CN110528268A - A kind of nanometer of light purification fabric and its manufacturing method - Google Patents
A kind of nanometer of light purification fabric and its manufacturing method Download PDFInfo
- Publication number
- CN110528268A CN110528268A CN201910765456.XA CN201910765456A CN110528268A CN 110528268 A CN110528268 A CN 110528268A CN 201910765456 A CN201910765456 A CN 201910765456A CN 110528268 A CN110528268 A CN 110528268A
- Authority
- CN
- China
- Prior art keywords
- nanometer
- fabric
- light purification
- graphene
- manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 82
- 238000000746 purification Methods 0.000 title claims abstract description 77
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 24
- 229920001661 Chitosan Polymers 0.000 claims abstract description 68
- 239000002131 composite material Substances 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003595 mist Substances 0.000 claims abstract description 31
- 239000004964 aerogel Substances 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 23
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 11
- 239000010936 titanium Substances 0.000 claims abstract description 11
- 239000000243 solution Substances 0.000 claims description 65
- 150000002500 ions Chemical class 0.000 claims description 46
- 239000000835 fiber Substances 0.000 claims description 40
- 239000000126 substance Substances 0.000 claims description 34
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 29
- 229910021389 graphene Inorganic materials 0.000 claims description 28
- 238000009987 spinning Methods 0.000 claims description 19
- 239000000843 powder Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- 238000010792 warming Methods 0.000 claims description 14
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 13
- 239000000017 hydrogel Substances 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 claims description 6
- 239000012670 alkaline solution Substances 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 3
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 2
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 2
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 7
- 239000011259 mixed solution Substances 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000006870 function Effects 0.000 abstract description 4
- 150000001450 anions Chemical class 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- 239000003929 acidic solution Substances 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 description 24
- 229910021641 deionized water Inorganic materials 0.000 description 24
- 239000006087 Silane Coupling Agent Substances 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000002156 mixing Methods 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 238000002166 wet spinning Methods 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
- 239000000908 ammonium hydroxide Substances 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 150000004676 glycans Chemical class 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 238000004887 air purification Methods 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000228245 Aspergillus niger Species 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 2
- 241001515917 Chaetomium globosum Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 229940095731 candida albicans Drugs 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 241000228197 Aspergillus flavus Species 0.000 description 1
- 241001478240 Coccus Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention discloses a kind of nanometer of light purification fabric and its manufacturing methods.By graphene-chitosan composite aerogel micro mist and titanium source, nanometer purification finishing agent is made in hydro-thermal reaction to the present invention in an acidic solution, it is purified in the mixed solution of finishing agent and water by the way that basic cloth is impregnated in nanometer light, after baking, then is washed, is dried to obtain a nanometer light purification fabric.Nanometer light purification fabric provided by the invention has long-acting mould-proof, antibacterial functions；Nanometer light purification fabric provided by the invention has the effect of purifying air except formaldehyde, moreover it is possible to continually and steadily discharge anion；Nanometer light provided by the invention purification fabric meets consumer and pursues the multiple demands such as comfortable, green, environmental protection, health care, can popularize on a large scale, has high economic benefit and social benefit.
Description
Technical field
The present invention relates to textile technology fields, in particular to a kind of nanometer of light purification fabric and its manufacturing method.
Background technique
As the life idea of health, ecology is gradually rooted in the hearts of the people, requirement of the people to textile fabric is higher and higher.Bacterium
Breeding can be mushroomed out in suitable environmental conditions, and by spreading the disease with human contact, the body for influencing people is strong.By
The textile fabric of fiber composition, since the chemical structure of its porous type body form and high molecular polymer is attached conducive to microorganism
, become the good parasitic body of the microbe survivals such as bacterium, fungi, breeding.The textile that people contact in daily life is this
The important propagating source of the ground of biological good existence and various diseases slightly；And the weaving of the overwhelming majority currently on the market
Fabric is not only mould proof, antibacterial can have been unable to meet consumer and pursue comfortable, green, environmental protection, guarantor also without the function except formaldehyde
The multiple demands such as strong.
Summary of the invention
The purpose of the present invention is intended to provide a kind of nanometer of light purification fabric and its manufacturing method, is asked with solving above-mentioned technology
Topic.
To achieve the goals above, the technical solution of the present invention is as follows:
In a first aspect, the manufacturing method of a kind of nanometer of light purification fabric provided by the invention, which is characterized in that including as follows
Step:
(1) titanium source is added in acid solution, adds graphene-chitosan composite aerogel micro mist, it is warming up to 120~
After 150 DEG C, hydro-thermal reaction 4~8 hours, alkaline solution tune pH value is added dropwise to 6.8~7.2, after standing 2~4 hours, through centrifugation point
From, clean, be dried to obtain a nanometer light purification finishing agent；
(2) in water by the resulting nanometer light purification finishing agent ultrasonic disperse of step (1), crosslinking agent is then added, through super
Sound disperses that nanometer light purification finisher solution is made；
(3) basic cloth is impregnated in the resulting nanometer light purification finisher solution of step (2), after baking, then is washed, done
It is dry to obtain a nanometer light purification fabric.
