CN110527009A - A kind of seed latex and its preparation method and application - Google Patents
A kind of seed latex and its preparation method and application Download PDFInfo
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- CN110527009A CN110527009A CN201910648561.5A CN201910648561A CN110527009A CN 110527009 A CN110527009 A CN 110527009A CN 201910648561 A CN201910648561 A CN 201910648561A CN 110527009 A CN110527009 A CN 110527009A
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- seed latex
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
Abstract
The invention discloses a kind of seed latex and its preparation method and application.The seed latex is formed by following monomer by emulsion polymerization, and the monomer includes: divinylic monomer according to mass percent: 30~40wt%；Styrene monomer: 54~68wt%；Unsaturated carboxylic acid: 2~6wt%；The glass transition temperature of the seed latex is 0 DEG C to 25 DEG C；Partial size is 30nm to 40nm；Current potential is -15~-25mv.Using seed latex prepared by the present invention, can be used in the emulsion polymerization of butadiene, styrene and other monomers producing styrene-butadiene latex.The beneficial effects of the present invention are: the styrene-butadiene latex prepared by the seed latex, partial size, glass transition temperature controllability are strong, good with Compatibility of Coating Color, have excellent mechanically and chemically stability, can satisfy the requirement of high-speed coating workability.
Description
[technical field]
The present invention relates to emulsion polymerized copolymer latex technology fields, specifically, being a kind of seed latex and its preparation
Methods and applications.
[background technique]
In recent years, as the raising of people's level of cultural life, publication and printing and commercial printing are with a plurality of types of coatings
The demand of paper and high-grade paper art paper increases rapidly, carboxylic styrene butadiene latex as one of most important raw material of Paper Coating,
Also increasing to its demand, quality requirement is also higher and higher.The development trend of current styrene-butadiene latex is to multi-functional and high
Functionalization direction is developed.The most excellent performance of the latex of multifunction is: film-forming temperature is low, performance is good, has under room temperature higher
Stress, so that stiffness, gloss and the print gloss of coating paper and surface strength is reached optimum balance.
Application No. is 201810250374.7 Chinese invention patent applications to disclose a kind of Paper Coating styrene-butadiene latex
And its seed latex and preparation method, according to the mass fraction, the raw material composition of seed latex includes lactic acid 5-10 parts, caprolactone
5-10 parts, 10-15 parts of atoleine, 1.0-1.5 parts of aminated lignin, 0.01-0.3 parts of catalyst, 0.2-0.4 parts of electrolyte,
0.05-0.2 parts of pH buffer, 0.5-1.6 parts of anion emulsifier, 40-60 parts of deionized water.Its main feature is that being adopted using emulsifier
With anion emulsifier, catalyst is used in sulfamic acid, sodiuim bisulfate, Ferric Chloride Hydrated and ferric sulfate hydrate ammonium extremely
Few one kind, and atoleine and lignin is added.
Application No. is 201510679768.0 Chinese invention patent applications to disclose a kind of paper grade (stock) high-performance butadiene-styrene rubber
Cream, seed latex A's the preparation method comprises the following steps: polymeric kettle put into after vacuumizing soft water, whole emulsifiers, molecular weight regulator,
PH buffer and whole monomers, are warming up to 60-80 DEG C, are added dropwise initiator 3-4 hours, 80 DEG C heat preservation 2-3 hours, conversion ratio reaches
After 98% or more, 30 DEG C of bottom discharges are cooled to.Its seed glue B's the preparation method comprises the following steps: polymeric kettle vacuumize after put into soft water, whole
Emulsifier, molecular weight regulator, pH buffer and whole monomer, be warming up to 40-60 DEG C, be added dropwise initiator 10-15 hour, turn
After rate reaches 98% or more, 30 DEG C of bottom discharges are cooled to.
The above patent all discloses the preparation method and application of the seed latex of paper grade (stock) styrene-butadiene latex, these seed latex
The latex particle size of preparation is controllable and wider distribution, and can improve the caking property and intensity of coating paper, assigns the good biology of paper
Degradability, resistance to ag(e)ing and ink adaptability, but be disadvantageous in that and be difficult to make resistance to printing stock intensity and ink to be reached by rationality
To requirement, and seed latex manufacturing cycle is longer, and technique is more complex.
