CN1105189A - Petroleum pesticide for tropical fruit tree - Google Patents
Petroleum pesticide for tropical fruit tree Download PDFInfo
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- CN1105189A CN1105189A CN 94110023 CN94110023A CN1105189A CN 1105189 A CN1105189 A CN 1105189A CN 94110023 CN94110023 CN 94110023 CN 94110023 A CN94110023 A CN 94110023A CN 1105189 A CN1105189 A CN 1105189A
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- pesticide
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- fruit tree
- acid
- tropical fruit
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Abstract
The petroleum pesticide for tropical fruit tree is prepared with industrial white oil and compound additive including fatty acid ethanolamide, fatty alcohol polyoxyethyleneether, fatty alcohol polyoxyethylene phosphate and sorbic acid oleate, and features high effect in preventing and killing sarcoptic mite, aphis and mite, and serving as disinfectant also for crops.
Description
The present invention relates to a kind of petroleum pesticide, is the petroleum pesticide that is used for tropical fruit tree specifically.
Aphid, the mite class, a red-spotted lizard class and wood louse etc. are apples, the primary pest of citrus and multiple tropical fruit tree, generally all use organophosphorous pesticide in order to prevent and treat this class pest, but this type of agricultural chemicals is a disadvantage is that insect is developed immunity to drugs to this type of medicine, thereby greatly reduce its drug effect, simultaneously above-mentioned insect is all effective simultaneously for any in this class medicine, and organophosphorous pesticide toxicity is bigger, not a kind of ideal pesticide. the U.S. scientist of the forties finds that oil gold-plating part has lethal effect to the insect of fruit tree, its mechanism of action mainly is to form one deck oil film on insect and ovum thereof, worm and ovum thereof are died of asphyxiation, insect is developed immunity to drugs, on the basis of above-mentioned research, foreign study goes out with petroleum cuts and emulsifier to concoct together as the fruit insecticide agent, China also begins to utilize unpurified No. 20 mechanical oil plants to add 50% polyoxyethylene alkylphenol in the seventies to produce the winter and use the fruit insecticide agent, add 5% polyoxyethylated alkyl phenol with No. 7 high-speed engine oils of commodity the eighties and produce the summer grade petroleum pesticide, this summer grade petroleum pesticide is used in the citrus in early spring, control citrus lecanium has been obtained obvious effects on the fruit trees such as red bayberry, but in the South China, because the evaporation and the photosynthesis of the hot leaf of weather are very fast, be sprayed on the new veteran with above-mentioned petroleum pesticide and can cause serious poisoning, as be sprayed on the bud, can cause the bud abnormity, cause the underproduction, existing petroleum pesticide expands at fruit simultaneously, after the colour-change period sprinkling, can make fruit few, coloured light is poor, and soluble solid content is low.
The purpose of this invention is to provide a kind of shortcoming that can overcome existing summer grade petroleum pesticide, be applicable to the petroleum pesticide of torrid areas mandarin orange, orange and other fruit tree.
Tropical fruit tree insecticide of the present invention is made up of mineral type feedstock oil and compound additive, feedstock oil is with oil plant hydrocracking tail oil or the technical white oil that makes with other method, and compound additive is made up of fatty acid=glycollic amide, fatty alcohol-polyoxyethylene ether, sorbitol oleate (department this--80) and four kinds of components of aliphatic alcohol polyethenoxy phosphate.
The preparation method of fatty acid=glycollic amide is: get the palmitoleic acid of 380 parts of weight and 80 parts of weight=monoethanolamine adds in the reactor, agitating heating, reaction is 1 hour under 150 ℃ ± 10 ℃ temperature, thing is mixed to 90 ℃ ± 5 ℃ in the cooling reactor; 4 parts of potassium hydroxide are joined in the 120 parts=monoethanolamine, make it dissolving, with dissolving well=the monoethanolamine potassium hydroxide solution, join in the aforementioned reactants under 90 ± 5 ℃ of temperature, keep 90 ± 5 ℃ to stir 3 hours, reaction is finished.
Above-mentioned fatty acid also can be cocinic acid, cotton seed oleic acid and other vegetable oil acid except that palmitoleic acid.
Fatty alcohol-polyoxyethylene ether is the mixture of A, two kinds of APEOs of B, and fatty alcohol-polyoxyethylene ether A is a tridecanol to the mixed alcohol of hexadecanol at N
aThe OH catalyzer exists down and three molecule oxireme reactions make; Aliphatic alcohol polyethenoxy B is 7 alkane--the mixed alcohol of 9 alkanols and the oxireme of 7--9 molecule are at N
aOH exists reaction down to make.
The method for making of aliphatic alcohol polyethenoxy phosphate is that molecule five oxidations=phosphorus and 1.5 molecular fats alcohol APEO A reacted 1 hour at normal temperatures.
The umber of the shared weight of each component is in the compound additive:
Fatty diglycollic amide 1.5--3.5 part
Fatty alcohol-polyoxyethylene ether 2.0--4.0 part
Sorbose pinolenic acid ester 0.5--1.5 part
Aliphatic alcohol polyethenoxy phosphoesterase 30 .5--1.5 part
Tropical fruit tree of the present invention is that 96--98: 4--2. just can get petroleum pesticide of the present invention with above-mentioned raw materials oil and compound additive in described ratio blending together with the anharmonic ratio of raw material in the petroleum pesticide and compound additive.
