CN110564458A - plant new energy fuel formula - Google Patents

plant new energy fuel formula Download PDF

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Publication number
CN110564458A
CN110564458A CN201910868043.4A CN201910868043A CN110564458A CN 110564458 A CN110564458 A CN 110564458A CN 201910868043 A CN201910868043 A CN 201910868043A CN 110564458 A CN110564458 A CN 110564458A
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China
Prior art keywords
new energy
stirring
emulsifier
plant new
energy fuel
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CN201910868043.4A
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Chinese (zh)
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靳长龙
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Individual
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/18Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a plant new energy fuel formula, and relates to the technical field of new energy fuels, wherein the formula comprises the following components in percentage by mass: 54.8% of industrial vegetable oil, 45% of liquid wax and 0.2% of emulsifier, wherein the emulsifier comprises the following components in percentage by mass: 5% absolute ethanol, 1% methyl tert-butyl ether, 62% glycerol and 32% isopropanol; the preparation method of the plant new energy dye comprises the steps of mixing and stirring industrial plant oil and liquid wax for 30min, then adding an emulsifier, continuously stirring for 1h, and standing for 2h after stirring; the plant new energy fuel provided by the invention has a flash point higher than 60 ℃, does not belong to dangerous chemicals, is safe and reliable, has high heat value, low consumption, sufficient combustion, no peculiar smell, no black smoke and no carbon deposition during combustion, has exhaust emission higher than that of petroleum liquid by more than 80 percent after combustion, and belongs to genuine green energy; the plant new energy fuel provided by the invention has wide raw material sources and belongs to renewable resources.