Based on above-mentioned technology status, the present inventor proposes following technical scheme.
[summary of the invention]
Technical problem to be solved by the present invention lies in, overcome the deficiencies in the prior art, propose a kind of seed latex and its
Preparation method, the seed latex that the present invention develops carry out molecule and particle design to it, the carboxy styrene-butadiene rubber milk particle prepared
Diameter, glass transition temperature controllability are strong, good with Compatibility of Coating Color, have excellent mechanically and chemically stability, can satisfy
The requirement of high-speed coating workability.
In order to solve the above-mentioned technical problem, the invention adopts the following technical scheme: a kind of seed latex, the seed
Latex is formed by following monomer by emulsion polymerization, and the monomer includes: divinylic monomer according to mass percent: 30~
40wt%；Styrene monomer: 54~68wt%；Unsaturated carboxylic acid: 2~6wt%；The glass transition temperature of the seed latex
It is 0 DEG C to 25 DEG C；Partial size is 30nm to 40nm；Current potential is -15~-25mv.
Furthermore, in above-mentioned technical proposal, the unsaturated carboxylic acid are as follows: acrylic acid, itaconic acid, metering system
One of acid, fumaric acid, maleic acid or several mixing, preferably acrylic acid, itaconic acid and methacrylic acid.
Furthermore, in above-mentioned technical proposal, the copolymer gel content of the seed latex is 50~75%.
The technical solution that preparation method of the present invention uses are as follows: a kind of preparation method of seed latex, the preparation method include
Following steps:
(1) pH adjusting agent of 0.01~0.03wt%, the emulsifier of 10~16wt%, 40~50wt% deionized water are added
Enter in reaction kettle, stirring is warming up to 75 DEG C~95 DEG C；
(2) it is added at one time the deionized water of 0.06~0.12wt% initiator, 0.5~0.8wt%, then it is added dropwise 15.5~
The divinylic monomer of 18.5wt% styrene monomer, 8.5~11wt%, 0.6~1.5wt% unsaturated carboxylic acid, 10.5~
14wt% emulsifier and 8.0~12.0wt% deionized water, time for adding 60~180 minutes；
(3) after in step (2) solution be added dropwise 30~90 minutes after, then be added dropwise 0.01~0.04wt% initiator, 0.25~
0.50wt% deionized water 30~90 minutes.
(4) after completion of dropwise addition, 75~95 DEG C keep the temperature 1~4 hour, and heat preservation terminates, and is cooled to 45 DEG C with bottom discharge.
Furthermore, in the technical solution of above-mentioned preparation method, the emulsifier is anion emulsifier, is used:
Neopelex, lauryl sodium sulfate, alkyl alcohol ether sulfate, sulfonation succinate, alkyl ether sulfosuccinate
Any one in ester or combination.
Furthermore, in the technical solution of above-mentioned preparation method, the initiator be persulfate, as ammonium persulfate,
Any one in potassium peroxydisulfate, sodium peroxydisulfate.
Furthermore, seed latex produced in the technical solution of above-mentioned preparation method is for producing butadiene, benzene
Styrene-butadiene latex is produced in the emulsion polymerization of ethylene and other monomers.
Using seed latex prepared by the present invention, it can be used for the emulsion polymerization of butadiene, styrene and other monomers
Middle production styrene-butadiene latex.The beneficial effects of the present invention are: the styrene-butadiene latex prepared by the seed latex, partial size, vitrifying turn
Temperature controllability is strong, good with Compatibility of Coating Color, has excellent mechanically and chemically stability, can satisfy high-speed coating operation
The requirement of property.
[specific embodiment]
The invention discloses a kind of seed latex, the seed latex is formed by following monomer by emulsion polymerization, institute
Monomer, which is stated, according to mass percent includes:
Divinylic monomer: 30~40wt%；
Styrene monomer: 54~68wt%；
Unsaturated carboxylic acid: 2~6wt%.
The glass transition temperature of the seed latex is 0 DEG C to 25 DEG C；Partial size is 30nm to 40nm；Current potential be -15~-
25mv。
The unsaturated carboxylic acid are as follows: one of acrylic acid, itaconic acid, methacrylic acid, fumaric acid, maleic acid or
Several mixing, preferably acrylic acid, itaconic acid and methacrylic acid.
