CN110526496A - A kind of cosmetics sewage treatment process - Google Patents
A kind of cosmetics sewage treatment process Download PDFInfo
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- CN110526496A CN110526496A CN201910762647.0A CN201910762647A CN110526496A CN 110526496 A CN110526496 A CN 110526496A CN 201910762647 A CN201910762647 A CN 201910762647A CN 110526496 A CN110526496 A CN 110526496A
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- sewage
- cosmetics
- pond
- treatment process
- sewage treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention belongs to technical field of sewage, and in particular to a kind of cosmetics sewage treatment process.Cosmetics sewage treatment process provided by the invention, cosmetics sewage successively pass through flocculation sedimentation tank, intermediate pool, hydrolysis acidification pool, pH adjustment pond, anaerobic pond, biological contact oxidation pond, secondary settling tank and clear water reserviors, last qualified discharge.Cosmetics sewage treatment process provided by the invention, it is excellent to the removal effect of the organic pollutant in cosmetics sewage, Chinese effluent can reach Guangdong Province " Sewage Water Emissions limit value " (DB44/26-2001) the second period primary standard, simultaneously, the simple process, efficiently, easy to operate, occupied area is small, it is at low cost, the on-road efficiency of enterprise and sewage treatment plant can be effectively improved.
Description
Technical field
The invention belongs to technical field of sewage, and in particular to a kind of cosmetics sewage treatment process.
Background technique
With the development of national economy, cosmetics gradually become the necessity of home life, and the production of cosmetics
Journey also brings certain pollution to resource environment.Cosmetics sewage is mainly from cleaning flushing waste water and product processing
Process drain.These cosmetics sewage have the following characteristics that (1) sewage quantity is generally little, but pollutant year concentration it is higher.It is dirty
COD concentration is about 10000~15000mg/L in water, and the concentration of BOD is also up to thousands of mg/L, if do not dealt carefully with, it will to ring
Cause serious pollution and destruction in border.(2) sewage composition is complicated: mainly due to material composition complexity, in addition, cosmetics are from raw material
The long flow path of finished product to the end is produced, by-product is more, leads to the various complexity of contaminant component, Colority of Sewage Water is higher, more increases
The difficulty of sewage treatment.(3) bio-refractory substance is more: the organic pollutant in sewage largely belongs to bio-refractory object
Matter, such as glycerol octadecyl alcolol, half glycerol grease pollutant and some cosmetic additive agents, emulsification degree are higher.(4)
Poisonous and harmful substance is more: the organic contamination of many of sewage is poisonous and harmful to microorganism, such as the phenylenediamine in hair dye, silty
Lead, mercury, arsenic in cosmetic remove quinhydrones and its derivative in the sun-proof equal cosmetics of freckle, the phthalic acid junket in nail polish
Deng.
Due to the above feature, so that cosmetics sewage has caused environmental protection sector to the very harmful of ecological environment
Person's concern.Chinese invention patent CN109052816A discloses a kind of cosmetics waste water treatment process, carries out in the following order useless
Water process, after conditioning tank, dosing reactive tank, diaphragm filter press, filter liquid pool, anaerobic digester, anaerobic precipitation pond, anoxic pond,
Membrane biological reaction pond, intermediate pool, COD resin container to reuse sink, through the waste water treatment process, treated although waste water reaches
Discharge standard has been arrived, but treatment process is more complex, occupied area is wide, higher cost.
Since cosmetics sewage treatment difficulty is larger, higher cost, technique is taken up a large area, and system operation energy consumption is high, dimension
Shield is difficult, how to develop a kind of simple process, efficiently, sewage treatment process easy to operate, at low cost has become currentization
The important research direction of cosmetic sewage treatment field.
Summary of the invention
In order to solve the problems in the existing technology, the purpose of the present invention is to provide a kind of cosmetics sewage treatment works
Skill.Cosmetics sewage treatment process provided by the invention, it is excellent to the removal effect of the organic pollutant in cosmetics sewage, out
Water discharge can reach Guangdong Province " Sewage Water Emissions limit value " (DB44/26-2001) the second period primary standard, meanwhile, the work
Skill is simple, efficient, easy to operate, at low cost, to improve the on-road efficiency of enterprise and sewage treatment plant.
