CN110508331A - Low-loss organic amine solution purification device and use method thereof - Google Patents
Low-loss organic amine solution purification device and use method thereof Download PDFInfo
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- CN110508331A CN110508331A CN201910889282.8A CN201910889282A CN110508331A CN 110508331 A CN110508331 A CN 110508331A CN 201910889282 A CN201910889282 A CN 201910889282A CN 110508331 A CN110508331 A CN 110508331A
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- fluid reservoir
- valve
- ion exchange
- exchange bed
- amine
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- 150000001412 amines Chemical class 0.000 title claims abstract description 96
- 238000000746 purification Methods 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000005342 ion exchange Methods 0.000 claims abstract description 95
- 239000007788 liquid Substances 0.000 claims abstract description 81
- 239000011261 inert gas Substances 0.000 claims abstract description 67
- 238000003860 storage Methods 0.000 claims abstract description 15
- 239000012530 fluid Substances 0.000 claims description 170
- 239000000243 solution Substances 0.000 claims description 62
- 238000010926 purge Methods 0.000 claims description 47
- 239000002699 waste material Substances 0.000 claims description 45
- 238000004483 ATR-FTIR spectroscopy Methods 0.000 claims description 44
- 238000011065 in-situ storage Methods 0.000 claims description 44
- 239000007789 gas Substances 0.000 claims description 40
- 238000011049 filling Methods 0.000 claims description 36
- 238000005406 washing Methods 0.000 claims description 28
- 239000003513 alkali Substances 0.000 claims description 27
- 239000011347 resin Substances 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 24
- 239000007864 aqueous solution Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 230000008929 regeneration Effects 0.000 claims description 13
- 238000011069 regeneration method Methods 0.000 claims description 13
- 238000005202 decontamination Methods 0.000 claims description 10
- 230000003588 decontaminative effect Effects 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 8
- 239000007924 injection Substances 0.000 claims description 8
- 238000010521 absorption reaction Methods 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 6
- 239000003480 eluent Substances 0.000 claims description 5
- 238000010828 elution Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000012544 monitoring process Methods 0.000 claims description 5
- 238000012360 testing method Methods 0.000 claims description 5
- 238000002242 deionisation method Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000004458 analytical method Methods 0.000 claims 1
- 238000007664 blowing Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 238000011897 real-time detection Methods 0.000 abstract description 4
- 230000004044 response Effects 0.000 abstract description 4
- 238000002329 infrared spectrum Methods 0.000 abstract 2
- 230000007547 defect Effects 0.000 abstract 1
- 238000005086 pumping Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 150000002500 ions Chemical class 0.000 description 18
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 15
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 10
- 235000011121 sodium hydroxide Nutrition 0.000 description 10
- 239000003456 ion exchange resin Substances 0.000 description 9
- 229920003303 ion-exchange polymer Polymers 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 229960004424 carbon dioxide Drugs 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000003957 anion exchange resin Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003729 cation exchange resin Substances 0.000 description 2
- 229920001429 chelating resin Polymers 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000006193 liquid solution Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PFNQVRZLDWYSCW-UHFFFAOYSA-N (fluoren-9-ylideneamino) n-naphthalen-1-ylcarbamate Chemical compound C12=CC=CC=C2C2=CC=CC=C2C1=NOC(=O)NC1=CC=CC2=CC=CC=C12 PFNQVRZLDWYSCW-UHFFFAOYSA-N 0.000 description 1
- PVXVWWANJIWJOO-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-N-ethylpropan-2-amine Chemical compound CCNC(C)CC1=CC=C2OCOC2=C1 PVXVWWANJIWJOO-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- QMMZSJPSPRTHGB-UHFFFAOYSA-N MDEA Natural products CC(C)CCCCC=CCC=CC(O)=O QMMZSJPSPRTHGB-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005262 decarbonization Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/02—Column or bed processes
- B01J47/04—Mixed-bed processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/02—Column or bed processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/06—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing cationic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/07—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing anionic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/09—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds of mixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/60—Cleaning or rinsing ion-exchange beds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/10—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Physical Water Treatments (AREA)
Abstract
The invention discloses a low-loss organic amine solution purification device and a using method thereof, wherein the device comprises an ion exchange bed, an inert gas cylinder, a fifth liquid storage tank and a second liquid adding pump are arranged at a feed inlet at the upper end of the ion exchange bed through a pipeline, a feed inlet at the lower end of the ion exchange bed is connected with a first liquid adding pump through a pipeline, and a material pumping port of the first liquid adding pump is connected with the first liquid storage tank through a pipeline; a discharge port at the lower end of the ion exchange bed is connected with a second liquid storage tank, a third liquid storage tank and a fourth liquid storage tank through pipelines, and a multiple total reflection infrared spectrum analyzer is installed on the discharge pipeline at the lower end of the ion exchange bed; and a discharge port at the upper end of the ion exchange bed is connected with a fourth liquid storage tank through a pipeline. The invention is convenient for workers to control the valve through the real-time detection result of the multiple total reflection infrared spectrum analyzer D1, and overcomes the defects that the response of a solidified operation program to the actual operation condition is poor and the operation parameters cannot be optimized independently in the prior art.
Description
Technical field
The invention belongs to solution purifying device technical field, in particular to a kind of low-loss Amine Solutions purification device and
Its application method.
