CN110510986A - Modification lotion filler material and preparation method based on chlorine oxygen magnesium gelling system - Google Patents
Modification lotion filler material and preparation method based on chlorine oxygen magnesium gelling system Download PDFInfo
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- CN110510986A CN110510986A CN201910879441.6A CN201910879441A CN110510986A CN 110510986 A CN110510986 A CN 110510986A CN 201910879441 A CN201910879441 A CN 201910879441A CN 110510986 A CN110510986 A CN 110510986A
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- salt
- filler material
- gelling system
- chlorine
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
- C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The present invention relates to the modification lotion filler materials based on a kind of oxygen magnesium gelling system by chlorine, belong to building material technical field.Component are as follows: brine 25%~30%, tail salt 20%~35%, magnesia 25%~40%, rice hull ash 1%~5%, kaolinite soil property spoil fluidized bed lime-ash 1%~5%, SHMP complex catalyst 0.5%~1%, rubber powder 1%~4%, M- blending agents 0.5%~2%, whisker 1%~5%.The present invention solves the chlorine oxygen magnesium gelling system bad performance issue such as strength retraction, damp suction surface halide accumulation in the prior art.
Description
Technical field
The present invention relates to the modification lotion filler materials based on a kind of oxygen magnesium gelling system by chlorine, belong to building material technology
Field.
Background technique
Due to sylvite ore resource scarcity, China's potash fertilizer external dependence degree is still maintained at 50% or so, needs import every year about
6000000~7,000,000 tons of potash fertilizer.Exploitation for underground soluble solids sylvite ore largely alleviates China's sylvite ore
The situation for producing resource scarcity, reduces the external interdependency of China's potash fertilizer.But goaf is formed by for underground mining, easily
Cause the Secondary Geological Hazards such as surface subsidence;Potash fertilizer production in a large amount of sodium chloride tail salt of by-product, magnesium chloride tail washings, if throw aside in
Ground will cause serious environmental pollution.This problem is never well solved, and hinders the extensive of sylvite ore
Exploitation.
In order to reduce as sylvite ore exploitation adverse effect caused by periphery geology, environment, the synthesis of Total tailing is realized
It utilizes, the main component feature of people generate according to sylvite ore recovery process in engineering tail salt, tail washings proposes to utilize chlorine oxygen magnesium
Gelling system carries out the packing job of underground goaf, both can largely dissolve the sodium chloride tail of by-product in potassium fertilizer production process in this way
Salt, magnesium chloride tail washings, and the environmental requirement of energy effective guarantee goaf ambient enviroment.But in practical applications, obturation occurs
The bad phenomenons such as strength retraction, damp suction surface halide accumulation.
For performance deficiency existing for chlorine oxygen magnesium gelling system, people have also carried out more deep exploration and have proposed one
A little modified measures.Research is found: chlorine oxygen magnesium gelling system is unstable, and there are following several respects reasons: (1) water of magnesia oxychloride cement
Changing product can not be stabilized, when surrounding liquid environment changes, facile hydrolysis or generation crystal transition;(2) due to glue
There are a large amount of chloride ion in solidifying system, chloride ion has stronger adsorption capacity to hydrone, liquid environment is caused to change, internal
Brine is dissolved out and (returns halogen), and then crystal phase is caused to hydrolyze, intensity decline;(3) skeleton structure in gelling system is by 518 phases
With the 318 interlaced formation of phase club shaped structure, once crystal phase is decomposed, the skeleton structure of whole system is destroyed, and then is caused
Volume contraction, intensity decline.
Currently, in the method for the performance improvement of chlorine oxygen magnesium gelling system, compared to other additives, phosphoric acid or can
Soluble phosphoric acid salt is preferable to the improvement of gelling system water-resistance.But its rate of set for slowing down magnesia oxychloride cement, causes
Magnesia oxychloride cement early strength reduces, and influences engineer application.
Summary of the invention
A kind of modification lotion of the present invention for defect existing for existing system, based on proposing the oxygen magnesium gelling system by chlorine
Filler material solves the chlorine oxygen magnesium gelling system bad performance issue such as strength retraction, damp suction surface halide accumulation in the prior art.