The copolymer gel content of the seed latex is 50~75%.
In preparation process of the present invention, in emulsion polymerization, the water of specified amount, the unsaturation are first added in the reactor
Initiator solution, rest part monomer is added when being warming up to reaction temperature in carboxylic acid, emulsifier, various compounding agent solutions and monomer.Separately
Outside, emulsifier and various compounding agent solutions and unsaturated carboxylic acid etc. are continuously added in the course of the polymerization process；When polymerisation conversion is greater than
Reaction, final latex solid content 30 ± 1% are terminated when 99%.
Specifically, the preparation method of the seed latex the following steps are included:
(1) pH adjusting agent of 0.01~0.03wt%, the emulsifier of 10~16wt%, 40~50wt% deionized water are added
Enter in reaction kettle, stirring is warming up to 75 DEG C~95 DEG C；
(2) it is added at one time the deionized water of 0.06~0.12wt% initiator, 0.5~0.8wt%, then it is added dropwise 15.5~
The divinylic monomer of 18.5wt% styrene monomer, 8.5~11wt%, 0.6~1.5wt% unsaturated carboxylic acid, 10.5~
14wt% emulsifier and 8.0~12.0wt% deionized water, time for adding 60~180 minutes；
(3) after in step (2) solution be added dropwise 30~90 minutes after, then be added dropwise 0.01~0.04wt% initiator, 0.25~
0.50wt% deionized water 30~90 minutes.
(4) after completion of dropwise addition, 75~95 DEG C keep the temperature 1~4 hour, and heat preservation terminates, and is cooled to 45 DEG C with bottom discharge.
The emulsifier is anion emulsifier, is used: neopelex, lauryl sodium sulfate, alkyl
Ether alcohol sulfate, sulfonation succinate, any one or combination in alkyl ether sulfosuccinates.
The initiator is persulfate, such as any one in ammonium persulfate, potassium peroxydisulfate, sodium peroxydisulfate.
The present invention is further detailed with reference to embodiments.
In embodiment, all materials are calculated by percentage to the quality.Emulsion polymerization is in replaced with nitrogen, dress
It is carried out in 10 liters of stainless steel autoclaves for having blender, temperature controllable.
Embodiment 1
In 10 liters of stainless steel autoclaves, sequentially add account for reactive component total weight pH adjusting agent 0.026wt%,
Emulsifier 13.3%, deionized water 44.4wt% deionized water, stirring are warming up to 85 DEG C；It is added at one time initiator
Styrene monomer 17.0wt%, divinylic monomer 10.0wt% is then continuously added dropwise in 0.10wt%, deionized water 0.71wt%,
Unsaturated carboxylic acid 1.04wt%, emulsifier 1.21wt% and deionized water 10.1wt%, time for adding 120 minutes；It is added dropwise 60 points
Zhong Hou, then initiator 0.02wt%, deionized water is added dropwise 0.40wt%60 minutes；After completion of dropwise addition, 85 DEG C keep the temperature 2 hours, protect
Temperature terminates, and is cooled to 45 DEG C with bottom discharge.
Embodiment 2~10
2~10 reaction process of embodiment is shown in Table 1 with embodiment 1, each composition and response parameter variation；
Gained butadiene~styrene copolymer latices property is shown in Table 2.
Respectively composition and the response parameter variation of table 1
The seed glue product property that 2 embodiment 1~11 of table and comparative example obtain
| Embodiment number | Glass transition temperature/DEG C | Partial size/nm | Zate current potential/- mV | Gel content/% |
| 1 | 12.9 | 35.0 | 18.9 | 65.2 |
| 2 | 4.2 | 41.2 | 19.2 | 68.4 |
| 3 | 22.3 | 29.4 | 18.4 | 67.1 |
| 4 | 21.1 | 30.1 | 17.6 | 70.2 |
| 5 | 19.2 | 33.2 | 16.8 | 66.8 |
| 6 | 16.7 | 32.4 | 18.0 | 71.0 |
| 7 | 14.2 | 35.6 | 19.7 | 74.5 |
| 8 | 11.1 | 37.1 | 18.3 | 63.2 |
| 9 | 9.0 | 36.9 | 18.8 | 62.1 |
| 10 | 6.7 | 38.6 | 17.5 | 65.5 |
Through overtesting, seed latex prepared by the present invention is when being used to prepare styrene-butadiene latex, partial size, glass transition temperature
Controllability is strong, good with Compatibility of Coating Color, has excellent mechanically and chemically stability, can satisfy wanting for high-speed coating workability
It asks.
