CN110523106A - A kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus - Google Patents

A kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus Download PDF

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Publication number
CN110523106A
CN110523106A CN201910840151.0A CN201910840151A CN110523106A CN 110523106 A CN110523106 A CN 110523106A CN 201910840151 A CN201910840151 A CN 201910840151A CN 110523106 A CN110523106 A CN 110523106A
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CN
China
Prior art keywords
driven
shaft
bearing
magnetic agitation
hollow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910840151.0A
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Chinese (zh)
Inventor
付贤树
王正亮
俞晓平
洪雪珍
叶子弘
张明洲
马骉
王建萍
刘光富
葛航
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China Jiliang University
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China Jiliang University
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Application filed by China Jiliang University filed Critical China Jiliang University
Priority to CN201910840151.0A priority Critical patent/CN110523106A/en
Publication of CN110523106A publication Critical patent/CN110523106A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/04Solvent extraction of solutions which are liquid
    • B01D11/0415Solvent extraction of solutions which are liquid in combination with membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/04Solvent extraction of solutions which are liquid
    • B01D11/0446Juxtaposition of mixers-settlers
    • B01D11/0457Juxtaposition of mixers-settlers comprising rotating mechanisms, e.g. mixers, mixing pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/45Magnetic mixers; Mixers with magnetically driven stirrers
    • B01F33/453Magnetic mixers; Mixers with magnetically driven stirrers using supported or suspended stirring elements
    • B01F33/4532Magnetic mixers; Mixers with magnetically driven stirrers using supported or suspended stirring elements using a bearing, tube, opening or gap for internally supporting the stirring element
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/23Mixing of laboratory samples e.g. in preparation of analysing or testing properties of materials

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The invention discloses a kind of high-throughput magnetic agitation systems of hollow-fibre membrane micro-extraction apparatus, including extractor body and magnetic agitation system, system setting driving shaft drives other driven shafts to rotate, finally drive turntable rotation, the power of stirring is provided, and it can according to need the stirring requirement for meeting different number sample, the magnetic agitation system can be realized the automation extracted to multiple groups sample, realize high-throughput testing goal, the efficiency of extraction can be improved, improve the degree of automation of hollow-fibre membrane micro-extraction apparatus, the stirring system is provided with a pair of magnetic body being arranged on multiple turntables and turntable simultaneously, that is, being equipped with multiple magnetic stirring apparatus, the sample in each group container can be made to stir relatively more uniform.

