CN110511615A - A kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture - Google Patents
A kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture Download PDFInfo
- Publication number
- CN110511615A CN110511615A CN201910509793.2A CN201910509793A CN110511615A CN 110511615 A CN110511615 A CN 110511615A CN 201910509793 A CN201910509793 A CN 201910509793A CN 110511615 A CN110511615 A CN 110511615A
- Authority
- CN
- China
- Prior art keywords
- spray printing
- flame retardant
- digital spray
- decorative picture
- retardant type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of flame retardant type visible-light curing digital spray printing chalks applied to stereo decorative picture, its ingredient and content are 1.5~2.5 parts of visible light free radical initiator, with helping initiation and 6~15 parts of flame retarding function compounded mix, 50~70 parts of ethyl ester of acrylic acid -2- (2- ethoxy ethoxy), three 8~15 parts of isocyanurate triacrylate of (2- ethoxy), 5~10 parts of tri (propylene glycol) diacrylate, 0.3~0.8 part of dispersing agent, 0.5~1 part of resin defoaming agent.By the present invention in that with safer, reliable visible-light curing technology, it is shallow to improve existing UV solidification chalk curing depth, the problems such as easy dusting and radiation hazradial bundle, the filler component selected and there is flame-retarding characteristic is designed simultaneously, the requirement for making stereo decorative picture produced meet house decorative material to anti-flammability has very wide market application prospect.
Description
Technical field
The invention belongs to decoration painting ink areas, and in particular to a kind of flame retardant type visible light applied to stereo decorative picture
Solidify digital spray printing chalk.
Background technique
With being continuously increased for home decoration demand, oil painting because its with rich in color, picture it is fine and smooth it is true to nature, three-dimensional sense is strong
The features such as, in the soft dress of family using more and more, at home and abroad there is great development prospect in house ornamentation market.But due to oil
Painter's paraphernalia has unique creating technique, and there are great technical bottlenecks in terms of decoration painting batch production.Conventional batch metaplasia produces
Mode mainly by the way that Freehandhand-drawing works are carried out with the mass production for completing in the way of digital printing decoration painting after flat scanning, but
It cannot achieve the three-dimensional sense and anaglyph of Freehandhand-drawing oil painting.This year, with the rapid development of photocuring technology, UV embossment 3D print
The exploitation of brush technology and application make it possible the mass production of oil painting ornamental picture.The technology is logical using a kind of UV chalk first
Crossing Spot Channel, successively cumulative shop fixtures realizes anaglyph, then prints cromogram again or gloss oil light tone completes the system of stereo oil painting
Make.However, depth as shallow is irradiated, and chalk covering used is strong since UV radiation source wavelength is short, it is past in UV Light Curing
It is bad toward solidification effect, easily there is bottom pulverizing problem, while there are the safeties such as radiation hazradial bundle to ask for the use of UV radiation source
Topic.
Summary of the invention
The purpose of the present invention is to provide a kind of flame retardant type visible-light curing digital spray printing applied to stereo decorative picture is white
Ink, by using safer, reliable visible-light curing technology, it is shallow to improve existing UV solidification chalk curing depth, Yi Fenhua
And the problems such as radiation hazradial bundle, while the filler component selected and there is flame-retarding characteristic is designed, meet stereo decorative picture produced
Requirement of the house decorative material to anti-flammability has very wide market application prospect.
In order to solve the above-mentioned technical problem, it adopts the following technical scheme that
A kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture, it is characterised in that including as follows
Ingredient and content:
After it is preferred that, the visible light free radical initiator includes the fluoro- 3- pyrroles's phenyl titanocenes of double 2,6- bis-, DL- camphor tree
Brain quinone, 3,3 '-two (7- diethylin) coumarin ketones, Eosin B, one of 6- amino tetraiodofluorescein or a variety of.
After it is preferred that, it is described have help initiation and flame retarding function compounded mix be comprising anatase-type nanometer titanium dioxide and
The compounded mix of nanometer antimony oxide.
After it is preferred that, the compounded mix of the anatase-type nanometer titanium dioxide and nanometer antimony oxide, the mass ratio of the two
For 0.3~0.5:1.
After it is preferred that, the dispersing agent includes Lu Borun SOLSPERSE 24000, Shi Rui SRE-42400, SILCO
One of SPERSE HLD-5, H-SPERSE 3000N.
After it is preferred that, the resin defoaming agent includes Clariant RC-920, watt gram SC-132, BYK-P104S, BASF
One of 8034.
After it is preferred that, which is pseudoplastic fluid, in 500s-1Shear viscosity under shear rate is 50~
100mPa·s。
A kind of flame retardant type visible-light curing digital spray printing chalk preparation method applied to stereo decorative picture, feature exist
In: the digital spray printing chalk of said components and dosage is solidified by visible light polymerization to be made.
After it is preferred that, the visible light source is one of blue light source, green-light source and xenon source.
After it is preferred that, the wavelength of the blue light source is 450~470nm, and power is 150~200W；The green-light source
Wavelength is 500~520nm, power 500W；The xenon source is all-wave elongated, power 500W.
As a result of the above technical solution, the following beneficial effects are obtained:
The present invention is a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture, by using more
For safe and reliable visible-light curing technology, improve that existing UV solidification chalk curing depth is shallow, and Yi Fenhua and radiation hazradial bundle etc. are asked
Topic, while the filler component selected and there is flame-retarding characteristic is designed, so that stereo decorative picture produced is met house decorative material pair
The requirement of anti-flammability has very wide market application prospect.Its specific beneficial effect shows as the following:
1, it is white can to improve existing UV solidification by safer, reliable visible light polymerization curing technology using the present invention
Black curing depth is shallow, Yi Fenhua and the problems such as radiation hazradial bundle.