Certainly, the above is only a specific embodiment of the present invention, be not to limit the scope of the present invention, it is all according to
The equivalent change or modification that structure, feature and principle described in scope of the present invention patent is done should be included in Shen of the present invention
It please be in the scope of the patents.
Claims (7)
1. a kind of seed latex, it is characterised in that: the seed latex is formed by following monomer by emulsion polymerization, the list
Body includes: according to mass percent
Divinylic monomer: 30~40wt%；
Styrene monomer: 54~68wt%；
Unsaturated carboxylic acid: 2~6wt%；
The glass transition temperature of the seed latex is 0 DEG C to 25 DEG C；Partial size is 30nm to 40nm；Current potential be -15~-
25mv。
2. a kind of seed latex according to claim 1, it is characterised in that: the unsaturated carboxylic acid are as follows: acrylic acid, clothing
One of health acid, methacrylic acid, fumaric acid, maleic acid or several mixing.
3. a kind of seed latex according to claim 1, it is characterised in that: the copolymer gel of the seed latex contains
Amount is 50~75%.
4. a kind of preparation method of seed latex, it is characterised in that: the preparation method the following steps are included:
(1) pH adjusting agent of 0.01~0.03wt%, the emulsifier of 10~16wt%, 40~50wt% deionized water are added anti-
It answers in kettle, stirring is warming up to 75 DEG C~95 DEG C；
(2) it is added at one time the deionized water of 0.06~0.12wt% initiator, 0.5~0.8wt%, then it is added dropwise 15.5~
The divinylic monomer of 18.5wt% styrene monomer, 8.5~11wt%, 0.6~1.5wt% unsaturated carboxylic acid, 10.5~
14wt% emulsifier and 8.0~12.0wt% deionized water, time for adding 60~180 minutes；
(3) after in step (2) solution be added dropwise 30~90 minutes after, then be added dropwise 0.01~0.04wt% initiator, 0.25~
0.50wt% deionized water 30~90 minutes.
(4) after completion of dropwise addition, 75~95 DEG C keep the temperature 1~4 hour, and heat preservation terminates, and is cooled to 45 DEG C with bottom discharge.
5. a kind of preparation method of seed latex according to claim 4, it is characterised in that: the emulsifier is anion
Emulsifier uses: neopelex, lauryl sodium sulfate, alkyl alcohol ether sulfate, sulfonation succinate, alkane
Any one in base ether sulfosuccinates or combination.
6. a kind of preparation method of seed latex according to claim 4, it is characterised in that: the initiator is persulfuric acid
Salt, such as any one in ammonium persulfate, potassium peroxydisulfate, sodium peroxydisulfate.
7. a kind of preparation method of seed latex according to claim 4, it is characterised in that: the seed latex is for producing
Styrene-butadiene latex is produced in the emulsion polymerization of butadiene, styrene and other monomers.
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| CN201910648561.5A CN110527009A (en) | 2019-07-18 | 2019-07-18 | A kind of seed latex and its preparation method and application |
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| EP1167061A1 (en) * | 2000-01-19 | 2002-01-02 | Mitsui Chemicals, Inc. | Emulsion for thermal recording material and thermal recording materials made by using the same |
| CN1861673A (en) * | 2005-03-24 | 2006-11-15 | 莱茵化学莱茵瑙有限公司 | Microgels and thickening agents-containing compositions |
| WO2009053688A2 (en) * | 2007-10-26 | 2009-04-30 | Fujifilm Imaging Colorants Limited | Improvements in and relating to toners made from latexes |
| CN102516460A (en) * | 2011-12-14 | 2012-06-27 | 广东腾龙化工科技有限公司 | Carboxy styrene-butadiene latex special for coating paper |
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| CN106749917A (en) * | 2016-11-30 | 2017-05-31 | 杭州蓝诚新材料有限公司 | Fabric coating styrene-butadiene latex and preparation method thereof |
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2019
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