CN110564208A - Low-temperature-resistant water-based high-temperature baking curing ink, and preparation method and application thereof - Google Patents
Low-temperature-resistant water-based high-temperature baking curing ink, and preparation method and application thereof Download PDFInfo
- Publication number
- CN110564208A CN110564208A CN201910785643.4A CN201910785643A CN110564208A CN 110564208 A CN110564208 A CN 110564208A CN 201910785643 A CN201910785643 A CN 201910785643A CN 110564208 A CN110564208 A CN 110564208A
- Authority
- CN
- China
- Prior art keywords
- parts
- temperature
- water
- low
- curing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04M—TELEPHONIC COMMUNICATION
- H04M1/00—Substation equipment, e.g. for use by subscribers
- H04M1/02—Constructional features of telephone sets
- H04M1/0202—Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets
- H04M1/026—Details of the structure or mounting of specific components
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
- C03C2217/478—Silica
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/48—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
- C03C2217/485—Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Geochemistry & Mineralogy (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Signal Processing (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
the invention discloses low-temperature-resistant water-based high-temperature baking curing ink, a preparation method and application thereof, wherein the low-temperature-resistant water-based high-temperature baking curing ink comprises the following components: 40-60 parts of water-based saturated polyester resin, 5-10 parts of high imino methylated amino resin, 5-10 parts of blocked isocyanate, 3-5 parts of film forming additive, 5-10 parts of wetting dispersant, 10-15 parts of pigment, 20-30 parts of superfine quartz powder, 2-5 parts of silane coupling agent and a proper amount of water. The glass base material has excellent adhesive force to a glass base material and the adhesive force after being boiled in water at 100 ℃ for 1h, has excellent low-temperature resistance, good light shading property, high surface tension, small VOC discharge amount and excellent construction performance, is particularly suitable for coating glass cover plates of electronic equipment such as mobile phones and the like, and meets the requirements of environmental protection and application.
Description
Technical Field
the invention relates to the technical field of ink, in particular to low-temperature-resistant water-based high-temperature baking curing ink, and a preparation method and application thereof.
Background
The printing ink for the mobile phone cover plate glass in the market at present is mainly a two-component solvent type thermosetting printing ink, a large amount of slow-drying solvents are used in the printing ink, in the high-temperature curing process of the printing ink, the discharge amount of VOC is large, the environmental pollution is serious, the ozone atmosphere is damaged, and meanwhile, the volatilization of the solvents causes great damage to the body health of staff. Along with the progress of society and the development of science and technology, people have stronger environmental awareness and higher requirements, environmental protection laws and regulations related to labor protection, safety, fire fighting and the like are improved day by day, and the price of the organic solvent is increased at present, so that the application of the two-component solvent type thermosetting ink is limited, and the ink with small VOC discharge, good adhesion to glass substrates and excellent low-temperature resistance is lacking at present.
Disclosure of Invention
the embodiment of the invention provides low-temperature-resistant aqueous high-temperature baking curing ink, a preparation method and application thereof, and solves the technical problems of large VOC (volatile organic compounds) emission amount, poor low-temperature resistance and the like of the existing ink. The technical scheme is as follows:
On the one hand, the low-temperature-resistant water-based high-temperature baking curing ink comprises the following components in parts by weight:
40-60 parts of water-based saturated polyester resin, 5-10 parts of high imino methylated amino resin, 5-10 parts of blocked isocyanate, 3-5 parts of film forming additive, 5-10 parts of wetting dispersant, 10-15 parts of pigment, 20-30 parts of superfine quartz powder, 2-5 parts of silane coupling agent and a proper amount of water.
Preferably, the aqueous saturated polyester resin is an aqueous silicone-modified saturated polyester resin.
Preferably, the fineness of the superfine quartz powder is less than or equal to 5 mu m.
Preferably, the silane coupling agent is an epoxy silane coupling agent.
in another aspect, a glass cover plate is provided, which includes a glass substrate and the low-temperature water-resistant high-temperature baking curing ink coated on the surface of the glass substrate, wherein the coating manner includes, but is not limited to, screen printing, air spraying, or the like.
In another aspect, an electronic device applying the glass cover plate is also provided.