Description

A kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus
Technical field
The present invention relates to hollow-fibre membrane micro-extraction apparatus, and in particular to a kind of high-throughput magnetic of hollow-fibre membrane micro-extraction apparatus Power stirring system.
Background technique
Liquid-liquid-liquid microextraction technology is a kind of extraction organic trace compounds residual pretreatment technology, is to develop in recent years The advanced remaining method of extraction organic trace compounds got up, it includes feed liquid phase (sample), organic phase, receives phase, whole A extraction process is as follows: the analyte in feed liquid phase (sample) is extracted in organic solvent first, and is stripped into In receptor, in different liquid phases, protonation and complexing change the chemical property of analyte, and drive its turn It moves.This machine compound Residue analysis method can be applied to agriculture, wild animal resources, be to food, beverage, milk middle peasant, The pioneering research of wild animal resources and important innovations.But there is operations to be difficult to control for liquid-liquid-liquid microextraction technology, small The disadvantages of drop is easily broken up, the operating time is long, therefore Many researchers improve liquid-liquid-liquid microextraction, have investigated hollow Tunica fibrosa micro-extraction technique.
A kind of hollow-fibre membrane micro-extraction apparatus of the patent of invention authorized and its application (application number: 2012104909781), which is that manpower operating process present in solution liquid-liquid-liquid microextraction is more, operates not The disadvantages of easy to control, poor repeatability, provides a kind of pre-processing device of automatic operation, and using it in agriculture, residue of veterinary drug Application in detection and analysis pre-treatment.The hollow-fibre membrane micro-extraction apparatus of the invention has disturbing factor few, flow control essence Really, it is easy to accomplish Sample Purification on Single, enrichment the advantages that, improve pre-treatment efficiency.But hollow-fibre membrane micro-extraction apparatus once can only Detection is extracted to three groups of samples to be tested, needs to reappose sample to be tested after the completion of detection every time, therefore efficiency is lower, and One group of sample to be tested of hollow-fibre membrane micro-extraction apparatus is to be stirred by a magnetic stirring apparatus to provide power, one group of sample Product include the more parts of samples for needing to stir extraction, and more remote apart from magnetic stirring apparatus center, the power stirred can be small, may go out Now stir non-uniform phenomenon, it is therefore desirable to have a kind of high degree of automation, can simultaneously automatically realize multichannel hollow-fibre membrane Micro-extraction apparatus work and each group sample stir more uniform high-throughput magnetic agitation system, improve the efficiency of test.
Summary of the invention
The purpose of the present invention is to solve shortcomings in the prior art, provide a kind of hollow-fibre membrane micro-extraction The high-throughput magnetic agitation system of device, the magnetic agitation system can be realized to multiple groups sample simultaneously, synchronous extracting operation, realize The high-throughput purpose of sample pre-treatments while guaranteeing that the stirring of each group sample is more uniform, and can be further improved extraction effect The automatization level of rate and hollow-fibre membrane micro-extraction apparatus.
To achieve the goals above, the invention adopts the following technical scheme: a kind of high pass of hollow-fibre membrane micro-extraction apparatus Magnetic agitation system is measured, including extractor body and magnetic agitation system, the magnetic agitation system include driving shaft, driven shaft And magnetic stirrer, the driving shaft are driven by adjustable speed motor, the adjustable speed motor is controlled by controller, driving shaft rotation Other axis are driven to rotate, the driving shaft includes being disposed with first bearing, the first drive sprocket, second from lower to upper actively Sprocket wheel, second bearing and turntable, the both ends of first bearing and second bearing support driving shaft, guarantee the correct position of driving shaft, Power is transferred to third driven sprocket by the first drive sprocket and the first driven sprocket, by the second drive sprocket by power It is transferred to the second driven sprocket, the driven shaft includes several first driven shafts and several second driven shafts, and described first is driven Axis include be disposed with that first driven shaft is held, the first driven sprocket, the second driven sprocket, second driven shaft are held from lower to upper and Turntable, the second driven shaft include the driven bearing of third, third driven sprocket, the 4th driven shaft set gradually from lower to upper It holds and turntable, the upper surface of described turntable is symmetrically arranged with magnetic substance, identical charges repel each other using magnetisable material for the principle of magnetic agitation Characteristic pushes magnetic stirrer to rotate, by the rotation of magnetic stirrer, adds by constantly converting the polarity at both ends of pedestal Object in fast sample to be tested is stripped to be taken into hollow-fibre membrane and be received in phase, the first bearing, second bearing, first Driven bearing, second driven shaft are held, the driven bearing of third and the 4th driven bearing are fixed in rack, and each bearing is all provided with The position for being capable of fixing bearing on the rack is set, the power between the driving shaft and driven shaft is transmitted by chain, chain conveyer tool Have the advantages that simple and reliable.