Preferably, in the step (1), the titanium source is selected from isopropyl titanate, titanium tetrachloride, titanium trichloride, metatitanic acid four
Any one or more in butyl ester, tetraethyl titanate.
Preferably, in the step (1), the titanium source and the graphene-chitosan composite aerogel micro mist weight
Than for 0.5~1:1.
Preferably, in the step (1), the graphene-chitosan composite aerogel micro mist is using following methods system
:
Graphene oxide is dispersed in water, sequentially adds organic solvent, chitosan solution is uniformly mixed, it is placed in 120~
10~20h is reacted in 160 DEG C of closed environment, graphene-chitosan composite hydrogel is obtained through cooling, by resulting graphite
It is freeze-dried after alkene-chitosan composite hydrogel is broken, obtain graphene-chitosan composite aerogel micro mist.
It is further preferred that the weight ratio of the chitosan and the graphene oxide is 3~10 in the step (1):
1。
It is further preferred that the organic solvent is dehydrated alcohol in the step (1).
Preferably, in the step (3), the basic cloth is any one in natural fiber and chemical fibre or two kinds
Intertexture.
Preferably, in the step (3), the basic cloth is the intertexture of negative ion chemical fiber；The negative ionization
Learning fiber is to be made using following methods:
It after spinning solution and nano-negative ion powder are mixed, stirs 0.5~2 hour, filters laggard at 30~50 DEG C
Row wet spinning obtains negative ion chemical fiber.
Preferably, in the step (3), the step of baking, is specifically included: it is warming up to 60~80 DEG C and keeps the temperature drying,
Then heat to 120~150 DEG C of 1~3min of baking.
Second aspect, a kind of nanometer of light provided by the invention purify fabric, for using nanometer light as described in relation to the first aspect
The manufacturing method for purifying fabric is made.
Compared with prior art, the beneficial effects of the present invention are:
Nanometer light purification fabric provided by the invention has long-acting mould-proof, antibacterial functions, to Escherichia coli, golden yellow grape
The strains such as coccus, Candida albicans play apparent antibacterial and preventive and therapeutic effect, and antimicrobial efficiency is up to 99%, to aspergillus niger, Huang
The suppression of the moulds such as aspergillus, Chaetomium globosum kill activity it is all very high, it is mouldy and corrupt in wet environment to can effectively avoid fabric；This
The nanometer light purification fabric that invention provides has the effect of purifying air except formaldehyde, moreover it is possible to anion is continually and steadily discharged, to people
Body has certain health-care effect；Nanometer light purification fabric provided by the invention, which meets consumer, to be pursued comfortable, green, environmental protection, protects
The multiple demands such as strong, can popularize on a large scale, have high economic benefit and social benefit.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below
Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
In a first aspect, the manufacturing method of a kind of nanometer of light purification fabric provided by the invention, which is characterized in that including as follows
Step:
(1) titanium source is added in acid solution, adds graphene-chitosan composite aerogel micro mist, it is warming up to 120~
After 150 DEG C, hydro-thermal reaction 4~8 hours, alkaline solution tune pH value is added dropwise to 6.8~7.2, after standing 2~4 hours, through centrifugation point
From, clean, be dried to obtain a nanometer light purification finishing agent；
(2) in water by the resulting nanometer light purification finishing agent ultrasonic disperse of step (1), crosslinking agent is then added, through super
Sound disperses that nanometer light purification finisher solution is made；
(3) basic cloth is impregnated in the resulting nanometer light purification finisher solution of step (2), after baking, then is washed, done
It is dry to obtain a nanometer light purification fabric.
In embodiments of the present invention, in the step (1), the titanium source is selected from isopropyl titanate, titanium tetrachloride, trichlorine
Change titanium, butyl titanate, any one or more in tetraethyl titanate.
In embodiments of the present invention, in the step (1), the titanium source and the compound airsetting of graphene-chitosan
The weight ratio of glue micro mist is 0.5~1:1.
In embodiments of the present invention, in the step (1), the concentration of the acid solution is 0.05~0.5mol/L.
In embodiments of the present invention, in the step (1), the acid solution is selected from hydrochloric acid solution, nitric acid solution, sulfuric acid
One of solution is a variety of.
In embodiments of the present invention, in the step (1), the alkaline solution is ammonium hydroxide.
In embodiments of the present invention, in the step (1), the mass concentration of the alkaline solution is 5~30%.
