CN110592729B - Continuous production electrolysis device for fibers - Google Patents
Continuous production electrolysis device for fibers Download PDFInfo
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- CN110592729B CN110592729B CN201911005624.1A CN201911005624A CN110592729B CN 110592729 B CN110592729 B CN 110592729B CN 201911005624 A CN201911005624 A CN 201911005624A CN 110592729 B CN110592729 B CN 110592729B
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- 239000000835 fiber Substances 0.000 title claims abstract description 58
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 35
- 238000010924 continuous production Methods 0.000 title claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 230000005611 electricity Effects 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 230000001502 supplementing effect Effects 0.000 claims abstract description 7
- 239000012528 membrane Substances 0.000 claims description 8
- 239000003792 electrolyte Substances 0.000 claims description 5
- 239000012535 impurity Substances 0.000 abstract description 12
- -1 hydroxide ions Chemical class 0.000 abstract description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 26
- 229920002451 polyvinyl alcohol Polymers 0.000 description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 239000000047 product Substances 0.000 description 20
- 238000006136 alcoholysis reaction Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- 206010052428 Wound Diseases 0.000 description 10
- 208000027418 Wounds and injury Diseases 0.000 description 10
- 239000003513 alkali Substances 0.000 description 8
- 230000015271 coagulation Effects 0.000 description 8
- 238000005345 coagulation Methods 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 7
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 239000001632 sodium acetate Substances 0.000 description 7
- 235000017281 sodium acetate Nutrition 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000010446 mirabilite Substances 0.000 description 6
- 229920002521 macromolecule Polymers 0.000 description 5
- 229920002689 polyvinyl acetate Polymers 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 210000000416 exudates and transudate Anatomy 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000035876 healing Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000000474 nursing effect Effects 0.000 description 2
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910021515 thallium hydroxide Inorganic materials 0.000 description 2
- QGYXCSSUHCHXHB-UHFFFAOYSA-M thallium(i) hydroxide Chemical compound [OH-].[Tl+] QGYXCSSUHCHXHB-UHFFFAOYSA-M 0.000 description 2
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 206010014418 Electrolyte imbalance Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- CWQSNJSRIUPVNR-UHFFFAOYSA-M [OH-].[Fr+] Chemical compound [OH-].[Fr+] CWQSNJSRIUPVNR-UHFFFAOYSA-M 0.000 description 1
- ARVNHJBMBBFPCP-UHFFFAOYSA-L [OH-].[OH-].[Ra+2] Chemical compound [OH-].[OH-].[Ra+2] ARVNHJBMBBFPCP-UHFFFAOYSA-L 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 239000007785 strong electrolyte Substances 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/04—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
- D01F11/06—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/34—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated alcohols, acetals or ketals as the major constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/50—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyalcohols, polyacetals or polyketals
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention discloses a continuous production electrolysis device for fibers, which comprises: an electrode ring with positive electricity on the inner side and negative electricity on the outer side and allowing fibers to pass through, a driving fan arranged beside the electrode ring and allowing fibers to pass through and drive to form water circulation, exhaust ports arranged on two sides of the upper end of the electrolytic cell, water supplementing ports arranged on the upper end of the electrolytic cell, and electrolytic product liquid draining ports arranged on two sides of the lower end of the electrolytic cell; the water circulation direction is opposite to the movement direction of the fiber; the invention can discharge the electrolytic product in time, reduce the impurity, facilitate the continuous production; the structure can ensure that the fiber only contacts hydroxide ions converged at the positive electrode, further improve the purity and reduce impurities.
Description
Technical Field
The invention relates to the field of fiber production, in particular to a continuous production electrolysis device for fibers.
Background
Polyvinyl alcohol (PVA) is a water-soluble polymer, and is obtained by alcoholysis of polyvinyl acetate, each repeating unit contains a hydroxyl group, and a large number of hydrogen bonds are contained in molecules and among molecules, so that the PVA molecule has high crystallinity, chemical stability, thermal stability and other performances. The average molecular weight of the polyvinyl alcohol fiber is 60000-250000, the thermal decomposition temperature is 200-220 ℃, and the melting point is 225-230 ℃.
