CN110527165A - A kind of urinal potent flame-resistant resin material and preparation method thereof - Google Patents
A kind of urinal potent flame-resistant resin material and preparation method thereof Download PDFInfo
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- CN110527165A CN110527165A CN201910699345.3A CN201910699345A CN110527165A CN 110527165 A CN110527165 A CN 110527165A CN 201910699345 A CN201910699345 A CN 201910699345A CN 110527165 A CN110527165 A CN 110527165A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2231—Oxides; Hydroxides of metals of tin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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Abstract
The present invention provides a kind of urinal potent flame-resistant resin material and preparation method thereof, is related to medical supplies production technical field.The resin material is made of raw material from the following weight: 50-60 parts of high density polyethylene (HDPE), 15-20 parts of ABS resin, 4-6 parts of stannic hydroxide, 3-5 parts of zirconium hydroxide, 4-6 parts of ammonium octamolybdate, 2-4 parts of barium metaborate, 4-6 parts of kayexalate, 6-8 parts of ODPP octyl diphenyl phosphate, 3-5 parts of octaphenylcyclotetrasiloxane, bis- 5-7 parts of (trimethyl fluoride sulfonyl) amine potassium, 2-4 parts of antioxidant, 3-5 parts of plasticizer, 2-4 parts of dispersing agent.The present invention overcomes the deficiencies in the prior art, can effectively improve the fire protecting performance of resin material, urinal is prevented to be ignited in the case of fire, and then aggravate the sprawling of fire, and resin material superior performance, fire protecting performance is good, highly-safe, are suitable for promoting.
Description
Technical field
The present invention relates to medical supplies production technical fields, and in particular to a kind of potent flame-resistant resin material of urinal and its
Preparation method.
Background technique
Urinal is the urine collection aids of some dysuria patients such as the urinary incontinence, paraplegia, long-term bed.Usually by moulding
Material bag, drainage catheter, hanging ring, pagoda connector, urisheath, drain pipe, plug composition.Urinal is usually disposable, needs periodically
Replacement.Indwelling catheter can bring a series of complication, especially multiple with urinary infection.
Urinal is usually made by resin material, but the formula composition and production technology of resin material are unreasonable at present, lead
Cause the fire protecting performance of resin material poor.Since urinal is usually disposable, amount of storage is generally large.In this way when
When fire occurs, urinal is easily ignited, to aggravate the sprawling of fire, safety is lower, is brought to user biggish
Trouble.Therefore, a kind of urinal with potent flame-resistant resin material be researchers research hot spot.
Summary of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of urinal potent flame-resistant resin material and preparation method thereof, this
Invention overcomes the deficiencies in the prior art, can effectively improve the fire protecting performance of resin material, prevent urinal in the case of fire
It being ignited, and then aggravates the sprawling of fire, resin material superior performance, fire protecting performance is good, and it is highly-safe, it is suitable for promoting.
In order to achieve the above object, technical solution of the present invention is achieved by the following technical programs:
A kind of potent flame-resistant resin material of urinal, the resin material are made of raw material from the following weight: high density
50-60 parts of polyethylene, 15-20 parts of ABS resin, 4-6 parts of stannic hydroxide, 3-5 parts of zirconium hydroxide, 4-6 parts of ammonium octamolybdate, metaboric acid
2-4 parts of barium, 4-6 parts of kayexalate, 6-8 parts of ODPP octyl diphenyl phosphate, 3-5 parts of octaphenylcyclotetrasiloxane, bis- (trifluoros
Sulfonyloxy methyl) 5-7 parts of amine potassium, 2-4 parts of antioxidant, 3-5 parts of plasticizer, 2-4 parts of dispersing agent.
Preferably, the antioxidant is by N, N- DPD di p phenylenediamine, zinc dibutyl dithiocarbamate and 2,6 di-t-butyls
Methylphenol is mixed with mass ratio for 5:3:2.
Preferably, the plasticizer is by repefral, phthalic acid ester and dioctyl sebacate with mass ratio
It is mixed for 4:3:1.