The technical scheme is that
A kind of cosmetics sewage treatment process, includes the following steps:
(1) cosmetics sewage enters flocculation sedimentation tank by drainage pipeline, and flocculant is then added into flocculation sedimentation tank,
Flocculation treatment is carried out to sewage, the stirring system in the flocculation sedimentation tank is machine mixer;
(2) sewage after flocculation treatment in step (1) is discharged into intermediate pool, the sludge of flocculation sedimentation by drainage pipeline
It is discharged into sludge concentration tank and carries out sludge condensation processing, the intermediate pool tankage is 2 times for handling water per hour;It will stablize
Sewage afterwards is passed through in hydrolysis acidification pool, and acidification is hydrolyzed;
(3) sewage that hydrolysis acidification in step (2) is handled is passed through PH adjustment pond, and adds pH adjusting agent, adjust sewage
PH to 6~9, the capacity in pH adjustment pond is 1.5 times for handling water per hour;
(4) sewage in step (3) is passed through in anaerobic pond, carries out Anaerobic Treatment, sewage is then passed through biological
Oxidation pond carries out Aerobic Process for Treatment;Into hydrolysis acidification pool, reflux ratio is a part of sludge reflux in the biological contact oxidation pond
7~9:1;
(5) sewage in step (4) Jing Guo Aerobic Process for Treatment is discharged into secondary settling tank, is entered after further precipitating clear
It is stored in pond, it can qualified discharge;The excess sludge precipitated in the secondary settling tank, which is discharged into sludge concentration tank, carries out concentration.
Further, the flocculant added in the step (1) is that sodium hydroxide, aluminium polychloride and polyacrylamide are pressed
Weight ratio 2:4:1 composition.
Further, the revolving speed of the machine mixer in the step (1) in flocculation sedimentation tank is 33r/min.
Further, residence time of the sewage in hydrolysis acidification pool is 12h in the step (2).
Further, anaerobic pond is provided with water distributor and the point water distribution such as carries out in the step (4), and is provided with three-phase separate
From device, rainwater catchment uses tooth form weir.
Further, biological contact oxidation pond uses combined stuffing in the step (4), and gap is 15cm as micro- life
Object carrier.
Further, biological contact oxidation pond bottom of pond is provided with rubber micro-hole aerator, layout density in the step (4)
For 3/m3。
Further, secondary settling tank described in the step (5) is inclined-tube sedimentation tank, and the diameter of the inclined tube is 50mm.
In a kind of cosmetics sewage treatment process provided by the invention, the flocculant of addition is by sodium hydroxide, polyaluminium
Aluminium and polyacrylamide form by a certain percentage, can make at the floccule body adsorption precipitant formed in flocculation process and coagulant
Reason is formed by colloidal solid, and co-precipitation not only guarantees except the calcium in decontaminated water, magnesium carbonate hardness, but also improves suspended matter
With the removal effect of colloidal impurity, environmentally protective, low in cost, dosage is few, and has bactericidal effect.
In a kind of cosmetics sewage treatment process provided by the invention, hydrolysis acidification pool is set in anaerobic pond leading portion, according to
Anaerobic Treatment control is being contained a large amount of hydrolytic bacterias, is being acidified bacterium by the difference of methanogen and hydrolysis acid-producing bacteria growth conditions
Under the conditions of, using hydrolytic bacteria, acidification bacterium by hydrolysis of organic matter insoluble in water be dissolved organic matter, by the big of difficult for biological degradation
Molecular substance is converted into the process of the small-molecule substance of easily biological-degradable, is subsequent biochemical so as to improve the biodegradability of waste water
Processing provides good aquatic environment.It is more conducive to the next step processing of sewage simultaneously.
In a kind of cosmetics sewage treatment process provided by the invention, use gap for 15cm group in biological contact oxidation pond
Box-like filler, the carrier as biomembrane.Waste water to be processed flows through filler after being oxygenated with certain flow rate, connects with biomembrane
Touching, the activated sludge collective effect of biomembrane and suspension have the function that purify waste water.Purifying water effect is good.