Background technique
Petrochemical industry, environmental protection industry (epi) are often used the chemical absorption method based on organic amine absorbent to separate the vulcanization in unstripped gas
The sour gas such as hydrogen, carbon dioxide, such as methyl diethanolamine is used in natural gas or synthesis gas from coal gasification depickling gas technique
(MDEA) solution removes hydrogen sulfide gas, and monoethanolamine (MEA) removal two is used in power-plant flue gas collecting carbonic anhydride technique
Carbon oxide gas.Impurity in unstripped gas participates in reaction or organic amine itself occurs degradation reaction and will lead to Amine Solutions change
The problems such as matter, deterioration, effective component constantly reduces in solution, and absorbability constantly declines, even if supplementing organic amine starting materials on time
It cannot guarantee that the even running of device, because the product of side reaction caused by impurity and organic amine degradation is mainly with thermal stability
The form of salt is accumulated in the solution, and ingredient mainly has formates, acetate, oxalates, sulfate, nitrate, sulfide etc.,
Thermal stability salinity increases the problems such as will lead to corrosion aggravation, solution foaming, device performance fluctuation.Therefore it need to generally guarantee heat
Stable salts concentration is lower than 1.0wt.%.The method for inhibiting thermal-stable salt to generate includes inert gas shielding, is added in solution
The methods of additive, but since impurities in feed gas is multifarious, the not high factor of organic amine chemical stability, it is such
Method is extremely limited for inhibiting the effect of organic amine deterioration.And thermal stability salt accumulation is let alone, it takes and directly replaces amine liquid
Then higher cost, waste liquid are also possible to that environmental problem can be brought method.
How to remove thermal-stable salt is to guarantee one of this kind of desulfurization, the key technology of decarbonization system continuous service, conventional
Mechanical filter, activated carbon adsorption purification method not can be removed with thermal-stable salt existing for ionic state.Side used at present
Method includes: (1), recuperation of heat method, by the way that alkali is added, so that organic impurities is become high boiling inorganic salts, the method for recycling distillation
Low-boiling organic amine component is recycled, but this method energy consumption is higher, the rate of recovery is low, can also introduce higher concentration in systems
Alkali；(2), electrodialysis separates foreign ion to the selective penetrated property of different ions using membrane technology, the disadvantage is that separation effect
Fruit is bad, film be easy it is contaminated；(3), ion-exchange is comparison used at present a kind of widely method, is handed over using ion
Resin is changed to the characteristic of the selective suction-operated of different ions, foreign ion is separated from Amine Solutions, by the way that alkali is added
The regeneration for realizing resin adsorption ability, achievees the purpose that resin recycles.
Ion exchange purification device is packed into amberlite in exchange bed container generally centered on ion exchange bed
Rouge, purification device are generally run on the branch line of process system, shunted from system a part of solution enter ion exchange bed into
Row purification, sets the operation of fixed presetting apparatus, is controlled by control solution flowing velocity in ion exchange bed
The time that solution is contacted with resin, after flowing purification continues for some time, by exchanging, the solution discharge in bed is clean, passes through water
Wash, alkali liquid regeneration and etc. realize ion exchange resin recycling.Adhesion and suction of this device due to resin to solution
Attached effect, device, the problems such as dead volume of pipeline is excessive, feed liquor ratio and residence time is unreasonable can make part solution resident
In exchange bed or pipeline, solution system can not be returned to and generate consumption.
Existing purification device control program be it is fixed, can not be made according to solution concentration and purification device operating condition
Response.And actually solution concentration is changing always, the absorption property of ion exchange resin also occurs over time
Variation, if run only according to fixed parameter, purification system performance just be cannot keep in optimum state, and can occur
The problem of excessive solution outlet.
Summary of the invention
The purpose of the present invention is to provide a kind of low-loss Amine Solutions purification device and its application methods, existing to solve
Some purification device control programs are fixed, the technology that can not be responded according to solution concentration and purification device operating condition
Problem.
To achieve the above object, the invention provides the following technical scheme:
A kind of low-loss Amine Solutions purification device, including ion exchange bed, the upper endfeed of the ion exchange bed
Mouth has inert gas gas cylinder, the 5th fluid reservoir and the second fluid filling pump, the escape pipe of the inert gas gas cylinder by Pipe installing
First flowmeter is installed on road, the 7th valve, the ion exchange bed are installed on the discharge pipe of the 5th fluid reservoir
Lower end feed inlet the first fluid filling pump is connected with by pipeline, the extraction opening of first fluid filling pump is connected with first by pipeline
Fluid reservoir；
The lower end discharge port of the ion exchange bed is connected with the second fluid reservoir, third fluid reservoir and the 4th storage by pipeline
Flow container, the lower end discharge pipe of the ion exchange bed are equipped with multiple In situ ATR-FTIR analyzer；
The upper end discharge port of the ion exchange bed is connected with the 4th fluid reservoir by pipeline, second fluid reservoir into
Third valve is installed on pipe material, the 4th valve, the 4th liquid storage are installed on the feed pipe of the third fluid reservoir
The 5th valve is installed on tank connection ion exchange bed lower end discharge opening pipeline, the 4th fluid reservoir connects on ion exchange bed
The second valve is installed on the discharge opening pipeline of end.
Further, second flowmeter is installed on the discharge pipe of second fluid filling pump, second fluid filling pump
Extraction opening is connected with third fluid reservoir and the 6th fluid reservoir by pipeline.
Further, the 6th valve is installed, the 6th fluid reservoir goes out on the discharge pipe of the third fluid reservoir
8th valve is installed on pipe material.
Further, third flowmeter and the first valve are installed on the discharge pipe of first fluid filling pump.
Further, the fluid reservoir is original fluid container, and the fluid reservoir is waste liquid tank, and the fluid reservoir is circulation alkali liquor
Tank, the fluid reservoir are filtering tank, and the fluid reservoir is deionization water pot.
Further, the 6th fluid reservoir is net alkali liquid tank.
Further, gas discharge outlet is equipped at the top of the second fluid reservoir and the 4th fluid reservoir.