Below in conjunction with embodiment petroleum pesticide for tropical fruit tree effect of the present invention and advantage thereof are described:
1992--vegetative period and fruit expanding period were tested at budding period, the bud stage of Zhongshan City, Guangdong Province usefulness present embodiment petroleum pesticide at citrus in 1993, and wherein the shared parts by weight of each component are in the compound additive:
2.5 parts of palmitic acid diglycollic amides
3 parts of fatty alcohol-polyoxyethylene ether
1 part of sorbose pinolenic acid ester
1 part of aliphatic alcohol polyethenoxy phosphate
The weight ratio of feedstock oil and compound additive is 98: 2 in the used insecticide, during use respectively with the water of 60 times, 100 times and 150 times in addition alkene release.Result of the test shows that petroleum pesticide for tropical fruit tree of the present invention is to blade, bud, fruit all do not produce poisoning, and find except that to the mite of control citrus, a red-spotted lizard, aphid effectively, can also reduce cystospore on the citrus rudiment initial stage blade to the infecting and prevent and treat citrus fat point maculopathy of spring tip blade, its control efficiency is better than carbendazim, Sukeling etc.
Petroleum pesticide of the present invention except that to fruit tree pest insects such as control mite, a red-spotted lizard, aphid effectively, also has bactericidal action, so can make the bactericide of other crop, because this insecticide is formulated with white oil and nontoxic additive, therefore can not produce public hazards, and can not influence its drug effect during with the compound use of other agricultural chemicals. petroleum pesticide of the present invention is except that being applicable to tropical fruit tree, also being applicable to the deciduous fruit tree and the evergreen fruit tree of all regions. tea trees etc. also are applicable to simultaneously insects such as mite on flowers such as control Milan, Chinese rose, jasmine and vegetables, the grain, aphid.
Claims (4)
1, a kind of petroleum pesticide for tropical fruit tree of forming by mineral type feedstock oil and additive, it is characterized in that feedstock oil is technical white oil, additive is the compound additive of being made up of fatty acid=glycollic amide, fatty alcohol-polyoxyethylene ether, sorbitol oleate, aliphatic alcohol polyethenoxy phosphate.
2, according to the described petroleum pesticide for tropical fruit tree of claim 1, the weight ratio that it is characterized in that described feedstock oil and compound additive is 96～98: 4～2.
3,, it is characterized in that the umber of the shared weight of each component in the described compound additive is according to the described petroleum pesticide for tropical fruit tree of claim 1:
Fatty acid=glycollic amide 1.5--3.5 part
Fatty alcohol-polyoxyethylene ether 2.0--4.0 part
Sorbose pinolenic acid ester 0.5--1.5 part
Aliphatic alcohol polyethenoxy phosphoesterase 30 .5--1.5 part
4,, it is characterized in that described fatty acid can be palmitic acid, cocinic acid, palmitoleic acid, cotton seed oleic acid and other vegetable oil acid according to the described petroleum pesticide for tropical fruit tree of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94110023 CN1105189A (en) | 1994-01-14 | 1994-01-14 | Petroleum pesticide for tropical fruit tree |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94110023 CN1105189A (en) | 1994-01-14 | 1994-01-14 | Petroleum pesticide for tropical fruit tree |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1105189A true CN1105189A (en) | 1995-07-19 |
Family
ID=5034016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94110023 Pending CN1105189A (en) | 1994-01-14 | 1994-01-14 | Petroleum pesticide for tropical fruit tree |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1105189A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651574A (en) * | 2013-12-12 | 2014-03-26 | 中国热带农业科学院环境与植物保护研究所 | Mineral oil emulsion, and preparation method and application thereof |
| CN108902203A (en) * | 2018-04-20 | 2018-11-30 | 钟祥品红植物免疫科技有限公司 | A kind of agricultural builder of coconut oil and its preparation method and application for killing harmful mite |
| CN109691445A (en) * | 2019-01-21 | 2019-04-30 | 深圳市爱美町植物营养免疫科技有限公司 | A kind of agricultural builder of palm oil and its preparation method and application |
| CN110250177A (en) * | 2019-08-02 | 2019-09-20 | 沧州佳和生物科技有限公司 | A kind of NEW TYPE OF COMPOSITE mineral spirits oil insecticidal and preparation method thereof |
-
1994
- 1994-01-14 CN CN 94110023 patent/CN1105189A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651574A (en) * | 2013-12-12 | 2014-03-26 | 中国热带农业科学院环境与植物保护研究所 | Mineral oil emulsion, and preparation method and application thereof |
| CN103651574B (en) * | 2013-12-12 | 2015-09-16 | 中国热带农业科学院环境与植物保护研究所 | Mineral oil emulsion and preparation method thereof and application |
| CN108902203A (en) * | 2018-04-20 | 2018-11-30 | 钟祥品红植物免疫科技有限公司 | A kind of agricultural builder of coconut oil and its preparation method and application for killing harmful mite |
| CN109691445A (en) * | 2019-01-21 | 2019-04-30 | 深圳市爱美町植物营养免疫科技有限公司 | A kind of agricultural builder of palm oil and its preparation method and application |
| CN110250177A (en) * | 2019-08-02 | 2019-09-20 | 沧州佳和生物科技有限公司 | A kind of NEW TYPE OF COMPOSITE mineral spirits oil insecticidal and preparation method thereof |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |