CN107747218A - A kind of flame-proof finishing process of bafta - Google Patents
A kind of flame-proof finishing process of bafta Download PDFInfo
- Publication number
- CN107747218A CN107747218A CN201710981705.XA CN201710981705A CN107747218A CN 107747218 A CN107747218 A CN 107747218A CN 201710981705 A CN201710981705 A CN 201710981705A CN 107747218 A CN107747218 A CN 107747218A
- Authority
- CN
- China
- Prior art keywords
- bafta
- flame
- fire retardant
- finishing process
- proof finishing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of flame-proof finishing process of bafta, comprise the following steps：S1, prepare dressing liquid；S2, arrangement；Baked after S3, preliminary drying；S4, washing are simultaneously dried；The concrete technology for preparing dressing liquid is as follows：Fire retardant, zinc nitrate, AEO, polypropylene glycol, carboxymethyl cellulose, amido silicon oil are added in ethanol water and be well mixed, regulation pH obtains the dressing liquid for 2.3 2.5.The flame-proof finishing process of bafta proposed by the present invention, its step is simple, and raw material is easy to get, and is easy to industrialized production, and obtained bafta has excellent anti-flammability, and intensity is high, is unlikely to deform.
Description
Technical field
The present invention relates to printing technology field, more particularly to a kind of flame-proof finishing process of bafta.
Background technology
Bafta is a kind of natural fabric, because it has soft handle and characteristic comfortable and easy to wear, more other conjunctions
Have into fiber and be more widely applied.But because Gossypium is in inflammable articles, it is the potential origin cause of formation of fire, needs to carry out mostly
Flame-proof treatment is to meet different degrees of fire prevention demand, but so far, what existing bafta flame-retardant finishing method obtained
The defects of anti-flammability is not good enough be present in bafta.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of flame-proof finishing process of bafta, and it is walked
Rapid simple, raw material is easy to get, and is easy to industrialized production, and obtained bafta has excellent anti-flammability, and intensity is high, not variable
Shape.
A kind of flame-proof finishing process of bafta proposed by the present invention, comprises the following steps：S1, prepare dressing liquid；It is S2, whole
Reason；Baked after S3, preliminary drying；S4, washing are simultaneously dried；
Wherein, the concrete technology for preparing dressing liquid is as follows：By fire retardant, zinc nitrate, AEO, poly- the third two
Alcohol, carboxymethyl cellulose, amido silicon oil are added in ethanol water and are well mixed, and regulation pH is that 2.3-2.5 obtains the arrangement
Liquid.
Preferably, in dressing liquid, the mass fraction of fire retardant is 20-45wt%, and nitric acid zinc concentration is 1-2g/L,
The concentration of AEO is 5-8g/L, and the concentration of polypropylene glycol is 1-3g/L, and the concentration of carboxymethyl cellulose is 1-
3g/L, the concentration of amido silicon oil is 1-2g/L.
Preferably, the raw material of the fire retardant includes phospho hetero phenanthrene fire retardant, urea, trimethylamine, MTMS
And APP, and phospho hetero phenanthrene fire retardant, urea, trimethylamine, the weight ratio of MTMS and APP are 5-
16：1-5：1-3：2-8：3-10.
Preferably, prepared by the following technique of phospho hetero phenanthrene fire retardant：By sodium methoxide, 9,10- dihydro -9- oxa-s -
10- phospho hetero phenanthrene -10- oxides and acrylamide are added in acetone, insulation reaction 50-130min after being warming up to 55-60 DEG C, instead
It is evaporated under reduced pressure after should terminating and obtains material A；Cyanuric Chloride is added in acetone, adds part thing after stirring at 0-5 DEG C
Expect A, stirring reaction 20-50min, remaining material A is added after being warming up to 45-55 DEG C, distills, dry after reaction 40-60min
To the phospho hetero phenanthrene fire retardant.
Preferably, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, the weight ratio of acrylamide are 20-25：
5-8。
Preferably, Cyanuric Chloride, the weight ratio of material A are 15-20：58-65.
Preferably, the weight of the partial material A is the 30-50wt% of material A gross weight.