On the other hand, the preparation method of the low-temperature-resistant aqueous high-temperature baking curing ink is also provided, and comprises the following steps:
weighing 40-60 parts of water-based saturated polyester resin, 5-10 parts of high imino methylated amino resin, 5-10 parts of enclosed isocyanate, 3-5 parts of film forming additive and 5-10 parts of wetting dispersant, uniformly dispersing, adding 10-15 parts of pigment and 20-30 parts of superfine quartz powder, dispersing, grinding, adding 2-5 parts of silane coupling agent and a proper amount of water, and uniformly dispersing.
Preferably, before adding the silane coupling agent and water, grinding to fineness of less than or equal to 5 μm.
The embodiment of the invention at least has the following beneficial effects:
the waterborne saturated polyester has good adhesion with glass and good toughness, and can improve the high and low temperature resistance of the coating; the high imino methylated amino resin and the blocked isocyanate are both used as curing agents, the high imino methylated amino resin has higher reaction activity, excellent resin compatibility and low VOC discharge, the crosslinking density and the reaction rate of a system can be improved, and the blocked isocyanate releases-NCO after being baked at high temperature, reacts with other active groups, can enhance the flexibility of a coating and improve the adhesive force of the coating with a glass substrate in an ultralow temperature environment; the superfine quartz powder has large specific surface area and more silicon hydroxyl groups on the surface, can be effectively combined with a silane coupling agent, reduces the curing shrinkage rate of the coating, and improves the water resistance and low temperature resistance of the coating. The paint has the advantages of excellent adhesion to glass substrates and 100 ℃ and 1h boiled water, excellent low-temperature resistance, light-shielding OD (optical density) value of more than 5, surface tension dyne value of more than 36, small VOC (volatile organic compound) emission, excellent construction performance and capability of meeting the requirements of environmental protection and application, and is particularly suitable for coating glass cover plates of electronic equipment such as mobile phones and the like.
Detailed Description
The embodiment of the invention provides low-temperature-resistant water-based high-temperature baking curing ink which comprises the following components in parts by weight: 40-60 parts of water-based saturated polyester resin, 5-10 parts of high imino methylated amino resin, 5-10 parts of blocked isocyanate, 3-5 parts of film forming additive, 5-10 parts of wetting dispersant, 10-15 parts of pigment, 20-30 parts of superfine quartz powder, 2-5 parts of silane coupling agent and a proper amount of water.
The waterborne saturated polyester resin has good adhesion with glass and good toughness, can improve the high and low temperature resistance of the coating, and is preferably waterborne organic silicon modified saturated polyester resin. The existing glass printing ink usually uses epoxy resin or acrylic resin, and the like, and the coating of the resin is relatively brittle and the adhesion with glass is obviously reduced under the ultralow temperature environment of-80 ℃ to-100 ℃.
The high imino methylated amino resin and the blocked isocyanate are both used as curing agents, and compared with other amino resins, the high imino methylated amino resin has higher reaction activity, excellent resin compatibility and low VOC discharge, and can improve the crosslinking density and the reaction rate of a system; the closed isocyanate releases-NCO after being baked at high temperature, reacts with other active groups, enhances the flexibility of the coating and improves the adhesive force between the coating and the glass substrate in an ultralow temperature environment.
The silane coupling agent is used as an adhesion promoter, preferably an epoxy silane coupling agent such as KH-560 and the like, can stably coexist with other components in a system at normal temperature, and participates in a system reaction after being baked at high temperature, so that the binding force between the coating and a glass substrate and between a film-forming substance in the coating and an inorganic substance is effectively improved.
The superfine quartz powder generally refers to quartz powder with the average particle size of less than 10 mu m, has large specific surface area and more silicon hydroxyl groups on the surface, can be effectively combined with a silane coupling agent, reduces the curing shrinkage rate of a coating, improves the water resistance and low temperature resistance of the coating, and has obviously better modification effect than common quartz powder and other inorganic fillers. Further, the inventors have experimentally found that the performance is more excellent when the fineness of the ultrafine quartz powder is 5 μm or less, for example, in a specific example, the average particle diameter thereof is 1.6 μm.
