CN110512426A - A kind of preparation method of water proof fire retardant textile - Google Patents
A kind of preparation method of water proof fire retardant textile Download PDFInfo
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- CN110512426A CN110512426A CN201910780719.4A CN201910780719A CN110512426A CN 110512426 A CN110512426 A CN 110512426A CN 201910780719 A CN201910780719 A CN 201910780719A CN 110512426 A CN110512426 A CN 110512426A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3564—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing phosphorus
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3568—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Fireproofing Substances (AREA)
Abstract
The present invention relates to after-finishing of textile products field, especially a kind of water proof fire retardant textile and preparation method thereof.Its textile is by fire retarding treating liquid and water-proof finish liquid successively treated textile；The fire retarding treating liquid at least is prepared to obtain by fire retardant, siloxanes, solvent, initiator, water and softening agent；The component of the waterproofing agent includes at least water, waterproofing agent and bleeding agent；It is successively arranged by fire retarding treating liquid and water-proof finish liquid, has obtained water-fastness, environmentally friendly, and the textile that anti-flammability and waterproof performance are very excellent.
Description
Technical field
The present invention relates to after-finishing of textile products field, especially a kind of preparation method of water proof fire retardant textile.
Background technique
In recent years, fire ratio caused by textile is on the rise, and causes immeasurable loss.Therefore, weaving resistance
Combustion technology is worth further investigated, more needs to adopt a series of measures to reduce the influence of textile fire.Currently, flame retardant textiles
Exploitation is one of effective way, and the technology that Fire-proof Finishing Agents for Textile arranges also is improved in the raising with science and technology.
Although there are many mature cotton flame retardant, there are still many problems, such as cost are relatively high, color control is tired
Difficulty, environmental pollution degree and risk are bigger.Many common cotton fabric permanent flame-retardants have Pyrovatex CP and THPC
And its improved products, though being not present, smoke amount is big, discharges the problems such as toxic chlorinated hydrogen, and these two types of fire retardants, which exist, to be released
The problem of putting formaldehyde (formaldehyde can induce to cancer).Some commercially available no aldehyde fire retardant environment protectings are good, but washability is poor, therefore open
Sending out cigarette, low toxicity, low-methoxyl aldehyde or formaldehydeless and durable product low is the new direction of cotton flame retardant development.
Further, since textile product becomes increasingly abundant, functional textile is given in international market and is paid high attention to, exploitation is assigned
The product for giving fabric functional, reforms existing textile technology, is not only able to satisfy consumer increasingly high quality, more function
Energy, the demand that pattern is more, superior, and the attached value of product can be improved energetically.But majority fire resistance fibre or fabric at present
Only single flame retarding function, it is difficult to provide service to become privileged market, flame retardant products are further improved, there is fabric more
Weight function, such as fire-resistant waterproof, flame-retardant and anti-static product.For this phenomenon, the prior art is often handled with fluorine-containing water repellent, though
Right waterproof effect is fine, but feel is harder, price is expensive, more poor to the natural fibers waterproofness such as cotton fabric than traditional.
Prepare as a result, at a low price, the textile of multi-functional become research emphasis at this stage.
Summary of the invention
In order to solve the above-mentioned technical problem, first aspect of the present invention provides a kind of water proof fire retardant textile, weaving
Product are by fire retarding treating liquid and water-proof finish liquid successively treated textile；The fire retarding treating liquid at least by fire retardant,
Siloxanes, solvent, initiator, water and softening agent are prepared to obtain；The component of the waterproofing agent includes at least water, waterproofing agent and infiltration
Agent.
As a preferred technical solution of the present invention, by weight, the fire retarding treating liquid is at least by following raw material
Preparation obtains, 35-38 parts of fire retardant, 42-50 parts of siloxanes, 40-50 parts of solvent, 1-1.5 parts of initiator, 50 parts of water and softening agent
3-5 parts.
As a preferred technical solution of the present invention, the fire retardant is the phosphate compounds containing alkenyl.
As a preferred technical solution of the present invention, the siloxanes is the siloxanes containing alkenyl, long chain alkane.
As a preferred technical solution of the present invention, the initiator is peroxide.
As a preferred technical solution of the present invention, the solvent is ethyl acetate, toluene, dimethylbenzene, acetone, acetic acid
One of butyl ester, cyclohexanone, butanone, methanol are a variety of.