Preferably, the first bearing and the second bearing and driving shaft are installed as transition fit, transition fit It is mainly used for requiring hole between centers to have preferably to neutral and concentricity and the positioning connection that is readily disassembled, assemble, such as rolling bearing Internal diameter couples with axis.
Match preferably, the first driven shaft holds the transition that is installed as held with the second driven shaft with first driven shaft It closes, the driven bearing of third and the 4th driven bearing and second driven shaft are installed as transition fit.
Preferably, the driving shaft and driven shaft are multi-diameter shaft, each sprocket wheel in the magnetic agitation system passes through The shaft shoulder does axially position, is connected by key and does circumferentially positioned, and the shaft shoulder on axis is usually used in being mounted on an axle the axially position of part, And it is circumferentially positioned usually using key connection.
Preferably, the turntable does axially position by the shaft shoulder, it is connected by key and does circumferentially positioned, the shaft shoulder on axis is normal For being mounted on an axle the axially position of part, and it is circumferentially positioned usually using key connection.
Preferably, one end of each sprocket wheel, each bearing and turntable in the high throughput magnetic agitation system passes through the shaft shoulder Positioning, the other end are positioned by circlip, and circlip positioning is simple and reliable, are easily changed.
Preferably, the second driven sprocket in the first driven shaft is with the second drive sprocket on driving shaft in axial direction The height in direction is identical, due to first driven shaft by driving shaft by chain-driving, according to chaindriven use condition, second from Movable sprocket is identical as the height of the second drive sprocket in the axial direction.
Preferably, third driven sprocket in the second driven shaft in the axial direction with first in first driven shaft Driven sprocket and the first drive sprocket height are identical, since second driven shaft drives rotation by first driven shaft and driving shaft, and It needs to realize power transmitting by chain conveyer, in order to correctly install chain, third driven sprocket is driven with first in the axial direction The first driven sprocket and the first drive sprocket height on axis is identical.
The advantageous effects that the present invention has are: a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus System, system setting driving shaft drive other driven shafts to rotate, finally drive turntable rotation, provide the power of stirring, and can To meet the stirring requirement of different number sample as needed, which, which can be realized, extracts multiple groups sample Automation, realize high-throughput testing goal, extraction efficiency can be improved, improve the automation journey of hollow-fibre membrane micro-extraction apparatus Degree, while the stirring system is provided with a pair of magnetic body being arranged on multiple turntables and turntable, that is, being equipped with multiple magnetic force Blender can be such that the sample in each group container stirs relatively more uniform.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of hollow-fibre membrane micro-extraction apparatus high throughput magnetic agitation system of the present invention.
Fig. 2 is a kind of hollow-fibre membrane micro-extraction apparatus high throughput magnetic agitation system of the present invention including driving shaft and first The structural schematic diagram of driven shaft.
In figure: driving shaft 1, first bearing 2, the first drive sprocket 3, the second drive sprocket 4, second bearing 5, turntable 6, One driven shaft 7, second driven shaft 8, first driven shaft hold the 9, first driven sprocket 10, the second driven sprocket 11, second driven shaft Hold the driven bearing 13 of 12, third, third driven sprocket 14, the 4th driven bearing 15, magnetic substance 16, adjustable speed motor 17.
Specific embodiment
The present invention will be further described with reference to the accompanying drawing, by the following description of the embodiment, will more help In the public understanding present invention, but the specific embodiment given by applicant should can't be considered as to the technology of the present invention side The definition of the limitation of case, any pair of component or technical characteristic be changed or to overall structure make form and immaterial transformation It is regarded as protection scope defined by technical solution of the present invention.
As shown in FIG. 1 to FIG. 2, a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus, including extractor Body and magnetic agitation system, the magnetic agitation system include driving shaft, driven shaft and magnetic stirrer, the driving shaft by Adjustable speed motor drives, and the adjustable speed motor is controlled by controller, and driving shaft rotation drives the rotation of other axis, the driving shaft Including being disposed with first bearing, the first drive sprocket, the second drive sprocket, second bearing and turntable from lower to upper, first Bearing and second bearing support driving shaft both ends, guarantee the correct position of driving shaft, by the first drive sprocket and first from Power is transferred to third driven sprocket by movable sprocket, and power is transferred to the second driven sprocket by the second drive sprocket, described Driven shaft includes several first driven shafts and several second driven shafts, and the first driven shaft includes being disposed with from lower to upper First driven shaft is held, the first driven sprocket, the second driven sprocket, second driven shaft is held and turntable, and the second driven shaft includes The driven bearing of the third set gradually from lower to upper, third driven sprocket, the 4th driven bearing and turntable, the upper surface of described turntable It is symmetrically arranged with magnetic substance, the principle of magnetic agitation is using the magnetisable material characteristic that identical charges repel each other, by