CN110529668A - Cementitious composite pipe and preparation method thereof - Google Patents

Cementitious composite pipe and preparation method thereof Download PDF

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Publication number
CN110529668A
CN110529668A CN201910802279.8A CN201910802279A CN110529668A CN 110529668 A CN110529668 A CN 110529668A CN 201910802279 A CN201910802279 A CN 201910802279A CN 110529668 A CN110529668 A CN 110529668A
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China
Prior art keywords
parts
plastic tube
tube body
composite pipe
outer layer
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Application number
CN201910802279.8A
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Chinese (zh)
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CN110529668B (en
Inventor
王强
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Fuzhou Senbaide Electromechanical Technology Co Ltd
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Fuzhou Senbaide Electromechanical Technology Co Ltd
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Priority to CN201910802279.8A priority Critical patent/CN110529668B/en
Publication of CN110529668A publication Critical patent/CN110529668A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B19/00Machines or methods for applying the material to surfaces to form a permanent layer thereon
    • B28B19/0038Machines or methods for applying the material to surfaces to form a permanent layer thereon lining the outer wall of hollow objects, e.g. pipes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16Homopolymers or copolymers or vinylidene fluoride
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

The invention discloses a kind of cementitious composite pipes and preparation method thereof comprising cement outer layer and plastic tube body, the raw material of the cement outer layer include seawater resistant cement, slag micropowder, fine sand, adhesive and water;The plastic tube body is fiber composite pipe, its raw material includes Kynoar, acrylic resin, nitrile rubber, methyl vinyl phenyl silicon rubber, dibenzothiazyl disulfide, N, N- dicyclohexyl -2-[4-morpholinodithio sulfenamide, polystyrene, basalt fibre, fire retardant, curing agent and antioxidant.Cement outer layer and plastic tube body are not easy delamination in cementitious composite pipe of the invention, cement outer layer can be effectively prevented plastic tube body and be corroded, reduce abrasion, the intensity of plastic tube body is improved simultaneously, and plastic tube body has good corrosion resistance, inoxidizability, resistant of high or low temperature, it can be used for transporting petroleum, water, service life reaches 50-100.

