CN110528118A - It is a kind of fire prevention, sound-insulating and heat-insulating fabric - Google Patents
It is a kind of fire prevention, sound-insulating and heat-insulating fabric Download PDFInfo
- Publication number
- CN110528118A CN110528118A CN201910784534.0A CN201910784534A CN110528118A CN 110528118 A CN110528118 A CN 110528118A CN 201910784534 A CN201910784534 A CN 201910784534A CN 110528118 A CN110528118 A CN 110528118A
- Authority
- CN
- China
- Prior art keywords
- parts
- insulating
- sound
- fabric
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to textile fields, specifically related to a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, following component: 10-15 parts of epoxy resin, 20-40 parts of organic siliconresin, 30-90 parts of polysulphonamide fiber, 40-70 parts of aramid fiber, 10-20 parts of fumed silica, 3-7 parts of binder, 5-10 parts of softening agent, 4.5-12 parts of maleimide, 1-3 parts of surfactant is included at least.It is prepared by the present invention fire prevention, sound-insulating and heat-insulating fabric, not only flame retardant effect is significantly improved, moreover it is possible to effectively solve the problems, such as fabric easily drip, easy pilling, to significantly improve the comfort of fabric.
Description
Technical field
The present invention relates to textile fields, and in particular to a kind of fire prevention, sound-insulating and heat-insulating fabric.
Background technique
In people's lives environment, it is easy to cause fire due to various unexpected or fault, when fire occurs in people
When mouthful intensive and region of space relative narrowness such as megastore, hotel, public place of entertainment, school, residential building, people is just easily caused
The injury and loss of member's lives and properties.Textile is the necessity of people's daily life, and the fire as caused by textile is in recent years
To have the tendency that rising.According to statistics, about 20% or more fire incident is because caused by textile is not fire-retardant, because of textile
The ratio for the fire incident that fire or sprawling are formed is bigger.
Fire-entry suit is that protection is active in one of important equipment product of fire fighter's personal safety of fire-fighting First Line, it is not
It is only the indispensable necessary article of fire salvation scene, and the fire prevention apparatus that protection fire fighter's body escapes injury.Currently,
Fireproof garment or fire-entry suit are typically all to directly adopt flame-retardant yarn or cotton fabric and carry out flame-proof treatment and then be fabricated,
Common flame-proof fireproof facing material burns to human skin although extraneous flare can effectively be cut off, and general fire-fighting place is all
With high temperature, these temperature can be transmitted to the skin of human contact, Ke Nengzao by inflaming retarding fabric or fireproof facing material
Pairs of skin is burnt, or makes one body-sensing to uncomfortable to heavens.
Currently used inflaming retarding fabric is all directly to apply one layer of fire retardant, such garment surface on fabric body surface mostly
Although expecting that flame retardant property is good, in the case where using and wearing for a long time, fire retardant, which can fall off, leads to the fire-retardant of fabric
Performance is substantially reduced up to failure, in addition, the comfort level of fabric is not good enough due to having applied one layer of fire retardant, easy pilling.
Summary of the invention
To solve the above-mentioned problems, first aspect of the present invention provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, by weight
Number meter includes at least following component: 10-15 parts of epoxy resin, 20-40 parts of organic siliconresin, 30-90 parts of polysulphonamide fiber, virtue
40-70 parts of synthetic fibre fiber, 10-20 parts of fumed silica, 3-7 parts of binder, 5-10 parts of softening agent, maleimide 4.5-12
Part, 1-3 parts of surfactant.
As a kind of perferred technical scheme, the polysulphonamide fiber, epoxy resin mass ratio be (3-6): 1.
As a kind of perferred technical scheme, the epoxy resin is bisphenol-type epoxy resin.
As a kind of perferred technical scheme, the epoxide number of the bisphenol-type epoxy resin is 0.02-0.14mol/100g.
As a kind of perferred technical scheme, the softening agent, maleimide mass ratio be 1:(0.8-1.1).
As a kind of perferred technical scheme, the softening agent is organosiloxane.
As a kind of perferred technical scheme, the organosiloxane is epoxy silicones oxygen alkane.
As a kind of perferred technical scheme, the maleimide is N substituted maleimide amine.
As a kind of perferred technical scheme, the organic siliconresin is alkylaryl organic siliconresin.
The second aspect of the invention provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric preparation method, step are as follows: will be above-mentioned
Organic siliconresin, the epoxy resin of parts by weight are heated into molten condition, and polysulphonamide fiber, the aramid fiber for adding above-mentioned parts by weight are fine
Dimension, fumed silica, binder, softening agent, maleimide, surfactant and 2-6 parts by weight water mixture, after
It is continuous mix after squeezed out from spinneret, form fiber, after by fibrage to get the fabric.
