CN110527340A - A kind of traditional Chinese Painting magnetic paint and preparation method thereof - Google Patents
A kind of traditional Chinese Painting magnetic paint and preparation method thereof Download PDFInfo
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- CN110527340A CN110527340A CN201910653219.4A CN201910653219A CN110527340A CN 110527340 A CN110527340 A CN 110527340A CN 201910653219 A CN201910653219 A CN 201910653219A CN 110527340 A CN110527340 A CN 110527340A
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- calcium carbonate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/23—Magnetisable or magnetic paints or lacquers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of preparation methods of traditional Chinese Painting magnetic paint, comprising the following steps: the preparation of S1. porous calcium carbonate；S2. the preparation of calcium carbonate carried titanium dioxide；S3. the preparation of magnetic material intermediate；S4. calcium carbonate-titanium dioxide-magnetic material preparation；S5. the preparation of magnetic paint.The object of the present invention is to provide a kind of traditional Chinese Painting magnetic paints and preparation method thereof, and pigment itself has magnetism, are magnetic iron plate by drawing board planar design, when drawing or after drawing, paintings can be directly anchored on magnetic iron plate.
Description
Technical field
The present invention relates to fields of pigments, and in particular to a kind of traditional Chinese Painting magnetic paint and preparation method thereof.
Background technique
Drawing is by the process of visual movement materialization.In face of natural landscape, it is desirable that painter is good at promoting the impression of oneself,
It is good at selecting a variety of different materials, using different expression means, expresses that the experience of soul fully.Thus, In
The characteristic of painting material and its unique visual appeal in works are not allowed in creation and enjoying art works
Ignore, expressive force of the painting material in drawing, usually becomes the striking point of visual language exchange.
The one kind of Chinese painting as China's traditional drawing art has a long history and unique style.And watercolor
And the wests such as oil painting drawing is compared, no matter in the technique of expression or on painting tool, Chinese painting suffers from oneself uniqueness
One side.In the past when drawing a picture, the common paperweight of artists is pressing against drawing paper and is drawing a picture, but this paperweight often in the horizontal plane could
Delivery effect, when if it is drawing a picture in certain tilt angle or vertical plane, paperweight cannot play one and fix well
It acts on.
Summary of the invention
Technical problems to be solved: the object of the present invention is to provide a kind of traditional Chinese Painting magnetic paint and preparation method thereof, face
Material has magnetism in itself, is magnetic iron plate by drawing board planar design, when drawing or after drawing, paintings can be directly anchored to magnetic
It inhales on iron plate.
A kind of technical solution: preparation method of traditional Chinese Painting magnetic paint, comprising the following steps:
S1. the preparation of porous calcium carbonate: in Ca (NO3)2In solution, kayexalate, stirring and dissolving, in ultrasound is added
Under the ultrasound of wave biomixer, the Na of isometric isoconcentration is added into mixed solution2CO3Solution, after continuing ultrasound, in room
Temperature is lower to be stood, and washing and drying obtains porous calcium titanate F1；
S2. the preparation of calcium carbonate carried titanium dioxide: the step S1 F1 prepared is placed in filter device, then in calcium carbonate
It is middle to instill the ethanol solution for being dissolved with butyl titanate, so that calcium carbonate surface is adsorbed butyl titanate, four fourth of metatitanic acid will have been adsorbed
The calcium carbonate of ester is put into steam, is made tetrabutyl titanate hydrolysis at titanium hydroxide, is obtained compound F2；
S3. the preparation of magnetic material intermediate: compound F2 is configured to suspension, suspension is placed in water bath with thermostatic control, In
Ferrous ions soln is added in suspension, intermediate F3 is obtained by filtration in heating stirring；
S4. calcium carbonate-titanium dioxide-magnetic material preparation: the intermediate F3 that step S3 is prepared is calcined, and obtains carbon
Sour calcium-titanium dioxide-magnetic material；
S5. the preparation of magnetic paint: calcium carbonate-titanium dioxide-magnetic material and dispersing agent is added in ball grinder, grinding is added
Medium zirconium pearl and deionized water carry out ball milling, continuously add odium stearate, sodium sulfate of polyethenoxy ether of fatty alcohol, pigment, carboxylic first
Base cellulose, polyvinylpyrrolidone and preservative are uniformly mixed, and grinder is added in uniformly mixed mixture and is ground repeatedly
Obtain traditional Chinese Painting magnetic paint.