Preferably, it is described to arrange using two two roll process of leaching, pick-up 80-95%.
Preferably, the temperature of preliminary drying is 100-110 DEG C, and the time of preliminary drying is 10-20min；The temperature baked is 155-170
DEG C, the time baked is 1-2.5min.
The flame-proof finishing process of bafta of the present invention, it have selected phospho hetero phenanthrene fire retardant, urea, trimethylamine, methyl three
Methoxy silane and APP are the fire retardant of dressing liquid, first in the preparation process of phospho hetero phenanthrene fire retardant in preferred embodiment
First using 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and acrylamide as raw material, by controlling the condition of reaction,
Make 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and acrylamide there occurs addition reaction to have obtained material A, it
After coordinating afterwards with Cyanuric Chloride, the chlorine in amino and Cyanuric Chloride in material A is reacted, so as to by Cyanuric Chloride, 9,
Miscellaneous -10- phospho hetero phenanthrenes -10- the oxides of 10- dihydro-9-oxies and acrylamide are combined as a whole, and it is fire-retardant to have obtained the phospho hetero phenanthrene
Agent, it is added into system, is uniformly dispersed in system, on the one hand, because introducing phospho hetero phenanthrene and class triazine structure in system,
Assign fabric excellent heat resistance and anti-flammability, on the one hand, to add urea in fire retardant, it has with phospho hetero phenanthrene fire retardant
Synergy, reduces the dosage of phospho hetero phenanthrene fire retardant, improves flame retardant effect, on the other hand, adds trimethylamine, energy and phosphorus
Miscellaneous luxuriant and rich with fragrance fire retardant forms quaternary ammonium salt, the reactivity of phospho hetero phenanthrene fire retardant and cellulose is enhanced, with MTMS
Coordinate with APP, assign fabric excellent anti-flammability, hydrophobicity and heat resistance；According to the property of dressing liquid fire retardant,
During baking, it is 155-170 DEG C to control the temperature baked, and the time baked is 1-2.5min, is keeping less cotton
In the case that fiber strength loses, the anti-flammability of fabric is significantly improved.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of flame-proof finishing process of bafta proposed by the present invention, comprises the following steps：S1, prepare dressing liquid；It is S2, whole
Reason；Baked after S3, preliminary drying；S4, washing are simultaneously dried；
Wherein, the concrete technology for preparing dressing liquid is as follows：By fire retardant, zinc nitrate, AEO, poly- the third two
Alcohol, carboxymethyl cellulose, amido silicon oil are added in ethanol water and are well mixed, and regulation pH obtains the dressing liquid for 2.5.
Embodiment 2
A kind of flame-proof finishing process of bafta proposed by the present invention, comprises the following steps：S1, prepare dressing liquid；It is S2, whole
Reason；Baked after S3, preliminary drying；S4, washing are simultaneously dried；
Wherein, the concrete technology for preparing dressing liquid is as follows：By fire retardant, zinc nitrate, AEO, poly- the third two
Alcohol, carboxymethyl cellulose, amido silicon oil are added in ethanol water and are well mixed, and regulation pH obtains the dressing liquid for 2.3.
