CN110552217A - Chinlon color fixation spot preventing agent - Google Patents
Chinlon color fixation spot preventing agent Download PDFInfo
- Publication number
- CN110552217A CN110552217A CN201910844964.7A CN201910844964A CN110552217A CN 110552217 A CN110552217 A CN 110552217A CN 201910844964 A CN201910844964 A CN 201910844964A CN 110552217 A CN110552217 A CN 110552217A
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- CN
- China
- Prior art keywords
- chinlon
- stirring
- minutes
- preventing agent
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8209—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing amide groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The invention discloses a polyamide color fixing spot preventing agent which is prepared from the following raw materials in percentage by mass: 10-20% of surfactant, 1-5% of dispersant, 5-10% of solvent and 65-80% of deionized water. The preparation method comprises the following steps: adding 5-10% of solvent, and stirring; then adding 10-20% of surfactant, and keeping stirring for 20 minutes; adding 65-80% deionized water, and stirring for 30 minutes; finally, 1-5% of dispersing agent is added, and stirring is carried out for 20 minutes, so as to obtain colorless to yellow clear liquid. The chinlon color fixation stain inhibitor has the advantages of wide application range, no influence on color fixation effect, excellent effect, biodegradability, simple process, strong operability, low cost and wide market prospect.
Description
Technical Field
The invention relates to a printing and dyeing auxiliary agent, in particular to a chinlon color-fixing spot-preventing agent applied to dyeing post-treatment of chinlon, chinlon/spandex, chinlon and blended fabrics and yarns thereof.
Background
Chinlon fiber, also called polyamide fiber, has many excellent characteristics, but has poor wet fastness such as washing fastness, perspiration fastness and the like after being dyed by acid dye. After dyeing, the color fixing agent added with the sulfonic macromolecular compound is combined with the amide group on the fiber to form a net structure to coat the dye, so that the wet fastness such as washing fastness can be improved. However, in the color fixing process, color fixing spots are formed due to the reasons of over high total hardness of water, residues of weak cationic auxiliaries on a dyeing cloth surface, unstable pH value of a dye bath, mechanical high shear failure and the like, and can be attached to the surface of a fabric and the wall of a dye vat randomly in a large quantity. The color fixing spots are mixed with dyes, oligomers, color fixing agents, surfactants and other substances, so that the fabric is damaged difficultly. Therefore, the color fixing stain preventing agent is added in the post-treatment process of the chinlon and the nylon/ammonia color fixing agent to effectively prevent the generation of color fixing stains.
The prior solution provided aiming at the color fixing of nylon and brocade/ammonia fabrics can only solve the problem of preventing the color fixing on one aspect, can not completely avoid the color fixing on the other aspect and can influence the color fixing fastness of the fabrics, for example, a chelating dispersant can only solve the problem of high yield of the color fixing due to the total hardness of water, a naphthalenesulfonic acid formaldehyde condensate sodium salt is used, but the effect is poor, the color fixing on the fabrics is generated, the color fixing on the fabrics can be eliminated by washing with Na 2 CO 3 after color fixing, but the color fastness of the fabrics is reduced, in addition, an anti-coagulant HPD has the effect of preventing the color fixing spots, but can only solve the color fixing spots generated by a leveling agent and a color fixing agent, and can not comprehensively and effectively prevent all the color fixing spots.
Therefore, the development of a chinlon fixing stain preventing agent becomes a problem to be solved by the technical personnel in the field.
Disclosure of Invention
In order to solve the defects in the prior art, the invention provides the polyamide color fixing spot preventing agent which has the advantages of wide application range, no influence on color fixing effect, good color fixing spot preventing effect, biodegradability, simple process, strong operability and low cost.
The above object of the present invention is achieved by the following technical means: a chinlon fixation spot preventing agent is characterized in that: the composite material consists of the following raw materials in percentage by mass: 10-20% of surfactant, 1-5% of dispersant, 5-10% of solvent and 65-80% of deionized water.