The components are matched according to the proportion, so that the VOC (volatile organic compound) emission of the printing ink is small, and the market environmental protection requirement is met. The paint has excellent adhesion to glass base materials and adhesion after being boiled in water at 100 ℃ for 1h, excellent low-temperature resistance, good light shielding property, high surface tension, small VOC discharge amount and good construction property, and is particularly suitable for coating glass cover plates of electronic equipment such as mobile phones and the like.
The present invention will be described in detail with reference to specific examples.
In the following examples and comparative examples, the aqueous saturated polyester resin was an aqueous silicone-modified saturated polyester resin available from cobalt commercial, Inc., Guangzhou under the designation ND-7732; the superfine quartz powder is selected from Silverbond 925 of Silybaceae, and has an average particle size of 1.6 μm; the high imino methylated amino resin is CYMEL327 of Zhan new company; the blocked isocyanate is F-70D of Wuhanshi Quanxing New Material science and technology Co., Ltd; the film-forming assistant is DPM (dipropylene glycol methyl ether), the pigment is carbon black, and the silane coupling agent is KH-560.
The ink formulations of examples 1 to 3 are shown in Table 1.
TABLE 1 (parts by weight)
Weighing water-based saturated polyester resin, high imino methylated amino resin, blocked isocyanate, a film forming aid and a wetting dispersant according to a formula shown in Table 1, dispersing for 20-30 min at a temperature of below 60 ℃ and at a dispersion speed of 500-800 r/min, sequentially adding pigment and superfine quartz powder, continuously dispersing for 10-20 min under the same condition, grinding the mixture by a three-roll mill until the fineness is below 5 mu m, adding a silane coupling agent and deionized water, and uniformly dispersing to obtain the low-temperature water-resistant high-temperature baking type curing ink.
The obtained ink can be coated on a glass substrate by adopting the following screen printing process:
The first layer is a 350-420 mesh screen plate, is subjected to 70-degree glue scraping, is screen-printed on a clean glass substrate, and is dried on the surface for 5min at the temperature of 150 ℃; and a second layer, a 300-350 mesh screen plate, 70-degree glue scraping, screen printing, baking at 150 ℃ for 30min for curing, and performing performance testing. In practical application, in order to prevent water from volatilizing in the printing construction process, causing drying of a screen plate and influencing continuous printing construction performance of the ink, a proper amount of cosolvent with the moisturizing effect, such as ethylene glycol or glycerol, can be added under the condition of meeting VOC (volatile organic compound) emission.
In addition to screen printing, air spraying, which can be applied to 3D substrates, and the like, may also be used, and an exemplary process is as follows: the first layer is added with deionized water accounting for 80-100% of the total weight of the ink, the deionized water is uniformly dispersed and sprayed on a clean 3D glass substrate, the thickness of the glass substrate is 8-12 mu m, the surface of the glass substrate is dried at 150 ℃ for 5min, the deionized water is added into the second layer according to the same proportion, the glass substrate is uniformly dispersed, the spraying thickness of the glass substrate is 8-12 mu m, the glass substrate is baked at 150 ℃ for 30min for curing, and then performance test is carried out.
For the convenience of analysis and comparison, the present example and the comparative example were coated by screen printing.
Comparative example 1
Based on example 1, with the difference that the ultrafine quartz powder is replaced by an equal amount of talc.
Comparative example 2
A commercially available solvent-based black high temperature bake curable ink was applied in the same manner as in example 1.
The test boards produced in the examples and comparative examples were tested by standard methods, wherein:
Adhesion force: GB 1720-1979;
VOC emission: GB/T23985-2009, unit is g/L;
Water resistance: GB/T1733 (method B), temperature 100 ℃, distilled water, time 60min, according to GB1720-1979 test coating adhesion after boiling;
Hiding power OD value: GB/T1726 (method B);
Dyne values: arcotesat dyne pen;
Low temperature resistance: the ink surfaces of the two test boards are adhered together by glue, one ends of the two test boards are mutually lapped to form a sample strip, and then the sample strip is placed into a drawing force tester with an ultra-low temperature box for testing. The test method is carried out according to GB/T13239-2006, the sample strip is placed in an environment of-90 ℃ for 10min before the test, then stretching is carried out at the same temperature, and the tensile strength when the ink is peeled from the glass is recorded, wherein the unit is N/mm2。
The test results are shown in table 2.