Embodiment 3
A kind of flame-proof finishing process of bafta proposed by the present invention, comprises the following steps：S1, prepare dressing liquid；It is S2, whole
Reason；Baked after S3, preliminary drying；S4, washing are simultaneously dried；
Wherein, the concrete technology for preparing dressing liquid is as follows：By fire retardant, zinc nitrate, AEO, poly- the third two
Alcohol, carboxymethyl cellulose, amido silicon oil are added in ethanol water and are well mixed, and regulation pH obtains the dressing liquid for 2.3；
Wherein, in dressing liquid, the mass fraction of fire retardant is 20wt%, and nitric acid zinc concentration is 2g/L, poly alkyl alcohol
The concentration of oxygen vinethene is 5g/L, and the concentration of polypropylene glycol is 3g/L, and the concentration of carboxymethyl cellulose is 1g/L, amido silicon oil
Concentration is 2g/L；
The raw material of the fire retardant includes phospho hetero phenanthrene fire retardant, urea, trimethylamine, MTMS and polyphosphoric acid
Ammonium, and phospho hetero phenanthrene fire retardant, urea, trimethylamine, the weight ratio of MTMS and APP are 5：5：1：8：3；
It is prepared by the following technique of phospho hetero phenanthrene fire retardant：By sodium methoxide, the miscellaneous -10- phosphorus of 9,10- dihydro-9-oxies
Miscellaneous phenanthrene -10- oxides and acrylamide are added in acetone, wherein, the miscellaneous -10- phospho hetero phenanthrenes -10- oxidations of 9,10- dihydro-9-oxies
Thing, the weight ratio of acrylamide are 20：8, insulation reaction 130min after being warming up to 55 DEG C, reaction are evaporated under reduced pressure after terminating and obtain thing
Expect A；Cyanuric Chloride is added in acetone, partial material A is added after stirring at 0 DEG C, stirring reaction 50min, is warming up to
Remaining material A is added after 45 DEG C, is distilled after reaction 60min, drying obtains the phospho hetero phenanthrene fire retardant；The partial material A
Weight be material A gross weight 30wt%, wherein, Cyanuric Chloride, material A weight ratio be 20：58；
It is described to arrange using two two roll process of leaching, pick-up 95%；
During being baked after preliminary drying, the temperature of preliminary drying is 100 DEG C, and the time of preliminary drying is 20min；The temperature baked is
155 DEG C, the time baked is 2.5min.
Embodiment 4
A kind of flame-proof finishing process of bafta proposed by the present invention, comprises the following steps：S1, prepare dressing liquid；It is S2, whole
Reason；Baked after S3, preliminary drying；S4, washing are simultaneously dried；
Wherein, the concrete technology for preparing dressing liquid is as follows：By fire retardant, zinc nitrate, AEO, poly- the third two
Alcohol, carboxymethyl cellulose, amido silicon oil are added in ethanol water and are well mixed, and regulation pH obtains the dressing liquid for 2.4；
Wherein, in dressing liquid, the mass fraction of fire retardant is 45wt%, and nitric acid zinc concentration is 1g/L, poly alkyl alcohol
The concentration of oxygen vinethene is 8g/L, and the concentration of polypropylene glycol is 1g/L, and the concentration of carboxymethyl cellulose is 3g/L, amido silicon oil
Concentration is 1g/L；
The raw material of the fire retardant includes phospho hetero phenanthrene fire retardant, urea, trimethylamine, MTMS and polyphosphoric acid
Ammonium, and phospho hetero phenanthrene fire retardant, urea, trimethylamine, the weight ratio of MTMS and APP are 16：1：3：2：
10；
It is prepared by the following technique of phospho hetero phenanthrene fire retardant：By sodium methoxide, the miscellaneous -10- phosphorus of 9,10- dihydro-9-oxies
Miscellaneous phenanthrene -10- oxides and acrylamide are added in acetone, wherein, the miscellaneous -10- phospho hetero phenanthrenes -10- oxidations of 9,10- dihydro-9-oxies
Thing, the weight ratio of acrylamide are 25：5, insulation reaction 50min after being warming up to 60 DEG C, reaction are evaporated under reduced pressure after terminating and obtain thing
Expect A；Cyanuric Chloride is added in acetone, partial material A is added after stirring at 5 DEG C, stirring reaction 20min, is warming up to
Remaining material A is added after 55 DEG C, is distilled after reaction 40min, drying obtains the phospho hetero phenanthrene fire retardant；The partial material A
Weight be material A gross weight 50wt%, Cyanuric Chloride, material A weight ratio be 15：65；
It is described to arrange using two two roll process of leaching, pick-up 80%；
During being baked after preliminary drying, the temperature of preliminary drying is 110 DEG C, and the time of preliminary drying is 10min；The temperature baked is