Further, the power of ultrasonic cell-break machine is 600-800W in step S1, and drying temperature is no more than 100
℃。
Further, the solution of step S3 ferrous ions is ferric nitrate, appointing in frerrous chloride or ferrous sulfate solution
It anticipates one kind.
Further, calcination temperature is 600-700 DEG C in step S4, calcination time 5-15min.
Further, dispersing agent is fatty acid cane sugar ester, sorbitan trioleate or maleic anhydride-vinegar in step S5
Any one in vinyl acetate copolymer.
Further, Ball-milling Time is 3-5 h in step S5, and abrasive media is 2 mm of diameter and 0.5 mm zirconium pearl, matter
Amount is than being 2:1.
A kind of traditional Chinese Painting magnetic paint that above-mentioned preparation method obtains.
The utility model has the advantages that being detected using magnetism of the portable magnetic detector to pigment.Using the instrument to the present invention
In sample detected, detect that the magnetic signal strength of sample is more strong, have good magnetic effect；Using simultaneously should
Kind pigment is painted, and after pigment air-dries, paintings can be good at being adsorbed in magnetic iron plate due to containing magnetic particle in pigment
Surface.
Specific embodiment
Embodiment 1
A kind of preparation method of traditional Chinese Painting magnetic paint, comprising the following steps:
S1. the preparation of porous calcium carbonate: in Ca (NO3)2In solution, kayexalate, stirring and dissolving, in ultrasound is added
Under the ultrasound of wave biomixer, the Na of isometric isoconcentration is added into mixed solution2CO3Solution, after continuing ultrasound, power
It for 600W, stands at room temperature, washing and drying, drying temperature is 90 DEG C, obtains porous calcium titanate F1；
S2. the preparation of calcium carbonate carried titanium dioxide: the step S1 F1 prepared is placed in filter device, then in calcium carbonate
It is middle to instill the ethanol solution for being dissolved with butyl titanate, so that calcium carbonate surface is adsorbed butyl titanate, four fourth of metatitanic acid will have been adsorbed
The calcium carbonate of ester is put into steam, is made tetrabutyl titanate hydrolysis at titanium hydroxide, is obtained compound F2；
S3. the preparation of magnetic material intermediate: compound F2 is configured to suspension, suspension is placed in water bath with thermostatic control, In
Ferrous sulfate solution is added in suspension, intermediate F3 is obtained by filtration in heating stirring；
S4. calcium carbonate-titanium dioxide-magnetic material preparation: the intermediate F3 that step S3 is prepared is calcined, calcining temperature
Degree is 600 DEG C, calcination time 15min, obtains calcium carbonate-titanium dioxide-magnetic material；
S5. calcium carbonate-titanium dioxide-magnetic material and maleic anhydride-acetic acid second the preparation of magnetic paint: is added in ball grinder
Abrasive media zirconium pearl and deionized water is added in enoate copolymer, carries out ball milling, and Ball-milling Time is 3 h, and abrasive media is diameter 2
Mm and 0.5mm zirconium pearl, mass ratio 2:1 continuously add odium stearate, sodium sulfate of polyethenoxy ether of fatty alcohol, pigment, carboxylic first
Base cellulose, polyvinylpyrrolidone and preservative are uniformly mixed, and grinder is added in uniformly mixed mixture and is ground repeatedly
Obtain traditional Chinese Painting magnetic paint.