The utility model has the advantages that the present invention provides a kind of fire prevention, sound-insulating and heat-insulating fabric, by using polysulphonamide fiber and bisphenol-A
Type epoxy resin, alkylaryl organic siliconresin, which is added, makes the flame retardant effect of fabric be significantly improved；And pass through epoxy group silicon
Oxygen alkane and maleimide interact, and not only further improve the flame retardant effect of fabric, moreover it is possible to effectively solve fabric and easily drip
Fall, easy pilling the problem of, to significantly improve the comfort of fabric.
Specific embodiment
It is further clear, complete that the technical characteristic work in technical solution is provided to the present invention With reference to embodiment
Description, not to the limitation of its protection scope.
Word " preferred " in the present invention etc. refers to that the present invention that can provide certain beneficial effects in some cases is real
Apply scheme.However, other embodiments are also likely to be preferred under identical circumstances or in the case of other.In addition, to one
Or the statement of multiple preferred embodiments does not imply that other embodiments are unavailable, is not intended to arrange other embodiments yet
In addition in the scope of the present invention.
In order to solve the above-mentioned technical problem, first aspect of the present invention provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, by weight
Number meter is measured, following component: 10-15 parts of epoxy resin, 20-40 parts of organic siliconresin, polysulphonamide fiber 30-90 is included at least
Part, 40-70 parts of aramid fiber, 10-20 parts of fumed silica, 3-7 parts of binder, 5-10 parts of softening agent, maleimide
4.5-12 parts, 1-3 parts of surfactant.
In a preferred embodiment, the fire prevention, sound-insulating and heat-insulating fabric include at least such as according to parts by weight
Lower component: 12 parts of epoxy resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, fumed silica 15
Part, 5 parts of binder, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant.
Epoxy resin
In the present invention, the epoxy resin refers to the total of the quasi polymer containing more than two epoxy groups in molecule
Claim.
In a preferred embodiment, the epoxy resin is bisphenol-type epoxy resin.
The bisphenol-type epoxy resin is bisphenol A type epoxy resin and/or bisphenol f type epoxy resin.
The bisphenol A type epoxy resin is in basic catalyst by bisphenol-A and epoxychloropropane (usually with NaOH) effect
Epoxy resin made of lower polycondensation.
The bisphenol F epoxy resin be reacted under acidic catalyst by phenol with formaldehyde generate Bisphenol F, then with epoxy chloropropionate
Alkane carries out epoxy resin made from polycondensation reaction in the presence of sodium hydroxide.
In a kind of preferred embodiment, the bisphenol-type epoxy resin is bisphenol A type epoxy resin.
The bisphenol A type epoxy resin, including but not limited to: bisphenol A type epoxy resin E-03, bisphenol A type epoxy resin
E-06, bisphenol A type epoxy resin E-12, bisphenol A type epoxy resin E-20, bisphenol A type epoxy resin E-35, bisphenol type epoxy
One of resin E-42, bisphenol A type epoxy resin E-44, bisphenol A type epoxy resin E-51, bisphenol A type epoxy resin E-55
Or it is a variety of.
In a kind of most preferred embodiment, the epoxide number of the bisphenol A type epoxy resin is 0.02-0.14mol/
100g。
The epoxide number is the amount of the substance of contained epoxy group in 100g epoxy resin.
The epoxide number is that the bisphenol A type epoxy resin of 0.02-0.14mol/100g can be selected from bisphenol A type epoxy resin
One of E-03, bisphenol A type epoxy resin E-06, bisphenol A type epoxy resin E-12 or a variety of.
From the point of view of currently preferred technical effect, the epoxy resin is preferably bisphenol A type epoxy resin E-06, model
For E-06 (607), epoxide number 0.04-0.07mol/100g is bought from bright and beautiful hundred million Biotechnology Co., Ltd in Hengyang.
Organic siliconresin
In the present invention, the organic siliconresin, also referred to as polysiloxanes are that one kind is alternately linked by silicon atom and oxygen atom
Form skeleton, the general designation for the polymer that different organic groups links with silicon atom again.
The organic siliconresin, including but not limited to, alkyl organic resin, aryl organic siliconresin and alkylaryl have
One of machine silicone resin is a variety of.
In a preferred embodiment, the organic siliconresin is alkylaryl organic siliconresin.