A kind of application method of low-loss Amine Solutions purification device, comprising:
1) purify: Amine Solutions to be clean are contained in the first fluid reservoir, and circulation starts, the first fluid filling pump of unlatching,
Amine liquid is added by ion exchange bed bottom in first valve, the second valve, into ion exchange bed solution after purification from top
Portion enters the 4th fluid reservoir, and after purification process runs a period of time, device replys original state；
2) inert gas purge: opening inert gas gas cylinder, first flowmeter and the 5th valve, by the top of ion exchange bed
It is blown into inert gas, makes to remain on the amine aqueous solution in ion exchange bed and is discharged into the 4th fluid reservoir, device replys original state；
3) it washes: opening the 7th valve, be added to the deionized water in the 5th fluid reservoir in ion exchange bed from top,
The 7th valve of closing is beaten after deionized water impregnates ion exchange bed ion exchange resin for a period of time after reaching certain liquid level
It opens third valve and waste liquid is discharged to the second fluid reservoir；
4) inert gas purge: inert gas bottle and first flowmeter are opened, by multiple In situ ATR-FTIR analyzer
Test result, which manually controls, opens third valve or the 5th valve, and the is opened if amine concentration in previous step is lower than setting value
Three valves, make waste liquid be discharged into the second fluid reservoir, and on the contrary then Open valve V5 makes waste liquid be discharged into fluid reservoir T4；；
5) pre- regeneration: manually opened fluid filling pump P2 opens valve V6, valve V3, by the circulation alkali liquor in fluid reservoir T3 from
Injection at the top of ion exchange bed X1, eluent ion exchanger resin is regenerated in advance from top to bottom, and the liquid of generation is flowed into liquid storage
In tank T2, device is returned to original state；
6) it regenerates: opening the second fluid filling pump, the 8th valve, the 4th valve, lye in the 6th fluid reservoir is added by second
Liquid pump injects at the top of ion exchange bed, washes away the foreign ion of resin surface absorption from top to bottom, makes resin regeneration, after elution
Waste collection is used as circulation alkali liquor into third fluid reservoir, and device returns to original state；
7) inert gas purge: opening inert gas gas cylinder, first flowmeter F1 and third valve manually, make to remain on from
Lye is discharged into the second fluid reservoir in son exchange bed, and device returns to original state；
8) circulation is completed, and opens next circulation.
Further, in step 3), such as amine aqueous solution concentration in multiple In situ ATR-FTIR analyzer monitoring washing waste liquid
Higher than setting value, then third valve is closed, while opening the 5th valve, flows into highly concentrated waste liquid in the 4th fluid reservoir, device
It returns to original state；
The time that gas purges in step 4) is controlled by multiple In situ ATR-FTIR analyzer, if amine in previous step
Concentration is higher than setting value and then extends purge time, washing step and inert gas purge step 3) and 4) is then repeated, until outlet
Amine concentration is lower than setting value in waste liquid, and system restPoses；
In step 5), the amine in multiple In situ ATR-FTIR analyzer record ion exchange bed bottom outflow waste liquid is dense
Degree reduces in next decontamination cycle multiple Total Reflection Infrared light in water-washing step if wherein amine concentration is higher than setting value
Spectrum analysis instrument extends the time of washing and inert gas purge to the decision content of amine concentration；
In step 6), in the circulation alkali liquor of multiple In situ ATR-FTIR analyzer record ion exchange bed bottom outflow
Amine concentration combines third flowmeter result to increase and flows into ion friendship if wherein amine concentration is higher than setting value in subsequent cycle
The amount for changing the amine aqueous solution of bed, extends the time of subsequent inert gas purge, and reduces in next decontamination cycle in water-washing step
Multiple In situ ATR-FTIR analyzer extends the time of washing and inert gas purge to the decision content of amine concentration.
Compared with prior art, the beneficial effects of the present invention are: the low-loss Amine Solutions purification device is by multiple
Organic amine concentration in solution is discharged in In situ ATR-FTIR analyzer D1 real-time detection ion exchange bed X1, logical convenient for staff
The on or off for crossing multiple In situ ATR-FTIR analyzer D1 real-time detection result control valve avoids the prior art using solid
The operation program of change is to practical operation situation difference in response, the shortcomings that cannot independently optimizing operating parameter, also, further, this
Invention can also measure amine aqueous solution and purification device operation program is combined from the function of main regulation, purification can be filled
The amine loss for setting operation key step is information-based, and loss is reduced by optimization operating parameter, reduces operating cost.
Detailed description of the invention
The accompanying drawings constituting a part of this application is used to provide further understanding of the present invention, and of the invention shows
Examples and descriptions thereof are used to explain the present invention for meaning property, does not constitute improper limitations of the present invention.In the accompanying drawings:
Fig. 1 is Amine Solutions purification device schematic diagram of the present invention.
In figure: X1 is ion exchange bed, D1 is multiple In situ ATR-FTIR analyzer, C1 is inert gas gas cylinder, F1-
It is fluid filling pump, T1-T6 be fluid reservoir, V1-V8 is valve that F3, which is flowmeter, P1 and P2,.
Specific embodiment
The present invention will be described in detail below with reference to the accompanying drawings and embodiments.It should be noted that in the feelings not conflicted
Under condition, the features in the embodiments and the embodiments of the present application be can be combined with each other.
Following detailed description is exemplary explanation, it is intended to provide further be described in detail to the present invention.Unless another
It indicates, all technical terms of the present invention contain with the normally understood of the application one of ordinary skill in the art
Justice is identical.Term used in the present invention is merely to describe specific embodiment, and be not intended to limit according to the present invention
Illustrative embodiments.