In embodiments of the present invention, in the step (1), the graphene-chitosan composite aerogel micro mist is to adopt
It is made with following methods:
After mixing by chitosan solution and graphene oxide dispersion, organic solvent, chitosan solution are sequentially added
It is uniformly mixed, is placed in 10~20h of reaction in 120~160 DEG C of closed environment, obtain graphene-chitosan Compound Water through cooling
Gel, it is freeze-dried after resulting graphene-chitosan composite hydrogel is crushed, obtain the compound gas of graphene-chitosan
Gel micro mist.
Further, in the step (1), the weight ratio of the chitosan and the graphene oxide is 3~10:1.
Further, in the step (1), the organic solvent is dehydrated alcohol.
In embodiments of the present invention, in the step (2), the weight ratio of the purification of nanometer the light finishing agent and the water
For 0.005~0.05:1.
In embodiments of the present invention, in the step (2), the crosslinking agent is selected from silane coupling agent 530, silane Europe chain
Connect 550, silane coupling agent 560, any one or more in silane coupling agent 570.
In embodiments of the present invention, in the step (2), the weight ratio of the crosslinking agent and the water is 0.005~
0.05:1。
In embodiments of the present invention, in the step (3), the basic cloth is any in natural fiber and chemical fibre
One or two kinds of intertextures.
Further, in the step (3), any one or more of the natural fiber in cotton, hair, silk, fiber crops.
Further, in the step (3), the chemical fibre in terylene, acrylic fibers, aramid fiber any one or it is more
Kind.
In embodiments of the present invention, in the step (3), the basic cloth is the intertexture of negative ion chemical fiber.
Further, in the step (3), the negative ion chemical fiber is to be made using following methods:
It after spinning solution and nano-negative ion powder are mixed, stirs 0.5~2 hour, filters laggard at 30~50 DEG C
Row wet spinning obtains negative ion chemical fiber.
Further, the weight ratio of the nano-negative ion powder and the spinning solution is 0.01~0.1:1.
In embodiments of the present invention, in the step (3), the time of the dipping is 2~4 hours.
In embodiments of the present invention, in the step (3), the step of baking, is specifically included: being warming up to 60~80
DEG C and keep the temperature drying, then heat to 120~150 DEG C of 1~3min of baking.
Second aspect, a kind of nanometer of light provided by the invention purify fabric, for using nanometer light as described in relation to the first aspect
The manufacturing method for purifying fabric is made.
The embodiment of the present invention is described further below.
Embodiment 1
The manufacturing method of nanometer light purification fabric provided in this embodiment, includes the following steps:
(1) it dissolves the chitosan in deionized water, acetic acid is added, the shell that mass concentration is 5% is obtained after ultrasonic disperse
Glycan solution disperses graphene oxide in and obtains the graphene oxide dispersion that mass concentration is 0.5% in deionized water, presses
The ratio for being 5:1 according to the weight ratio of chitosan and graphene oxide, graphene oxide dispersion is added dropwise in chitosan solution,
After being added dropwise, mixed solution is transferred in hydrothermal reaction kettle, reaction kettle is put into hydro-thermal case, is placed in 140 DEG C of closed loop
Hydro-thermal reaction 18h in border obtains graphene-chitosan composite hydrogel through cooling, by resulting graphene-chitosan Compound Water
It is freeze-dried after gel is broken, obtain graphene-chitosan composite aerogel micro mist；According to isopropyl titanate and graphene-
The weight ratio of chitosan composite aerogel micro mist is the ratio of 0.75:1, and it is 0.5mol/L's that isopropyl titanate, which is added to concentration,
In sulfuric acid solution, graphene-chitosan composite aerogel micro mist is added, is transferred in hydrothermal reaction kettle after mixing evenly, it will be anti-
Kettle is answered to be put into hydro-thermal case, after being warming up to 130 DEG C, hydro-thermal reaction 6 hours, opening reaction kettle and mass concentration is added dropwise is 15%
Ammonium hydroxide tune pH value after standing 3 hours, is centrifuged, cleans, being dried to obtain a nanometer light purification finishing agent to 6.8~7.2；
(2) ratio for being 0.03:1:0.03 according to the weight ratio of nanometer light purification finishing agent, deionized water and silane coupling agent
Then in deionized water by resulting nanometer light purification finishing agent ultrasonic disperse silane coupling agent KH560 is added, through super in example
Sound disperses that nanometer light purification finisher solution is made；
(3) basic cloth is put into the resulting nanometer light purification finisher solution of step (2) and is impregnated 3 hours, heated up after taking-up
To 70 DEG C and drying is kept the temperature, then heats to 130 DEG C of baking 2min, then washed, be dried to obtain a nanometer light purification fabric；Its
In, basic cloth is the intertexture of negative ion chemical fiber, and negative ion chemical fiber is to be made using following methods: negative according to nanometer
The weight ratio of ion powder and spinning solution 0.05:1 is stirred at 45 DEG C after mixing spinning solution and nano-negative ion powder
It mixes 1 hour, wet spinning is carried out after filtering and obtains negative ion chemical fiber.