The alkylaryl organic siliconresin is that alkyl and aryl are directly connected on same silicon atom in synthesis,
The copolymer either generated in the method for alkyl and arylchlorosilane hydrolysis and cocondensation.
The alkylaryl organic siliconresin, including but not limited to, methylphenylsiloxane and/or propyl phenyl have
Machine silicone resin.
In a kind of preferred embodiment, the alkylaryl organic siliconresin is methylphenylsiloxane.
The methylphenylsiloxane, the trade mark that can be enumerated have: KR-112, KR-211, KR-212, KR-255,
KR-271、KR-272、KR-282、KR-300、KR-311、KR-2621-1、X-40-2667A、KR-480。
From the point of view of currently preferred technical effect, the organic siliconresin is preferably methylphenylsiloxane, board
It number is KR-2621-1, purchase is from Suzhou Jian Dao Electronics Co., Ltd., organosilicon first class agency, SHIN-ETSU HANTOTAI.
Alkylaryl organic siliconresin is used in the present invention, can be interted between the fibers containing aryl fragments, be reduced fiber
Internal regularity improves its flexibility, while anti-flammability equally improves, and inventor thinks that densification can be formed in burning due to it
Silicon carbon layer plays the role of preferably at charcoal, and dehydration forms stratiform silica at high temperature, completely cuts off the transmitting of heat and substance, from
And flame retardant effect is preferable, but discovery is easier to drip phenomenon occur under study for action.
Polysulphonamide fiber
In the present invention, the polysulphonamide fiber refers to that polyphenylsulfone terephthalamide fiber, abbreviation PSA fiber are a kind of
On high polymer main chain, contain sulfuryl (- SO2) aromatic polyamide fibre.
In a preferred embodiment, the polysulphonamide fiber, epoxy resin mass ratio be (3-6): 1.
In a preferred embodiment, the polysulphonamide fiber, epoxy resin mass ratio be 5:1.
From the point of view of currently preferred technical effect, the polysulphonamide fiber is preferably that specification is 278dtex/2, the twist
The polysulphonamide fiber of 220 ± 5 twirls/m, intensity 800-1200Cn is bought from Shanghai Tanlon Fibre Co., Ltd..
In the present invention together using polysulphonamide fiber and epoxy resin, weatherability is improved, and makes fabric that there is caking property.Hair
When using different epoxy resin, fire line is different for bright people's discovery, and is bisphenol-type epoxy resin, epoxide number when selecting epoxy resin
When bisphenol A type epoxy resin between 0.02-0.14mol/100g range, obtained fabric excellent heat stability is fire-retardant
Effect is good.Inventor is considered since epoxide number is in 0.02-0.14mol/100g in bisphenol A type epoxy resin, phenyl ring knot
Structure is easier and polysulphonamide fiber forms big pi-conjugated, and is further promoted and the crosslinking of aramid fiber, is restricted the deformation of its own
Ability, while the crystallization regularity of polysulphonamide fiber is destroyed to a certain extent, compatibility is improved while reducing thermal conductivity.
Furthermore inventor also found that by adjusting the ratio of above-mentioned polysulphonamide fiber and epoxy resin be (3-6): when 1, product items
It can improve, inventor is considered since system is in Blending Processes, and segment distance increases, and fumed silica can be used as bridge
Beam, the phenyl ring in polysulphonamide fiber and epoxy resin receive the lone pair electrons of fumed silica, will be apart from farther away PSA fiber
Fiber and epoxy resin conjugation connection, performance is more stable, improves flame retardant effect.
Aramid fiber
In the present invention, the aramid fiber, full name is poly- phenyl-diformyl phenylenediamine, and it is one that English, which is Aramid fiber,
The novel high-tech synthetic fibers of kind.
The aramid fiber includes p-aramid fiber Kevlar, Nomex fiber, Twaron fiber, Technora fiber, contraposition
One of aramid fiber II fiber, virtue III fiber, F-12 fiber are a variety of.
From the point of view of currently preferred technical effect, the aramid fiber is preferably Twaron 1020, fiber number 1680/
The aramid fiber of dtex, purchase is from Dongguan City Suo Weite distinct line with Co., Ltd.
Fumed silica
In the present invention, the fumed silica, also known as fume colloidal silica, molecular formula SiO2, white puff powder
Foam, porosity are a kind of important ultra tiny New Inorganic Materials of high-tech.
The fumed silica is hydrophilic fumed silica and/or hydrophobicity aerosil.