Description

Cementitious composite pipe and preparation method thereof
Technical field
The invention belongs to composite pipe fields, and in particular to a kind of cementitious composite pipe and preparation method thereof.
Background technique
It is raw material that plastic tube, which is usually with synthetic resin, that is, polyester, stabilizer, lubricant, plasticizer is added etc., with The method of " modeling " forms in tuber through extrusion process.Due to it have light, corrosion-resistant, good appearance, without bad smell, Handling ease, it is easy for construction the features such as, be more and more widely used in construction projects.It is mainly used as building construction Tap water supply system piping, draining, exhaust and blowdown sanitary pipe, subsoil drain system, rain pipe and electric wire installation are matched The penetration pipe etc. applied.There are many plastic tube type, are divided into thermoplastic pipes and thermosetting plastics pipe two major classes.Belong to thermoplasticity Have polyvinyl chloride pipe, polyethylene pipe, PA tube, polyformaldehyde pipe etc.;Belonging to heat cured has phenola plastics pipe etc..
The major advantage of plastic tube is good corrosion resisting property, light weight, convenient formation, handling ease, the disadvantage is that intensity is lower, Poor heat resistance.However, especially in petrochemical industry, existing plastic tube is not able to satisfy mostly in certain particular surroundings Demand.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of cementitious composite pipe and preparation method thereof, lead to The outer layer that cement is coated on to plastic tube body is crossed, the cementitious composite pipe for meeting petrochemical industry requirement is obtained, service life reaches 50-100.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of cementitious composite pipe, including cement outer layer and plastic tube body, the raw material of the cement outer layer is by weight are as follows: anti-sea 140-160 parts of water cement, 290-300 parts of slag micropowder, 600-680 parts of fine sand, 80-100 parts of adhesive, 150-165 parts of water.
Further, the plastic tube body is fiber composite pipe, and raw material is by weight are as follows: Kynoar 100~ 120 parts, 30~50 parts of acrylic resin, 30~50 parts of nitrile rubber, 35 ~ 45 parts of methyl vinyl phenyl silicon rubber, curing 4 ~ 8 parts of bisbenzothiazole, N, N- dicyclohexyl -5 ~ 7 parts of 2-[4-morpholinodithio sulfenamide, 30~50 parts of polystyrene, basalt 20~30 parts of fiber, 8~12 parts of fire retardant, 2~5 parts of curing agent and 2~5 parts of antioxidant.Its overall diameter is 30-40cm, the thickness of pipe 5-8cm。
The preparation method of above-mentioned cementitious composite pipe, comprising the following steps:
(1) extrusion molding after being kneaded the raw material of fiber composite pipe in proportion, obtains plastic tube body;
(2) after plastic tube body is cooled to room temperature, cement outer layer raw material is stirred uniformly obtains cement mortar according to the proportion, Then by its spray coating in the outer surface of plastic tube body, then temperature be 20 ± 2 DEG C, relative humidity be greater than 95% under the conditions of into Cementitious composite pipe is obtained after row maintenance.
The beneficial effects of the present invention are: cement outer layer and plastic tube body are not easy delamination in cementitious composite pipe of the invention, Cement outer layer can be effectively prevented plastic tube body and be corroded, reduce abrasion, while improve the intensity of plastic tube body, and plastic tube body Have good corrosion resistance, inoxidizability, resistant of high or low temperature, can be used for transporting petroleum, water.
Detailed description of the invention
Fig. 1 is cementitious composite pipe structural schematic diagram of the invention;
In figure: 1- cement outer layer, 2- plastic tube body.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
A kind of cementitious composite pipe, including cement outer layer and plastic tube body, the raw material of the cement outer layer is by weight are as follows: anti-sea 160 parts of water cement, 300 parts of slag micropowder, 650 parts of fine sand, 90 parts of adhesive, 155 parts of water.
In the present embodiment, plastic tube body is fiber composite pipe, and raw material is by weight are as follows: 110 parts of Kynoar, third 40 parts of olefin(e) acid resin, 40 parts of nitrile rubber, 40 parts of methyl vinyl phenyl silicon rubber, 5 parts of dibenzothiazyl disulfide, N, N- Dicyclohexyl -6 parts of 2-[4-morpholinodithio sulfenamide, 40 parts of polystyrene, 25 parts of basalt fibre, 10 parts of fire retardant, curing agent 4 Part and 3 parts of antioxidant.Its overall diameter is 35cm, thickness of pipe 7cm.
The preparation method of above-mentioned cementitious composite pipe, comprising the following steps:
(1) extrusion molding after being kneaded the raw material of fiber composite pipe in proportion, obtains plastic tube body;
(2) after plastic tube body is cooled to room temperature, cement outer layer raw material is stirred uniformly obtains cement mortar according to the proportion, Then by its spray coating in the outer surface of plastic tube body, then temperature be 20 ± 2 DEG C, relative humidity be greater than 95% under the conditions of into Cementitious composite pipe is obtained after row maintenance.
Embodiment 2
A kind of cementitious composite pipe, including cement outer layer and plastic tube body, the raw material of the cement outer layer is by weight are as follows: anti-sea 140 parts of water cement, 290 parts of slag micropowder, 600 parts of fine sand, 80 parts of adhesive, 150 parts of water.
In the present embodiment, plastic tube body is fiber composite pipe, and raw material is by weight are as follows: 100 parts of Kynoar, third 30 parts of olefin(e) acid resin, 30 parts of nitrile rubber, 45 parts of methyl vinyl phenyl silicon rubber, 4 parts of dibenzothiazyl disulfide, N, N- Dicyclohexyl -5 parts of 2-[4-morpholinodithio sulfenamide, 30 parts of polystyrene, 20 parts of basalt fibre, 12 parts of fire retardant, curing agent 2 Part and 2 parts of antioxidant.Its overall diameter is 30cm, thickness of pipe 5cm.
The preparation method of above-mentioned cementitious composite pipe, comprising the following steps:
(1) extrusion molding after being kneaded the raw material of fiber composite pipe in proportion, obtains plastic tube body;
(2) after plastic tube body is cooled to room temperature, cement outer layer raw material is stirred uniformly obtains cement mortar according to the proportion, Then by its spray coating in the outer surface of plastic tube body, then temperature be 20 ± 2 DEG C, relative humidity be greater than 95% under the conditions of into Cementitious composite pipe is obtained after row maintenance.
Embodiment 3
A kind of cementitious composite pipe, including cement outer layer and plastic tube body, the raw material of the cement outer layer is by weight are as follows: anti-sea 160 parts of water cement, 300 parts of slag micropowder, 680 parts of fine sand, 100 parts of adhesive, 160 parts of water.
In the present embodiment, plastic tube body is fiber composite pipe, and raw material is by weight are as follows: 120 parts of Kynoar, third 50 parts of olefin(e) acid resin, 45 parts of nitrile rubber, 40 parts of methyl vinyl phenyl silicon rubber, 6 parts of dibenzothiazyl disulfide, N, N- Dicyclohexyl -7 parts of 2-[4-morpholinodithio sulfenamide, 45 parts of polystyrene, 30 parts of basalt fibre, 2 parts of fire retardant, curing agent 4 Part and 5 parts of antioxidant.Its overall diameter is 40cm, thickness of pipe 8cm.
The preparation method of above-mentioned cementitious composite pipe, comprising the following steps:
(1) extrusion molding after being kneaded the raw material of fiber composite pipe in proportion, obtains plastic tube body;
(2) after plastic tube body is cooled to room temperature, cement outer layer raw material is stirred uniformly obtains cement mortar according to the proportion, Then by its spray coating in the outer surface of plastic tube body, then temperature be 20 ± 2 DEG C, relative humidity be greater than 95% under the conditions of into Cementitious composite pipe is obtained after row maintenance.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with Modification, is all covered by the present invention.