Preferably, the dispersing agent is 2:4:5 with mass ratio by polyacrylamide, lauryl sodium sulfate and Potassium Suceinate
It mixes.
The preparation method of the resin material the following steps are included:
(1) stannic hydroxide, zirconium hydroxide, ammonium octamolybdate and barium metaborate are added in crusher mix and are crushed, after
It is mixed object to be placed in high temperature furnace, is first warming up to 260-280 DEG C, is warming up to 430-450 DEG C again after heat preservation roasting 0.5-1h, after
It is rapidly cooled to 80-100 DEG C after continuation of insurance temperature roasting 1-1.5h, it is spare that rear cooled to room temperature obtains mixture；
(2) mixture obtained is placed in refrigerator, and subzero 35 DEG C-it is 25 DEG C subzero at cryo-conservation 1-1.5h,
Cryogrinding is at powder afterwards, then to obtain auxiliary material A spare by cryo-conservation 2-3h；
(3) by kayexalate, ODPP octyl diphenyl phosphate, octaphenylcyclotetrasiloxane and bis- (trimethyl fluoride sulfonyl)
The mixing of amine potassium is added in autoclave, is warming up to 180-200 DEG C, and boost to 13-15MPa, adjustment revolving speed to 120-150r/min,
It is depressurized to 5-8MPa rapidly after pressure maintaining infiltration 1-1.5h, pressure maintaining slowly restores to normal pressure after being kneaded 0.5-1h, then keeps the temperature standing
1.5-2h it is spare to obtain auxiliary material B；
(4) high density polyethylene (HDPE) and ABS resin are mixed and is added in mixer, be first warming up to 130-150 DEG C, adjust revolving speed
To 140-160r/min, heat preservation is warming up to 200-220 DEG C after being kneaded 0.5-1h again, continues heat preservation and is kneaded 2-3h to obtain base-material spare；
(5) auxiliary material A obtained and auxiliary material B are mixed and are added in the mixer in above-mentioned steps (4), add antioxidant,
Plasticizer and dispersing agent continue to be mixed object after heat preservation is kneaded 4-6h and squeeze into molding machine, product are obtained after cooling and shaping.
Preferably, the speed of heating is 10-15 DEG C/min for the first time in the step (1), and the speed of second of heating is
5-8 DEG C/min, cooling velocity is 15-20 DEG C/min.
Preferably, mixing was crushed to 80 meshes in the step (1), and cryogrinding is to crossing 200 meshes in step (2).
Preferably, the speed boosted in the step (3) is 100-150Pa/min, and the speed of decompression is 150-200Pa/
Min restores to the speed of normal pressure to be 50-100Pa/min.
The present invention provides a kind of urinal potent flame-resistant resin material and preparation method thereof, and advantage exists compared with prior art
In:
(1) added with stannic hydroxide, zirconium hydroxide, ammonium octamolybdate and barium metaborate and auxiliary material A is made in the present invention, passes through two
It is modified that the mode of secondary heating carries out high-temperature roasting to it, and cools down rapidly after roasting, then successively saved at low ambient temperatures,
Grinding and preservation, can effectively improve the fire protecting performance of resin material, urinal is prevented to be ignited in the case of fire, and then aggravate
The sprawling of fire, resin material fire protecting performance is good, highly-safe；
(2) present invention is also added with kayexalate, ODPP octyl diphenyl phosphate, octaphenylcyclotetrasiloxane and double
Auxiliary material B is simultaneously made in (trimethyl fluoride sulfonyl) amine potassium, by way of high-pressure osmosis, decompression finally slowly restores to normal pressure rapidly again,
It can be made to cooperate with auxiliary material A, further promote the fire protecting performance of resin material, resin material superior performance is suitable for pushing away
Extensively.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below with reference to the embodiment of the present invention pair
Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention
Embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making wound
Every other embodiment obtained under the premise of the property made labour, shall fall within the protection scope of the present invention.