The hydrophilic fumed silica, the trade mark that can be enumerated have: Y150, Y200, Y300, Y380, LM-150, M-
5、EH-5、HL-150、HL-200、HL-200M、HL-300、HL-380、V15、V15P、N20、N20P、T30、T40、QS-102、
QS-20LS, QS-30, QS-40, Degussa-A380, Degussa A-200.
The hydrophobicity aerosil, the trade mark that can be enumerated have: HB-215, HB-612, HB-615, HB-620,
HB-630、HB-132、HB-135、HB-139。
From the point of view of currently preferred technical effect, the fumed silica is preferably hydrophilic fumed silica,
The trade mark is Degussa A-200, is bought from Ying Chuan company, Germany.
Binder
In the present invention, the binder, English name adhesive also known as adhesive are commonly called as " glue ".It is by two kinds of materials
Expect the substance to link together by the adherency and cohesive strength at interface, significant variation do not had to the structure of material to be bonded,
And cement plane is assigned with enough intensity.
The binder includes one of inorganic glue binder, organic bond or a variety of.
The inorganic glue binder be selected from silicate, phosphate, sulfate, borate, ceramics, zirconium oxide, aluminium oxide,
One of lead, tin are a variety of.
The organic bond includes one of natural organic bond, organic synthesis binder or a variety of.
The natural organic bond is selected from starch, soybean protein, casein, gelatine, fish glue, shellac, rosin, natural gum, wood
One of quality, natural rubber and latex, pitch are a variety of.
The organic synthesis binder is selected from one of thermosetting resin, thermoplastic resin, synthetic rubber, compound glue
Or it is a variety of.
From the point of view of actual effect of the invention, the binder is preferably cis- Isosorbide-5-Nitrae-polyisoprene, is bought from Maoming Shandong
Magnificent Chemical Co., Ltd..
Softening agent
In the present invention, the softening agent is a kind of quiet, dynamic friction coefficient chemical substance that can change fiber.
In a preferred embodiment, the softening agent is organosiloxane.
The organosiloxane, molecular formula are (R2SiO)x, it is the polymer that key containing Si-O-Si constitutes backbone structure, habit
Upper title organosilicon or poly(silicon aether) can be line style, ring-type or the polymer of crosslinking.
In the present invention, the organosiloxane is selected from amido organosilicon oxygen alkane, epoxy silicones oxygen alkane, carboxyl organosilicon
Oxygen alkane, alkyl organic siloxane, phenyl organosiloxane, acyloxy organosiloxane, vinylic organosiloxane, sulfydryl are organic
One of siloxanes is a variety of.
In a kind of preferred embodiment, the organosiloxane is epoxy silicones oxygen alkane.
The epoxy silicones oxygen alkane is selected from γ-glycidyl ether oxygen propyl trimethoxy silicane, 3- glycidol ether
Oxygroup propyl-triethoxysilicane, γ-glycidylpropyl methyl dimethoxysilane, 3- glycydoxy first
One of base diethoxy silicon, 2- (3,4- 7-oxa-bicyclo[4.1.0 base) ethyl trimethoxy silane are a variety of.
From the point of view of currently preferred technical effect, the softening agent is preferably γ-glycidyl ether oxygen propyl trimethoxy
Base silane, trade mark KH-560, purchase is from Nanjing Chemical Co., Ltd. forward.
Maleimide
In the present invention, the maleimide is reacted with potassium bichromate by pyrroles and is obtained, colorless needle crystals or have it is light
The thin slice of brown gloss.
In a preferred embodiment, the maleimide is N substituted maleimide amine.
The N substituted maleimide amine is selected from N, N '-ethylidene-bismaleimide, N, and N '-hexa-methylene-span comes
Acid imide, N, N '-(metaphenylene)-bismaleimide, N, N '-(to phenylene)-bismaleimide, N, N '-is (to methylene
Phenyl)-bismaleimide, N, N '-(methylene two-is to phenylene)-bismaleimide, N, (oxygen two-is to sub- benzene by N '-
Base)-bismaleimide, N- methylmaleimido, N- isopropylmaleimide, N- butyl maleimide, N- hexyl
Maleimide, N- octyl maleimide, N- dodecyl maleimide, N-phenylmaleimide, N- cyclohexyl Malaysia
Acid imide, N-2,3- xylyl maleimide, N-2,4- xylyl maleimide, N- carbamyl maleimide
One of or it is a variety of.
From the point of view of currently preferred technical effect, the maleimide is preferably N- carbamyl maleimide,
CAS:3345-50-4 is bought from Hubei Heng Jingrui Chemical Co., Ltd..