Claims (3)

1. a kind of cementitious composite pipe, it is characterised in that: including cement outer layer and plastic tube body, the raw material of the cement outer layer is by weight Amount part be calculated as: 140-160 parts of seawater resistant cement, 290-300 parts of slag micropowder, 600-680 parts of fine sand, 80-100 parts of adhesive, 150-165 parts of water.
2. cementitious composite pipe according to claim 1, it is characterised in that: the plastic tube body is fiber composite pipe, former Material is by weight are as follows: 100~120 parts of Kynoar, 30~50 parts of acrylic resin, 30~50 parts of nitrile rubber, methyl 35 ~ 45 parts of ethenylphenyl silicon rubber, 4 ~ 8 parts of dibenzothiazyl disulfide, N, N- dicyclohexyl -2-[4-morpholinodithio time sulphonyl 5 ~ 7 parts of amine, 30~50 parts of polystyrene, 20~30 parts of basalt fibre, 8~12 parts of fire retardant, 2~5 parts of curing agent and antioxygen 2~5 parts of agent.Its overall diameter is 30-40cm, thickness of pipe 5-8cm.
3. a kind of preparation method of such as described in any item cementitious composite pipes of claim 1-2, it is characterised in that: including following step It is rapid:
(1) extrusion molding after being kneaded the raw material of fiber composite pipe in proportion, obtains plastic tube body;
(2) after plastic tube body is cooled to room temperature, cement outer layer raw material is stirred uniformly obtains cement mortar according to the proportion, Then by its spray coating in the outer surface of plastic tube body, then temperature be 20 ± 2 DEG C, relative humidity be greater than 95% under the conditions of into Cementitious composite pipe is obtained after row maintenance.
CN201910802279.8A 2019-08-28 2019-08-28 Cement composite pipe and preparation method thereof Active CN110529668B (en)

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Application Number Priority Date Filing Date Title
CN201910802279.8A CN110529668B (en) 2019-08-28 2019-08-28 Cement composite pipe and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201910802279.8A CN110529668B (en) 2019-08-28 2019-08-28 Cement composite pipe and preparation method thereof

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CN110529668B CN110529668B (en) 2024-08-20

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1333162A (en) * 1971-01-11 1973-10-10 Thyssen Great Britain Ltd Pipes and cylindrical structural members
US5268226A (en) * 1991-07-22 1993-12-07 Diversitech Corporation Composite structure with waste plastic core and method of making same
TW201323206A (en) * 2011-12-14 2013-06-16 Yokohama Rubber Co Ltd Rubber/resin composite hose
CN107325399A (en) * 2017-06-26 2017-11-07 黄小明 High-strength corrosion-resisting plastic tube and preparation method thereof
CN107382205A (en) * 2017-08-16 2017-11-24 西安建筑科技大学 A kind of super high strength high performance fiber concrete of C160 strength grades and preparation method thereof
CN107725907A (en) * 2017-10-27 2018-02-23 广汉海格曼石油科技有限公司 A kind of fiber composite pipe
CN107857542A (en) * 2017-10-27 2018-03-30 广西横县恒丰建材有限责任公司 The production method of cement for construction in sea wind and wave resistance mortar
WO2018130188A1 (en) * 2017-01-13 2018-07-19 杭州星庐科技有限公司 Rubber composite, processing method, rubber belt and rubber roller applying composite, and manufacturing method
CN109593285A (en) * 2017-09-30 2019-04-09 扬州海龙化工助剂有限公司 A kind of fire-retardant fire hose material

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1333162A (en) * 1971-01-11 1973-10-10 Thyssen Great Britain Ltd Pipes and cylindrical structural members
US5268226A (en) * 1991-07-22 1993-12-07 Diversitech Corporation Composite structure with waste plastic core and method of making same
TW201323206A (en) * 2011-12-14 2013-06-16 Yokohama Rubber Co Ltd Rubber/resin composite hose
WO2018130188A1 (en) * 2017-01-13 2018-07-19 杭州星庐科技有限公司 Rubber composite, processing method, rubber belt and rubber roller applying composite, and manufacturing method
CN107325399A (en) * 2017-06-26 2017-11-07 黄小明 High-strength corrosion-resisting plastic tube and preparation method thereof
CN107382205A (en) * 2017-08-16 2017-11-24 西安建筑科技大学 A kind of super high strength high performance fiber concrete of C160 strength grades and preparation method thereof
CN109593285A (en) * 2017-09-30 2019-04-09 扬州海龙化工助剂有限公司 A kind of fire-retardant fire hose material
CN107725907A (en) * 2017-10-27 2018-02-23 广汉海格曼石油科技有限公司 A kind of fiber composite pipe
CN107857542A (en) * 2017-10-27 2018-03-30 广西横县恒丰建材有限责任公司 The production method of cement for construction in sea wind and wave resistance mortar

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