Technical solution of the present invention:
Modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine, by following components in percentage by weight group
At: magnesia, brine, tail salt, modified material, the modified material are made of siliceous material, organic matter, whisker.It is described siliceous
Material component is kaolinite soil property spoil fluidized bed lime-ash, rice hull ash, and the organic constituents are redispersible rubber powder, SHMP network
Close catalyst, M- blending agents.
The present invention solves the intrinsic poor water resistance of chlorine oxygen magnesium gelling system, strength retraction, easy damp suction surface halide accumulation performance defect,
Industrial applications for chlorine oxygen magnesium gelling system provide technical guarantee.
As further technical solution, consist of the following components in percentage by weight:
Brine 25%~30%, tail salt 20%~35%, magnesia 25%~40%, rice hull ash 1%~5%, kaolin
Matter spoil fluidized bed lime-ash 1%~5%, SHMP complex catalyst 0.5%~1%, redispersible rubber powder 1%~4%, M- tune
Mixture 0.5%~2%, whisker 1%~5%.
As further technical solution, the concentration of magnesium chloride is 20%~32% in the brine.
As further technical solution, the tail salt is the formation certain granules gradation after mechanical grinding, by crude salt, in
The salt mine composition of three kinds of salt, fine salt size fractionateds, the mass ratio of the crude salt, middle salt, fine salt in modified lotion filler material are
(5%~20%): (5%~15%): (5%~15%), the partial size of the crude salt are 2.36~4.75mm, the grain of the middle salt
Diameter is 1.18~2.36mm, and the partial size of the fine salt is 0.6~1.18mm.
As further technical solution, the activity of the magnesia is 65%~70%.
As further technical solution, the polymer dispersion powder is the copolymer by ethylene, vinylacetate, with poly-
VAE solid rubber powder of the vinyl alcohol as protecting colloid.
As further technical solution, the rice hull ash is through using rice husk as combustion residue, after low temperature calcination
High activity rice hull ash.
As further technical solution, the kaolinite soil property spoil fluidized bed lime-ash is by salic minerals 600~900
DEG C calcining generate, and need to be improved through mechanical grinding its activity, lime-ash is put and carries out grinding in the ball mill, revolving speed be 220~
240r/min, grinding time are 30min~50min.
As further technical solution, the SHMP complex catalyst is calgon solid powder.
As further technical solution, the M- blending agents is water-soluble organic compounds solid powder.
As further technical solution, the whisker is calcium carbonate crystal whisker.
A kind of preparation method of modification lotion filler material based on the oxygen magnesium gelling system by chlorine, comprising the following steps:
The formula of S1, modification lotion filler material according to any one of the above based on chlorine oxygen magnesium gelling system, weigh
Each component is spare;
S2, magnesia, whisker and brine are mixed, and uniform stirring 5min~15min, obtains uniform slurry;
S3, rice hull ash, kaolinite soil property spoil fluidized bed lime-ash and SHMP complex catalyst are uniformly mixed;
S4, the uniform mixture for obtaining step S3 are added in the slurry of step S2, stir 10min~15min;
S5, it redispersible rubber powder and M- blending agents is added to step S4 simultaneously obtains in mixture, and stir 5min
~10min;
S6, the tail salt of certain gradation is added in the deployed slurry of step S5, stir 10min~30min, obtain with
Modification lotion filler material based on chlorine oxygen magnesium gelling system, the wherein gradation of tail salt are as follows: crude salt, middle salt, fine salt are in modified cream
Mass ratio in body filler material is 5%~20%:5%~15%:5%~15%.
It further include step S30 between step S2 and step S3 as further technical solution: by kaolinite soil property spoil stream
Change bed lime-ash and carry out grinding in the ball mill that revolving speed is 220~240r/min, grinding time is 30min~50min, is lived
Kaolinite soil property spoil fluidized bed lime-ash after change.