As shown in figure 1, the existing scheme adopts PVA as raw material and mirabilite as coagulation bath; however, such a process has the following drawbacks:
1, the purity of the PVA fiber is not high, and the impurity is more;
2, the coagulation bath needs to use mirabilite, and the problem brought by mirabilite is that: the polyvinyl alcohol fiber preparation links in Chinese patent 201210416178.5 and Chinese patent 200610032535.2 adopt mirabilite solution with a certain concentration to be used as coagulation bath for spinning. In both patents, although the residual weight ratio of mirabilite is made to be less than 0.1% by the process, na2 so4.10h2o remained on the polyvinyl alcohol fiber is a strong electrolyte, and if such fiber is applied to the wound surface of the nursing human body, the water/electrolyte imbalance of the wound surface is caused, and the use risk is increased.
3, Byproducts such as sodium acetate and the like are generated in the process: alcoholysis of polyvinyl acetate can be carried out under acidic or basic conditions. The alkaline condition process has absolute advantage of economic benefit, so that the prior polyvinyl alcohol production mostly adopts sodium hydroxide and potassium hydroxide for alcoholysis. The alkaline alcoholysis has two alcoholysis processes, namely a high alkaline process and a low alkaline process in the PVA production process. The high-alkali method has the advantages of high alcoholysis speed, high production capacity, more side reactions, more sodium acetate content in PVA products, lower purity of PVA and high ash content; the low-alkali method has the outstanding advantages of low sodium hydroxide consumption, less side reaction, correspondingly less sodium acetate byproduct, low ash content and low alcoholysis speed due to low alkali mole ratio. The polyvinyl alcohol prepared by the high-alkali method or the low-alkali method can generate a certain amount of sodium acetate, and the existence of the sodium acetate has potential risks for wounds, because the exudate components of the wounds are mostly water, the water and the sodium acetate generate acetic acid and sodium hydroxide which are easy to volatilize, and the sodium hydroxide is taken as a strong alkali to cause certain harm. In addition, researches show that the wound surface of the human body is beneficial to healing in a slightly acidic environment, and the sodium hydroxide changes the alkalinity of the wound surface which is nursed by the polyvinyl alcohol fiber, so that the wound surface healing is not facilitated, and a pH value environment which is suitable for bacteria is generated, thereby increasing the infection risk. Ash is composed of fine particles which contain or adhere to many substances harmful to the human body, such as heavy metals.
4, Hydroxyl-OH is a polar group, can form a hydrogen bond with water of wound exudates, and has good adsorptivity to water molecules; acetate acetoxy-OCOCH 3 is an ester group that does not absorb water. It can be seen that for medical dressings, -OH properties are much greater than-OCOCH 3, which requires a very high degree of alcoholysis. When PVA alcoholysis degree is high, the volume of side groups-H and-OH is small, and the side groups can enter crystallization points without causing stress, so that hydroxyl groups in PVA macromolecules are mutually associated in a hydrogen bond mode, macromolecules are orderly arranged, water molecules are difficult to enter the PVA macromolecules, solvation is difficult, water solubility is poor, and performance is stable. When the PVA alcoholysis degree is low, the association of hydrogen bonds is further weakened due to the increase of-OCOCH 3, and the directionality of PVA macromolecules is destroyed, so that water molecules easily enter between the PVA macromolecules, and the dissolution effect of water on the PVA is improved. For a dressing for nursing a wound surface, the risk of leaving foreign matters on the wound surface is increased due to the existence of water in exudates.
The company develops a preparation method of PVA fibers, and patent numbers: PCT/CN2019/110559; PVAc (polyvinyl acetate) is adopted to replace PVA, and then an electrolytic coagulation bath is used in a matching way, so that mirabilite is not required to be used in the coagulation bath, PVA is obtained by alcoholysis of PVAc in an electrolytic cell, and the produced PVA fiber has high purity and few impurities.