Embodiment 2
The manufacturing method of nanometer light purification fabric provided in this embodiment, includes the following steps:
(1) it dissolves the chitosan in deionized water, acetic acid is added, the shell that mass concentration is 5% is obtained after ultrasonic disperse
Glycan solution disperses graphene oxide in and obtains the graphene oxide dispersion that mass concentration is 0.5% in deionized water, presses
The ratio for being 6:1 according to the weight ratio of chitosan and graphene oxide, graphene oxide dispersion is added dropwise in chitosan solution,
After being added dropwise, mixed solution is transferred in hydrothermal reaction kettle, reaction kettle is put into hydro-thermal case, is warming up to 145 DEG C, keeps the temperature water
Thermal response 16h obtains graphene-chitosan composite hydrogel through cooling, resulting graphene-chitosan composite hydrogel is broken
It is freeze-dried after broken, obtain graphene-chitosan composite aerogel micro mist；According to isopropyl titanate and graphene-chitosan
The weight ratio of composite aerogel micro mist is the ratio of 0.6:1, and it is molten that isopropyl titanate is added to the sulfuric acid that concentration is 0.5mol/L
In liquid, graphene-chitosan composite aerogel micro mist is added, is transferred in hydrothermal reaction kettle after mixing evenly, reaction kettle is put
Enter in hydro-thermal case, after being warming up to 130 DEG C, hydro-thermal reaction 7 hours, opens reaction kettle and the ammonium hydroxide tune that mass concentration is 15% is added dropwise
PH value after standing 3 hours, is centrifuged, cleans, being dried to obtain a nanometer light purification finishing agent to 6.8~7.2；
(2) ratio for being 0.04:1:0.04 according to the weight ratio of nanometer light purification finishing agent, deionized water and silane coupling agent
Then in deionized water by resulting nanometer light purification finishing agent ultrasonic disperse silane coupling agent KH560 is added, through super in example
Sound disperses that nanometer light purification finisher solution is made；
(3) basic cloth is put into the resulting nanometer light purification finisher solution of step (2) and is impregnated 2~4 hours, risen after taking-up
Temperature is to 70 DEG C and keeps the temperature drying, then heats to 140 DEG C of baking 1min, then is washed, is dried to obtain a nanometer light purification fabric；Its
In, basic cloth is the intertexture of negative ion chemical fiber, and negative ion chemical fiber is to be made using following methods: negative according to nanometer
The weight ratio of ion powder and spinning solution 0.08:1 is stirred at 40 DEG C after mixing spinning solution and nano-negative ion powder
It mixes 1 hour, wet spinning is carried out after filtering and obtains negative ion chemical fiber.
Embodiment 3
The manufacturing method of nanometer light purification fabric provided in this embodiment, includes the following steps:
(1) it dissolves the chitosan in deionized water, acetic acid is added, the shell that mass concentration is 5% is obtained after ultrasonic disperse
Glycan solution disperses graphene oxide in and obtains the graphene oxide dispersion that mass concentration is 0.5% in deionized water, presses
The ratio for being 4:1 according to the weight ratio of chitosan and graphene oxide, graphene oxide dispersion is added dropwise in chitosan solution,
After being added dropwise, mixed solution is transferred in hydrothermal reaction kettle, reaction kettle is put into hydro-thermal case, is placed in 160 DEG C of closed loop
Hydro-thermal reaction 14h in border obtains graphene-chitosan composite hydrogel through cooling, by resulting graphene-chitosan Compound Water
It is freeze-dried after gel is broken, obtain graphene-chitosan composite aerogel micro mist；According to isopropyl titanate and graphene-
The weight ratio of chitosan composite aerogel micro mist is the ratio of 0.5:1, and it is 0.5mol/L's that isopropyl titanate, which is added to concentration,
In sulfuric acid solution, graphene-chitosan composite aerogel micro mist is added, is transferred in hydrothermal reaction kettle after mixing evenly, it will be anti-
Kettle is answered to be put into hydro-thermal case, after being warming up to 130 DEG C, hydro-thermal reaction 6 hours, opening reaction kettle and mass concentration is added dropwise is 15%
Ammonium hydroxide tune pH value after standing 2 hours, is centrifuged, cleans, being dried to obtain a nanometer light purification finishing agent to 6.8~7.2；
(2) ratio for being 0.03:1:0.03 according to the weight ratio of nanometer light purification finishing agent, deionized water and silane coupling agent
Then in deionized water by resulting nanometer light purification finishing agent ultrasonic disperse silane coupling agent KH560 is added, through super in example
Sound disperses that nanometer light purification finisher solution is made；
(3) basic cloth is put into the resulting nanometer light purification finisher solution of step (2) and is impregnated 4 hours, heated up after taking-up
To 60~80 DEG C and drying is kept the temperature, then heats to 130 DEG C of baking 1min, then washed, be dried to obtain a nanometer light purification fabric；
Wherein, basic cloth is the intertexture of negative ion chemical fiber, and negative ion chemical fiber is to be made using following methods: according to nanometer
The weight ratio of anion powder and spinning solution 0.08:1, after spinning solution and nano-negative ion powder are mixed, at 40 DEG C
Stirring 1.5 hours carries out wet spinning and obtains negative ion chemical fiber after filtering.