It the principle of the present invention and has the beneficial effect that
1, it in the present invention, in order to increase stability of the hydrated product in gelling system, is introduced in modified material siliceous
Material component.In the process for preparation of magnesium oxychloride material, MgO is usually excessive.The appropriate dosage for increasing MgO, not only can be with
The pH value of slurry is improved, and to reaction rate is improved, guarantees MgCl2Abundant reaction it is advantageous, but excessive magnesia is in body
It will affect the volume stability of MOC in system, while will also result in scum.Active siliceous material rice hull ash, height are introduced in system
Ridge soil property spoil fluidized bed lime-ash, inside active siliceous material contained by active SiO2It is anti-aquation to occur with excessive magnesia
It answers, forms indissoluble salt MgSiO3:
3MgO+4Si02+8H20→3MgO·4SiO2·H2O
Amorphous Si O in low-temperature rice husk ash (L-RHA)2Content is all nano level active SiO up to 90% or more2Gel
Particle, the huge (50~100m of specific surface area2/ g), so low-temperature rice husk ash has very high pozzolanic activity.Nanometer in L-RHA
The active SiO of grade2Particle can not only eliminate the influence of extra magnesia, and Si is also solid-solution in 5-1-8 crystalline phase hole, together
When also change 5-1-8 crystalline phase and Mg (OH)2Match, more tend to the structure matching of reaction product rationally, micro- knot
Structure is finer and close, and time more long this effect is more obvious.
Kaolinite soil property spoil fluidized bed lime-ash is widely present in the near coal-mine power station in various regions.Kaolinite soil property gangue is widely present
It the use of fluidized bed combustion is the effective technique for handling low calorie fuels in northern China coal bases.The coal of power plant emission
Spoil CFB ash slag not only substantial amounts, cheap, and be usually to be forged by salic minerals in middle warm area (600-900 DEG C)
Burn generation, potential pozzolanic activity with higher.
Although activity SiO in siliceous material2It can react at normal temperature with MgO, but its reaction speed is slower.In order to
Accelerate its reaction, introduces hexametaphosphate (SHMP).Catalyst energy and Ca2+、Mg2+Complex is formed, chemical reaction energy is reduced
It builds, makes to chemically react required activation energy reduction, remarkably promote Mg (OH)2Dissolution, make the Mg in solution2+And OH-Concentration is simultaneously
It improves, so that free [SiO3]2-Concentration increases.Since the concentration of reactant increases, so that alkali-activated carbonatite reaction accelerates, have
Conducive to raising MgO-SiO2–H 2The reaction speed of O system improves the formation speed of M-S-H.
2, magnesium oxychloride cement is porous polycrystal packed structures.The decline of its matrix strength, volume stability unstability,
Basic reason is that internal crystal structure occurs hydrolysis and destroys, and causes the skeleton of threadiness to be dissolved, with hydrolysate
It dissolves out, the space occupied originally by crystal structure in matrix is transformed into loose hole configurations.Skeleton structure is destroyed, and is caused strong
Degree decline also occurs apparent volume and shrinks under ambient pressure effect.
Whisker not only has needle bar shape structure similar with slurry matrix skeleton, but also its granule size has reached micron
Grade, may be implemented filling effect largely, therefore the filler can be formed and reaction product crystal phase phase in the base
As three-dimensional network skeleton structure;The chemical stability of whisker makes it still be able to play after 518 crystal phases decompose destruction
Skeleton function, to improve the stability of microstructure.Whisker belongs to inorganic salts, according to similar compatibility theory, with MOC matrix
It with preferable physical chemistry " caking property ", can preferably inhibit the generation of micro-crack on a microscopic scale, improve base structure
Density and stability.
3, in the present invention, the content of M- blending agents control Chlorine in Solution ion is utilized.M- blending agents is that a kind of water solubility has
Machine compound, it can form complex compound with small anion with that can wrap the ring shaped molecule structure for connecing anion.Chlorine oxygen magnesium glue
The solidifying easy damp suction surface halide accumulation of system, it is largely related with the chloride ion in solution.Chloride ion due to its electron rich structure easily and H2O
Forming quasi- hydrogen bond and affinity, a large amount of moisture, which enters in gelling system, in air has broken fluid balance, and crystal is hydrolyzed,
Magnesium chloride dissolves out, causes to return halogen phenomenon.Since M- blending agents volume is few and the speed of organic complex reaction is slower, adjust
Agent will not to the crystal hardened of early stage react have an impact, and to the chloride ion after matrix hardening in solid interior solution have compared with
Good fixed function.