As a preferred technical solution of the present invention, by weight, the water-proof finish liquid is included at least with the following group
Point, 100 parts of water, 6-10 parts of waterproofing agent and 0.6-0.7 parts of bleeding agent.
As a preferred technical solution of the present invention, the waterproofing agent is the amide containing long chain alkane.
As a preferred technical solution of the present invention, the textile is cotton fabric.
The second aspect of the invention provides the preparation method of water proof fire retardant textile, and the preparation method includes as follows
Step:
(1) textile is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
It closes, 40-60min is stirred at 80 DEG C, by the initiation of the fire retardant of remaining one third, the solvent of half, one third
Agent and siloxanes mix, and keeping temperature is to instill in reaction system at 80 DEG C, stir 1-2h, cooling to get solution 1；
S2: by weight, solution 1 and water, softening agent that S1 is obtained is mixed to get fire retarding treating liquid, textile is set
Enter in fire retarding treating liquid, impregnates 2-5h, dry to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 2-4h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
The utility model has the advantages that the present invention provides a kind of water proof fire retardant textiles and preparation method thereof, and compared with prior art, solution
The problem that textile of having determined has water proof fire retardant also water-fastness, so that textile not only has the performance of water proof fire retardant, Er Qieshi
Proved recipe case has the advantages that low cost, environmental protection.
Specific embodiment
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily to understand
Bright content.Unless otherwise defined, all technologies used herein and scientific term have common with fields of the present invention
The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... preparation " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements
Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or
Such composition, step, method, product or the intrinsic element of device.
Singular includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " any
It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit
When the Range Representation that choosing value limits, this should be understood as specifically disclosing by any range limit or preferred value and any range
Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open
When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise the range is intended to include its end
Value and all integers and score in the range.
In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component
(i.e. frequency of occurrence) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number
The element or component of form also include plural form, unless the obvious purport of the quantity refers to singular.
In order to solve the above-mentioned technical problem, the first aspect of the invention provides a kind of water proof fire retardant textile, spins
Fabric is by fire retarding treating liquid and water-proof finish liquid successively treated textile.
In a preferred embodiment, the fire retarding treating liquid at least is prepared to obtain by following raw material, fire retardant 35-
38 parts, 42-50 parts of siloxanes, 40-50 parts of solvent, 1-1.5 parts of initiator, 50 parts of water and 3-5 parts of softening agent.
In a kind of preferred embodiment, the fire retarding treating liquid at least is prepared to obtain by following raw material, fire retardant
36-37 parts, 45-48 parts of siloxanes, 42-48 parts of solvent, 1.2-1.4 parts of initiator, 50 parts of water and 4-4.8 parts of softening agent.
In a kind of most preferred embodiment, the fire retarding treating liquid at least is prepared to obtain by following raw material, fire retardant
36.5 parts, 47 parts of siloxanes, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent.
In a preferred embodiment, the water-proof finish liquid includes at least following components, 100 parts of water, waterproofing agent
6-10 parts and bleeding agent 0.6-0.7 parts.
In a kind of preferred embodiment, the water-proof finish liquid includes at least following components, 100 parts of water, waterproof
7-9 parts and bleeding agent 0.62-0.68 parts of agent.
In a kind of most preferred embodiment, the water-proof finish liquid includes at least following components, 100 parts of water, waterproof
8 parts and 0.65 part of bleeding agent of agent.
Fire retardant
Fire retardant of the present invention is a kind of functional aid for assigning combustible polymers flame retardancy, primarily directed to high score
The Principle And Method of Flame Retardation Design of sub- material；There are many types for fire retardant, are divided into additive flame retardant and reactive flame retardant by application method.
In a preferred embodiment, fire retardant of the present invention is the phosphate compounds containing alkenyl.
In a preferred embodiment, fire retardant of the present invention is selected from: dimethyl ethenyl phosphate, 1- diformazan
Oxygroup phosphinylidyne vinyl diethyl phosphate, diethyl vinyl phosphate.
In a kind of most preferred embodiment, the phosphate compounds of the present invention containing alkenyl are dimethyl second
Alkenyl phosphate (CAS:4645-32-3).