Referring to Fig. 1, the present invention provides a kind of technical solution: a kind of low-loss Amine Solutions purification device, including from
Son exchanges bed X1, and ion exchange bed X1 contains top cover, bottom cover and connected strainer, is packed into amberlite in ion exchange bed X1
Rouge, the ion exchange resin contained in ion exchange bed X1 are that cation exchange resin, anion exchange resin or yin-yang are mixed
Ion exchange resin is closed, the strainer for pushing up bottom cover can guarantee that resin will not flow out ion exchange bed X1, and ion exchange bed X1's is upper
Endfeed mouth has inert gas gas cylinder C1, fluid reservoir T5 and a fluid filling pump P2 by Pipe installing, in inert gas gas cylinder C1 gas cylinder
The gas of splendid attire is the inert gases such as nitrogen, argon gas or helium, is equipped with flowmeter on the outlet pipe of inert gas gas cylinder C1
F1 is equipped with valve V7 on the discharge pipe of fluid reservoir T5, flowmeter F2, fluid filling pump is equipped on the discharge pipe of fluid filling pump P2
The extraction opening of P2 is connected with fluid reservoir T3 and fluid reservoir T6 by pipeline, and valve V6 is equipped on the discharge pipe of fluid reservoir T3,
Valve V8 is installed, the lower end feed inlet of ion exchange bed X1 is connected with fluid filling pump by pipeline on the discharge pipe of fluid reservoir T6
The extraction opening of P1, fluid filling pump P1 are connected with fluid reservoir T1 by pipeline, and flowmeter F3 is equipped on the discharge pipe of fluid filling pump P1
Fluid reservoir T2, fluid reservoir T3 and fluid reservoir T4 are connected with by pipeline with the lower end discharge port of valve V1, ion exchange bed X1, from
The upper end discharge port of son exchange bed X1 is connected with fluid reservoir T4 by pipeline, and the lower end discharge pipe of ion exchange bed X1 is equipped with
The detection window of multiple In situ ATR-FTIR analyzer D1, multiple In situ ATR-FTIR analyzer D1 are embedded into ion exchange
The outer wall of bed X1 bottom conduit, window surface are directly contacted with waste liquid, concentration of the measurable flow through organic amine in the liquid of window,
Its measurement result divides the duration of each step during decision subsequent purification and number of repetition, multiple In situ ATR-FTIR
The material of analyzer D1 infrared spectroscopy window is monocrystalline silicon, zinc selenide, diamond or calcirm-fluoride, is pacified on the feed pipe of fluid reservoir T2
Equipped with valve V3, valve V4, the discharging of the fluid reservoir T4 connection lower end ion exchange bed X1 are installed on the feed pipe of fluid reservoir T3
Valve V5 is installed on mouth pipeline, valve V2 is installed on the discharge opening pipeline of the upper end fluid reservoir T4 connection ion exchange bed X1.
Referring to Fig. 1, fluid reservoir T1 is original fluid container, fluid reservoir T2 is waste liquid tank, and fluid reservoir T3 is circulation alkali flow container, liquid storage
Tank T4 is filtering tank, and fluid reservoir T5 is deionization water pot, and fluid reservoir T6 is net alkali liquid tank, is had at the top of fluid reservoir T2, fluid reservoir T4
Gas discharge outlet, being contained in fluid reservoir T6 is the alkali solubles such as sodium hydroxide needed for ion exchange resin regeneration, potassium hydroxide
Liquid.
Referring to Fig. 1, device original state is that valve V1-V8, flowmeter F1-F3 are turned off, after device starting under
It states step and circuits sequentially operation:
1) purify: Amine Solutions to be clean are contained in fluid reservoir T1, and circulation starts, manually opened fluid filling pump P1,
Amine liquid is added by the bottom ion exchange bed X1 in valve V1, valve V2, into ion exchange bed X1 solution after purification from top
Portion enters fluid reservoir T4, and after purification process runs a period of time, device replys original state；
2) inert gas purge: inert gas gas cylinder C1, flowmeter F1 and valve V5 are opened manually, by ion exchange bed X1
Top is blown into inert gas, and the amine aqueous solution remained in ion exchange bed X1 is made to be discharged into fluid reservoir T4, and device replys original state；
3) it washes: opening valve V7 manually, the deionized water in fluid reservoir T5 is made to be added to ion exchange bed X1 from top
In, valve V7 is closed after reaching certain liquid level, after deionized water impregnates ion exchange bed X1 ion exchange resin for a period of time,
Valve V3 is opened manually, and waste liquid is discharged to fluid reservoir T2, such as amine in multiple In situ ATR-FTIR analyzer D1 monitoring washing waste liquid
Solution concentration is higher, then it closes valve V3, while Open valve V5, flows into highly concentrated waste liquid in fluid reservoir T4, device is extensive
Original state is arrived again；
4) inert gas purge: opening inert gas bottle C1 and flowmeter F1 manually, by multiple In situ ATR-FTIR point
Analyzer D1 test result, which manually controls, opens valve V3 or valve V5, opens if amine concentration in previous step is lower than setting value
Valve V3, makes waste liquid be discharged into fluid reservoir T2, and on the contrary then Open valve V5 makes waste liquid be discharged into fluid reservoir T4；The time of gas purging
It is controlled by multiple In situ ATR-FTIR analyzer D1, when extending purging if amine concentration in previous step is higher than setting value
Between, then repeating washing step and inert gas purge step (3) and (4) until amine concentration is lower than setting value in discharging any waste liquor is
System restPoses；
5) pre- regeneration: manually opened fluid filling pump P2 opens valve V6, valve V3, by the circulation alkali liquor in fluid reservoir T3 from
Injection at the top of ion exchange bed X1, eluent ion exchanger resin is regenerated in advance from top to bottom, and the liquid of generation is flowed into liquid storage
In tank T2, device is returned to original state；The bottom the ion exchange bed X1 outflow of multiple In situ ATR-FTIR analyzer D1 record
Amine concentration in waste liquid reduces multiple total reflection in water-washing step in next decontamination cycle if wherein amine concentration is higher
Infrared spectrometric analyzer D1 extends the time of washing and inert gas purge to the decision content of amine concentration；
6) regenerate: manually opened fluid filling pump P2, valve V8, valve V4, by lye in fluid reservoir T6 by fluid filling pump P2 from
Injection at the top of ion exchange bed X1, washes away the foreign ion of resin surface absorption from top to bottom, makes resin regeneration, waste liquid after elution
It is collected into fluid reservoir T3 as circulation alkali liquor, device returns to original state；Multiple In situ ATR-FTIR analyzer D1 note
Amine concentration in the circulation alkali liquor of the record bottom ion exchange bed X1 outflow is tied in subsequent cycle if wherein amine concentration is higher
Collaborate meter F3 result and increase the amount for flowing into the amine aqueous solution of ion exchange bed X1, extends the time of subsequent inert gas purge, and
Reduce decision content of the multiple In situ ATR-FTIR analyzer D1 to amine concentration, extension in water-washing step in next decontamination cycle
The time of washing and inert gas purge；
7) inert gas purge: opening inert gas gas cylinder C1, flowmeter F1 and valve V3 manually, makes to remain on ion friendship
It changes lye in an X1 and is discharged into fluid reservoir T2, device returns to original state；
8) circulation is completed, and opens next circulation.