In continuous production, electrolyte accumulation in the electrolytic cell can affect electrolytic reaction in the electrolytic cell or residual electrolyte pollutes fibers so that the fibers carry impurities, and the electrolytic cell is required to continuously produce the fibers.
Disclosure of Invention
In order to solve the defects in the prior art, the invention aims to provide a continuous production electrolysis device for fibers, which can timely discharge electrolysis products, reduce impurities and is convenient for continuous production; the structure can ensure that the fiber only contacts hydroxide ions converged at the positive electrode, further improve the purity and reduce impurities.
In order to achieve the above object, the present invention adopts the following technical scheme:
a continuous production electrolysis apparatus for fibers comprising: an electrode ring with positive electricity on the inner side and negative electricity on the outer side and allowing fibers to pass through, a driving fan arranged beside the electrode ring and allowing fibers to pass through and drive to form water circulation, exhaust ports arranged on two sides of the upper end of the electrolytic cell, water supplementing ports arranged on the upper end of the electrolytic cell, and electrolytic product liquid draining ports arranged on two sides of the lower end of the electrolytic cell; the water circulation direction is opposite to the movement direction of the fiber.
In the continuous production electrolysis device for the fiber, a proton exchange membrane is arranged between the electrode ring and the electrolysis cell.
The continuous production electrolysis device for the fiber is characterized in that the electrode ring is formed by a plurality of groups of electrodes, each group of electrodes is externally connected with a direct current power supply, the inner side of the electrode ring is a positive electrode, and the outer side of the electrode ring is a negative electrode.
The continuous production electrolysis device for the fiber has the advantages that the positive electrode and the negative electrode are connected through the insulating bracket.
In the continuous production electrolysis device for the fibers, a guide slope is arranged between the lower end of the electrode ring and the liquid outlet of the electrolysis product.
In the continuous production electrolysis device for the fibers, the lower end of the electrode ring is provided with the convex plate; the upper end of the convex plate is a plane plate, and the two sides of the convex plate are sloping plates.
The continuous production electrolysis device for the fibers has the slope plate with the inclination angle of 45 degrees.
In the continuous production electrolysis device for the fibers, the outer frame of the driving fan is overlapped with the inner ring of the electrode ring.
The invention has the advantages that:
According to the invention, water can be timely supplemented and the electrolysis product can be timely discharged through the cooperation of the water circulation, the water supplementing port and the electrolysis product liquid discharging port, when the blades of the driving fan rotate, the driven water flow direction is opposite to the fiber trend, so that the fiber is prevented from contacting the electrolysis product, the impurity is reduced, and the continuous production is convenient;
the design of the proton exchange membrane further isolates the electrolysis products and prevents the electrolysis products from entering the fiber channel;
the structural design of the invention can ensure that the fiber only contacts hydroxide ions converged at the positive electrode, further improve the purity and reduce the impurities.
Drawings
FIG. 1 is a cross-sectional view of one embodiment of the present invention;
FIG. 2 is a schematic view of one embodiment of a water cycle of the present invention;
Fig. 3 is a schematic view of an embodiment of the drive fan of the present invention.
Meaning of reference numerals in the drawings:
1 electrode ring, 2 driving fan, 201 sheets, 3 exhaust port, 4 water supplementing port, 5 electrolyte product liquid discharging port, 6 proton exchange membrane, 7 convex plates, 701 plane plates and 702 slope plates.
Detailed Description
The invention is described in detail below with reference to the drawings and the specific embodiments.