TABLE 2
From the above results, it can be seen that the inks of examples 1 to 3 have excellent adhesion to glass substrates, high hiding power, and an OD value of not less than 5; the waterproof performance is excellent, the appearance is not obviously abnormal when the paint is boiled for 60min at 100 ℃, the adhesive force is good, the surface tension is higher, the dyne value is more than or equal to 38, and the pasting of the post-processing procedure is facilitated. Particularly, the low temperature resistance is excellent, the VOC emission is low, and the market demand can be well met. Comparative example 1, talc powder is used to replace ultrafine quartz powder, the low temperature resistance of the coating is poor, the VOC emission of the commercially available solvent-based ink of comparative example 2 is high, and the comprehensive performance of the coating is obviously inferior to that of each example of the invention.
The above embodiments are illustrative of the present invention, but the present invention is not limited to the details of the above embodiments, and various equivalent substitutions or simple modifications within the technical spirit of the present invention by those skilled in the art should be included in the scope of the present invention.
Claims (8)
1. The low-temperature-resistant water-based high-temperature baking curing ink is characterized by comprising the following components in parts by weight:
40-60 parts of water-based saturated polyester resin, 5-10 parts of high imino methylated amino resin, 5-10 parts of blocked isocyanate, 3-5 parts of film forming additive, 5-10 parts of wetting dispersant, 10-15 parts of pigment, 20-30 parts of superfine quartz powder, 2-5 parts of silane coupling agent and a proper amount of water.
2. The low-temperature-resistant aqueous high-temperature baking curing ink according to claim 1, wherein the aqueous saturated polyester resin is an aqueous silicone-modified saturated polyester resin.
3. The low-temperature-resistant aqueous high-temperature baking curing ink as claimed in claim 1, wherein the fineness of the ultrafine quartz powder is less than or equal to 5 μm.
4. The low-temperature-resistant aqueous high-temperature baking curing ink according to claim 1, wherein the silane coupling agent is an epoxy silane coupling agent.
5. a glass cover plate, which is characterized by comprising a glass substrate and the low-temperature water-resistant high-temperature baking curing ink according to any one of claims 1 to 4 coated on the surface of the glass substrate.
6. an electronic device using the glass cover plate according to claim 5.
7. A preparation method of low-temperature-resistant water-based high-temperature baking curing ink is characterized by comprising the following steps:
weighing 40-60 parts of water-based saturated polyester resin, 5-10 parts of high imino methylated amino resin, 5-10 parts of enclosed isocyanate, 3-5 parts of film forming additive and 5-10 parts of wetting dispersant, uniformly dispersing, adding 10-15 parts of pigment and 20-30 parts of superfine quartz powder, dispersing, grinding, adding 2-5 parts of silane coupling agent and a proper amount of water, and uniformly dispersing.