Siloxanes
Siloxanes of the present invention is that polymerization reaction can occur with alkenyl and can have chemical work with hydroxyl after hydrolyzing
Compound.
In a preferred embodiment, siloxanes of the present invention is the siloxanes containing alkenyl, long chain alkane.
In a kind of most preferred embodiment, siloxanes of the present invention is docosene ethyl triethoxy silicane alkane
(CAS:330457-44-8)。
The inventors of the present application found that passing through the group of dimethyl ethenyl phosphate and the long chain alkane siloxanes containing alkenyl
It closes and uses, effectively improve fabric intolerant to the phenomenon of washing and flame retardant effect difference, possible cause is due to dimethylvinylsiloxy
Base phosphate presented in high-temp combustion it is high dehydrated, occur the endothermic reaction and generate easily form fine and close carbonization in fabric surface
The covering of layer, has obstructed the transmitting of heat and oxygen, has slowed down the burning of fabric, had the effect of cotton fabric fire-retardant；And contain
The polar group that the long chain alkane siloxanes of alkenyl generates after hydrolysis easily forms active force, another party with surface of cotton fabric hydroxyl
Alkenyl in long chain alkane siloxanes of the face containing alkenyl is crosslinked with the unsaturated bond in fire retardant to react, and effectively improves
Fixation rate of the fire retardant on cotton fabric improves the phenomenon of flame retardant effect difference after cotton fabric is repeatedly washed；In addition, the present invention is logical
It crosses experiment to be found surprisingly that, the presence of the long chain alkane siloxanes containing alkenyl also contributes to improving the anti-flammability of cotton fabric, can
It can be the reason is that since long chain alkane siloxanes in the case where high-temp combustion containing alkenyl easily forms the oxygen barrier guarantor containing Si-O key
Sheath has synergistic effect with above-mentioned dimethyl ethenyl phosphate, the thermal decomposition of cotton fabric is not only inhibited to be also prevented from cotton
The evolution of fabric combustion product, so that cotton fabric has superior flame retardant property.
Initiator
Initiator of the present invention is also known as radical initiator, refer to it is a kind of be easy to be thermally decomposed into free radical (it is i.e. primary from
By base) compound, can be used for causing alkenes, the free radical polymerization of double vinyl monomers and copolymerization, it can also be used to insatiable hunger
It is reacted with the crosslinking curing and high molecular crosslink of polyester.
In a preferred embodiment, initiator of the present invention is peroxide or azo compound.
As the example of peroxide, including but not limited to: benzoyl peroxide, benzoyl peroxide, peroxide
Change methyl ethyl ketone.
In a kind of most preferred embodiment, initiator of the present invention is benzoyl peroxide.
Solvent
Solvent of the present invention is that one kind can dissolve solid, and the liquid (gas or solid) of liquid or gaseous solute is (molten
Agent, solute can be solid, liquid, gas), then become solution.
In a kind of preferred real mode, solvent of the present invention is esters, benzene class, ketone, any one in alcohols.
In a kind of preferred real mode, solvent of the present invention is ethyl acetate, toluene, dimethylbenzene, acetone, acetic acid fourth
Ester, cyclohexanone, butanone, any one in methanol.
In a kind of most preferred embodiment, solvent of the present invention is ethyl acetate.
Softening agent
Softening agent is a kind of quiet, dynamic friction coefficient chemical substance that can change fiber.When changing confficient of static friction, hand
Thoughts and feelings touches with smooth sense, is easy to move on fiber or fabric；It is fine between fiber and fiber when changing dynamic friction coefficient
Structure is easy to be mutually shifted, that is, fiber or fabric it is easily deformable.The comprehensive of the two feels to be exactly soft.
In a preferred embodiment, softening agent of the present invention is non-ionic softening agent.
As the example of non-ionic softening agent, including but not limited to: pentaerythritol fatty ester, monoglycerides fat acid
Ester, sorbitan fatty acid ester, fatty diglycollic amide.
In a kind of most preferred embodiment, softening agent of the present invention be fatty diglycollic amide (CAS:
68603-42-9)。
Waterproofing agent
Waterproofing agent of the present invention is no fluoro water proofing agent.
In a preferred embodiment, waterproofing agent of the present invention is the amide containing long chain alkane.