Embodiment 2
A kind of preparation method of traditional Chinese Painting magnetic paint, comprising the following steps:
S1. the preparation of porous calcium carbonate: in Ca (NO3)2In solution, kayexalate, stirring and dissolving, in ultrasound is added
Under the ultrasound of wave biomixer, the Na of isometric isoconcentration is added into mixed solution2CO3Solution, after continuing ultrasound, power
It for 800W, stands at room temperature, washing and drying, drying temperature is 80 DEG C, obtains porous calcium titanate F1；
S2. the preparation of calcium carbonate carried titanium dioxide: the step S1 F1 prepared is placed in filter device, then in calcium carbonate
It is middle to instill the ethanol solution for being dissolved with butyl titanate, so that calcium carbonate surface is adsorbed butyl titanate, four fourth of metatitanic acid will have been adsorbed
The calcium carbonate of ester is put into steam, is made tetrabutyl titanate hydrolysis at titanium hydroxide, is obtained compound F2；
S3. the preparation of magnetic material intermediate: compound F2 is configured to suspension, suspension is placed in water bath with thermostatic control, In
Iron nitrate solution is added in suspension, intermediate F3 is obtained by filtration in heating stirring；
S4. calcium carbonate-titanium dioxide-magnetic material preparation: the intermediate F3 that step S3 is prepared is calcined, calcining temperature
Degree is 700 DEG C, calcination time 5min, obtains calcium carbonate-titanium dioxide-magnetic material；
S5. the preparation of magnetic paint: calcium carbonate-titanium dioxide-magnetic material and fatty acid cane sugar ester is added in ball grinder, adds
Enter abrasive media zirconium pearl and deionized water, carry out ball milling, Ball-milling Time is 5 h, and abrasive media is 2 mm and 0.5mm zirconium of diameter
Pearl, mass ratio 2:1 continuously add odium stearate, sodium sulfate of polyethenoxy ether of fatty alcohol, pigment, carboxymethyl cellulose, gather
Vinylpyrrolidone and preservative are uniformly mixed, and uniformly mixed mixture addition grinder is ground repeatedly and obtains traditional Chinese Painting magnetic
Property pigment.
Embodiment 3
A kind of preparation method of traditional Chinese Painting magnetic paint, comprising the following steps:
S1. the preparation of porous calcium carbonate: in Ca (NO3)2In solution, kayexalate, stirring and dissolving, in ultrasound is added
Under the ultrasound of wave biomixer, the Na of isometric isoconcentration is added into mixed solution2CO3Solution, after continuing ultrasound, power
It for 650W, stands at room temperature, washing and drying, drying temperature is 95 DEG C, obtains porous calcium titanate F1；
S2. the preparation of calcium carbonate carried titanium dioxide: the step S1 F1 prepared is placed in filter device, then in calcium carbonate
It is middle to instill the ethanol solution for being dissolved with butyl titanate, so that calcium carbonate surface is adsorbed butyl titanate, four fourth of metatitanic acid will have been adsorbed
The calcium carbonate of ester is put into steam, is made tetrabutyl titanate hydrolysis at titanium hydroxide, is obtained compound F2；
S3. the preparation of magnetic material intermediate: compound F2 is configured to suspension, suspension is placed in water bath with thermostatic control, In
Iron nitrate solution is added in suspension, intermediate F3 is obtained by filtration in heating stirring；
S4. calcium carbonate-titanium dioxide-magnetic material preparation: the intermediate F3 that step S3 is prepared is calcined, calcining temperature
Degree is 640 DEG C, calcination time 12min, obtains calcium carbonate-titanium dioxide-magnetic material；
S5. calcium carbonate-titanium dioxide-magnetic material and three oleic acid of anhydrous sorbitol the preparation of magnetic paint: is added in ball grinder
Abrasive media zirconium pearl and deionized water is added in ester, carries out ball milling, and Ball-milling Time is 4 h, and abrasive media is diameter 2 mm and 0.5
Mm zirconium pearl, mass ratio 2:1 continuously add odium stearate, sodium sulfate of polyethenoxy ether of fatty alcohol, pigment, carboxymethyl cellulose
Element, polyvinylpyrrolidone and preservative are uniformly mixed, and uniformly mixed mixture addition grinder is ground repeatedly and obtains state
Picture magnetic paint.