Preferably, the surfactant is one of triphenylethylene phenol polyoxyethylene ether (20), fatty alcohol polyoxyethylene ether (9) sodium sulfonate and castor oil polyoxyethylene ether (60).
Preferably, the dispersant is maleic acid-acrylic acid copolymer sodium salt.
Preferably, the solvent is one of ethylene glycol monobutyl ether, ethylene glycol phenyl ether and diethylene glycol.
The invention relates to a preparation method of a chinlon fixation stain inhibitor, which comprises the following steps: adding 5-10% of solvent, and stirring; then adding 10-20% of surfactant, and keeping stirring for 20 minutes; adding 65-80% deionized water, and stirring for 30 minutes; finally, 1-5% of dispersing agent is added, and stirring is carried out for 20 minutes, so as to obtain colorless to yellow clear liquid.
Compared with the prior art, the invention has the advantages that: the chinlon color fixation stain inhibitor has the advantages of wide application range, no influence on color fixation effect, excellent effect, biodegradability, simple process, strong operability, low cost and wide market prospect.
Detailed Description
The present invention will be described in more detail with reference to examples.
Example 1: the chinlon color fixation spot preventing agent comprises the following raw materials in percentage by mass: 10% of surfactant, 5% of dispersant, 5% of solvent and 80% of deionized water. The surfactant is triphenylethylene phenol polyoxyethylene ether (20). The dispersant is maleic acid-acrylic acid copolymer sodium salt. The solvent is ethylene glycol monobutyl ether.
The preparation method comprises the following steps: firstly, adding 10% of solvent, and starting stirring; then adding 10% of surfactant, and keeping stirring for 20 minutes; adding 80% deionized water, and stirring for 30 minutes; finally, 5% dispersant was added and stirred for 20 minutes to give a colorless to yellow clear liquid.
Example 2: the chinlon color fixation spot preventing agent comprises the following raw materials in percentage by mass: 15% of surfactant, 5% of dispersant, 10% of solvent and 70% of deionized water. The surfactant is fatty alcohol-polyoxyethylene ether (9) sodium sulfonate. The dispersant is maleic acid-acrylic acid copolymer sodium salt. The solvent is ethylene glycol phenyl ether.
The preparation method comprises the following steps: firstly, adding 10% of solvent, and starting stirring; then adding 15% of surfactant, and keeping stirring for 20 minutes; adding 70% deionized water, and stirring for 30 minutes; finally, 5% dispersant was added and stirred for 20 minutes to give a colorless to yellow clear liquid.
Example 3: the chinlon color fixation spot preventing agent comprises the following raw materials in percentage by mass: 20% of surfactant, 5% of dispersant, 10% of solvent and 65% of deionized water. The surfactant is castor oil polyoxyethylene ether (60). The dispersant is maleic acid-acrylic acid copolymer sodium salt. The solvent is diethylene glycol.
The preparation method comprises the following steps: firstly, adding 10% of solvent, and starting stirring; then 20% of surfactant is added, and stirring is kept for 20 minutes; adding 65% deionized water, and stirring for 30 minutes; finally, 5% dispersant was added and stirred for 20 minutes to give a colorless to yellow clear liquid.
Example 4: the chinlon color fixation spot preventing agent comprises the following raw materials in percentage by mass: 18% of surfactant, 1% of dispersant, 5% of solvent and 76% of deionized water. The surfactant is triphenylethylene phenol polyoxyethylene ether (20). The dispersant is maleic acid-acrylic acid copolymer sodium salt. The solvent is ethylene glycol monobutyl ether.
The preparation method comprises the following steps: adding 5% of solvent, and starting stirring; then adding 18% of surfactant, and keeping stirring for 20 minutes; adding 16% deionized water, and stirring for 30 minutes; finally, 1% dispersant was added and stirred for 20 minutes to give a colorless to yellow clear liquid.
The application process of the invention comprises the following steps:
1) The additives were tested for their ability to prevent color staining in cationic, hard water, high shear environments.