The low-loss Amine Solutions purification device passes through multiple In situ ATR-FTIR analyzer D1 real-time detection ion
Organic amine concentration in bed X1 discharge solution is exchanged, is examined in real time convenient for staff by multiple In situ ATR-FTIR analyzer D1
The on or off for surveying result control valve, avoids the prior art using cured operation program to practical operation situation difference in response,
The shortcomings that operating parameter cannot independently be optimized.Also, further, the present invention can also set electrically-controlled valve for valve V1-V7,
Multiple In situ ATR-FTIR analyzer D1 detection added input purification device control device, can be corresponded to according to the concentration of detection
Automatically control each electrically-controlled valve；The present invention can measure amine aqueous solution and purification device runs program and combines from the function of main regulation
To together, informationization is lost in the amine that purification device can be run to key step, and loss, drop are reduced by optimization operating parameter
Low operating cost.
Embodiment 1:
II type anion exchange resin is packed into ion exchange bed X1, multiple In situ ATR-FTIR analyzer D1 uses silicon
Window, the order of reflection on window are 20 times, and inert gas gas cylinder C1 is nitrogen cylinder, are packed into methyl to be clean in fluid reservoir T1
Diethanolamine solution is packed into the potassium hydroxide aqueous solution of 5wt% in concentration 30wt%, fluid reservoir T6.
It is carried out as follows after system starting:
1) purify: Amine Solutions to be clean are contained in fluid reservoir T1, and circulation starts, manually opened fluid filling pump P1,
Amine liquid is added by the bottom ion exchange bed X1 in valve V1, valve V2, into ion exchange bed X1 solution after purification from top
Portion enters fluid reservoir T4；The linear velocity that methyldiethanolamine solution flows through resin surface is 1 centimeters/minute；Purifying step continues 0.5
Hour, device replys original state；
2) inert gas purge: inert gas gas cylinder C1, flowmeter F1 and valve V5 are opened manually, by ion exchange bed X1
Top is blown into inert gas, and the amine aqueous solution remained in ion exchange bed X1 is made to be discharged into fluid reservoir T4, and purging lasting default value is 2
Minute, device replys original state；
3) it washes: opening valve V7 manually, the deionized water in fluid reservoir T5 is made to be added to ion exchange bed X1 from top
In, valve V7 is closed after reaching certain liquid level, after deionized water impregnates ion exchange bed X1 ion exchange resin for a period of time,
Valve V3 is opened manually, and waste liquid is discharged to fluid reservoir T2, such as amine in multiple In situ ATR-FTIR analyzer D1 monitoring washing waste liquid
Solution concentration is higher than 3%, then it closes valve V3, while Open valve V5, flows into highly concentrated waste liquid in fluid reservoir T4, device
It returns to original state；
4) inert gas purge: opening inert gas bottle C1 and flowmeter F1 manually, by multiple In situ ATR-FTIR point
Analyzer D1 test result, which manually controls, opens valve V3 or valve V5, the opening valve if amine concentration in previous step is lower than 3%
Door V3, makes waste liquid be discharged into fluid reservoir T2, on the contrary then Open valve V5 makes waste liquid be discharged into fluid reservoir T4；Gas purging time by
Multiple In situ ATR-FTIR analyzer D1 control, when extending purging if amine concentration in previous step is higher than setting value 3%
Between, then repeating washing step and inert gas purge step (3) and (4) until amine concentration is lower than setting value in discharging any waste liquor is
System restPoses；
5) pre- regeneration: manually opened fluid filling pump P2 opens valve V6, valve V3, by the circulation alkali liquor in fluid reservoir T3 from
Injection at the top of ion exchange bed X1, eluent ion exchanger resin is regenerated in advance from top to bottom, and the liquid of generation is flowed into liquid storage
In tank T2, device is returned to original state；The bottom the ion exchange bed X1 outflow of multiple In situ ATR-FTIR analyzer D1 record
Amine concentration in waste liquid reduces multiple in water-washing step in next decontamination cycle be all-trans if wherein amine concentration is higher than 3%
Infrared spectrometric analyzer D1 is penetrated to the decision content of amine concentration to 2%, and extends the time of washing and inert gas purge as default
2 times of value；
6) regenerate: manually opened fluid filling pump P2, valve V8, valve V4, by lye in fluid reservoir T6 by fluid filling pump P2 from
Injection at the top of ion exchange bed X1, washes away the foreign ion of resin surface absorption from top to bottom, makes resin regeneration, waste liquid after elution
It is collected into fluid reservoir T3 as circulation alkali liquor, device returns to original state；Multiple In situ ATR-FTIR analyzer D1 note
Amine concentration in the circulation alkali liquor of the record bottom ion exchange bed X1 outflow is tied in subsequent cycle if wherein amine concentration is higher
The amount for collaborating the amine aqueous solution that meter F3 result increases inflow ion exchange bed X1 is 1.5 times of epicycle, extends subsequent inert gas
The time of purging reduces in next decontamination cycle multiple In situ ATR-FTIR point in water-washing step to 2 times of default value
Analyzer D1, to 2%, extends 2 times washed with the time of inert gas purge to default time to the decision content of amine concentration；
7) inert gas purge: opening inert gas gas cylinder C1, flowmeter F1 and valve V3 manually, makes to remain on ion friendship
It changes lye in an X1 and is discharged into fluid reservoir T2, device returns to original state；
8) circulation is completed, and opens next circulation.