constantly converting pedestal two The polarity at end pushes magnetic stirrer to rotate, and by the rotation of magnetic stirrer, the object accelerated in sample to be tested is anti- It is extracted into hollow-fibre membrane and receives in phase, the first bearing, second bearing, first driven shaft are held, second driven shaft is held, the Three driven bearings and the 4th driven bearing are fixed in rack, and each bearing is respectively provided on the rack, are capable of fixing bearing Position, the power between the driving shaft and driven shaft are transmitted by chain, and chain conveyer has the advantages that simple and reliable;Described One bearing and the second bearing and driving shaft are installed as transition fit, and transition fit is mainly used for that hole between centers is required to have preferably To neutral and concentricity and the positioning connection that is readily disassembled, assemble, such as coupling for rolling bearing internal diameter and axis;Described first from Dynamic bearing and the second driven shaft hold the transition fit that is installed as with first driven shaft, the driven bearing of the third and described Four driven bearings and second driven shaft are installed as transition fit;The driving shaft and driven shaft are multi-diameter shaft, and the magnetic force stirs The each sprocket wheel mixed in system does axially position by the shaft shoulder, is connected by key and does circumferentially positioned, the shaft shoulder on axis is usually used in pacifying Mounted in the axially position of parts on shaft, and circumferentially positioned usually use is keyed;The turntable does axially position by the shaft shoulder, leads to It crosses key connection and does circumferentially positioned, the shaft shoulder on axis is usually used in being mounted on an axle the axially position of part, and circumferentially positioned usually adopts With key connection;One end of each sprocket wheel, each bearing and turntable in the high throughput magnetic agitation system is positioned by the shaft shoulder, another End is positioned by circlip, and circlip positioning is simple and reliable, is easily changed;The second driven sprocket and active in the first driven shaft The height of the second drive sprocket in the axial direction on axis is identical, since first driven shaft passes through chain-driving, root by driving shaft According to chaindriven use condition, the second driven sprocket is identical as the height of the second drive sprocket in the axial direction;Described second from Third driven sprocket on moving axis in the axial direction with the first driven sprocket and the first drive sprocket height in first driven shaft It is identical, since second driven shaft drives rotation by first driven shaft and driving shaft, and need to realize power transmitting by chain conveyer, In order to correctly install chain, third driven sprocket in the axial direction with the first driven sprocket and first in first driven shaft actively Sprocket wheel height is identical.
A kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus, driving shaft is driven by adjustable speed motor to be revolved Turn, the revolving speed of driving shaft is changed by the adjustable speed motor that controller controls, and the rotation of driving shaft is by first bearing and second Bearing supports, and the first drive sprocket and the second drive sprocket is equipped on driving shaft, using driving shaft as origin, in the horizontal direction Several first driven shafts are set gradually, the quantity of setting and their mutual distances are determined by the demand used, driving shaft On the second drive sprocket the second driven sprocket for passing through the farthest first driven shaft of chain driving shaft at a distance from horizontal direction Connection, driving shaft rotation will drive the rotation of all first driven shafts in horizontal direction, then according to first in horizontal direction Driven shaft, each first driven shaft set gradually a number of second driven shaft along vertical direction, in all first driven shafts First driven sprocket by the third in the second driven shaft on chain and the vertical direction farthest apart from the first driven shaft from Movable sprocket connection, setting gradually on driving shaft vertical direction identical as the quantity being arranged on any first driven shaft vertical direction is Second driven shaft, the first drive sprocket on driving shaft pass through the second driven shaft on vertical direction on chain and driving shaft the Three driven sprockets are connected, and driven shaft rotation is driven when first driven shaft rotates, and electric motor starting can drive all axis to rotate, into And all turntables are rotated, each turntable top is to place the sample for needing to stir.
In the present embodiment, a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus, system setting is actively Axis drives other driven shafts to rotate, and finally drives turntable rotation, provides the power of stirring, and it is different to can according to need satisfaction The stirring requirement of quantity sample, the magnetic agitation system can be realized the automation extracted to multiple groups sample, realize high pass Testing goal is measured, extraction efficiency can be improved, improves the degree of automation of hollow-fibre membrane micro-extraction apparatus, while the stirring system is set A pair of magnetic body being arranged on multiple turntables and turntable has been set, that is, being equipped with multiple magnetic stirring apparatus, each group container can be made In sample stirring it is relatively more uniform.
Certainly, the present invention can also have other various embodiments, without deviating from the spirit and substance of the present invention, Those skilled in the art can make various corresponding changes and modifications according to the present invention, but these it is corresponding change and Deformation all should fall within the scope of protection of the appended claims of the present invention.