Description

plant new energy fuel formula
Technical Field
The invention relates to the technical field of new energy fuels, in particular to a plant new energy fuel formula.
Background
among the fuels used in the catering industry are coal, natural gas, liquefied gas and alcohol-based fuels that are currently in common use. Coal has a long history of use, and has excellent performance in transportation, storage and safety, but the emission of sulfur dioxide, nitrogen oxides and particulate matters generated by coal combustion has a serious influence on air quality. Natural gas contains 95% methane, 3% ethane, 0.5% propane and a trace amount of carbon dioxide, methane being its most major component. Methane is colorless and tasteless, inflammable and high in heat value, combustion products mainly comprise carbon dioxide and water, a small amount of carbon monoxide is contained, and the heat value is high, so that the methane is an ideal coal alternative fuel. However, the boiling point of methane is-162 ℃, the methane is in a gas state at normal temperature and normal pressure, and the flash point of the methane is-188 ℃, so the largest technical difficulty of the methane as a raw material is storage and transportation. The liquefied gas mainly contains propane, propylene, butane and butylene, and is mainly obtained by liquefying petroleum and natural gas. Liquefied petroleum gas is volatile, and can explode when meeting open fire after reaching a certain concentration in the air. The alcohol-based fuel is prepared by mixing alcohols as main raw materials through a chemical formula. The main components of the alcohol-based fuel comprise methanol, ethanol and the like, and the alcohol-based fuel is liquid at normal temperature. The alcohol-based fuel has low calorific value, is easy to explode in the transportation process, and the main components in the alcohol-based fuel are extracted from coal and natural gas, so that the extraction process is complex, the cost is high, and the use of the alcohol-based fuel is limited.
In conclusion, because coal does not have environmental protection conditions, the nation has mandated banning; natural gas and liquefied gas belong to gas fuels, leakage is not easy to find, potential safety hazards exist, and explosion accidents are easy to cause; the alcohol-based fuel has low calorific value and large consumption, and has great potential safety hazard in the aspects of transportation and storage. Therefore, it is very important to provide a new energy source that can solve the above technical problems.
disclosure of Invention
The invention aims to provide a plant new energy fuel formula, and the technical problems are solved.
a plant new energy fuel formula comprises the following components in percentage by mass:
54.8 percent of industrial vegetable oil
Liquid wax 45%
0.2 percent of emulsifier.
as a preferable scheme, the emulsifier comprises the following components in percentage by mass:
As a preferable scheme, the preparation method of the emulsifier comprises the following steps:
Step one, mixing absolute ethyl alcohol and methyl tert-butyl ether, stirring uniformly, and standing for later use;
And step two, adding glycerol and isopropanol into the uniformly stirred solution obtained in the step one, continuously stirring, and standing for reaction for 1h after sufficient stirring to obtain the emulsifier.
As a preferable scheme, the preparation method of the plant new energy fuel comprises the following steps:
Step one, mixing and stirring industrial vegetable oil and liquid wax for 30min for later use;
and step two, adding an emulsifier into the mixed solution prepared in the step one, continuously stirring for 1h, and standing for 2h after stirring to obtain the plant new energy fuel.
Compared with the prior art, the invention has the following beneficial effects:
1. The plant new energy fuel provided by the invention has a flash point higher than 60 ℃, does not belong to dangerous chemicals, is safe and reliable, and is safe to use.
2. the plant new energy fuel provided by the invention has high calorific value and low consumption, and is matched with a pneumatic atomization system to ensure that the combustion is more sufficient and the energy is saved.
3. The plant new energy fuel provided by the invention has neutral pH value, no peculiar smell, no black smoke and no carbon deposition during combustion, and the exhaust emission of the combusted waste gas is more than 80% higher than that of petroleum liquid, thereby belonging to a genuine green energy.
4. the plant new energy fuel provided by the invention has wide raw material sources and belongs to renewable resources.
Detailed Description
the technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
mixing and stirring 5kg of absolute ethyl alcohol and 1kg of methyl tert-butyl ether fully, then adding 62kg of glycerol and 32kg of isopropanol, continuously stirring uniformly, and standing for reacting for 1h to obtain an emulsifier;
Mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.2kg of emulsifier, continuously stirring for 1h, standing for 2h after stirring to obtain the plant new energy fuel, and measuring to obtain the flash point of the finished fuel of 64.3 ℃.
Example two
Mixing 10kg of absolute ethyl alcohol and 2kg of methyl tert-butyl ether, stirring fully, adding 124kg of glycerol and 64kg of isopropanol, stirring uniformly, and standing for reaction for 1h to obtain an emulsifier;
Mixing and stirring 109.6kg of industrial vegetable oil and 90kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.4kg of emulsifier, continuously stirring for 1h, standing for 2h after stirring to obtain the plant new energy fuel, and measuring the flash point of the finished fuel to be 64.3 ℃.
EXAMPLE III
Mixing and stirring 5kg of absolute ethyl alcohol and 1kg of methyl tert-butyl ether fully, then adding 31kg of glycerol and 32kg of isopropanol, continuously stirring uniformly, and standing for reacting for 1h to obtain an emulsifier;
Mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; and adding 0.2kg of emulsifier, continuously stirring for 1h, and standing for 2h after stirring to obtain the plant new energy fuel with the glycerol dosage reduced by half as a comparative example I.
Example four
Mixing 5kg of absolute ethyl alcohol and 1kg of methyl tert-butyl ether, stirring fully, adding 32kg of isopropanol, continuously stirring uniformly, and standing for reacting for 1h to obtain an emulsifier;
Mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.2kg of emulsifier, continuously stirring for 1h, standing for 2h after stirring to obtain the plant new energy fuel, namely obtaining the plant new energy fuel without glycerol as a comparative example II.
EXAMPLE five
Mixing and stirring 5kg of absolute ethyl alcohol and 1kg of methyl tert-butyl ether fully, then adding 62kg of glycerol and 16kg of isopropanol, continuously stirring uniformly, and standing for reacting for 1h to obtain an emulsifier;
Mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.2kg of emulsifier, continuing stirring for 1h, standing for 2h after stirring to obtain the plant new energy fuel, namely obtaining the plant new energy fuel with half of the dosage of the isopropanol as a third comparative example.
EXAMPLE six
mixing 5kg of absolute ethyl alcohol and 1kg of methyl tert-butyl ether, stirring fully, adding 62kg of glycerol, stirring uniformly, and standing for reaction for 1h to obtain an emulsifier;
mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.2kg of emulsifier, continuing stirring for 1h, and standing for 2h after stirring to obtain the plant new energy fuel, namely obtaining the plant new energy fuel without isopropanol as a comparative example IV.
EXAMPLE seven
2.5kg of absolute ethyl alcohol and 1kg of methyl tert-butyl ether are taken, mixed and stirred fully, 62kg of glycerol and 32kg of isopropanol are added, the mixture is stirred uniformly, and the mixture is kept stand and reacted for 1 hour to obtain an emulsifier;
mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.2kg of emulsifier, continuously stirring for 1h, standing for 2h after stirring to obtain the plant new energy fuel, namely obtaining the plant new energy fuel with half of the consumption of the absolute ethyl alcohol, and taking the plant new energy fuel as a fifth comparative example.
example eight
Taking 1kg of methyl tert-butyl ether, 62kg of glycerol and 32kg of isopropanol, uniformly stirring, and standing for reaction for 1h to obtain an emulsifier;
Mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.2kg of emulsifier, continuously stirring for 1h, standing for 2h after stirring to obtain the plant new energy fuel, namely obtaining the plant new energy fuel without absolute ethyl alcohol, which is taken as a comparative example six.
example nine
Mixing and stirring 5kg of absolute ethyl alcohol and 0.5kg of methyl tert-butyl ether fully, then adding 62kg of glycerol and 32kg of isopropanol, continuously stirring uniformly, and standing for reacting for 1h to obtain an emulsifier;
Mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.2kg of emulsifier, continuing stirring for 1h, and standing for 2h after stirring to obtain the plant new energy fuel, namely obtaining the plant new energy fuel with half of the amount of methyl tert-butyl ether, wherein the comparative example seven is shown.
Example ten
Taking 5kg of absolute ethyl alcohol, 62kg of glycerol and 32kg of isopropanol, uniformly stirring, and standing for reaction for 1 hour to obtain an emulsifier;
Mixing and stirring 54.8kg of industrial vegetable oil and 45kg of liquid wax for 30min to prepare a mixed solution of the industrial vegetable oil and the liquid wax; adding 0.2kg of emulsifier, continuing stirring for 1h, and standing for 2h after stirring to obtain the plant new energy fuel, namely obtaining the plant new energy fuel without absolute ethyl alcohol, which is used as a comparative example eight.
The combustion heat of the fuels prepared in example one, comparative example two, comparative example three, comparative example four, comparative example five, comparative example six, comparative example seven and comparative example eight was measured, and it was observed whether the fuels prepared in example one, comparative example two, comparative example three, comparative example four, comparative example five, comparative example six, comparative example seven and comparative example eight had harmful gas emissions, odor, black smoke and carbon deposition during the combustion process. The results of the observations of example one, comparative example two, comparative example three, comparative example four, comparative example five, comparative example six, comparative example seven and comparative example eight were compared with coal, petroleum natural gas and alcohol based fuel, and the results are shown in the following table. As can be seen from the following table, the combustion heat in the first example is higher than that of liquefied petroleum gas, coal and alcohol-based fuel, and no odor, black smoke and carbon deposit are generated during the combustion process. Therefore, compared with the three fuels, the fuel provided by the invention is more environment-friendly. Compared with the first comparative example, the second comparative example, the third comparative example, the fourth comparative example, the fifth comparative example, the sixth comparative example, the seventh comparative example, the eighth comparative example and the first example, the calorific value is reduced, and therefore, the formula of the emulsifier provided by the invention is an optimal formula.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (4)