Such as continuous 3 circulate in step 5) or 6) repair to the water system of subsequent cycle and inert gas purge Step Time
Change, the lasting default time of this two step is improved 1 times.5 times or more such as are improved by several circulation default times, device is then to fortune
Administrative staff, which gives notice, carries out overhaul of the equipments and maintenance.
Embodiment 2:
Anion-cation exchange resin is packed into ion exchange bed X1, multiple In situ ATR-FTIR analyzer D1 uses selenizing
Zinc window, the order of reflection on window are 25 times, and inert gas gas cylinder C1 is nitrogen cylinder, are packed into be clean one in fluid reservoir T1
Ethanolamine solutions are packed into the sodium hydrate aqueous solution of 5wt% in concentration 35wt%, fluid reservoir T6.
It is carried out as follows after system starting:
1) purify: monoethanolamine solution to be clean is contained in fluid reservoir T1, and circulation starts, manually opened fluid filling pump
P1, valve V1, valve V2, by the bottom ion exchange bed X1 be added amine liquid, into ion exchange bed X1 solution by purification after
Enter fluid reservoir T4 from top；The linear velocity that monoethanolamine solution flows through resin surface is 0.5 centimeters/minute；Purifying step continues
50 minutes, device replied original state；
2) inert gas purge: inert gas gas cylinder C1, flowmeter F1 and valve V5 are opened manually, by ion exchange bed X1
Top is blown into inert gas, and the monoethanolamine solution remained in ion exchange bed X1 is made to be discharged into fluid reservoir T4, and purging is persistently write from memory
Recognizing value is 2 minutes, and device replys original state；
3) it washes: opening valve V7 manually, the deionized water in fluid reservoir T5 is made to be added to ion exchange bed X1 from top
In, valve V7 is closed after reaching certain liquid level, after deionized water impregnates ion exchange bed X1 ion exchange resin for a period of time,
Valve V3 is opened manually, and waste liquid is discharged to fluid reservoir T2, as one in multiple In situ ATR-FTIR analyzer D1 monitoring washing waste liquid
Ethanolamine solutions concentration is higher than 3%, then it closes valve V3, while Open valve V5, and highly concentrated waste liquid is made to flow into fluid reservoir T4
In, device returns to original state；
4) inert gas purge: opening inert gas bottle C1 and flowmeter F1 manually, by multiple In situ ATR-FTIR point
Analyzer D1 test result, which manually controls, opens valve V3 or valve V5, if monoethanolamine solution in previous step is lower than 3%
Open valve V3, makes waste liquid be discharged into fluid reservoir T2, and on the contrary then Open valve V5 makes waste liquid be discharged into fluid reservoir T4；Gas purging
Time is controlled by multiple In situ ATR-FTIR analyzer D1, if monoethanolamine solution concentration is higher than setting value in previous step
3% extends purge time, then repeats washing step and inert gas purge step (3) and (4), until a second in discharging any waste liquor
Alkanolamine solution concentration is lower than setting value 3%, and system restPoses；
5) pre- regeneration: manually opened fluid filling pump P2 opens valve V6, valve V3, by the circulation alkali liquor in fluid reservoir T3 from
Injection at the top of ion exchange bed X1, eluent ion exchanger resin is regenerated in advance from top to bottom, and the liquid of generation is flowed into liquid storage
In tank T2, device is returned to original state；The bottom the ion exchange bed X1 outflow of multiple In situ ATR-FTIR analyzer D1 record
Amine concentration in waste liquid reduces water-washing step in next decontamination cycle if wherein monoethanolamine solution concentration is higher than 3%
In multiple In situ ATR-FTIR analyzer D1 to the decision content of monoethanolamine solution concentration to 2%, and extend washing and inertia
The time of gas purging is 2 times of default value；
6) regenerate: manually opened fluid filling pump P2, valve V8, valve V4, by lye in fluid reservoir T6 by fluid filling pump P2 from
Injection at the top of ion exchange bed X1, washes away the foreign ion of resin surface absorption from top to bottom, makes resin regeneration, waste liquid after elution
It is collected into fluid reservoir T3 as circulation alkali liquor, device returns to original state；Multiple In situ ATR-FTIR analyzer D1 note
The monoethanolamine solution concentration in the circulation alkali liquor of the bottom ion exchange bed X1 outflow is recorded, if wherein monoethanolamine solution concentration
Higher, then combining flowmeter F3 result to increase the amount of the amine aqueous solution of inflow ion exchange bed X1 in subsequent cycle is the 1.5 of epicycle
Times, extend time of subsequent inert gas purge to 2 times of default value, and reduce more in water-washing step in next decontamination cycle
Weight In situ ATR-FTIR analyzer D1, to 2%, extends and washes with the time of inert gas purge extremely to the decision content of amine concentration
2 times of default time；
7) inert gas purge: opening inert gas gas cylinder C1, flowmeter F1 and valve V3 manually, makes to remain on ion friendship
It changes lye in an X1 and is discharged into fluid reservoir T2, device returns to original state；
8) circulation is completed, and opens next circulation.