In a preferred embodiment, the softening agent, maleimide mass ratio be 1:(0.8-1.1).
In a kind of preferred embodiment, the softening agent, maleimide mass ratio be 1:0.9.
Polysulphonamide fiber, bisphenol-type epoxy resin, aramid fiber are used in the present invention, are reduced the flexibility of fabric, are adopted
It is handled with softening agent, and softening agent is epoxy radical siloxane, when using epoxy radical siloxane further as KH-560,
It is easy first to occur to answer with maleimide in system in mixed process, forms the maleimide of KH-560 grafting, work as KH-
560, it is 1:(0.8-1.1 that the mass ratio of maleimide, which is mass ratio) when, KH-560 can not only be physical crosslinking with fiber,
Itself can also be constantly crosslinked in subsequent mixed process, improve flexibility and the obvolvent of fabric to form a film in fiber surface
Power plays the role of anti pilling.Inventor has found in follow-up study, when fabric anti-flammability mentions significantly during high-temp combustion
Height, inventor speculate due in the present invention use N- carbamyl maleimide reacted with above-mentioned softening agent after in fiber surface
The hyperbranched siloxane structure of dimaleoyl imino sealing end easy to form, to contain a large amount of dimaleoyl imino in unit
Group, the selfreparing behavior in high temperature can further stop to completely cut off combustible with oxygen to inhibit to burn, and have preferable
It is acted at charcoal, effectively solves the drip phenomenon of esters of silicon acis.
Surfactant
In the present invention, the surfactant refers to that the interface state that can make its solution system on a small quantity, which is added, occurs obvious become
The substance of change.
In the present invention, there is no limit can be selected from castor oil, polyethenoxy ether class, alkanolamide with the surfactant
Class, alkyl phenol polyoxyethylene ether class, lauric acid polyoxyethylene ester, polyoxyethylene oleic acid ester, appointing in polyethylene glycol dioleic acid ester
It anticipates one or more mixing.
From the point of view of actual effect of the invention, the surfactant is preferably polysorbate60/polyoxyethylene sorbitol acid anhydride list
Stearate is bought from Nantong Feng Yuan Chemical Co., Ltd..
The second aspect of the invention provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric preparation method, step are as follows: will be above-mentioned
Organic siliconresin, the epoxy resin of parts by weight are heated into molten condition, and polysulphonamide fiber, the aramid fiber for adding above-mentioned parts by weight are fine
Dimension, fumed silica, binder, softening agent, maleimide, surfactant and 2-6 parts by weight water mixture, after
It is continuous mix after squeezed out from spinneret, form fiber, after by fibrage to get the fabric.
In a preferred embodiment, it is described fire prevention, sound-insulating and heat-insulating fabric preparation method, step are as follows: will be above-mentioned
Organic siliconresin, the epoxy resin of parts by weight are heated into molten condition, and polysulphonamide fiber, the aramid fiber for adding above-mentioned parts by weight are fine
Dimension, fumed silica, binder, softening agent, maleimide, surfactant and 4 parts by weight water mixture, continue
After mixing from injection diameter be 0.1mm spinneret in squeeze out, formed fiber, after by fibrage to get the fabric.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used
In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field
The some nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used to be all commercially available, it is purchased from traditional Chinese medicines chemical reagent.
Embodiment
Embodiment 1
Embodiment 1 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
10 parts of resin, 20 parts of organic siliconresin, 30 parts of polysulphonamide fiber, 40 parts of aramid fiber, 10 parts of fumed silica, binder 3
Part, 5 parts of softening agent, 4.5 parts of maleimide, 1 part of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, sound-insulating and heat-insulating fabric preparation method, step are as follows: by the organic siliconresin of above-mentioned parts by weight, epoxy
Resin is heated into molten condition, add the polysulphonamide fibers of above-mentioned parts by weight, aramid fiber, fumed silica, binder,
Softening agent, maleimide, surfactant and 4 parts by weight water mixture, continue after mixing from injection diameter to be 0.1mm
Spinneret in squeeze out, formed fiber, after by fibrage to get the fabric.