It 2, can be by selecting the anatase-type nanometer titanium dioxide with visible light catalysis activity as white using the present invention
Color filler can produce with the living radical for causing polymerization property after visible light exposure, further increase esters of acrylic acid
The polymerizing curable of monomer.
3, there can be the nanometer antimony oxide of flame-retarding characteristic as white filler by preparing using the present invention, make stereo decoration
It draws product and has good flame retardant property, to meet requirement of the house decorative material to anti-flammability.
Specific embodiment
Below with reference to specific embodiment, the invention will be further described:
Embodiment 1:
A kind of stereo decorative picture flame retardant type visible-light curing digital spray printing chalk, ingredient and content are as follows:
It is 450nm that wavelength, which can be selected, by the photocuring flame retardant type digital spray printing chalk that said components dosage is prepared, and power is
The blue light source of 200W is as radiation source.
Embodiment 2:
A kind of stereo decorative picture flame retardant type visible-light curing digital spray printing chalk, ingredient and content are as follows:
It is 500~520nm, function that wavelength, which can be selected, by the photocuring flame retardant type digital spray printing chalk that said components dosage is prepared
Rate is the green-light source of 500W as radiation source.
Embodiment 3:
A kind of stereo decorative picture flame retardant type visible-light curing digital spray printing chalk, ingredient and content are as follows:
It is 450~470nm, function that wavelength, which can be selected, by the photocuring flame retardant type digital spray printing chalk that said components dosage is prepared
Rate is the blue light source of 150W as radiation source.
Embodiment 4:
A kind of stereo decorative picture flame retardant type visible-light curing digital spray printing chalk, ingredient and content are as follows:
The all-wave length that power is 500W can be selected by the photocuring flame retardant type digital spray printing chalk that said components dosage is prepared
Xenon source is as radiation source.
The above is only specific embodiments of the present invention, but technical characteristic of the invention is not limited thereto.It is any with this hair
Based on bright, to solve essentially identical technical problem, essentially identical technical effect is realized, made ground simple change, etc.
With replacement or modification etc., all it is covered by among protection scope of the present invention.
Claims (10)
1. a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture, it is characterised in that including as follows at
Point and content:
2. a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture according to claim 1,
It is characterized by: the visible light free radical initiator includes double fluoro- 3- pyrroles's phenyl titanocenes of 2,6- bis-, DL- camphorquinone,
3,3 '-two (7- diethylin) coumarin ketones, Eosin B, one of 6- amino tetraiodofluorescein or a variety of.
3. a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture according to claim 1,
It is characterized by: described having helps initiation and flame retarding function compounded mix is comprising anatase-type nanometer titanium dioxide and nanometer
The compounded mix of antimony oxide.
4. a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture according to claim 3,
It is characterized by: the compounded mix of the anatase-type nanometer titanium dioxide and nanometer antimony oxide, the mass ratio of the two is 0.3
~0.5:1.
5. a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture according to claim 1,
It is characterized by: the dispersing agent includes Lu Borun SOLSPERSE 24000, Shi Rui SRE-42400, SILCO SPERSE
One of HLD-5, H-SPERSE 3000N.
6. a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture according to claim 1,
It is characterized by: the resin defoaming agent includes Clariant RC-920, watt gram SC-132, BYK-P104S, in BASF 8034
One kind.
7. a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture according to claim 1,
It is characterized by: the digital spray printing chalk is pseudoplastic fluid, in 500s-1Shear viscosity under shear rate is 50~
100mPa·s。
8. prepared by a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture as described in claim 1
Method, it is characterised in that: the digital spray printing chalk of said components and dosage is solidified by visible light polymerization to be made.
9. a kind of flame retardant type visible-light curing digital spray printing chalk system applied to stereo decorative picture according to claim 8
Preparation Method, it is characterised in that: the visible light source is one of blue light source, green-light source and xenon source.
10. a kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture according to claim 9
Preparation method, it is characterised in that: the wavelength of the blue light source is 450~470nm, and power is 150~200W；The green light light
The wavelength in source is 500~520nm, power 500W；The xenon source is all-wave elongated, power 500W.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910509793.2A CN110511615A (en) | 2019-06-13 | 2019-06-13 | A kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910509793.2A CN110511615A (en) | 2019-06-13 | 2019-06-13 | A kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110511615A true CN110511615A (en) | 2019-11-29 |
Family
ID=68623453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910509793.2A Withdrawn CN110511615A (en) | 2019-06-13 | 2019-06-13 | A kind of flame retardant type visible-light curing digital spray printing chalk applied to stereo decorative picture |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110511615A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111116822A (en) * | 2019-12-31 | 2020-05-08 | 东莞市德聚胶接技术有限公司 | Acrylic resin composition |
| CN114618404A (en) * | 2021-12-17 | 2022-06-14 | 浙江画之都文化创意有限公司 | Temperature-control color-changing microcapsule and preparation method thereof |
-
2019
- 2019-06-13 CN CN201910509793.2A patent/CN110511615A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111116822A (en) * | 2019-12-31 | 2020-05-08 | 东莞市德聚胶接技术有限公司 | Acrylic resin composition |
| CN111116822B (en) * | 2019-12-31 | 2021-04-16 | 东莞市德聚胶接技术有限公司 | Acrylic resin composition |
| CN114618404A (en) * | 2021-12-17 | 2022-06-14 | 浙江画之都文化创意有限公司 | Temperature-control color-changing microcapsule and preparation method thereof |
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| PB01 | Publication | ||
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20191129 |
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| WW01 | Invention patent application withdrawn after publication |