Embodiment 4
The manufacturing method of nanometer light purification fabric provided in this embodiment, includes the following steps:
(1) it dissolves the chitosan in deionized water, acetic acid is added, the shell that mass concentration is 5% is obtained after ultrasonic disperse
Glycan solution disperses graphene oxide in and obtains the graphene oxide dispersion that mass concentration is 0.5% in deionized water, presses
The ratio for being 3:1 according to the weight ratio of chitosan and graphene oxide, graphene oxide dispersion is added dropwise in chitosan solution,
After being added dropwise, mixed solution is transferred in hydrothermal reaction kettle, reaction kettle is put into hydro-thermal case, is placed in 160 DEG C of closed loop
Hydro-thermal reaction 10h in border obtains graphene-chitosan composite hydrogel through cooling, by resulting graphene-chitosan Compound Water
It is freeze-dried after gel is broken, obtain graphene-chitosan composite aerogel micro mist；According to isopropyl titanate and graphene-
The weight ratio of chitosan composite aerogel micro mist is the ratio of 1:1, and isopropyl titanate is added to the sulphur that concentration is 0.5mol/L
In acid solution, graphene-chitosan composite aerogel micro mist is added, is transferred in hydrothermal reaction kettle, will react after mixing evenly
Kettle is put into hydro-thermal case, after being warming up to 120 DEG C, hydro-thermal reaction 8 hours, opens reaction kettle and the ammonia that mass concentration is 15% is added dropwise
Water tune pH value after standing 4 hours, is centrifuged, cleans, being dried to obtain a nanometer light purification finishing agent to 6.8~7.2；
(2) ratio for being 0.05:1:0.05 according to the weight ratio of nanometer light purification finishing agent, deionized water and silane coupling agent
Then in deionized water by resulting nanometer light purification finishing agent ultrasonic disperse silane coupling agent KH560 is added, through super in example
Sound disperses that nanometer light purification finisher solution is made；
(3) basic cloth is put into the resulting nanometer light purification finisher solution of step (2) and is impregnated 2 hours, heated up after taking-up
To 80 DEG C and drying is kept the temperature, then heats to 120 DEG C of baking 1min, then washed, be dried to obtain a nanometer light purification fabric；Its
In, basic cloth is the intertexture of negative ion chemical fiber, and negative ion chemical fiber is to be made using following methods: negative according to nanometer
The weight ratio of ion powder and spinning solution 0.01:1 is stirred at 30 DEG C after mixing spinning solution and nano-negative ion powder
It mixes 2 hours, wet spinning is carried out after filtering and obtains negative ion chemical fiber.
Embodiment 5
The manufacturing method of nanometer light purification fabric provided in this embodiment, includes the following steps:
(1) it dissolves the chitosan in deionized water, acetic acid is added, the shell that mass concentration is 5% is obtained after ultrasonic disperse
Glycan solution disperses graphene oxide in and obtains the graphene oxide dispersion that mass concentration is 0.5% in deionized water, presses
The ratio for being 10:1 according to the weight ratio of chitosan and graphene oxide, is added dropwise to chitosan solution for graphene oxide dispersion
In, after being added dropwise, mixed solution is transferred in hydrothermal reaction kettle, reaction kettle is put into hydro-thermal case, is placed in 120 DEG C closed
Hydro-thermal reaction 20h in environment obtains graphene-chitosan composite hydrogel through cooling, and resulting graphene-chitosan is compound
It is freeze-dried after hydrogel is broken, obtain graphene-chitosan composite aerogel micro mist；According to isopropyl titanate and graphite
Alkene-chitosan composite aerogel micro mist weight ratio is the ratio of 0.5:1, and it is 0.5mol/L that isopropyl titanate, which is added to concentration,
Sulfuric acid solution in, add graphene-chitosan composite aerogel micro mist, be transferred in hydrothermal reaction kettle after mixing evenly, will
Reaction kettle is put into hydro-thermal case, and after being warming up to 150 DEG C, hydro-thermal reaction 4 hours, opening reaction kettle and mass concentration is added dropwise is 15%
Ammonium hydroxide tune pH value to 6.8~7.2, after standing 2 hours, be centrifuged, clean, being dried to obtain a nanometer light purification finishing agent；
It (2) is 0.005:1:0.005's according to the weight ratio of nanometer light purification finishing agent, deionized water and silane coupling agent
Then in deionized water by resulting nanometer light purification finishing agent ultrasonic disperse silane coupling agent KH560, warp is added in ratio
Ultrasonic disperse is made nanometer light and purifies finisher solution；
(3) basic cloth is put into the resulting nanometer light purification finisher solution of step (2) and is impregnated 4 hours, heated up after taking-up
To 60 DEG C and drying is kept the temperature, then heats to 150 DEG C of baking 3min, then washed, be dried to obtain a nanometer light purification fabric；Its
In, basic cloth is the intertexture of negative ion chemical fiber, and negative ion chemical fiber is to be made using following methods: negative according to nanometer
The weight ratio of ion powder and spinning solution 0.1:1 stirs at 50 DEG C after mixing spinning solution and nano-negative ion powder
0.5 hour, wet spinning was carried out after filtering and obtains negative ion chemical fiber.