As known by the technical knowledge, the present invention can pass through the embodiment party of other essence without departing from its spirit or essential feature
Case is realized.Therefore, embodiment disclosed above, in all respects are merely illustrative, not the only.Institute
Have within the scope of the present invention or is included in the invention in the change being equal in the scope of the present invention.
Claims (9)
1. a kind of low-loss Amine Solutions purification device, including ion exchange bed (X1), it is characterised in that: the ion exchange
The upper end feed inlet of bed (X1) has inert gas gas cylinder (C1), the 5th fluid reservoir (T5) and the second fluid filling pump by Pipe installing
(P2), it is equipped with first flowmeter (F1) on the outlet pipe of the inert gas gas cylinder (C1), the 5th fluid reservoir (T5)
Discharge pipe on the 7th valve (V7) is installed, the lower end feed inlet of the ion exchange bed (X1) is connected with by pipeline
The extraction opening of one fluid filling pump (P1), first fluid filling pump (P1) is connected with the first fluid reservoir (T1) by pipeline；
The lower end discharge port of the ion exchange bed (X1) is connected with the second fluid reservoir (T2), third fluid reservoir (T3) by pipeline
With the 4th fluid reservoir (T4), the lower end discharge pipe of the ion exchange bed (X1) is equipped with multiple In situ ATR-FTIR analysis
Instrument (D1)；
The upper end discharge port of the ion exchange bed (X1) is connected with the 4th fluid reservoir (T4), second fluid reservoir by pipeline
(T2) it is equipped on feed pipe third valve (V3), the 4th valve is installed on the feed pipe of the third fluid reservoir (T3)
Door (V4), the 4th fluid reservoir (T4) connect and are equipped with the 5th valve on the discharge opening pipeline of the lower end ion exchange bed (X1)
(V5), the second valve (V2) is installed on the 4th fluid reservoir (T4) the connection upper end ion exchange bed (X1) discharge opening pipeline.
2. a kind of low-loss Amine Solutions purification device according to claim 1, it is characterised in that: second liquid feeding
It pumps and is equipped with second flowmeter (F2) on the discharge pipe of (P2), the extraction opening of second fluid filling pump (P2) is connected by pipeline
There are third fluid reservoir (T3) and the 6th fluid reservoir (T6).
3. a kind of low-loss Amine Solutions purification device according to claim 2, it is characterised in that: the third liquid storage
6th valve (V6) is installed on the discharge pipe of tank (T3), is equipped with the 8th on the discharge pipe of the 6th fluid reservoir (T6)
Valve (V8).
4. a kind of low-loss Amine Solutions purification device according to claim 1, it is characterised in that: first liquid feeding
It pumps and third flowmeter (F3) and the first valve (V1) is installed on the discharge pipe of (P1).
5. a kind of low-loss Amine Solutions purification device according to claim 1, it is characterised in that: the fluid reservoir
It (T1) is original fluid container, the fluid reservoir (T2) is waste liquid tank, and the fluid reservoir (T3) is circulation alkali flow container, the fluid reservoir (T4)
For filtering tank, the fluid reservoir (T5) is deionization water pot.
6. a kind of low-loss Amine Solutions purification device according to claim 2, it is characterised in that: the 6th liquid storage
Tank (T6) is net alkali liquid tank.
7. a kind of low-loss Amine Solutions purification device according to claim 1, it is characterised in that: the second fluid reservoir
(T2) and at the top of the 4th fluid reservoir (T4) it is equipped with gas discharge outlet.
8. a kind of application method of low-loss Amine Solutions purification device according to any one of claim 1 to 7,
It is characterized in that, comprising:
1) purify: Amine Solutions to be clean are contained in the first fluid reservoir (T1), and circulation starts, and open the first fluid filling pump
(P1), amine liquid is added by the ion exchange bed bottom (X1), into ion exchange bed in the first valve (V1), the second valve (V2)
(X1) solution enters the 4th fluid reservoir (T4) from top after purification, and after purification process runs a period of time, device is replied
Original state；
2) inert gas purge: inert gas gas cylinder (C1), first flowmeter (F1) and the 5th valve (V5) are opened, is handed over by ion
It changes at the top of bed (X1) and is blown into inert gas, the amine aqueous solution remained in ion exchange bed (X1) is made to be discharged into the 4th fluid reservoir (T4),
Device replys original state；
3) it washes: opening the 7th valve (V7), the deionized water in the 5th fluid reservoir (T5) is made to be added to ion exchange from top
In bed (X1), the 7th valve (V7) is closed after reaching certain liquid level, deionized water impregnates the exchange of ion exchange bed (X1) intermediate ion
Resin for a period of time after, open third valve (V3) and waste liquid be discharged to the second fluid reservoir (T2)；
4) inert gas purge: opening inert gas bottle (C1) and first flowmeter (F1), by multiple In situ ATR-FTIR point
Analyzer (D1) test result, which manually controls, opens third valve (V3) or the 5th valve (V5), if amine concentration is low in previous step
Third valve (V3) is then opened in setting value, is discharged into waste liquid the second fluid reservoir (T2), on the contrary then Open valve V5 arranges waste liquid
Enter fluid reservoir T4；；
5) pre- regeneration: manually opened fluid filling pump P2 opens valve V6, valve V3, by the circulation alkali liquor in fluid reservoir T3 from ion
Injection at the top of bed X1 is exchanged, eluent ion exchanger resin is regenerated in advance from top to bottom, and the liquid of generation is flowed into fluid reservoir T2
In, device returns to original state；
6) it regenerates: the second fluid filling pump (P2), the 8th valve (V8), the 4th valve (V4) is opened, by alkali in the 6th fluid reservoir (T6)
Liquid is injected at the top of the ion exchange bed (X1) by the second fluid filling pump (P2), wash away from top to bottom the impurity of resin surface absorption from
Son makes resin regeneration, and waste collection is used as circulation alkali liquor in third fluid reservoir (T3) after elution, and device is restored to initial shape
State；
7) inert gas purge: inert gas gas cylinder (C1), first flowmeter F1 and third valve (V3) are opened manually, makes to remain
Lye is discharged into the second fluid reservoir (T2) in ion exchange bed (X1), and device returns to original state；
8) circulation is completed, and opens next circulation.