Embodiment 1:
A kind of potent flame-resistant resin material of urinal, the resin material are made of raw material from the following weight: high density
50 parts of polyethylene, 15 parts of ABS resin, 4 parts of stannic hydroxide, 3 parts of zirconium hydroxide, 4 parts of ammonium octamolybdate, 2 parts of barium metaborate, polyphenyl second
4 parts of alkene sodium sulfonate, 3 parts of octaphenylcyclotetrasiloxane, bis- 5 parts of (trimethyl fluoride sulfonyl) amine potassium, resists 6 parts of ODPP octyl diphenyl phosphate
2 parts of oxygen agent, 3 parts of plasticizer, 2 parts of dispersing agent.
Wherein, the antioxidant is by N, N- DPD di p phenylenediamine, zinc dibutyl dithiocarbamate and 2,6 di-t-butyl first
Base phenol is mixed with mass ratio for 5:3:2；The plasticizer is by repefral, phthalic acid ester and decanedioic acid
Dioctyl ester is mixed with mass ratio for 4:3:1；The dispersing agent is by polyacrylamide, lauryl sodium sulfate and Potassium Suceinate
It is mixed with mass ratio for 2:4:5.
The preparation method of the resin material the following steps are included:
(1) stannic hydroxide, zirconium hydroxide, ammonium octamolybdate and barium metaborate are added in crusher mix and are crushed, after
It is mixed object to be placed in high temperature furnace, is first warming up to 260-280 DEG C, is warming up to 430-450 DEG C again after heat preservation roasting 0.5-1h, after
It is rapidly cooled to 80-100 DEG C after continuation of insurance temperature roasting 1-1.5h, it is spare that rear cooled to room temperature obtains mixture；
(2) mixture obtained is placed in refrigerator, and subzero 35 DEG C-it is 25 DEG C subzero at cryo-conservation 1-1.5h,
Cryogrinding is at powder afterwards, then to obtain auxiliary material A spare by cryo-conservation 2-3h；
(3) by kayexalate, ODPP octyl diphenyl phosphate, octaphenylcyclotetrasiloxane and bis- (trimethyl fluoride sulfonyl)
The mixing of amine potassium is added in autoclave, is warming up to 180-200 DEG C, and boost to 13-15MPa, adjustment revolving speed to 120-150r/min,
It is depressurized to 5-8MPa rapidly after pressure maintaining infiltration 1-1.5h, pressure maintaining slowly restores to normal pressure after being kneaded 0.5-1h, then keeps the temperature standing
1.5-2h it is spare to obtain auxiliary material B；
(4) high density polyethylene (HDPE) and ABS resin are mixed and is added in mixer, be first warming up to 130-150 DEG C, adjust revolving speed
To 140-160r/min, heat preservation is warming up to 200-220 DEG C after being kneaded 0.5-1h again, continues heat preservation and is kneaded 2-3h to obtain base-material spare；
(5) auxiliary material A obtained and auxiliary material B are mixed and are added in the mixer in above-mentioned steps (4), add antioxidant,
Plasticizer and dispersing agent continue to be mixed object after heat preservation is kneaded 4-6h and squeeze into molding machine, product are obtained after cooling and shaping.
Wherein, the speed of heating is 10-15 DEG C/min for the first time in the step (1), and the speed of second of heating is 5-8
DEG C/min, cooling velocity is 15-20 DEG C/min；Mixing was crushed to 80 meshes in the step (1), and low temperature is ground in step (2)
It was milled to 200 meshes；The speed boosted in the step (3) is 100-150Pa/min, and the speed of decompression is 150-200Pa/
Min restores to the speed of normal pressure to be 50-100Pa/min.
Embodiment 2:
A kind of potent flame-resistant resin material of urinal, the resin material are made of raw material from the following weight: high density
55 parts of polyethylene, 18 parts of ABS resin, 5 parts of stannic hydroxide, 4 parts of zirconium hydroxide, 5 parts of ammonium octamolybdate, 3 parts of barium metaborate, polyphenyl second
5 parts of alkene sodium sulfonate, 4 parts of octaphenylcyclotetrasiloxane, bis- 6 parts of (trimethyl fluoride sulfonyl) amine potassium, resists 7 parts of ODPP octyl diphenyl phosphate
3 parts of oxygen agent, 4 parts of plasticizer, 3 parts of dispersing agent.