In a preferred embodiment, waterproofing agent of the present invention is selected from: N- octadecyl-erucyl amide, 2- (ten
Dialkyl)-acetamide, 3- nitro-N- octadecyl benzamide, N- dodecyl -2- methyl propyl- 2- acrylamide, N-
Dodecyl -2- methyl propyl- 2- acrylamide.
In a kind of most preferred embodiment, waterproofing agent of the present invention is N- dodecyl -2- methyl propyl- 2- alkene acyl
Amine (CAS:1191-39-5).
Since fluorine atom has the advantages that low-surface-energy, strong electronegativity, high C-F key bond energy, the prior art is often used fluorine-containing
The compound of alkyl chain handles the waterproof performance of fabric, but for cotton fabric, feel compares after being handled with fluorine-containing water repellent
Firmly, waterproofness is poor；Present inventor then uses floride-free waterproofing agent i.e. N- dodecyl -2- methyl propyl- 2- alkene acyl
Amine handles cotton fabric, so that cotton fabric has excellent waterproof performance；Ordinary circumstance, N- dodecyl -2- methyl propyl-
2- acrylamide is commonly used to the waterproofness of processing synthetic fiber surface, but present invention N- dodecyl -2- methyl propyl- 2- alkene acyl
Amine also achieves excellent effect to handle cotton fabric, and reason may be due to N- dodecyl -2- methyl propyl- 2- acrylamide
In polar group easily with the hydroxyl generation of fiber surface act on, non-polar group is densely aligned in fiber surface, so that cotton
Fabric not only has the function of waterproof, but also the washing of its waterproofness through a long time will not be deteriorated；In addition, N- dodecyl -2-
Methyl propyl- 2- acrylamide and docosene ethyl triethoxy silicane alkane have synergistic effect, strengthen the waterproofness of cotton fabric jointly,
Its possible cause is that the crosslinking of fiber and fire retardant has not only been ensured due to docosene ethyl triethoxy silicane alkane, is also cotton fabric
Long carbon chain is introduced, the reticulated film for forming water repellency in surface of cotton fabric is aligned, reduces the surface tension of fiber,
Further enhance the waterproofness of cotton fabric.
Bleeding agent
The full name of bleeding agent of the present invention is fatty alcohol polyoxyethylene ether, and abbreviation JFC belongs to nonionic surfactant.
In a preferred embodiment, bleeding agent of the present invention is fatty alcohol polyoxyethylene ether (CAS:68131-
39-5)。
Textile
Textile of the present invention is cotton fabric.
The second aspect of the invention provides the preparation method of water proof fire retardant textile, and the preparation method includes as follows
Step:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
It closes, 40-60min is stirred at 80 DEG C, by the initiation of the fire retardant of remaining one third, the solvent of half, one third
Agent and siloxanes mix, and keeping temperature is to instill in reaction system at 80 DEG C, stir 1-2h, cooling to get solution 1；
S2: by weight, solution 1 and water, softening agent that S1 is obtained is mixed to get fire retarding treating liquid, textile is set
Enter in fire retarding treating liquid, impregnates 2-5h, dry to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 2-4h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment
Embodiment 1
Embodiment 1 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；The fire retarding treating liquid at least is prepared to obtain by the raw material of following parts by weight, 36.5 parts of fire retardant, silicon oxygen
47 parts of alkane, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent；The water-proof finish liquid includes at least following heavy
Measure the component of part, 100 parts of water, 8 parts of waterproofing agent and 0.65 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is docosene ethyl triethoxy silicane alkane.
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 2
Embodiment 2 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；The fire retarding treating liquid at least is prepared to obtain by the raw material of following parts by weight, 35 parts of fire retardant, siloxanes
42 parts, 40 parts of solvent, 1.2 parts of initiator, 50 parts of water and 4 parts of softening agent；The water-proof finish liquid includes at least following parts by weight
Component, 100 parts of water, 6 parts of waterproofing agent and 0.62 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is docosene ethyl triethoxy silicane alkane.
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 3
Embodiment 3 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；The fire retarding treating liquid at least is prepared to obtain by the raw material of following parts by weight, 38 parts of fire retardant, siloxanes
50 parts, 50 parts of solvent, 1.4 parts of initiator, 50 parts of water and 4.8 parts of softening agent；The water-proof finish liquid includes at least following weight
The component of part, 100 parts of water, 10 parts of waterproofing agent and 0.68 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is docosene ethyl triethoxy silicane alkane.