Compared with prior art, a kind of cosmetics sewage treatment process provided by the invention has the advantage that
(1) a kind of cosmetics sewage treatment process provided by the invention, each step setting is reasonable and easy to operate, fortune
Row efficiently, when the cosmetics sewage that can make that treated reaches Guangdong Province " Sewage Water Emissions limit value " (DB44/26-2001) second
Section primary standard.
(2) a kind of cosmetics sewage treatment process provided by the invention is filled out using knockdown in biological contact oxidation pond
Material has heat dissipation performance high, and resistance is small, and water distribution, gas distribution performance are good, easy long film, while cutting bubble.
(3) a kind of cosmetics sewage treatment process provided by the invention, flocculant sodium hydroxide, the aluminium polychloride of addition
It is formed by a certain percentage with polyacrylamide, which can play flocculation well, reduce turbidity of sewage, reduce bubble
Formation, the flocculant each ingredient synergistic effect for improving sewage treating efficiency, while adding effectively can carry out sterilization work to sewage
With.
Detailed description of the invention
Fig. 1 is the flow chart of cosmetics sewage treatment process of the present invention.
Specific embodiment
The following describes the present invention further through the description of specific embodiments, but it is to limit of the invention that this, which is not,
System, those skilled in the art's basic thought according to the present invention can make various modifications or improvements, but without departing from this
The basic thought of invention, it is within the scope of the present invention.
PH adjusting agent is purchased from Guangzhou flourishing age Tian Jiao Environmental Protection Technology Co., Ltd.
Referring to Fig.1, it is a kind of flow chart of cosmetics sewage treatment process of the present invention, specifically includes following step
It is rapid:
(1) cosmetics wastewater influent COD is 12000mg/L, enters flocculation sedimentation tank by drainage pipeline, then to flocculation
Flocculant is added in sedimentation basin, and flocculation treatment is carried out to sewage, the stirring system in the flocculation sedimentation tank is machine mixer,
The revolving speed of the machine mixer is 33r/min;The flocculant is sodium hydroxide, aluminium polychloride and polyacrylamide by weight
Amount is formed than 2:4:1.
(2) sewage after flocculation treatment in step (1) is discharged into intermediate pool, the sludge of flocculation sedimentation by drainage pipeline
It is discharged into sludge concentration tank and carries out sludge condensation processing, the intermediate pool tankage is 2 times for handling water per hour;It will stablize
Sewage afterwards is passed through in hydrolysis acidification pool, and acidification is hydrolyzed, and residence time of the sewage in hydrolysis acidification pool is 12h.
(3) sewage that hydrolysis acidification in step (2) is handled is passed through PH adjustment pond, and adds pH adjusting agent, adjust sewage
PH to 7, the capacity in pH adjustment pond is 1.5 times for handling water per hour.
(4) sewage in step (3) is passed through in anaerobic pond, carries out Anaerobic Treatment, the anaerobic pond is provided with water distributor
It the point water distribution such as carries out, and is provided with three phase separator, rainwater catchment uses tooth form weir;Then sewage is passed through biological contact oxidation
Change pond, carry out Aerobic Process for Treatment, the biological contact oxidation pond uses combined stuffing, and gap is 15cm as microbe carrier;
Biological contact oxidation pond bottom of pond is provided with rubber micro-hole aerator simultaneously, layout density is 3/m3, the biological contact oxidation
A part of sludge reflux is into hydrolysis acidification pool in change pond, reflux ratio 8:1.
(5) sewage in step (4) Jing Guo Aerobic Process for Treatment is discharged into secondary settling tank, is entered after further precipitating clear
It is stored in pond, it can qualified discharge;The excess sludge precipitated in the secondary settling tank, which is discharged into sludge concentration tank, carries out concentration;
The secondary settling tank is inclined-tube sedimentation tank, and the diameter of the inclined tube is 50mm.
It is as follows by the processed cosmetics sewage effluent index for the treatment of process of the invention:
As can be seen from the table, the cosmetics after the 1 cosmetics treatment process provided processes through the embodiment of the present invention
Sewage, every effluent index are below Guangdong Province " Sewage Water Emissions limit value " (DB44/26-2001) the second period level-one mark
Standard, being capable of directly safety compliance discharge.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (8)
1. a kind of cosmetics sewage treatment process, which comprises the steps of:
(1) cosmetics sewage enters flocculation sedimentation tank by drainage pipeline, flocculant is then added into flocculation sedimentation tank, to dirt
Water carries out flocculation treatment, and the stirring system in the flocculation sedimentation tank is machine mixer;
(2) sewage after flocculation treatment in step (1) is discharged into intermediate pool by drainage pipeline, the sludge of flocculation sedimentation is discharged into
Sludge concentration tank carries out sludge condensation processing, and the intermediate pool tankage is 2 times for handling water per hour;After stabilization
Sewage is passed through in hydrolysis acidification pool, and acidification is hydrolyzed;
(3) sewage that hydrolysis acidification in step (2) is handled is passed through PH adjustment pond, and adds pH adjusting agent, adjust the pH of sewage
To 6~9, the capacity in pH adjustment pond is 1.5 times for handling water per hour;
(4) sewage in step (3) is passed through in anaerobic pond, carries out Anaerobic Treatment, sewage is then passed through bio-contact oxidation
Pond carries out Aerobic Process for Treatment;A part of sludge reflux is into hydrolysis acidification pool in the biological contact oxidation pond, and reflux ratio is 7~
9:1;
(5) sewage in step (4) Jing Guo Aerobic Process for Treatment is discharged into secondary settling tank, clear water reserviors is entered after further precipitating
Middle storage, can qualified discharge;The excess sludge precipitated in the secondary settling tank, which is discharged into sludge concentration tank, carries out concentration.
2. a kind of cosmetics sewage treatment process as described in claim 1, which is characterized in that added in the step (1)
Flocculant is that sodium hydroxide, aluminium polychloride and polyacrylamide are formed by weight 2:4:1.
3. a kind of cosmetics sewage treatment process as described in claim 1, which is characterized in that flocculation is heavy in the step (1)
The revolving speed of machine mixer in the pond of shallow lake is 33r/min.
4. a kind of cosmetics sewage treatment process as described in claim 1, which is characterized in that sewage exists in the step (2)
Residence time in hydrolysis acidification pool is 12h.
5. a kind of cosmetics sewage treatment process as described in claim 1, which is characterized in that anaerobic pond in the step (4)
It is provided with water distributor and the point water distribution such as carries out, and be provided with three phase separator, rainwater catchment uses tooth form weir.
6. a kind of cosmetics sewage treatment process as described in claim 1, which is characterized in that biology connects in the step (4)
It touches oxidation pond and uses combined stuffing, gap is 15cm as microbe carrier.
7. a kind of cosmetics sewage treatment process as described in claim 1, which is characterized in that biology connects in the step (4)
Touching oxidation pond bottom of pond is provided with rubber micro-hole aerator, and layout density is 3/m3。
8. a kind of cosmetics sewage treatment process as described in claim 1, which is characterized in that two described in the step (5)
Heavy pond is inclined-tube sedimentation tank, and the diameter of the inclined tube is 50mm.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113072247A (en) * | 2021-03-23 | 2021-07-06 | 昆山水清华环保科技有限公司 | Cosmetics sewage treatment system |
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CN104150713A (en) * | 2014-08-12 | 2014-11-19 | 宁波市恒洁水务发展有限公司 | Treatment method for waste water during rutin production process |
-
2019
- 2019-08-19 CN CN201910762647.0A patent/CN110526496A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US20030201225A1 (en) * | 2002-04-30 | 2003-10-30 | Josse Juan Carlos | Organic slurry treatment process |
CN104150713A (en) * | 2014-08-12 | 2014-11-19 | 宁波市恒洁水务发展有限公司 | Treatment method for waste water during rutin production process |
Non-Patent Citations (2)
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113072247A (en) * | 2021-03-23 | 2021-07-06 | 昆山水清华环保科技有限公司 | Cosmetics sewage treatment system |
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