Comparative example 1
Graphene-chitosan composite aerogel micro mist is made according to (1) the step of embodiment 1, according to graphene-chitosan
The weight ratio of composite aerogel micro mist, deionized water and silane coupling agent is the ratio of 0.03:1:0.03, by resulting graphite
In deionized water, silane coupling agent KH560 is then added in alkene-chitosan composite aerogel micro mist ultrasonic disperse, through ultrasound point
It dissipates obtained nanometer light and purifies finisher solution；
Basic cloth is put into resulting nanometer light purification finisher solution and is impregnated 3 hours, 70 DEG C are warming up to after taking-up and is protected
Temperature drying, then heats to 130 DEG C of baking 2min, then is washed, is dried to obtain a nanometer light purification fabric；Wherein, basic cloth is
The intertexture of negative ion chemical fiber, negative ion chemical fiber are to be made using following methods: according to nano-negative ion powder and
The weight ratio of spinning solution 0.05:1 stirs 1 hour, mistake after mixing spinning solution and nano-negative ion powder at 45 DEG C
Wet spinning is carried out after filter obtains negative ion chemical fiber.
Comparative example 2
It is 0.03:0.03:1 according to the weight ratio of nano-graphene, titanium dioxide, deionized water and silane coupling agent:
Then 0.03 ratio in deionized water by resulting nano-graphene and titanium dioxide ultrasonic disperse is added silane coupled
Nanometer light purification finisher solution is made through ultrasonic disperse in agent KH560；
Basic cloth is put into resulting nanometer light purification finisher solution and is impregnated 3 hours, 70 DEG C are warming up to after taking-up and is protected
Temperature drying, then heats to 130 DEG C of baking 2min, then is washed, is dried to obtain a nanometer light purification fabric；Wherein, basic cloth is
The intertexture of negative ion chemical fiber, negative ion chemical fiber are to be made using following methods: according to nano-negative ion powder and
The weight ratio of spinning solution 0.05:1 stirs 1 hour, mistake after mixing spinning solution and nano-negative ion powder at 45 DEG C
Wet spinning is carried out after filter obtains negative ion chemical fiber.Effect example 1
Beneficial effect in order to further illustrate the present invention, the present invention is to above-described embodiment and the resulting fabric of comparative example
Antibacterial effect is tested: cutting 2 pieces of areas respectively from above-described embodiment and the resulting fabric of comparative example is 2cm × 2cm
Fabric sample, fabric sample is respectively placed in clean culture dish, to fabric sample spray mycotic spore suspension, mould
Spore suspension includes aspergillus niger, aspergillus flavus, Chaetomium globosum, cultivates 30 culture dish to be transferred in constant temperature and humidity incubator
It, cultivation temperature is 28 ± 1 DEG C, and culture humidity is 90 ± 5%, observes the mildew situation of fabric sample surfaces.
1 anti-mold effect test result of table
| Serial number | Fabric source | Mould proof grade |
| 1 | Embodiment 1 | 0 grade |
| 2 | Embodiment 2 | 0 grade |
| 3 | Embodiment 3 | 0 grade |
| 4 | Embodiment 4 | 0 grade |
| 5 | Embodiment 5 | 0 grade |
| 6 | Comparative example 1 | 1 grade |
| 7 | Comparative example 2 | 1 grade |
Effect example 2
Beneficial effect in order to further illustrate the present invention, the present invention use JC/T1074-2008 " indoor air purification function
Can coating material purifying property " air purification ability of test above-described embodiment and the resulting fabric of comparative example tested, surveyed
Test result is as shown in table 2.