Wherein, the antioxidant is by N, N- DPD di p phenylenediamine, zinc dibutyl dithiocarbamate and 2,6 di-t-butyl first
Base phenol is mixed with mass ratio for 5:3:2；The plasticizer is by repefral, phthalic acid ester and decanedioic acid
Dioctyl ester is mixed with mass ratio for 4:3:1；The dispersing agent is by polyacrylamide, lauryl sodium sulfate and Potassium Suceinate
It is mixed with mass ratio for 2:4:5.
The preparation method of the resin material the following steps are included:
(1) stannic hydroxide, zirconium hydroxide, ammonium octamolybdate and barium metaborate are added in crusher mix and are crushed, after
It is mixed object to be placed in high temperature furnace, is first warming up to 260-280 DEG C, is warming up to 430-450 DEG C again after heat preservation roasting 0.5-1h, after
It is rapidly cooled to 80-100 DEG C after continuation of insurance temperature roasting 1-1.5h, it is spare that rear cooled to room temperature obtains mixture；
(2) mixture obtained is placed in refrigerator, and subzero 35 DEG C-it is 25 DEG C subzero at cryo-conservation 1-1.5h,
Cryogrinding is at powder afterwards, then to obtain auxiliary material A spare by cryo-conservation 2-3h；
(3) by kayexalate, ODPP octyl diphenyl phosphate, octaphenylcyclotetrasiloxane and bis- (trimethyl fluoride sulfonyl)
The mixing of amine potassium is added in autoclave, is warming up to 180-200 DEG C, and boost to 13-15MPa, adjustment revolving speed to 120-150r/min,
It is depressurized to 5-8MPa rapidly after pressure maintaining infiltration 1-1.5h, pressure maintaining slowly restores to normal pressure after being kneaded 0.5-1h, then keeps the temperature standing
1.5-2h it is spare to obtain auxiliary material B；
(4) high density polyethylene (HDPE) and ABS resin are mixed and is added in mixer, be first warming up to 130-150 DEG C, adjust revolving speed
To 140-160r/min, heat preservation is warming up to 200-220 DEG C after being kneaded 0.5-1h again, continues heat preservation and is kneaded 2-3h to obtain base-material spare；
(5) auxiliary material A obtained and auxiliary material B are mixed and are added in the mixer in above-mentioned steps (4), add antioxidant,
Plasticizer and dispersing agent continue to be mixed object after heat preservation is kneaded 4-6h and squeeze into molding machine, product are obtained after cooling and shaping.
Wherein, the speed of heating is 10-15 DEG C/min for the first time in the step (1), and the speed of second of heating is 5-8
DEG C/min, cooling velocity is 15-20 DEG C/min；Mixing was crushed to 80 meshes in the step (1), and low temperature is ground in step (2)
It was milled to 200 meshes；The speed boosted in the step (3) is 100-150Pa/min, and the speed of decompression is 150-200Pa/
Min restores to the speed of normal pressure to be 50-100Pa/min.
Embodiment 3:
A kind of potent flame-resistant resin material of urinal, the resin material are made of raw material from the following weight: high density
60 parts of polyethylene, 20 parts of ABS resin, 6 parts of stannic hydroxide, 5 parts of zirconium hydroxide, 6 parts of ammonium octamolybdate, 4 parts of barium metaborate, polyphenyl second
6 parts of alkene sodium sulfonate, 5 parts of octaphenylcyclotetrasiloxane, bis- 7 parts of (trimethyl fluoride sulfonyl) amine potassium, resists 8 parts of ODPP octyl diphenyl phosphate
4 parts of oxygen agent, 5 parts of plasticizer, 4 parts of dispersing agent.
Wherein, the antioxidant is by N, N- DPD di p phenylenediamine, zinc dibutyl dithiocarbamate and 2,6 di-t-butyl first
Base phenol is mixed with mass ratio for 5:3:2；The plasticizer is by repefral, phthalic acid ester and decanedioic acid
Dioctyl ester is mixed with mass ratio for 4:3:1；The dispersing agent is by polyacrylamide, lauryl sodium sulfate and Potassium Suceinate
It is mixed with mass ratio for 2:4:5.