4, due to magnesium oxychloride cement microstructure have porosity, internal pore structure be conducive to outside moisture into
Enter, destroys the chemical balance in internal liquid, cause the hydrolysis of crystal phase, while also the dissolution for hydrolysate magnesium chloride provides
Channel, forms a kind of vicious circle, leads to structural damage.Therefore the present invention from different angles, carries out porous matrix
Improve, improves the compactness of matrix.On physical layer, mainly start with from introducing organic matter.Redispersible rubber powder can be uniform
Be dispersed in cementitious material, meeting water will become lotion, and lotion enters in pore structure, can play certain closure and make
With;Secondly lotion can block contact of the crystal structure with water in the membrane structure that inside is formed, and prevent its aquation from decomposing.
Specific embodiment
Specific embodiments of the present invention are described in detail below in conjunction with technical solution.
Used chemical admixture in following instance: redispersible rubber powder is the copolymerization by ethylene, vinylacetate
Object, the VAE rubber powder using polyvinyl alcohol as protecting colloid;Rice hull ash is the useless excess that certain rice husk power generating unit generates;Kaolin
Matter spoil fluidized bed lime-ash comes from certain Gangue Power Plant;CaCO3Whisker is produced by domestic enterprise, and length is 20~30 μm, and diameter is
0.5~2 μm;M- blending agents is the pure chemistry reagent of certain company production.
Embodiment 1
Modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine, by following components in percentage by weight group
At:
Brine 28%, tail salt 30%, magnesia 32%, rice hull ash 3%, kaolinite soil property spoil fluidized bed lime-ash 2%, SHMP
Complex catalyst 0.5%, redispersible rubber powder 2%, M- blending agents 0.5%, whisker 2%.
Preparation method includes the following steps:
S1, according to the formula of the modification lotion filler material based on a kind of above-mentioned oxygen magnesium gelling system by chlorine, weigh each
A component is spare;
S2, magnesia, whisker, brine (density of magnesium chloride 28.0%) are subjected to uniform stirring 8min, obtained uniform
Slurry;
S30, kaolinite soil property spoil fluidized bed lime-ash is subjected to grinding in the ball mill that revolving speed is 220r/min, when grinding
Between be 45min, the kaolinite soil property spoil fluidized bed lime-ash after being activated.
S3, rice hull ash, kaolinite soil property spoil fluidized bed lime-ash and SHMP complex catalyst are uniformly mixed, is stirred
Mix 5min;
S4, the uniform mixture for obtaining step S3 are added in the slurry of step S2, stir 10min;
S5, it redispersible rubber powder and M- blending agents is added to step S4 simultaneously obtains in mixture, and stir 5min;
S6, by gradation are as follows: crude salt, middle salt, fine salt mass ratio be 15%:8%:7% tail salt be added to it is deployed
In slurry, 15min is stirred, the modification lotion filler material based on chlorine oxygen magnesium gelling system is obtained.
Modification lotion filler material performance test such as table 1 based on the be able to chlorine oxygen magnesium gelling system of this example shows.
The modification lotion filler material the performance test results based on chlorine oxygen magnesium gelling system that 1 embodiment 1 of table obtains
Embodiment 2
Modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine, by following components in percentage by weight group
At:
Brine 25%, tail salt 22%, magnesia 40%, rice hull ash 1%, kaolinite soil property spoil fluidized bed lime-ash 1%, SHMP
Complex catalyst 0.8%, redispersible rubber powder 4%, M- blending agents 1.2%, whisker 5%.