2 air purification effect test result of table
| Serial number | Fabric source | Purifying formaldehyde efficiency (%) |
| 1 | Embodiment 1 | 87 |
| 2 | Embodiment 2 | 83 |
| 3 | Embodiment 3 | 85 |
| 4 | Embodiment 4 | 76 |
| 5 | Embodiment 5 | 72 |
| 6 | Comparative example 1 | 41 |
| 7 | Comparative example 2 | 32 |
Effect example 3
Beneficial effect in order to further illustrate the present invention, the present invention is to above-described embodiment and the resulting fabric of comparative example
Antibacterial effect is tested, and test strain is Escherichia coli, staphylococcus aureus and Candida albicans, test result such as table
Shown in 3.
3 antibacterial effect test result of table
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall in protection scope of the present invention.
Claims (10)
1. the manufacturing method of a kind of nanometer of light purification fabric, which comprises the steps of:
(1) titanium source is added in acid solution, adds graphene-chitosan composite aerogel micro mist, is warming up to 120~150
DEG C, after hydro-thermal reaction 4~8 hours, dropwise addition alkaline solution tune pH value to 6.8~7.2, after standing 2~4 hours, be centrifuged,
It cleans, be dried to obtain a nanometer light purification finishing agent；
(2) in water by the resulting nanometer light purification finishing agent ultrasonic disperse of step (1), crosslinking agent is then added, through ultrasound point
It dissipates obtained nanometer light and purifies finisher solution；
(3) basic cloth is impregnated in the resulting nanometer light purification finisher solution of step (2), after baking, then is washed, dried
Fabric is purified to nanometer light.
2. the manufacturing method of according to claim 1 nanometer of light purification fabric, which is characterized in that in the step (1), institute
State titanium source in isopropyl titanate, titanium tetrachloride, titanium trichloride, butyl titanate, tetraethyl titanate any one or it is more
Kind.
3. the manufacturing method of according to claim 1 nanometer of light purification fabric, which is characterized in that in the step (1), institute
It states titanium source and the graphene-chitosan composite aerogel micro mist weight ratio is 0.5~1:1.
4. the manufacturing method of according to claim 1 nanometer of light purification fabric, which is characterized in that in the step (1), institute
Stating graphene-chitosan composite aerogel micro mist is to be made using following methods:
Graphene oxide is dispersed in water, sequentially add organic solvent, chitosan solution be uniformly mixed, be placed in 120~160 DEG C
Closed environment in react 10~20h, through cooling obtain graphene-chitosan composite hydrogel, resulting graphene-shell is gathered
It is freeze-dried after sugared composite hydrogel is broken, obtain graphene-chitosan composite aerogel micro mist.
5. the manufacturing method of according to claim 1 nanometer of light purification fabric, which is characterized in that in the step (1), institute
The weight ratio for stating chitosan and the graphene oxide is 3~10:1.
6. the manufacturing method of according to claim 1 nanometer of light purification fabric, which is characterized in that in the step (1), institute
Stating organic solvent is dehydrated alcohol.
7. the manufacturing method of according to claim 1 nanometer of light purification fabric, which is characterized in that in the step (3), institute
State the intertexture that basic cloth is any one in natural fiber and chemical fibre or two kinds.
8. the manufacturing method of according to claim 1 nanometer of light purification fabric, which is characterized in that in the step (3), institute
State the intertexture that basic cloth is negative ion chemical fiber；The negative ion chemical fiber is to be made using following methods:
After spinning solution and nano-negative ion powder are mixed, stirs 0.5~2 hour, carried out after filtering wet at 30~50 DEG C
Method spinning obtains negative ion chemical fiber.
9. the manufacturing method of according to claim 1 nanometer of light purification fabric, which is characterized in that in the step (3), institute
The step of stating baking specifically includes: be warming up to 60~80 DEG C and keep the temperature drying, then heat to 120~150 DEG C bake 1~
3min。
10. a kind of nanometer of light purifies fabric, which is characterized in that for using such as nanometer light according to any one of claims 1 to 9
The manufacturing method for purifying fabric is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910765456.XA CN110528268A (en) | 2019-08-19 | 2019-08-19 | A kind of nanometer of light purification fabric and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910765456.XA CN110528268A (en) | 2019-08-19 | 2019-08-19 | A kind of nanometer of light purification fabric and its manufacturing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110528268A true CN110528268A (en) | 2019-12-03 |
Family
ID=68663777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910765456.XA Pending CN110528268A (en) | 2019-08-19 | 2019-08-19 | A kind of nanometer of light purification fabric and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110528268A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205890A (en) * | 2013-03-28 | 2013-07-17 | 苏州正业昌智能科技有限公司 | Preparation of nanometer graphene oxide modified cotton fibers and antibiosis product thereof |