The spinning step of the preparation method of PVA fiber needs to inject spinning solution into a spinneret plate under the conditions of 0.05-0.6MPa and the temperature of 45-55 ℃, the sprayed fiber enters a direct current electrolytic cell for coagulation bath, the direct current voltage of the direct current electrolytic cell is 1.23V-200V, and a series of reactions of alcoholysis, electrolytic catalysis alcoholysis and alcohol lever are carried out; the solution formulation in the electrolytic coagulation bath comprises: alkali, alcohol, water; the solution formulation in the electrolytic coagulation bath comprises: alkali, alcohol, water; the base includes: lithium hydroxide, sodium hydroxide, potassium hydroxide, rubidium hydroxide, cesium hydroxide, francium hydroxide, calcium hydroxide, strontium hydroxide, barium hydroxide, radium hydroxide, thallium hydroxide, silver diammine hydroxide, choline, thallium hydroxide, NR 4 OH. The alcohol includes: R-CH 2OH(CH3CH2 OH),
As shown in fig. 1, in order to allow continuous production of fibers, an electrolytic cell is designed comprising: an electrode ring 1 with positive electricity on the inner side and negative electricity on the outer side and allowing fibers to pass through, a driving fan 2 which is arranged beside the electrode ring 1 and allows fibers to pass through and drive to form water circulation, an exhaust port 3 which is arranged at two sides of the upper end of the electrolytic cell, a water supplementing port 4 which is arranged at the upper end of the electrolytic cell, and an electrolytic product liquid draining port 5 which is arranged at two sides of the lower end of the electrolytic cell; the water circulation direction is opposite to the movement direction of the fiber. The outer frame of the driving fan 2 is overlapped with the inner ring of the electrode ring 1, so that the design ensures that the fiber can smoothly pass through the channel between the electrode ring 1 and the driving fan 2, the fiber passes through the middle of the electrode ring 1 and the blades 201 of the driving fan 2, and when the blades 201 rotate, the driven water flow direction is opposite to the fiber trend; avoiding the fiber contacting the electrolysis product, reducing the impurity and facilitating the continuous production.
A proton exchange membrane 6 is arranged between the electrode ring 1 and the electrolytic cell. As shown in fig. 2, the water circulation is driven by the sheet 201, the water firstly passes through the positive electrode area inside the electrode ring 1, then passes through the proton exchange membrane 6 connected with the electrode ring 1 and the edge of the electrolytic cell, enters the negative electrode area, and then flows into the area of the sheet 201 from the negative electrode area for the next circulation. The design of the proton exchange membrane 6 further isolates the electrolysis products from entering the fibre channels.
As one preferable mode, the electrode ring 1 is formed by a plurality of groups of electrodes, each group of electrodes is externally connected with a direct current power supply, the inner side of the electrode ring 1 is a positive electrode, and the outer side of the electrode ring is a negative electrode; the positive electrode and the negative electrode are connected by an insulating bracket.
A guide slope is arranged between the lower end of the electrode ring 1 and the electrolyte outlet 5; as shown in fig. 1, the lower end of the electrode ring 1 is provided with a convex plate 7; the upper end of the convex plate 7 is a plane plate 701, and two sides are sloping plates 702. Preferably, the slope plate 702 is inclined at 45 degrees. The relationship of the electrolysis products due to gravity, such as: sodium sulfate, sodium acetate, sulfuric acid, sodium hydroxide, etc., all having a specific gravity greater than that of water, slide along 45 deg. downward sloping plates 702 on both sides toward the electrolysis product drain 5 at the bottom of the cell.
According to the invention, water can be timely supplemented and the electrolysis product can be timely discharged through the cooperation of the water circulation, the water supplementing port 4 and the electrolysis product liquid discharging port 5, when the blades 201 of the driving fan 2 rotate, the driving water flow direction is opposite to the trend of the fibers, the fibers are prevented from contacting the electrolysis product, the impurities are reduced, and the continuous production is convenient; the design of the proton exchange membrane 6 further isolates the electrolysis products and prevents the electrolysis products from entering the fiber channel; the structural design of the invention can ensure that the fiber only contacts hydroxide ions converged at the positive electrode, further improve the purity and reduce the impurities.
The foregoing has shown and described the basic principles, principal features and advantages of the invention. It will be appreciated by persons skilled in the art that the above embodiments are not intended to limit the invention in any way, and that all technical solutions obtained by means of equivalent substitutions or equivalent transformations fall within the scope of the invention.