The preparation method of the resin material the following steps are included:
(1) stannic hydroxide, zirconium hydroxide, ammonium octamolybdate and barium metaborate are added in crusher mix and are crushed, after
It is mixed object to be placed in high temperature furnace, is first warming up to 260-280 DEG C, is warming up to 430-450 DEG C again after heat preservation roasting 0.5-1h, after
It is rapidly cooled to 80-100 DEG C after continuation of insurance temperature roasting 1-1.5h, it is spare that rear cooled to room temperature obtains mixture；
(2) mixture obtained is placed in refrigerator, and subzero 35 DEG C-it is 25 DEG C subzero at cryo-conservation 1-1.5h,
Cryogrinding is at powder afterwards, then to obtain auxiliary material A spare by cryo-conservation 2-3h；
(3) by kayexalate, ODPP octyl diphenyl phosphate, octaphenylcyclotetrasiloxane and bis- (trimethyl fluoride sulfonyl)
The mixing of amine potassium is added in autoclave, is warming up to 180-200 DEG C, and boost to 13-15MPa, adjustment revolving speed to 120-150r/min,
It is depressurized to 5-8MPa rapidly after pressure maintaining infiltration 1-1.5h, pressure maintaining slowly restores to normal pressure after being kneaded 0.5-1h, then keeps the temperature standing
1.5-2h it is spare to obtain auxiliary material B；
(4) high density polyethylene (HDPE) and ABS resin are mixed and is added in mixer, be first warming up to 130-150 DEG C, adjust revolving speed
To 140-160r/min, heat preservation is warming up to 200-220 DEG C after being kneaded 0.5-1h again, continues heat preservation and is kneaded 2-3h to obtain base-material spare；
(5) auxiliary material A obtained and auxiliary material B are mixed and are added in the mixer in above-mentioned steps (4), add antioxidant,
Plasticizer and dispersing agent continue to be mixed object after heat preservation is kneaded 4-6h and squeeze into molding machine, product are obtained after cooling and shaping.
Wherein, the speed of heating is 10-15 DEG C/min for the first time in the step (1), and the speed of second of heating is 5-8
DEG C/min, cooling velocity is 15-20 DEG C/min；Mixing was crushed to 80 meshes in the step (1), and low temperature is ground in step (2)
It was milled to 200 meshes；The speed boosted in the step (3) is 100-150Pa/min, and the speed of decompression is 150-200Pa/
Min restores to the speed of normal pressure to be 50-100Pa/min.
Embodiment 4:
The fire protecting performance of urinal resin material obtained by common on the market urinal resin material and embodiment 1-3 is detected,
Detecting step is as follows:
(1) control group 1-3 is set by 3 kinds of common resin materials on the market, the resin material setting in embodiment 1-3
For experimental group 1-3, control group and the resin material of experimental group are prepared into the sample that specification is 10 × 5 × 5mm；
(2) standard GB/T 2406-80 for using oxygen index (OI) (LOI) method, sample is placed in vacuum combustion chamber, is passed through
Oxygen-nitrogen mixture body detects the concentration of oxygen-nitrogen mixture body after sample burning, that is, measures oxygen index (OI) LOI (%) number of each sample
According to；
(3) sample is placed in air and carries out heating burning, observe and record its burn form and flaming combustion time
(s)。
Its testing result is as shown in the table:
Required oxygen concentration highest when as seen from the above table, due to the sample burning of experimental group 2, when lighting flaming combustion for the first time
Between it is most short and without dripping off, therefore its fire protecting performance of resin material obtained by embodiment 2 is best.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features；And these modification or
Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (8)
1. a kind of potent flame-resistant resin material of urinal, which is characterized in that the resin material by following parts by weight raw material system
At: 50-60 parts of high density polyethylene (HDPE), 15-20 parts of ABS resin, 4-6 parts of stannic hydroxide, 3-5 parts of zirconium hydroxide, ammonium octamolybdate 4-6
Part, 2-4 parts of barium metaborate, 4-6 parts of kayexalate, 6-8 parts of ODPP octyl diphenyl phosphate, octaphenylcyclotetrasiloxane 3-5
Part, bis- 5-7 parts of (trimethyl fluoride sulfonyl) amine potassium, 2-4 parts of antioxidant, 3-5 parts of plasticizer, 2-4 parts of dispersing agent.