Embodiment 4
A kind of preparation method of traditional Chinese Painting magnetic paint, comprising the following steps:
S1. the preparation of porous calcium carbonate: in Ca (NO3)2In solution, kayexalate, stirring and dissolving, in ultrasound is added
Under the ultrasound of wave biomixer, the Na of isometric isoconcentration is added into mixed solution2CO3Solution, after continuing ultrasound, power
It for 760W, stands at room temperature, washing and drying, drying temperature is 90 DEG C, obtains porous calcium titanate F1；
S2. the preparation of calcium carbonate carried titanium dioxide: the step S1 F1 prepared is placed in filter device, then in calcium carbonate
It is middle to instill the ethanol solution for being dissolved with butyl titanate, so that calcium carbonate surface is adsorbed butyl titanate, four fourth of metatitanic acid will have been adsorbed
The calcium carbonate of ester is put into steam, is made tetrabutyl titanate hydrolysis at titanium hydroxide, is obtained compound F2；
S3. the preparation of magnetic material intermediate: compound F2 is configured to suspension, suspension is placed in water bath with thermostatic control, In
Solution of ferrous chloride is added in suspension, intermediate F3 is obtained by filtration in heating stirring；
S4. calcium carbonate-titanium dioxide-magnetic material preparation: the intermediate F3 that step S3 is prepared is calcined, calcining temperature
Degree is 660 DEG C, calcination time 8min, obtains calcium carbonate-titanium dioxide-magnetic material；
S5. calcium carbonate-titanium dioxide-magnetic material and maleic anhydride-acetic acid second the preparation of magnetic paint: is added in ball grinder
Abrasive media zirconium pearl and deionized water is added in enoate copolymer, carries out ball milling, and Ball-milling Time is 3 h, and abrasive media is diameter 2
Mm and 0.5 mm zirconium pearl, mass ratio 2:1 continuously add odium stearate, sodium sulfate of polyethenoxy ether of fatty alcohol, pigment, carboxylic
Methylcellulose, polyvinylpyrrolidone and preservative are uniformly mixed, and grinder is added in uniformly mixed mixture and is ground repeatedly
Mill obtains traditional Chinese Painting magnetic paint.
Table one is the weight ratio of each ingredient in embodiment 1-4
The magnetism of pigment is detected using portable magnetic detector in pigment of the embodiment of the present invention.Since the model detects
Instrument magnetic head is sensitive, and strong interference immunity.As long as magnetic head finds that magnetic signal, the mini-detector will issue continuously when test
" serge serge " voice prompt.Sample is detected using the instrument, detects that the magnetic signal strength of sample is more strong, is had very
Good magnetic effect；It is painted simultaneously using this kind of pigment, after pigment air-dries, paintings are due to containing magnetic particle energy in pigment
Enough surfaces for being adsorbed in magnetic iron plate well.
Claims (7)
1. a kind of preparation method of traditional Chinese Painting magnetic paint, which comprises the following steps:
S1. the preparation of porous calcium carbonate: in Ca (NO3)2In solution, kayexalate, stirring and dissolving, in ultrasound is added
Under the ultrasound of wave biomixer, the Na of isometric isoconcentration is added into mixed solution2CO3Solution, after continuing ultrasound, in room
Temperature is lower to be stood, and washing and drying obtains porous calcium titanate F1；
S2. the preparation of calcium carbonate carried titanium dioxide: the step S1 F1 prepared is placed in filter device, then in calcium carbonate
It is middle to instill the ethanol solution for being dissolved with butyl titanate, so that calcium carbonate surface is adsorbed butyl titanate, four fourth of metatitanic acid will have been adsorbed
The calcium carbonate of ester is put into steam, is made tetrabutyl titanate hydrolysis at titanium hydroxide, is obtained compound F2；
S3. the preparation of magnetic material intermediate: compound F2 is configured to suspension, suspension is placed in water bath with thermostatic control, In
Ferrous ions soln is added in suspension, intermediate F3 is obtained by filtration in heating stirring；
S4. calcium carbonate-titanium dioxide-magnetic material preparation: the intermediate F3 that step S3 is prepared is calcined, and obtains carbon
Sour calcium-titanium dioxide-magnetic material；
S5. the preparation of magnetic paint: calcium carbonate-titanium dioxide-magnetic material and dispersing agent is added in ball grinder, grinding is added
Medium zirconium pearl and deionized water carry out ball milling, continuously add odium stearate, sodium sulfate of polyethenoxy ether of fatty alcohol, pigment, carboxylic first
Base cellulose, polyvinylpyrrolidone and preservative are uniformly mixed, and grinder is added in uniformly mixed mixture and is ground repeatedly
Obtain traditional Chinese Painting magnetic paint.