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 4
Embodiment 4 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；The fire retarding treating liquid at least is prepared to obtain by the raw material of following parts by weight, 36.5 parts of fire retardant, silicon oxygen
47 parts of alkane, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent；The water-proof finish liquid includes at least following heavy
Measure the component of part, 100 parts of water, 4 parts of waterproofing agent and 0.65 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is docosene ethyl triethoxy silicane alkane.
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 5
Embodiment 5 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；The fire retarding treating liquid at least is prepared to obtain by the raw material of following parts by weight, 36.5 parts of fire retardant, silicon oxygen
30 parts of alkane, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent；The water-proof finish liquid includes at least following heavy
Measure the component of part, 100 parts of water, 8 parts of waterproofing agent and 0.65 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is docosene ethyl triethoxy silicane alkane.
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 6
Embodiment 6 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；The fire retarding treating liquid at least is prepared to obtain by the raw material of following parts by weight, 36.5 parts of fire retardant, silicon oxygen
60 parts of alkane, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent；The water-proof finish liquid includes at least following heavy
Measure the component of part, 100 parts of water, 8 parts of waterproofing agent and 0.65 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is docosene ethyl triethoxy silicane alkane.
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 7
Embodiment 7 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；The fire retarding treating liquid at least is prepared to obtain by the raw material of following parts by weight, 30 parts of fire retardant, siloxanes
47 parts, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent；The water-proof finish liquid includes at least following weight
The component of part, 100 parts of water, 8 parts of waterproofing agent and 0.65 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is docosene ethyl triethoxy silicane alkane.
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 8
Embodiment 8 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；By weight, the fire retarding treating liquid at least is prepared to obtain by following raw material, 36.5 parts of fire retardant,
47 parts of siloxanes, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent；The water-proof finish liquid include at least with
The component of lower parts by weight, 100 parts of water, 8 parts of waterproofing agent and 0.65 part of bleeding agent.
The fire retardant is phosphate.
The siloxanes is docosene ethyl triethoxy silicane alkane.
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 9
Embodiment 9 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；The fire retarding treating liquid at least is prepared to obtain by the raw material of following parts by weight, 36.5 parts of fire retardant, silicon oxygen
47 parts of alkane, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent；The water-proof finish liquid includes at least following heavy
Measure the component of part, 100 parts of water, 8 parts of waterproofing agent and 0.65 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is myristyl triethoxysilane (CAS:16153-27-8).
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Embodiment 10
Embodiment 1 provides a kind of water proof fire retardant textile, and textile is by fire retarding treating liquid and water-proof finish liquid
Treated textile；, the fire retarding treating liquid at least prepared to obtain by the raw material of following parts by weight, 36.5 parts of fire retardant, silicon
47 parts of oxygen alkane, 45 parts of solvent, 1.3 parts of initiator, 50 parts of water and 4.5 parts of softening agent；The water-proof finish liquid includes at least following
The component of parts by weight, 100 parts of water, 8 parts of waterproofing agent and 0.65 part of bleeding agent.
The fire retardant is dimethyl ethenyl phosphate.
The siloxanes is methylvinyldimethoxysilane (CAS:16753-62-1).
The initiator is benzoyl peroxide.
The solvent is ethyl acetate.
The softening agent is fatty diglycollic amide.
The waterproofing agent is N- dodecyl -2- methyl propyl- 2- acrylamide.
The bleeding agent is fatty alcohol polyoxyethylene ether.
The textile is cotton fabric.
The preparation method of the water proof fire retardant textile, comprising the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator it is mixed
Close, stir 50min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and
Siloxanes mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1.5h, cooling to get solution 1；
S2: by weight, 1 water of solution that S1 is obtained, softening agent is mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 3.5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 3h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
Performance evaluation
1. flame retardant property is tested
With reference to GB/T5455-2014 test method, by water proof fire retardant textile prepared by embodiment 1 to embodiment 10 into
The test of row flame retardant property.
2. waterproof performance is tested
With reference to GB/T4745-1997 test method, by water proof fire retardant textile prepared by embodiment 1 to embodiment 10 into
The test of row waterproof performance.