Embodiment 2
Embodiment 2 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
15 parts of resin, 40 parts of organic siliconresin, 90 parts of polysulphonamide fiber, 70 parts of aramid fiber, 20 parts of fumed silica, binder 7
Part, 10 parts of softening agent, 12 parts of maleimide, 3 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 3
Embodiment 3 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
12 parts of resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder 5
Part, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 4
Embodiment 4 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
2 parts of resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder 5
Part, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 5
Embodiment 5 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
60 parts of resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder 5
Part, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 6
Embodiment 6 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
12 parts of resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder 5
Part, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-51 (618), epoxide number 0.48-0.54mol/100g, purchase
From Xi'an Xing Hua Chemical Group Co., Ltd；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 7
Embodiment 7 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
12 parts of resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder 5
Part, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is vinyl cyclohexene dioxide, CAS:106-87-6, purchase biotechnology from upper lake
Co., Ltd；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 8
Embodiment 8 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
12 parts of resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder 5
Part, 1 part of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 9
Embodiment 9 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: epoxy
12 parts of resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder 5
Part, 30 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 10
Embodiment 10 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: ring
12 parts of oxygen resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder
5 parts, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is methyltrimethoxysilane, and purchase reaches Zhong Cheng Science and Technology Ltd. from Qingdao perseverance；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 11
Embodiment 11 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: ring
12 parts of oxygen resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder
5 parts, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is bis- (dimaleoyl imino) butane of Isosorbide-5-Nitrae-, and CAS:28537-70-4 buys from Shanghai and discriminates
Quasi- Biotechnology Co., Ltd；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 12
Embodiment 12 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: ring
12 parts of oxygen resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder
5 parts, 7.5 parts of softening agent, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylsiloxane resin, and trade mark KR-220LP is bought from organosilicon first-level agent, SHIN-ETSU HANTOTAI
Quotient Suzhou Jian Dao Electronics Co., Ltd.；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 13
Embodiment 13 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: ring
12 parts of oxygen resin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, 5 parts of binder, softening agent 7.5
Part, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 14
Embodiment 14 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: ring
12 parts of oxygen resin, 30 parts of organic siliconresin, 55 parts of aramid fiber, 15 parts of fumed silica, 5 parts of binder, softening agent 7.5
Part, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 15
Embodiment 15 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: ring
12 parts of oxygen resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder
5 parts, 8.2 parts of maleimide, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 16
Embodiment 16 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: ring
12 parts of oxygen resin, 30 parts of organic siliconresin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, binder
5 parts, 7.5 parts of softening agent, 2 parts of surfactant；
The epoxy resin is bisphenol A type epoxy resin E-06 (607), epoxide number 0.04-0.07mol/100g；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Embodiment 17
Embodiment 17 provide it is a kind of fire prevention, sound-insulating and heat-insulating fabric, according to parts by weight, include at least following component: have
30 parts of machine silicone resin, 60 parts of polysulphonamide fiber, 55 parts of aramid fiber, 15 parts of fumed silica, 5 parts of binder, softening agent 7.5
Part, 8.2 parts of maleimide, 2 parts of surfactant；
The organic siliconresin is methylphenylsiloxane, trade mark KR-2621-1；
The specification of the polysulphonamide fiber is 278dtex/2,220 ± 5 twirls of the twist/m, intensity 800-1200Cn；
The aramid fiber is Twaron 1020, fiber number 1680/dtex；
The fumed silica is hydrophilic fumed silica, and the trade mark is Degussa A-200；
The binder is cis- 1,4- polyisoprene；
The softening agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, trade mark KH-560；
The maleimide is N- carbamyl maleimide；
The surfactant is polysorbate60/polyoxyethylene sorbitan monostearate.
It is a kind of fire prevention, the preparation method is the same as that of Example 1 for sound-insulating and heat-insulating fabric.
Performance evaluation:
1. anti-flammability: using HC900-2 type oxygen index measurer, referring to GB/T 5545-1997 standard, measure embodiment
The limit oxygen index of fabric sample；Using LFY-601 type normal beam technique flame retardant property tester, " spun referring to GB/T 5455-2014
The measurement that fabric combustibility vertical direction char length, is glowed with after flame time " standard, measurement fabric after flame time glows
Time, drippage situation.
2. flexibility: embodiment fabric being put in water, control water temperature is 27 DEG C, persistently washes 4min, continuously washs 10
It is secondary, 7min is then dried at 90 DEG C, evaluates flexibility.
3. pilling is tested: using YG502 type fabric lousiness pilling instrument, every piece of fabric takes three pieces of samples, first fluffs and rise afterwards
Ball, Rubbing number are 50, according to GB/T4802.1-1997, evaluate pilling grade.
1 the performance test results of table
As can be seen from Table 1, the fire prevention in the present invention, sound-insulating and heat-insulating fabric, when not only there is high oxygen index (OI), low afterflame
Between, low smoldering time, and phenomenon without dripping off also has excellent washing feel, flexibility good, while also can effectively solve easily
Pilling problem is conducive to the wearing comfort for improving fireproof garment or fire-entry suit, this has the application in fireproof facing material
Very important influence.