170 DEG C, the time baked is 1min.
Embodiment 5
A kind of flame-proof finishing process of bafta proposed by the present invention, comprises the following steps：S1, prepare dressing liquid；It is S2, whole
Reason；Baked after S3, preliminary drying；S4, washing are simultaneously dried；
Wherein, the concrete technology for preparing dressing liquid is as follows：By fire retardant, zinc nitrate, AEO, poly- the third two
Alcohol, carboxymethyl cellulose, amido silicon oil are added in ethanol water and are well mixed, and regulation pH obtains the dressing liquid for 2.4；
Wherein, in dressing liquid, the mass fraction of fire retardant is 40wt%, and nitric acid zinc concentration is 1.5g/L, fatty alcohol
The concentration of APEO is 6g/L, and the concentration of polypropylene glycol is 2g/L, and the concentration of carboxymethyl cellulose is 2g/L, amido silicon oil
Concentration be 1.3g/L；
The raw material of the fire retardant includes phospho hetero phenanthrene fire retardant, urea, trimethylamine, MTMS and polyphosphoric acid
Ammonium, and phospho hetero phenanthrene fire retardant, urea, trimethylamine, the weight ratio of MTMS and APP are 11：4：2：5：8；
It is prepared by the following technique of phospho hetero phenanthrene fire retardant：By sodium methoxide, the miscellaneous -10- phosphorus of 9,10- dihydro-9-oxies
Miscellaneous phenanthrene -10- oxides and acrylamide are added in acetone, wherein, the miscellaneous -10- phospho hetero phenanthrenes -10- oxidations of 9,10- dihydro-9-oxies
Thing, the weight ratio of acrylamide are 22：7, insulation reaction 110min after being warming up to 58 DEG C, reaction are evaporated under reduced pressure after terminating and obtain thing
Expect A；Cyanuric Chloride is added in acetone, partial material A is added after stirring at 3 DEG C, stirring reaction 35min, is warming up to
Remaining material A is added after 50 DEG C, is distilled after reaction 55min, drying obtains the phospho hetero phenanthrene fire retardant；The partial material A
Weight be material A gross weight 42wt%, Cyanuric Chloride, material A weight ratio be 17：60；
It is described to arrange using two two roll process of leaching, pick-up 85%；
During being baked after preliminary drying, the temperature of preliminary drying is 105 DEG C, and the time of preliminary drying is 15min；The temperature baked is
160 DEG C, the time baked is 2min.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (9)
1. a kind of flame-proof finishing process of bafta, it is characterised in that comprise the following steps：S1, prepare dressing liquid；S2, arrangement；
Baked after S3, preliminary drying；S4, washing are simultaneously dried；
Wherein, the concrete technology for preparing dressing liquid is as follows：By fire retardant, zinc nitrate, AEO, polypropylene glycol,
Carboxymethyl cellulose, amido silicon oil are added in ethanol water and are well mixed, and regulation pH is that 2.3-2.5 obtains the dressing liquid.
2. the flame-proof finishing process of bafta according to claim 1, it is characterised in that in dressing liquid, the matter of fire retardant
Amount fraction is 20-45wt%, and nitric acid zinc concentration is 1-2g/L, and the concentration of AEO is 5-8g/L, poly- the third two
The concentration of alcohol is 1-3g/L, and the concentration of carboxymethyl cellulose is 1-3g/L, and the concentration of amido silicon oil is 1-2g/L.
3. the flame-proof finishing process of bafta according to claim 1 or claim 2, it is characterised in that the raw material bag of the fire retardant
Include phospho hetero phenanthrene fire retardant, urea, trimethylamine, MTMS and APP, and phospho hetero phenanthrene fire retardant, urea, three
The weight ratio of methylamine, MTMS and APP is 5-16：1-5：1-3：2-8：3-10.
4. the flame-proof finishing process of bafta according to claim 3, it is characterised in that the following work of phospho hetero phenanthrene fire retardant
It is prepared by skill：Sodium methoxide, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and acrylamide are added in acetone,
Insulation reaction 50-130min after being warming up to 55-60 DEG C, reaction are evaporated under reduced pressure after terminating and obtain material A；Cyanuric Chloride is added third
In ketone, partial material A, stirring reaction 20-50min are added after stirring at 0-5 DEG C, is added after being warming up to 45-55 DEG C surplus
Remaining material A, react 40-60min after distillation, drying obtain the phospho hetero phenanthrene fire retardant.