2. a kind of potent flame-resistant resin material of urinal according to claim 1, which is characterized in that the antioxidant by N,
N- DPD di p phenylenediamine, zinc dibutyl dithiocarbamate and 2,6 di-t-butyl methylphenols with mass ratio be 5:3:2 mix and
At.
3. a kind of potent flame-resistant resin material of urinal according to claim 1, which is characterized in that the plasticizer is by neighbour
Rutgers, phthalic acid ester and dioctyl sebacate are mixed with mass ratio for 4:3:1.
4. a kind of potent flame-resistant resin material of urinal according to claim 1, which is characterized in that the dispersing agent is by gathering
Acrylamide, lauryl sodium sulfate and Potassium Suceinate are mixed with mass ratio for 2:4:5.
5. a kind of urinal preparation method of potent flame-resistant resin material, which is characterized in that the preparation method of the resin material
The following steps are included:
(1) stannic hydroxide, zirconium hydroxide, ammonium octamolybdate and barium metaborate be added in crusher to carry out mixing broken, after by its
Mixture is placed in high temperature furnace, is first warming up to 260-280 DEG C, 430-450 DEG C is warming up to again after heat preservation roasting 0.5-1h, after continuation of insurance
It is rapidly cooled to 80-100 DEG C after temperature roasting 1-1.5h, it is spare that rear cooled to room temperature obtains mixture；
(2) mixture obtained is placed in refrigerator, and subzero 35 DEG C-it is 25 DEG C subzero at cryo-conservation 1-1.5h, it is rear low
Temperature is pulverized, then to obtain auxiliary material A spare by cryo-conservation 2-3h；
(3) by kayexalate, ODPP octyl diphenyl phosphate, octaphenylcyclotetrasiloxane and bis- (trimethyl fluoride sulfonyl) amine potassium
Mixing is added in autoclave, is warming up to 180-200 DEG C, and boost to 13-15MPa, adjustment revolving speed to 120-150r/min, pressure maintaining
5-8MPa is depressurized to after infiltration 1-1.5h rapidly, pressure maintaining slowly restores to normal pressure after being kneaded 0.5-1h, then keeps the temperature and stand 1.5-2h
It is spare to obtain auxiliary material B；
(4) high density polyethylene (HDPE) and ABS resin are mixed and is added in mixer, be first warming up to 130-150 DEG C, adjustment revolving speed is extremely
140-160r/min, heat preservation are warming up to 200-220 DEG C after being kneaded 0.5-1h again, continue heat preservation and are kneaded 2-3h to obtain base-material spare；
(5) auxiliary material A obtained and auxiliary material B are mixed and is added in the mixer in above-mentioned steps (4), add antioxidant, plasticising
Agent and dispersing agent continue to be mixed object after heat preservation is kneaded 4-6h and squeeze into molding machine, product are obtained after cooling and shaping.
6. a kind of urinal according to claim 5 preparation method of potent flame-resistant resin material, which is characterized in that described
The speed of heating is 10-15 DEG C/min for the first time in step (1), and the speed of second of heating is 5-8 DEG C/min, and cooling velocity is
15-20℃/min。
7. a kind of urinal according to claim 5 preparation method of potent flame-resistant resin material, which is characterized in that described
Mixing was crushed to 80 meshes in step (1), and cryogrinding is to crossing 200 meshes in step (2).
8. a kind of urinal according to claim 5 preparation method of potent flame-resistant resin material, which is characterized in that described
The speed boosted in step (3) is 100-150Pa/min, and the speed of decompression is 150-200Pa/min, is restored to the speed of normal pressure
For 50-100Pa/min.
Priority Applications (1)
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