Example above-mentioned is merely illustrative, and is used to explain the present invention some features of the method.Appended right is wanted
The range as wide as possible for being intended to require to be contemplated that is sought, and embodiments as presented herein is only according to all possible implementation
The explanation of the embodiment of the combined selection of example.Therefore, the purpose of applicant is that the attached claims are not illustrated this hair
The exemplary selectional restriction of bright feature.Some numberical ranges used also include sub- model in the claims
It encloses, the variation in these ranges should also be construed to be covered by the attached claims in the conceived case.
Claims (10)
1. a kind of fire prevention, sound-insulating and heat-insulating fabric, which is characterized in that according to parts by weight, include at least following component: epoxy resin
10-15 parts, 20-40 parts of organic siliconresin, 30-90 parts of polysulphonamide fiber, 40-70 parts of aramid fiber, fumed silica 10-20
Part, 3-7 parts of binder, 5-10 parts of softening agent, 4.5-12 parts of maleimide, 1-3 parts of surfactant.
2. fire prevention according to claim 1, sound-insulating and heat-insulating fabric, which is characterized in that the polysulphonamide fiber, epoxy resin
Mass ratio be (3-6): 1.
3. fire prevention according to claim 1, sound-insulating and heat-insulating fabric, which is characterized in that the epoxy resin is bis-phenol type ring
Oxygen resin.
4. fire prevention according to claim 3, sound-insulating and heat-insulating fabric, which is characterized in that the ring of the bisphenol-type epoxy resin
Oxygen value is 0.02-0.14mol/100g.
5. fire prevention according to claim 1, sound-insulating and heat-insulating fabric, which is characterized in that the softening agent, maleimide
Mass ratio is 1:(0.8-1.1).
6. fire prevention according to claim 1, sound-insulating and heat-insulating fabric, which is characterized in that the softening agent is organosiloxane.
7. fire prevention according to claim 6, sound-insulating and heat-insulating fabric, which is characterized in that the organosiloxane is epoxy group
Organosiloxane.
8. fire prevention according to claim 1, sound-insulating and heat-insulating fabric, which is characterized in that the maleimide is that N replaces horse
Carry out acid imide.
9. fire prevention according to claim 1-8, sound-insulating and heat-insulating fabric, which is characterized in that the organic siliconresin
For alkylaryl organic siliconresin.
10. the preparation method of a kind of -9 described in any item fire prevention according to claim 1, sound-insulating and heat-insulating fabric, which is characterized in that
Step are as follows: the organic siliconresin of above-mentioned parts by weight, epoxy resin are heated into molten condition, add the fragrant sulfone of above-mentioned parts by weight
Synthetic fibre fiber, aramid fiber, fumed silica, binder, softening agent, maleimide, surfactant and 2-6 parts by weight
The mixture of water, continue mix after squeezed out from spinneret, formed fiber, after by fibrage to get the fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910784534.0A CN110528118A (en) | 2019-08-23 | 2019-08-23 | It is a kind of fire prevention, sound-insulating and heat-insulating fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910784534.0A CN110528118A (en) | 2019-08-23 | 2019-08-23 | It is a kind of fire prevention, sound-insulating and heat-insulating fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110528118A true CN110528118A (en) | 2019-12-03 |
Family
ID=68664132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910784534.0A Withdrawn CN110528118A (en) | 2019-08-23 | 2019-08-23 | It is a kind of fire prevention, sound-insulating and heat-insulating fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110528118A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105113044A (en) * | 2015-09-15 | 2015-12-02 | 苏州顺唐化纤有限公司 | Inflaming-retarding polyamide fiber preparing method |
| CN106916413A (en) * | 2015-12-24 | 2017-07-04 | 比亚迪股份有限公司 | A kind of composition epoxy resin and preparation method thereof, fiber resin composite material, aluminium/fiber/resin composite |
| CN106977772A (en) * | 2017-04-19 | 2017-07-25 | 马志明 | Fire-type textile material for fire-fighting operation and preparation method thereof |