5. the flame-proof finishing process of bafta according to claim 4, it is characterised in that the miscellaneous -10- phosphorus of 9,10- dihydro-9-oxies
Miscellaneous phenanthrene -10- oxides, the weight ratio of acrylamide are 20-25：5-8.
6. according to the flame-proof finishing process of the bafta of claim 4 or 5, it is characterised in that Cyanuric Chloride, the weight of material A
It is 15-20 to measure ratio：58-65.
7. according to the flame-proof finishing process of bafta any one of claim 4-6, it is characterised in that the partial material
A weight is the 30-50wt% of material A gross weight.
8. according to the flame-proof finishing process of bafta any one of claim 1-7, it is characterised in that described arrange uses
Two two roll process of leaching, pick-up 80-95%.
9. according to the flame-proof finishing process of bafta any one of claim 1-8, it is characterised in that the temperature of preliminary drying is
100-110 DEG C, the time of preliminary drying is 10-20min；The temperature baked is 155-170 DEG C, and the time baked is 1-2.5min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710981705.XA CN107747218A (en) | 2017-10-20 | 2017-10-20 | A kind of flame-proof finishing process of bafta |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710981705.XA CN107747218A (en) | 2017-10-20 | 2017-10-20 | A kind of flame-proof finishing process of bafta |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107747218A true CN107747218A (en) | 2018-03-02 |
Family
ID=61253710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710981705.XA Pending CN107747218A (en) | 2017-10-20 | 2017-10-20 | A kind of flame-proof finishing process of bafta |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107747218A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109235029A (en) * | 2018-09-03 | 2019-01-18 | 常熟华尚新材料科技有限公司 | Cotton fabric category fire retardant |
| CN110512426A (en) * | 2019-08-22 | 2019-11-29 | 张媛婷 | A kind of preparation method of water proof fire retardant textile |
| CN110924140A (en) * | 2019-12-18 | 2020-03-27 | 福建省德奥针织科技有限公司 | Production process of flame-retardant all-cotton knitted fabric |
| CN111021088A (en) * | 2019-12-27 | 2020-04-17 | 刘大刚 | Flame-retardant heat-insulation cloth |
| CN111155223A (en) * | 2020-01-10 | 2020-05-15 | 张威劲 | Preparation method of high-strength flame-retardant fabric |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101376665A (en) * | 2008-09-29 | 2009-03-04 | 四川东材科技集团股份有限公司 | Phosphaphenanthrene flame-retardant compound containing s-triazine structure, and preparation and use thereof |
| CN105040403A (en) * | 2015-06-11 | 2015-11-11 | 常熟新锦江印染有限公司 | Novel flame-proof treatment technology for cotton fabric |
| CN105780494A (en) * | 2014-12-19 | 2016-07-20 | 上海氟聚化学产品有限公司 | Formaldehyde-free easy-care crease-resistance finishing process for cotton fabrics |
| CN105986481A (en) * | 2015-01-27 | 2016-10-05 | 江苏联发纺织股份有限公司 | Durable flame-retarding finishing process for whole-cotton shirt fabric |
-
2017
- 2017-10-20 CN CN201710981705.XA patent/CN107747218A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101376665A (en) * | 2008-09-29 | 2009-03-04 | 四川东材科技集团股份有限公司 | Phosphaphenanthrene flame-retardant compound containing s-triazine structure, and preparation and use thereof |
| CN105780494A (en) * | 2014-12-19 | 2016-07-20 | 上海氟聚化学产品有限公司 | Formaldehyde-free easy-care crease-resistance finishing process for cotton fabrics |
| CN105986481A (en) * | 2015-01-27 | 2016-10-05 | 江苏联发纺织股份有限公司 | Durable flame-retarding finishing process for whole-cotton shirt fabric |
| CN105040403A (en) * | 2015-06-11 | 2015-11-11 | 常熟新锦江印染有限公司 | Novel flame-proof treatment technology for cotton fabric |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109235029A (en) * | 2018-09-03 | 2019-01-18 | 常熟华尚新材料科技有限公司 | Cotton fabric category fire retardant |