Test result is as follows shown in 1 table.
1 test data of table summarizes
As can be seen from Table 1, the water proof fire retardant textile in the present invention has excellent waterproofness and flame retardant property, especially
It is that its flame retardant property and waterproof performance are still very excellent after repeatedly washing；In addition, when the present invention uses the phosphorus containing alkenyl
Acid esters compound is waterproofing agent using the amide containing long chain alkane as fire retardant, and with contain alkenyl, long chain alkane
Siloxanes matches, and waterproof performance and flame retardant property are all optimal.
Example above-mentioned is merely illustrative, and is used to explain the present invention some features of the method.Appended right is wanted
The range as wide as possible for being intended to require to be contemplated that is sought, and embodiments as presented herein is only according to all possible implementation
The explanation of the embodiment of the combined selection of example.Therefore, the purpose of applicant is that the attached claims are not illustrated this hair
The exemplary selectional restriction of bright feature.Some numberical ranges used also include sub- model in the claims
It encloses, the variation in these ranges should also be construed to be covered by the attached claims in the conceived case.
Claims (10)
1. a kind of water proof fire retardant textile, which is characterized in that its textile be by fire retarding treating liquid and water-proof finish liquid successively
Treated textile；The fire retarding treating liquid is at least by fire retardant, siloxanes, solvent, initiator, water and softening agent with obtained
It arrives；The component of the waterproofing agent includes at least water, waterproofing agent and bleeding agent.
2. a kind of water proof fire retardant textile according to claim 1, which is characterized in that by weight, described fire-retardant whole
Reason liquid at least is prepared to obtain by following raw material, 35-38 parts of fire retardant, 42-50 parts of siloxanes, 40-50 parts of solvent, initiator 1-
1.5 parts, 50 parts of water and 3-5 parts of softening agent.
3. a kind of water proof fire retardant textile according to claim 2, which is characterized in that the fire retardant is to contain alkenyl
Phosphate compounds.
4. a kind of water proof fire retardant textile according to claim 2, which is characterized in that the siloxanes is containing alkenyl, length
The siloxanes of alkane.
5. a kind of water proof fire retardant textile according to claim 2, which is characterized in that the initiator be peroxide or
Azo compound.
6. a kind of water proof fire retardant textile according to claim 2, which is characterized in that the solvent is esters, benzene class, ketone
Any one in class, alcohols.
7. a kind of water proof fire retardant textile according to claim 1, which is characterized in that by weight, the waterproof is whole
It manages liquid and includes at least following components, 100 parts of water, 6-10 parts of waterproofing agent and 0.6-0.7 parts of bleeding agent.
8. a kind of water proof fire retardant textile according to claim 7, which is characterized in that the waterproofing agent is to contain long alkane
The amide of hydrocarbon.
9. a kind of water proof fire retardant textile according to claim 1, which is characterized in that the textile is cotton fabric.
10. a kind of preparation method of -9 described in any item water proof fire retardant textiles according to claim 1, which is characterized in that institute
Preparation method is stated to include the following steps:
(1) cotton fabric is subjected to flame-proof treatment:
S1: by weight, by 2/3rds fire retardant, the solvent of half and 2/3rds initiator mix, In
Stir 40-60min at 80 DEG C, by the fire retardant of remaining one third, the solvent of half, one third initiator and silicon
Oxygen alkane mixes, and keeping temperature is to instill in reaction system at 80 DEG C, stirs 1-2h, cooling to get solution 1；
S2: water, the softening agent of solution 1 and above-mentioned parts by weight that S1 is obtained are mixed to get fire retarding treating liquid, textile is placed in
In fire retarding treating liquid, 2-5h is impregnated, is dried to get textile 1；
(2) textile 1 is subjected to water-proof finish:
S1: by weight, water, waterproofing agent and bleeding agent are mixed to get water-proof finish liquid；
S2: textile 1 is placed in water-proof finish liquid and impregnates 2-4h, dry to get textile 2；
(3) post-process: after the textile 2 after water-proofing treatment is soaped and is washed dry to get.
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| CN111960799A (en) * | 2020-07-16 | 2020-11-20 | 北京奥克森节能环保科技有限公司 | Fireproof coating material and application thereof |
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