Preparation method includes the following steps:
S1, according to the formula of the modification lotion filler material based on a kind of above-mentioned oxygen magnesium gelling system by chlorine, weigh each
A component is spare;
S2, magnesia, whisker, brine (density of magnesium chloride 32.0%) are subjected to uniform stirring 10min, obtained uniform
Slurry;
S30, kaolinite soil property spoil fluidized bed lime-ash is subjected to grinding in the ball mill that revolving speed is 230r/min, when grinding
Between be 40min, the kaolinite soil property spoil fluidized bed lime-ash after being activated.
S3, rice hull ash, kaolinite soil property spoil fluidized bed lime-ash and SHMP complex catalyst are uniformly mixed, is stirred
Mix 8min;
S4, the uniform mixture for obtaining step S3 are added in the slurry of step S2, stir 12min;
S5, it redispersible rubber powder and M- blending agents is added to step S4 simultaneously obtains in mixture, and stir 7min;
S6, by gradation are as follows: crude salt, middle salt, fine salt mass ratio be 10%:7%:5% tail salt be added to it is deployed
In slurry, 20min, the modification lotion filler material being able to based on chlorine oxygen magnesium gelling system are stirred.
The test of high-early-strength type composite repair mortar performance obtained by this example is as shown in table 2.
The high-early-strength type composite repair mortar performance test result that 2 embodiment 2 of table obtains
Embodiment 3
Modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine, by following components in percentage by weight group
At:
Brine 30%, tail salt 20%, magnesia 35%, rice hull ash 5%, kaolinite soil property spoil fluidized bed lime-ash 5%, SHMP
Complex catalyst 1%, redispersible rubber powder 1%, M- blending agents 2%, whisker 1%.
Preparation method includes the following steps:
S1, according to the formula of the modification lotion filler material based on a kind of above-mentioned oxygen magnesium gelling system by chlorine, weigh each
A component is spare;
S2, magnesia, whisker, brine (density of magnesium chloride 20%) are subjected to uniform stirring 10min, are uniformly expected
Slurry;
S30, kaolinite soil property spoil fluidized bed lime-ash is subjected to grinding in the ball mill that revolving speed is 240r/min, when grinding
Between be 40min, the kaolinite soil property spoil fluidized bed lime-ash after being activated.
S3, rice hull ash, kaolinite soil property spoil fluidized bed lime-ash and SHMP complex catalyst are uniformly mixed, is stirred
Mix 10min;
S4, the uniform mixture for obtaining step S3 are added in the slurry of step S2, stir 15min;
S5, it redispersible rubber powder and M- blending agents is added to step S4 simultaneously obtains in mixture, and stir
10min;
S6, by gradation are as follows: crude salt, middle salt, fine salt mass ratio be 10%:5%:5% tail salt be added to it is deployed
In slurry, 25min is stirred, the modification lotion filler material based on chlorine oxygen magnesium gelling system is obtained.
The test of high-early-strength type composite repair mortar performance obtained by this example is as shown in table 3.
The high-early-strength type composite repair mortar performance test result that 3 embodiment 3 of table obtains
Embodiment 4
Modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine, by following components in percentage by weight group
At:
Brine 25%, tail salt 35%, magnesia 25%, rice hull ash 5%, kaolinite soil property spoil fluidized bed lime-ash 5%, SHMP
Complex catalyst 1%, redispersible rubber powder 1%, M- blending agents 2%, whisker 1%.
Preparation step is the same as embodiment 3.
Claims (10)
1. the modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine, which is characterized in that by following weight percent
Group be grouped as: brine 25%~30%, tail salt 20%~35%, magnesia 25%~40%, rice hull ash 1%~5%, kaolinite
Soil property spoil fluidized bed lime-ash 1%~5%, SHMP complex catalyst 0.5%~1%, redispersible rubber powder 1%~4%, M-
Blending agents 0.5%~2%, whisker 1%~5%.
2. the modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine according to claim 1, feature exist
In the tail salt is made of the salt mine of three kinds of crude salt, middle salt, fine salt size fractionateds, and the crude salt, middle salt, fine salt are in modified cream
Mass ratio in body filler material is (5%~20%): (5%~15%): (5%~15%), and the partial size of the crude salt is 2.36
~4.75mm, the partial size of the middle salt are 1.18~2.36mm, and the partial size of the fine salt is 0.6~1.18mm.
