined by the appended claims.
Claims (4)
1. Cs (volatile organic Compounds)3Cu2I5The preparation method of the film is characterized by comprising the following steps: applying differential spin coating method to coat Cs3Cu2I5Coating the precursor solution on ITO glass, and dropwise adding an anti-solvent within the last 5 seconds of spin coating; the differential speed is firstly slow and then fast; the antisolvent is selected from the group consisting of3Cu2I5Methyl acetate with the volume ratio of the precursor solution being 5:3-2 to form a uniform and compact film, and annealing the spin-coated ITO glass at 50-60 ℃ for 0.5-1 h;
the Cs3Cu2I5The preparation method of the precursor solution comprises the steps of dissolving CsI and CuI in a mixed solution of DMF and DMSO;
the dissolving mode is heating and stirring for 0.5-1.2h at 50-70 ℃;
the mass-volume ratio of the CsI to the CuI to the DMF to the DMSO is 2g to 1g to 3-3.5ml to 0.85-1.0 ml;
the differential speed spin coating comprises the following specific steps:
1) mixing the Cs3Cu2I5Dripping precursor solution at the central position of the ITO glass;
2) in the center of the ITO glass, Cs is slowly spin-coated at the rotating speed of 800-3Cu2I5Precursor solution for 10-20 s;
3) at the center of the ITO glass, the rotation speed of 3000 plus 5000r/min, Cs is quickly spin-coated3Cu2I5Precursor solution for 20-40 s;
4) quickly dripping methyl acetate in the center of the ITO glass within the last 5 seconds of the quick spin coating in the step 3) to obtain a mixed solution;
for the mixed solution, the total vapor pressure of the mixed solution is equal to the sum of the vapor pressures of all the component solvents in the mixed solution, and the total boiling point is lower than the solvent with the lowest boiling point in the mixed solution;
5) heating the ITO glass prepared in the step 4) at 50-60 ℃ for 0.5-1h, and cooling to obtain Cs3Cu2I5A film.
2. The Cs of claim 13Cu2I5The preparation method of the film is characterized by comprising the following steps: and (3) carrying out ultrasonic treatment on the ITO glass by using a detergent, deionized water, acetone, alcohol and isopropanol in sequence and carrying out UV ozone treatment.
3. The Cs of claim 23Cu2I5The preparation method of the film is characterized by comprising the following steps: the ultrasonic time is 25-35 min; the UV ozone treatment time is 25-35 min.
4. Cs (volatile organic Compounds)3Cu2I5A film prepared by the method of any one of claims 1 to 3, wherein: the film is used for a deep ultraviolet photodetector.
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| CN111721744B (en) * | 2020-01-19 | 2022-06-07 | 中国科学院上海微系统与信息技术研究所 | Preparation method of fluorescent film sensor |
| CN111293218B (en) * | 2020-02-28 | 2022-11-08 | 重庆大学 | Resistive random access memory based on cesium copper iodoperovskite thin film and preparation method thereof |
| CN111592232A (en) * | 2020-05-28 | 2020-08-28 | 重庆师范大学 | One-dimensional lead-free cesium copper iodine perovskite yellow light film and preparation method thereof |
| CN112048764B (en) * | 2020-08-17 | 2021-12-07 | 南京航空航天大学 | Zero-dimensional Cs3Cu2I5Perovskite scintillation crystal and application thereof |
| CN112820825A (en) * | 2021-01-13 | 2021-05-18 | 福州大学 | Preparation method of artificial synapse device based on lead-free perovskite |
| CN113013328B (en) * | 2021-02-09 | 2022-08-26 | 凯里学院 | Cesium-copper-iodine-calcium-titanium ore resistive random access memory with excellent resistance performance and preparation method thereof |
| CN113054067B (en) * | 2021-03-15 | 2022-09-02 | 南京邮电大学 | Perovskite light emitting diode and method for smoothly orienting perovskite thin film thereof |
| CN114592239B (en) * | 2022-03-04 | 2023-03-31 | 广州大学 | Method for improving performance of deep ultraviolet photoelectric detector |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108269918A (en) * | 2016-12-31 | 2018-07-10 | 中国科学院上海硅酸盐研究所 | Porous perovskite thin film, carbon pastes and the solar cell based on carbon electrode |
| CN109860403A (en) * | 2019-04-10 | 2019-06-07 | 西南石油大学 | Obtain post-processing method and its application of big crystal grain high quality perovskite thin film |
| CN109950407A (en) * | 2019-04-01 | 2019-06-28 | 广州新视界光电科技有限公司 | A kind of perovskite thin film and preparation method thereof |
| CN110164998A (en) * | 2019-04-11 | 2019-08-23 | 北京宏泰创新科技有限公司 | A kind of full-inorganic calcium titanium ore bed and its preparation method and application |
| CN110165000A (en) * | 2019-07-10 | 2019-08-23 | 合肥工业大学 | A kind of deep ultraviolet light electric explorer and preparation method thereof based on the unleaded perovskite caesium copper iodine microcrystalline film in broad stopband |
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| CN108649121B (en) * | 2018-05-11 | 2021-07-16 | 南京理工大学 | Method for preparing perovskite film by dynamic spin coating |
| CN108726583B (en) * | 2018-07-17 | 2020-05-19 | 中山大学 | Stable lead-free low-band-gap all-inorganic perovskite A2PdX6Nanocrystalline and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108269918A (en) * | 2016-12-31 | 2018-07-10 | 中国科学院上海硅酸盐研究所 | Porous perovskite thin film, carbon pastes and the solar cell based on carbon electrode |
| CN109950407A (en) * | 2019-04-01 | 2019-06-28 | 广州新视界光电科技有限公司 | A kind of perovskite thin film and preparation method thereof |
| CN109860403A (en) * | 2019-04-10 | 2019-06-07 | 西南石油大学 | Obtain post-processing method and its application of big crystal grain high quality perovskite thin film |
| CN110164998A (en) * | 2019-04-11 | 2019-08-23 | 北京宏泰创新科技有限公司 | A kind of full-inorganic calcium titanium ore bed and its preparation method and application |
| CN110165000A (en) * | 2019-07-10 | 2019-08-23 | 合肥工业大学 | A kind of deep ultraviolet light electric explorer and preparation method thereof based on the unleaded perovskite caesium copper iodine microcrystalline film in broad stopband |
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