2. a kind of preparation method of traditional Chinese Painting magnetic paint according to claim 1, it is characterised in that: ultrasonic in step S1
The power of wave biomixer is 600-800W, and drying temperature is no more than 100 DEG C.
3. a kind of preparation method of traditional Chinese Painting magnetic paint according to claim 1, it is characterised in that: ferrous in step S3
The solution of ion is ferric nitrate, any one in frerrous chloride or ferrous sulfate solution.
4. a kind of preparation method of traditional Chinese Painting magnetic paint according to claim 1, it is characterised in that: calcined in step S4
Temperature is 600-700 DEG C, calcination time 5-15min.
5. a kind of preparation method of traditional Chinese Painting magnetic paint according to claim 1, it is characterised in that: disperse in step S5
Agent is fatty acid cane sugar ester, any one in sorbitan trioleate or maleic anhydride vinyl acetate copolymer.
6. a kind of preparation method of traditional Chinese Painting magnetic paint according to claim 1, it is characterised in that: ball milling in step S5
Time is 3-5 h, and abrasive media is 2 mm of diameter and 0.5 mm zirconium pearl, mass ratio 2:1.
7. a kind of traditional Chinese Painting magnetic paint that the preparation method as described in claim 1-6 obtains.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910653219.4A CN110527340A (en) | 2019-07-19 | 2019-07-19 | A kind of traditional Chinese Painting magnetic paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910653219.4A CN110527340A (en) | 2019-07-19 | 2019-07-19 | A kind of traditional Chinese Painting magnetic paint and preparation method thereof |
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| CN110527340A true CN110527340A (en) | 2019-12-03 |
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| US20080182130A1 (en) * | 2007-01-26 | 2008-07-31 | Hung-Chih Wu | Magnet structure with colorable surface and a method for manufacturing the magnet |
| CN101256872A (en) * | 2007-02-09 | 2008-09-03 | 吴泓志 | Magnet with surface capable of coloring and manufacturing method thereof |
| CN103849178A (en) * | 2012-11-29 | 2014-06-11 | 陈永煌 | High-density pearlescent pigment |
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| CN104530772A (en) * | 2014-12-22 | 2015-04-22 | 常熟市环虹化工颜料厂 | Composite pigment and preparation method thereof |
| CN106700699A (en) * | 2016-12-14 | 2017-05-24 | 四川熹玥广告传媒有限公司 | Water-based pigment and preparation method of water-based pigment |
| CN106752222A (en) * | 2017-01-24 | 2017-05-31 | 中国地质大学（武汉） | A kind of magnetic paint and its production and use |
| CN109135347A (en) * | 2018-09-07 | 2019-01-04 | 成都新柯力化工科技有限公司 | A kind of microspheroidal composite titanium dioxide and preparation method for coating |
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2019
- 2019-07-19 CN CN201910653219.4A patent/CN110527340A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1803938A (en) * | 2005-01-10 | 2006-07-19 | 北京化工大学 | TiO2/CaCO3 nano composite particle, hollow TiO2 nano material and method for preparing the same |
| US20080182130A1 (en) * | 2007-01-26 | 2008-07-31 | Hung-Chih Wu | Magnet structure with colorable surface and a method for manufacturing the magnet |
| CN101256872A (en) * | 2007-02-09 | 2008-09-03 | 吴泓志 | Magnet with surface capable of coloring and manufacturing method thereof |
| CN103849178A (en) * | 2012-11-29 | 2014-06-11 | 陈永煌 | High-density pearlescent pigment |
| CN104292886A (en) * | 2014-10-01 | 2015-01-21 | 湖南磊鑫新材料科技有限公司 | Method for preparing titanium dioxide-coated ground calcium carbonate powdered inorganic filler |
| CN104530772A (en) * | 2014-12-22 | 2015-04-22 | 常熟市环虹化工颜料厂 | Composite pigment and preparation method thereof |
| CN106700699A (en) * | 2016-12-14 | 2017-05-24 | 四川熹玥广告传媒有限公司 | Water-based pigment and preparation method of water-based pigment |
| CN106752222A (en) * | 2017-01-24 | 2017-05-31 | 中国地质大学（武汉） | A kind of magnetic paint and its production and use |
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Application publication date: 20191203 |