| CN110512426A (en) * | 2019-08-22 | 2019-11-29 | 张媛婷 | A kind of preparation method of water proof fire retardant textile |
| CN110512426B (en) * | 2019-08-22 | 2021-11-23 | 江苏大毛牛新材料有限公司 | Preparation method of waterproof flame-retardant textile |
| CN110924140A (en) * | 2019-12-18 | 2020-03-27 | 福建省德奥针织科技有限公司 | Production process of flame-retardant all-cotton knitted fabric |
| CN111021088A (en) * | 2019-12-27 | 2020-04-17 | 刘大刚 | Flame-retardant heat-insulation cloth |
| CN111021088B (en) * | 2019-12-27 | 2022-05-27 | 杭州琪瑶纺织有限公司 | Flame-retardant heat-insulation cloth |
| CN111155223A (en) * | 2020-01-10 | 2020-05-15 | 张威劲 | Preparation method of high-strength flame-retardant fabric |
| CN111155223B (en) * | 2020-01-10 | 2021-10-22 | 台州市凯达利塑纺有限公司 | Preparation method of high-strength flame-retardant fabric |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107747218A (en) | A kind of flame-proof finishing process of bafta | |
| CN110273295B (en) | Flame-retardant antibacterial ammonium phytate finishing agent for cellulose fibers and finishing method thereof | |
| CN104975497B (en) | Flame retardant, preparation method and applications thereof | |
| CN104727145A (en) | Preparation method and application of cotton environment-friendly flame retardant | |
| CN108049173A (en) | A kind of preparation method of phosphorus-nitrogen containing antiflaming finishing agent and flame retardant cellulose fiber fabric | |
| US2782133A (en) | Process of impregnating cellulosic material halogeno-nitrides of phosphorus | |
| CN105348326B (en) | A kind of N P fire proofings and preparation method thereof and the application in textile | |
| CN106939511B (en) | A kind of phosphorus nitrogen chlorine-resistant fire retardant and its synthetic method | |
| CN106958143A (en) | A kind of preparation method of antiflaming finishing agent and its fire-retardant Lyocell fiber fabric | |
| CN101829527B (en) | Method for preparing microcapsule-coated ammonium polyphosphate | |
| CN104120197B (en) | Leather expanded polystyrene veneer Collagon base nanometer composite flame-proof functional materials | |
| Yang et al. | The bonding of a hydroxy-functional organophosphorus oligomer to nylon fabric using the formaldehyde derivatives of urea and melamine as the bonding agents | |
| CN105316936A (en) | Flame-retardant finishing agent and use thereof | |
| CN105133295B (en) | Insoluble halogen-free flame retardants that a kind of inorganic polymer is modified and its preparation method and application | |
| CN105734964A (en) | Textile auxiliary agent for auxiliary textile sizing and preparation method thereof | |
| CN105113205A (en) | Flame retardant tidying method for purified cotton or blended cotton textile fabric | |
| CN110054648A (en) | A kind of preparation method of cotton response type phosphorus-nitrogen-sulphur synergistic flame retardant | |
| US4136037A (en) | Phosphoramide-hydroxymethyl phosphine condensation products for textile fire retardation | |
| CN104995246A (en) | Formaldehyde-free flame retardant compositions and their use for manufacturing durable formaldehyde-free flame retardant cellulosic materials | |
| CN105218812A (en) | Insoluble halogen-free flame retardants of a kind of cross-linking type and its preparation method and application | |
| CN105648756B (en) | A kind of preparation method and applications of cotton non-formaldehyde flame retardant | |
| CN105200765A (en) | Pure cotton or cotton blended fabric and preparation method thereof | |
| CN102691215A (en) | Non-formaldehyde washable flame-retardant finishing liquid and application thereof | |
| CN1012187B (en) | Fabric with fire-proof, water proof, and fungicidal properties | |
| CN103534404B (en) | The resistance to ignition method of fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180302 |
|
| RJ01 | Rejection of invention patent application after publication |