| CN107998813A (en) * | 2017-09-25 | 2018-05-08 | 浙江海洋大学 | Remove the inorganic agent of indoor formaldehyde and indoor organic volatile matter |
| CN109537271A (en) * | 2018-12-11 | 2019-03-29 | 佛山市名洲纺织有限公司 | A kind of flame-retardant textile and preparation method thereof that the graphene aerogel based on microvesicle templated sol gel method is modified |
| CN109907039A (en) * | 2019-02-20 | 2019-06-21 | 雷江勇 | A kind of preparation method of nanometer of Compositional type antimicrobial powder material |
| CN110105632A (en) * | 2019-04-30 | 2019-08-09 | 合肥工业大学 | It is a kind of to inhibit the two-layer compound aeroge of biofilm formation, preparation method and application |
| CN110130105A (en) * | 2019-03-29 | 2019-08-16 | 南通和清纺织科技有限公司 | A kind of preparation method of antibacterial photocatalytic functional fabric |
-
2019
- 2019-08-19 CN CN201910765456.XA patent/CN110528268A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205890A (en) * | 2013-03-28 | 2013-07-17 | 苏州正业昌智能科技有限公司 | Preparation of nanometer graphene oxide modified cotton fibers and antibiosis product thereof |
| CN107998813A (en) * | 2017-09-25 | 2018-05-08 | 浙江海洋大学 | Remove the inorganic agent of indoor formaldehyde and indoor organic volatile matter |
| CN109537271A (en) * | 2018-12-11 | 2019-03-29 | 佛山市名洲纺织有限公司 | A kind of flame-retardant textile and preparation method thereof that the graphene aerogel based on microvesicle templated sol gel method is modified |
| CN109907039A (en) * | 2019-02-20 | 2019-06-21 | 雷江勇 | A kind of preparation method of nanometer of Compositional type antimicrobial powder material |
| CN110130105A (en) * | 2019-03-29 | 2019-08-16 | 南通和清纺织科技有限公司 | A kind of preparation method of antibacterial photocatalytic functional fabric |
| CN110105632A (en) * | 2019-04-30 | 2019-08-09 | 合肥工业大学 | It is a kind of to inhibit the two-layer compound aeroge of biofilm formation, preparation method and application |
Non-Patent Citations (1)
| Title |
|---|
| 董永春主编: "《纺织助剂化学》", 31 January 2010, 上海：东华大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107326470B (en) | A kind of processing method of the lasting modified polyester fiber of antibacterial | |
| CN100379481C (en) | Filtering material for purifying air and its mfg. method | |
| CN101775745B (en) | Melt-down non-woven material, preparation method and product | |
| WO2020228808A1 (en) | Borneol surface-modified antimicrobial natural textile material, and preparation method and application thereof | |
| CN105797193B (en) | A kind of Thermo-sensitive arginine base long acting antibiotic aerogel dressing and preparation method thereof | |
| CN103951765B (en) | The rich horse ester-N-chitosan quaternary ammonium salt of O-and method for making thereof and application | |
| CA2961956A1 (en) | Environment-controlling fibers, method manufacturing the same and fabrics using the same | |
| CN102579399A (en) | Preparation method of antibacterial Chinese mugwort oil microcapsules | |
| CN103239948A (en) | Air cleaning filter and method for manufacturing the same | |
| CN109200334A (en) | A kind of composite hydrogel dressing of optical dynamic therapy wound infection and preparation method thereof | |
| CN108301066A (en) | A kind of antibacterial polyester fibre | |
| CN102600493A (en) | Natural pullulan polysaccharide hydrogel wound dressing and preparation method thereof | |
| CN107333755A (en) | Hydrogel preparation method with the stranded structures of G tetra- and its application in staphylococcus aureus and Escherichia coli are killed | |
| CN106366214A (en) | Chitosan-quaternary-ammonium-salt antibacterial agent and antibacterial liquid, preparing technology of chitosan-quaternary-ammonium-salt antibacterial agent and preparing technology of chitosan-quaternary-ammonium-salt antibacterial liquid | |
| US20170167073A1 (en) | Antimicrobial textiles and methods for production of the same | |
| CN110528268A (en) | A kind of nanometer of light purification fabric and its manufacturing method | |
| CN101619539A (en) | Method for producing bacteria, fungus and virus resisting fiber | |
| CN102936353B (en) | Method for preparing high air tightness antibacterial reinforced membrane by using straws | |
| CN104784739A (en) | Preparation method of composite antibacterial dressing loaded with silver sulfadiazine | |
| CN103451914A (en) | Production method of antibacterial silk fabric | |
| CN102517668B (en) | Functional luffa regenerated fiber and preparation method thereof | |
| CN112281477A (en) | Preparation method of nano-silver pure cotton fabric with antibacterial function | |
| CN109875762A (en) | A kind of novel antibacterial adhesive bandage and the preparation method and application thereof | |
| CN108513987A (en) | Amine polymer-modified activated carbon of a kind of halogen for indoor sterilization and preparation method thereof | |
| CN104358123A (en) | Preparation method of propionyloxy ethyl trimethyl ammonium chloride chitosan fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191203 |