Preparing hard water (500ppm) by using calcium chloride and magnesium chloride, taking 100ml of hard water, adding 2g of nylon color fixing agent and 1g of nylon soaping agent, taking 15ml of color fixing spot preventive solution, putting the color fixing spot preventive solution into a test tube, shaking the test tube up and down for 20 minutes, putting the test tube into a water bath kettle at the temperature of 80 ℃, stirring the test tube for 20 minutes at the stirring speed of 1800 plus materials and 2000r/min, observing the state of the solution in the bottle, and if the solution is still clear liquid, indicating that the effect of the color fixing spot preventive is ideal;
2) And (3) testing the influence of the auxiliary agent on the washing fastness and the color light of the fabric after fixation.
And fixing the color of the bright black, bright red and turquoise blue brocade/ammonia fabric, and adding a color fixing spot preventing agent into the color fixing solution to contrast the color fastness and the color light. The process comprises the following steps:
The foregoing detailed description is given by way of example only, and is provided to better enable one skilled in the art to understand the patent, and is not intended to limit the scope of the patent; any equivalent alterations or modifications made according to the spirit of the disclosure of this patent are intended to be included in the scope of this patent.
Claims (5)
1. A chinlon fixation spot preventing agent is characterized in that: the composite material consists of the following raw materials in percentage by mass: 10-20% of surfactant, 1-5% of dispersant, 5-10% of solvent and 65-80% of deionized water.
2. The chinlon fixing stain preventing agent as claimed in claim 1, wherein: the surfactant is one of triphenylethylene phenol polyoxyethylene ether (20), fatty alcohol polyoxyethylene ether (9) sodium sulfonate and castor oil polyoxyethylene ether (60).
3. The chinlon fixing stain preventing agent as claimed in claim 1, wherein: the dispersant is maleic acid-acrylic acid copolymer sodium salt.
4. The chinlon fixing stain preventing agent as claimed in claim 1, wherein: the solvent is one of ethylene glycol monobutyl ether, ethylene glycol phenyl ether and diethylene glycol.
5. A preparation method of a chinlon fixation spot preventing agent is characterized by comprising the following steps: the preparation method comprises the following steps: adding 5-10% of solvent, and stirring; then adding 10-20% of surfactant, and keeping stirring for 20 minutes; adding 65-80% deionized water, and stirring for 30 minutes; finally, 1-5% of dispersing agent is added, and stirring is carried out for 20 minutes, so as to obtain colorless to yellow clear liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910844964.7A CN110552217A (en) | 2019-09-07 | 2019-09-07 | Chinlon color fixation spot preventing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910844964.7A CN110552217A (en) | 2019-09-07 | 2019-09-07 | Chinlon color fixation spot preventing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110552217A true CN110552217A (en) | 2019-12-10 |
Family
ID=68739434
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910844964.7A Pending CN110552217A (en) | 2019-09-07 | 2019-09-07 | Chinlon color fixation spot preventing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110552217A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112941938A (en) * | 2020-07-20 | 2021-06-11 | 广东创新精细化工实业有限公司 | Chinlon dyeing anti-color-spot-fixing agent and application method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974855A (en) * | 2010-10-18 | 2011-02-16 | 南通曙光染织有限公司 | levelling agent used for environmentally friendly cotton and preparation method thereof |
-
2019
- 2019-09-07 CN CN201910844964.7A patent/CN110552217A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974855A (en) * | 2010-10-18 | 2011-02-16 | 南通曙光染织有限公司 | levelling agent used for environmentally friendly cotton and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 刘大越等: "氨纶弹力经编织物的染整工艺", 《针织工业》 * |
| 夏德慧: "锦氨经编织物的染整加工", 《印染》 * |
| 李炎洪: "尼龙织物喷射染色工艺", 《印染》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112941938A (en) * | 2020-07-20 | 2021-06-11 | 广东创新精细化工实业有限公司 | Chinlon dyeing anti-color-spot-fixing agent and application method thereof |
| CN112941938B (en) * | 2020-07-20 | 2021-09-14 | 广东创新精细化工实业有限公司 | Chinlon dyeing anti-color-spot-fixing agent and application method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191210 |
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| RJ01 | Rejection of invention patent application after publication |