8. The production method according to claim 7, wherein the grinding is performed to a fineness of 5 μm or less before the silane coupling agent and water are charged.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910785643.4A CN110564208A (en) | 2019-08-23 | 2019-08-23 | Low-temperature-resistant water-based high-temperature baking curing ink, and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910785643.4A CN110564208A (en) | 2019-08-23 | 2019-08-23 | Low-temperature-resistant water-based high-temperature baking curing ink, and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110564208A true CN110564208A (en) | 2019-12-13 |
Family
ID=68776104
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910785643.4A Pending CN110564208A (en) | 2019-08-23 | 2019-08-23 | Low-temperature-resistant water-based high-temperature baking curing ink, and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110564208A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113880448A (en) * | 2021-09-14 | 2022-01-04 | 湖南松井新材料股份有限公司 | Spraying method and application of water-based ink |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009161710A (en) * | 2008-01-10 | 2009-07-23 | Dic Corp | Surface printing mat ink composition for laminated film |
| CN104263069A (en) * | 2014-08-29 | 2015-01-07 | 湖南新力华纳米科技有限公司 | Water-based thermosetting glass printing ink and preparation method thereof |
| CN108944231A (en) * | 2017-05-19 | 2018-12-07 | 比亚迪股份有限公司 | The trailing and 3D ambetti of printing ink composition and 3D glass |
| CN109181408A (en) * | 2018-09-11 | 2019-01-11 | 江苏世泰实验器材有限公司 | One kind can marking glass slide ink and preparation method thereof |
-
2019
- 2019-08-23 CN CN201910785643.4A patent/CN110564208A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009161710A (en) * | 2008-01-10 | 2009-07-23 | Dic Corp | Surface printing mat ink composition for laminated film |
| CN104263069A (en) * | 2014-08-29 | 2015-01-07 | 湖南新力华纳米科技有限公司 | Water-based thermosetting glass printing ink and preparation method thereof |
| CN108944231A (en) * | 2017-05-19 | 2018-12-07 | 比亚迪股份有限公司 | The trailing and 3D ambetti of printing ink composition and 3D glass |
| CN109181408A (en) * | 2018-09-11 | 2019-01-11 | 江苏世泰实验器材有限公司 | One kind can marking glass slide ink and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 封晓花: "球粒石英砂及其综合利用研究", 《河北化工》 * |
| 辽宁省石油化学工业厅编: "《辽宁化工产品大全》", 31 December 1994 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113880448A (en) * | 2021-09-14 | 2022-01-04 | 湖南松井新材料股份有限公司 | Spraying method and application of water-based ink |
| CN113880448B (en) * | 2021-09-14 | 2023-07-28 | 湖南松井新材料股份有限公司 | Spraying method of water-based ink and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10827660B2 (en) | Conductive composition for low frequency EMI shielding | |
| TWI449762B (en) | Antistatic coating, method for manufacturing antistatic film and antistatic film obtained thereby | |
| DE112018002915B4 (en) | Resin composition for ink-jet printing and circuit board manufactured using the same and method of manufacturing the circuit board | |
| CN107418410A (en) | Low-VOC aqueous UV solidification single layer coatings composition, painting method and the substrate through its coating | |
| CN110564208A (en) | Low-temperature-resistant water-based high-temperature baking curing ink, and preparation method and application thereof | |
| JP2009263567A (en) | Coating material for forming antistatic hard coat film, antistatic hard coat film, plastic base material with antistatic hard coat film, and method for manufacturing plastic base material with antistatic hard coat film | |
| CN101696341A (en) | Ultraviolet cured vacuum spraying colored paint | |
| CN111944394B (en) | Handfeel light-variable UV (ultraviolet) curing coating and preparation method and application thereof | |
| CN105440894B (en) | For Metal surface anti-corrosion light solidifying paint composition | |
| CN108219578A (en) | A kind of inflatable toy halftone aqueous ink | |
| CN107053779B (en) | A kind of slim half overlay film television set metal backing | |
| CN104031496B (en) | A kind of electrostatic dura mater antirust paint and preparation method thereof | |
| CN110964419A (en) | High-solid-content solvent-free three-proofing paint and preparation method thereof | |
| JP5826694B2 (en) | Ink composition for painted steel sheet | |
| CN106243969A (en) | A kind of coating and preparation method thereof | |
| TW201800474A (en) | Photosensitive resin composition, film and circuit board using the same | |
| CN108517183A (en) | A kind of novel light curable conductive coating and preparation method thereof based on black phosphorus alkene | |
| CN102898940A (en) | Solvent-based coating for preventing black coffee pollution and production method thereof | |
| CN104152042A (en) | Surface insulation paint | |
| CN107011795B (en) | Application process of the silane system adhesive ingredients in solventless coatings | |
| CN114133861A (en) | Weather-proof and anti-icing composite insulator umbrella skirt sheath and preparation method and application thereof | |
| CN104974569A (en) | UV electrostatic-spraying flat finish coating varnish | |
| WO2022088149A1 (en) | Water-based ultra-thin intumescent fire-retardant paint, preparation method and application thereof | |
| CN110713784A (en) | Novel wear-resistant waterproof electronic material coating and preparation method thereof | |
| CN104017471B (en) | A kind of stainless steel PVD cured coating and production method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191213 |
|
| RJ01 | Rejection of invention patent application after publication |