Claims (4)
1. A continuous production electrolysis apparatus for fibers, comprising: an electrode ring with positive electricity on the inner side and negative electricity on the outer side and allowing fibers to pass through, a driving fan arranged beside the electrode ring and allowing fibers to pass through and drive to form water circulation, exhaust ports arranged on two sides of the upper end of the electrolytic cell, water supplementing ports arranged on the upper end of the electrolytic cell, and electrolytic product liquid draining ports arranged on two sides of the lower end of the electrolytic cell; the water circulation direction is opposite to the movement direction of the fiber; a guide slope is arranged between the lower end of the electrode ring and the electrolyte outlet; a convex plate is arranged at the lower end of the electrode ring; the upper end of the convex plate is a plane plate, and two sides of the convex plate are sloping plates; the inclination angle of the slope plate is 45 degrees; the electrode ring is formed by a plurality of groups of electrodes, each group of electrodes is externally connected with a direct current power supply, the inner side of the electrode ring is a positive electrode, and the outer side of the electrode ring is a negative electrode.
2. A continuous production electrolysis apparatus for fibers according to claim 1, wherein a proton exchange membrane is disposed between the electrode ring and the electrolysis cell.
3. The continuous production electrolysis apparatus for fibers according to claim 1, wherein the positive electrode and the negative electrode are connected by an insulating bracket.
4. A continuous production electrolysis apparatus for fibers according to claim 1, wherein the outer frame of the drive fan coincides with the inner ring of the electrode ring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911005624.1A CN110592729B (en) | 2019-10-22 | 2019-10-22 | Continuous production electrolysis device for fibers |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911005624.1A CN110592729B (en) | 2019-10-22 | 2019-10-22 | Continuous production electrolysis device for fibers |
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| Publication Number | Publication Date |
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| CN110592729A CN110592729A (en) | 2019-12-20 |
| CN110592729B true CN110592729B (en) | 2024-05-17 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339520A (en) * | 2001-09-29 | 2002-03-13 | 清华大学 | Method for preparing polymer gradient material by using electric field |
| CN103787468A (en) * | 2014-01-26 | 2014-05-14 | 成都玉龙化工有限公司 | Electrolysis wastewater treatment device, PVB (Polyvinyl Butyral) production wastewater treatment device and PVB production wastewater treatment process |
| CN104088022A (en) * | 2014-07-02 | 2014-10-08 | 北京化工大学 | Combination electrostatic spinning device and method for preparing multi-stage ultrafine fiber |
| KR20180023305A (en) * | 2016-08-25 | 2018-03-07 | 한국기계연구원 | Manufacturing method of nanocomposite fiber and nanocomposite fiber manufactured therefrom |
| CN211142250U (en) * | 2019-10-22 | 2020-07-31 | 振德医疗用品股份有限公司 | Continuous production electrolytic device for fibers |
-
2019
- 2019-10-22 CN CN201911005624.1A patent/CN110592729B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339520A (en) * | 2001-09-29 | 2002-03-13 | 清华大学 | Method for preparing polymer gradient material by using electric field |
| CN103787468A (en) * | 2014-01-26 | 2014-05-14 | 成都玉龙化工有限公司 | Electrolysis wastewater treatment device, PVB (Polyvinyl Butyral) production wastewater treatment device and PVB production wastewater treatment process |
| CN104088022A (en) * | 2014-07-02 | 2014-10-08 | 北京化工大学 | Combination electrostatic spinning device and method for preparing multi-stage ultrafine fiber |
| KR20180023305A (en) * | 2016-08-25 | 2018-03-07 | 한국기계연구원 | Manufacturing method of nanocomposite fiber and nanocomposite fiber manufactured therefrom |
| CN211142250U (en) * | 2019-10-22 | 2020-07-31 | 振德医疗用品股份有限公司 | Continuous production electrolytic device for fibers |
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| CN110592729A (en) | 2019-12-20 |
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