1. The plant new energy fuel formula is characterized by comprising the following components in percentage by mass:
54.8 percent of industrial vegetable oil
liquid wax 45%
0.2 percent of emulsifier.
2. the plant new energy fuel formulation according to claim 1, wherein the emulsifier comprises the following components in percentage by mass:
3. The plant new energy fuel formulation according to claim 2, wherein the preparation method of the emulsifier comprises the following steps:
step one, mixing absolute ethyl alcohol and methyl tert-butyl ether, stirring uniformly, and standing for later use;
And step two, adding glycerol and isopropanol into the uniformly stirred solution obtained in the step one, continuously stirring, and standing for reaction for 1h after sufficient stirring to obtain the emulsifier.
4. The plant new energy fuel formulation according to claim 1, wherein the plant new energy fuel preparation method comprises the following steps:
Step one, mixing and stirring industrial vegetable oil and liquid wax for 30min for later use;
and step two, adding an emulsifier into the mixed solution prepared in the step one, continuously stirring for 1h, and standing for 2h after stirring to obtain the plant new energy fuel.
CN201910868043.4A 2019-09-12 2019-09-12 plant new energy fuel formula Pending CN110564458A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690446A (en) * 2020-06-24 2020-09-22 张兰华 Novel open-fire non-combustible energy fuel formula

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075979A (en) * 1993-03-25 1993-09-08 夏斌 Synthetic fuel oil
CN1912074A (en) * 2006-08-29 2007-02-14 贺永德 Methanol vapour diesel oil and its preparation method
CN106520224A (en) * 2016-11-30 2017-03-22 广西东奇能源技术有限公司 Biofuel composition
CN110218591A (en) * 2019-06-20 2019-09-10 桂林千升元环保能源有限公司 A kind of low oil consumption F- T synthesis crude liquid ceryl alcohol ether fuel of automobile

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075979A (en) * 1993-03-25 1993-09-08 夏斌 Synthetic fuel oil
CN1912074A (en) * 2006-08-29 2007-02-14 贺永德 Methanol vapour diesel oil and its preparation method
CN106520224A (en) * 2016-11-30 2017-03-22 广西东奇能源技术有限公司 Biofuel composition
CN110218591A (en) * 2019-06-20 2019-09-10 桂林千升元环保能源有限公司 A kind of low oil consumption F- T synthesis crude liquid ceryl alcohol ether fuel of automobile

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
FEREIDOON SHAHIDI主编: "《贝雷油脂化学与工艺学》", 31 July 2016 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690446A (en) * 2020-06-24 2020-09-22 张兰华 Novel open-fire non-combustible energy fuel formula

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