3. the modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine according to claim 1 or 2, feature
It is, the rice hull ash is the high activity rice hull ash after low temperature calcination;The kaolinite soil property spoil fluidized bed lime-ash is by sial
Matter mineral are generated in 600~900 DEG C of calcinings.
4. the modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine according to claim 1 or 2, feature
It is, the SHMP complex catalyst is calgon solid powder;The M- blending agents is solid for water-soluble organic compounds
Body powder;The whisker is calcium carbonate crystal whisker;The polymer dispersion powder is the copolymer by ethylene, vinylacetate, with poly-
VAE rubber powder of the vinyl alcohol as protecting colloid.
5. the modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine according to claim 3, feature exist
In the SHMP complex catalyst is calgon solid powder;The M- blending agents is water-soluble organic compounds solid
Powder;The whisker is calcium carbonate crystal whisker;The polymer dispersion powder is the copolymer by ethylene, vinylacetate, with poly- second
VAE rubber powder of the enol as protecting colloid.
6. a kind of according to claim 1, the modification lotion filler material described in 2 or 5 based on the oxygen magnesium gelling system by chlorine, special
Sign is that the concentration of magnesium chloride is 20%~32% in the brine;The activity of the magnesia is 65%~70%.
7. the modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine according to claim 3, feature exist
In the concentration of magnesium chloride is 20%~32% in the brine;The activity of the magnesia is 65%~70%.
8. the modification lotion filler material based on a kind of oxygen magnesium gelling system by chlorine according to claim 4, feature exist
In the concentration of magnesium chloride is 20%~32% in the brine;The activity of the magnesia is 65%~70%.
9. a kind of preparation method of the modification lotion filler material based on oxygen magnesium gelling system by chlorine, which is characterized in that including with
Lower step:
S1, it is filled according to the modification lotion based on a kind of oxygen magnesium gelling system by chlorine described in claim 1~8 any one
It is spare to weigh each component for the formula of material;
S2, magnesia, whisker and brine are mixed, and uniform stirring 5min~15min, obtains uniform slurry;
S3, rice hull ash, kaolinite soil property spoil fluidized bed lime-ash and SHMP complex catalyst are uniformly mixed;
S4, the uniform mixture for obtaining step S3 are added in the slurry of step S2, stir 10min~15min;
S5, redispersible rubber powder and M- blending agents are added to step S4 simultaneously obtain in mixture, and stir 5min~
10min;
S6, tail salt is added in the deployed slurry of step S5, stirs 10min~30min, obtains with chlorine oxygen magnesium gelling system
Based on modification lotion filler material, the wherein gradation of tail salt are as follows: the matter of crude salt, middle salt, fine salt in modified lotion filler material
Amount is than being (5%~20%): (5%~15%): (5%~15%).
10. preparation method according to claim 9, which is characterized in that the kaolinite soil property spoil fluidized bed lime-ash exists
Before mixing with rice hull ash and SHMP complex catalyst, grinding, grinding first are carried out in the ball mill that revolving speed is 220~240r/min
Time is 30min~50min, the kaolinite soil property spoil fluidized bed lime-ash after being activated.
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Cited By (2)
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CN114685140A (en) * | 2022-04-24 | 2022-07-01 | 青海民族大学 | Ecological protective layer for improving concrete durability, preparation method and application thereof |
CN114804813A (en) * | 2022-04-28 | 2022-07-29 | 中南林业科技大学 | Bamboo ash-fly ash/magnesium oxychloride composite material and preparation method thereof |
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CN114685140A (en) * | 2022-04-24 | 2022-07-01 | 青海民族大学 | Ecological protective layer for improving concrete durability, preparation method and application thereof |
CN114685140B (en) * | 2022-04-24 | 2022-11-15 | 青海民族大学 | Ecological protection layer for improving concrete durability, preparation method and application thereof |
CN114804813A (en) * | 2022-04-28 | 2022-07-29 | 中南林业科技大学 | Bamboo ash-fly ash/magnesium oxychloride composite material and preparation method thereof |
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