Claims (8)

1. a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus, including extractor body and magnetic agitation system System, which is characterized in that the magnetic agitation system includes driving shaft (1), driven shaft and magnetic stirrer, and the driving shaft is by can Speed regulating motor (17) drives, and the adjustable speed motor is controlled by controller, and the driving shaft includes being disposed with from lower to upper First bearing (2), the first drive sprocket (3), the second drive sprocket (4), second bearing (5) and turntable (6), the driven shaft packet Include several first driven shafts (7) and several second driven shafts (8), the first driven shaft includes being disposed with the from lower to upper One driven bearing (9), the first driven sprocket (10), the second driven sprocket (11), second driven shaft hold (12) and turntable, and described Two driven shafts include the driven bearing of third (13) set gradually from lower to upper, third driven sprocket (14), the 4th driven bearing (15) and turntable, the upper surface of described turntable are symmetrically arranged with magnetic substance (16), the first bearing, second bearing, first driven shaft It holds, second driven shaft is held, the driven bearing of third and the 4th driven bearing are fixed in rack, the driving shaft and driven shaft Between power pass through chain transmit.
2. a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus according to claim 1, feature exist Transition fit is installed as in, the first bearing and the second bearing and driving shaft.
3. a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus according to claim 1, feature exist Held in, the first driven shaft and hold the transition fit that is installed as with first driven shaft with the second driven shaft, the third from Dynamic bearing and the 4th driven bearing and second driven shaft are installed as transition fit.
4. a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus, feature exist according to claim 1 In, the driving shaft and driven shaft are multi-diameter shaft, and each sprocket wheel in the magnetic agitation system does axially position by the shaft shoulder, Be connected by key do it is circumferentially positioned.
5. a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus according to claim 1, feature exist In, the turntable does axially position by the shaft shoulder, be connected by key do it is circumferentially positioned.
6. a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus according to claim 1 or 4 or 5, It is characterized in that, one end of each sprocket wheel, each bearing and turntable in the high throughput magnetic agitation system is positioned by the shaft shoulder, separately One end is positioned by circlip.
7. a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus according to claim 1, feature exist In height phase of second driven sprocket with the second drive sprocket on driving shaft in the axial direction in the first driven shaft Together.
8. a kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus according to claim 1, feature exist In, third driven sprocket in the second driven shaft in the axial direction with the first driven sprocket or first in first driven shaft Drive sprocket height is identical.
CN201910840151.0A 2019-09-06 2019-09-06 A kind of high-throughput magnetic agitation system of hollow-fibre membrane micro-extraction apparatus Pending CN110523106A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110935194A (en) * 2019-12-12 2020-03-31 中国计量大学 Micro-extraction system of hollow fiber membrane

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205055921U (en) * 2015-07-21 2016-03-02 天津市欧诺仪器仪表有限公司 Ultralow fast magnetic stirrers of four -head
CN211273640U (en) * 2019-09-06 2020-08-18 中国计量大学 High-flux magnetic stirring system of hollow fiber membrane micro-extractor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205055921U (en) * 2015-07-21 2016-03-02 天津市欧诺仪器仪表有限公司 Ultralow fast magnetic stirrers of four -head
CN211273640U (en) * 2019-09-06 2020-08-18 中国计量大学 High-flux magnetic stirring system of hollow fiber membrane micro-extractor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110935194A (en) * 2019-12-12 2020-03-31 中国计量大学 Micro-extraction system of hollow fiber membrane
CN110935194B (en) * 2019-12-12 2021-08-06 中国计量大学 Micro-extraction system of hollow fiber membrane

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