| CN107142552A (en) * | 2017-07-03 | 2017-09-08 | 苏州市丹纺纺织研发有限公司 | A kind of waterproof composite textile materials and preparation method thereof |
| CN107805854A (en) * | 2017-11-27 | 2018-03-16 | 福州市晋安区技智企业管理咨询有限公司 | A kind of preparation method of graphene fire-retardant polyamide fibre fiber |
| CN108823991A (en) * | 2018-07-11 | 2018-11-16 | 周华 | A kind of vapor-permeable type arc resistant fabric and preparation method thereof |
-
2019
- 2019-08-23 CN CN201910784534.0A patent/CN110528118A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105113044A (en) * | 2015-09-15 | 2015-12-02 | 苏州顺唐化纤有限公司 | Inflaming-retarding polyamide fiber preparing method |
| CN106916413A (en) * | 2015-12-24 | 2017-07-04 | 比亚迪股份有限公司 | A kind of composition epoxy resin and preparation method thereof, fiber resin composite material, aluminium/fiber/resin composite |
| CN106977772A (en) * | 2017-04-19 | 2017-07-25 | 马志明 | Fire-type textile material for fire-fighting operation and preparation method thereof |
| CN107142552A (en) * | 2017-07-03 | 2017-09-08 | 苏州市丹纺纺织研发有限公司 | A kind of waterproof composite textile materials and preparation method thereof |
| CN107805854A (en) * | 2017-11-27 | 2018-03-16 | 福州市晋安区技智企业管理咨询有限公司 | A kind of preparation method of graphene fire-retardant polyamide fibre fiber |
| CN108823991A (en) * | 2018-07-11 | 2018-11-16 | 周华 | A kind of vapor-permeable type arc resistant fabric and preparation method thereof |
Non-Patent Citations (6)
| Title |
|---|
| 张书华等: "《高性能电缆材料及其应用技术》", 30 November 2015, 上海交通大学出版社 * |
| 张祥麟: "《无机化学（下册）》", 30 September 1983, 湖南教育出版社 * |
| 杨东武等: "《塑料材料选用技术》", 31 January 2008, 中国轻工业出版社 * |
| 瞿金平等: "《物料工业手册 注塑、模压工艺与设备》", 30 October 2001, 化学工业出版社 * |
| 金碚等: "《新材料产业现状与发展前景》", 31 May 2015, 广东经济出版社 * |
| 闫承花: "《化学纤维生产工艺学》", 31 January 2018, 东华大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| He et al. | Preparation and flame retardancy of reactive flame retardant for cotton fabric | |
| CN103614951A (en) | Flame-retardant wallpaper base paper and preparation method thereof | |
| CN106189608A (en) | Water-soluble flame retardant and application thereof | |
| CN106400235B (en) | Organic silazane system fire resistance fibre is blended with organic phosphorus fire resistance fibre | |
| CN107936303A (en) | A kind of microcapsule-type fire retardant and preparation method thereof | |
| CN102061615A (en) | Anti-creasing softener | |
| CN110558646A (en) | Fireproof suit based on silicon dioxide aerogel composite material and preparation method | |
| CN109320772A (en) | A kind of anti-dripping agent and preparation method thereof containing organosilicon and inorganic silicon | |
| KR101302974B1 (en) | Method for manufacturing fire-retardant fabric and the fire-retardant fabric used manufacturing fire cloth | |
| CN105780175B (en) | A kind of flame retardant viscose fiber and preparation method thereof | |
| CN106009857A (en) | Flame retardation and antibiosis fabric | |
| CN110528118A (en) | It is a kind of fire prevention, sound-insulating and heat-insulating fabric | |
| CN105401444B (en) | A kind of finish and its application as carbon fiber production auxiliary agent | |
| CN114645453B (en) | Durable flame-retardant protein fiber product and preparation method thereof | |
| JP4043358B2 (en) | Heat resistant fabric | |
| CN114318589A (en) | High-flame-retardant superfine sea island filament and preparation process thereof | |
| CN109868657A (en) | A kind of preparation method of flame-proof abrasion-resistant curtain | |
| CN109306169A (en) | A kind of hydridization organic matter and the organic silicon fibre retardant of nano silica and preparation method thereof | |
| CN101381959B (en) | Method for producing flame-retardant silk | |
| CN109233160A (en) | A kind of organic silicon fibre retardant and preparation method thereof containing PTFE and nano silica | |
| CN101544761A (en) | Flame-proof organosilicon polymer, a method for manufacturing the same and a method for preparing an emulsion of the polymer | |
| CN108749181A (en) | A kind of tencel product with flame retarding function | |
| CN108660586A (en) | Wash resistant is without melting the fire-retardant curtain of drop and its processing method | |
| CN114990877A (en) | Novel flame-retardant composite material for protective clothing and preparation method and application thereof | |
| TW589338B (en) | Fire-resistant resin compounds |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20191203 |
|
| WW01 | Invention patent application withdrawn after publication |