9. application method according to claim 8, which is characterized in that in step 3), such as multiple In situ ATR-FTIR point
Amine aqueous solution concentration is higher than setting value in analyzer (D1) monitoring washing waste liquid, then closes third valve (V3), while opening the 5th
Valve (V5) flows into highly concentrated waste liquid in the 4th fluid reservoir (T4), and device returns to original state；
The time that gas purges in step 4) is controlled by multiple In situ ATR-FTIR analyzer (D1), if amine in previous step
Concentration is higher than setting value and then extends purge time, washing step and inert gas purge step 3) and 4) is then repeated, until outlet
Amine concentration is lower than setting value in waste liquid, and system restPoses；
Amine in step 5), in multiple In situ ATR-FTIR analyzer (D1) the record ion exchange bed bottom (X1) outflow waste liquid
Concentration reduces in next decontamination cycle multiple Total Reflection Infrared in water-washing step if wherein amine concentration is higher than setting value
Spectroanalysis instrument (D1) extends the time of washing and inert gas purge to the decision content of amine concentration；
In step 6), the circulation alkali liquor of multiple In situ ATR-FTIR analyzer (D1) the record ion exchange bed bottom (X1) outflow
In amine concentration combine third flowmeter (F3) result to increase stream in subsequent cycle if wherein amine concentration is higher than setting value
The amount for entering the amine aqueous solution of ion exchange bed (X1), extends the time of subsequent inert gas purge, and reduces next decontamination cycle
Multiple In situ ATR-FTIR analyzer (D1) extends washing and inert blowing gas to the decision content of amine concentration in middle water-washing step
The time swept.
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| CN201910889282.8A CN110508331B (en) | 2019-09-19 | 2019-09-19 | Low-loss organic amine solution purification device and application method thereof |
| AU2020347721A AU2020347721B2 (en) | 2019-09-19 | 2020-09-17 | Low-loss organic amine solution purification device and use method thereof |
| JP2021600151U JP3238723U (en) | 2019-09-19 | 2020-09-17 | Low loss organic amine solution purifier |
| DE202020005624.3U DE202020005624U1 (en) | 2019-09-19 | 2020-09-17 | A low-loss cleaning device for organic amine solutions |
| PCT/CN2020/115961 WO2021052432A1 (en) | 2019-09-19 | 2020-09-17 | Low-loss organic amine solution purification device and use method thereof |
| US17/488,693 US20220016616A1 (en) | 2019-09-19 | 2021-09-29 | Device and method for purifying organic amine solution |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102125803A (en) * | 2010-12-10 | 2011-07-20 | 北京科技大学 | Method for purifying degraded amine solution |
| JP2011161303A (en) * | 2010-02-04 | 2011-08-25 | Kurita Engineering Co Ltd | Method for regenerating ion exchange resin having been used for regeneration of amine liquid |
| CN104192946A (en) * | 2014-08-12 | 2014-12-10 | 江西瑞林电气自动化有限公司 | Amine liquid purification control method and device |
| CN205019965U (en) * | 2015-09-29 | 2016-02-10 | 成都赛普瑞兴科技有限公司 | Amine liquid purifier |
| CN105366766A (en) * | 2014-08-25 | 2016-03-02 | 中石化洛阳工程有限公司 | Resin bed thermal stabilization salt removing method |
| CN210875372U (en) * | 2019-09-19 | 2020-06-30 | 华能国际电力股份有限公司 | Low-loss organic amine solution purification device |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3465291B2 (en) * | 1993-04-23 | 2003-11-10 | 三菱化学株式会社 | Method for producing water for beverage and food production |
| CN103769249B (en) * | 2012-10-25 | 2016-01-20 | 中国石油化工股份有限公司 | A kind of ion-exchange process |
| CN203402946U (en) * | 2013-07-31 | 2014-01-22 | 神华集团有限责任公司 | Water treatment system |
| CN203866136U (en) * | 2014-05-22 | 2014-10-08 | 西安热工研究院有限公司 | Amine liquid purification and recycling system of system for capturing CO2 in flue gas of coal-fired power plant |
| CN209205318U (en) * | 2018-11-20 | 2019-08-06 | 杭州多能环保科技有限公司 | A kind of efficient recovery device for alkanolamine solution cleaning equipment |
| CN110508331B (en) * | 2019-09-19 | 2023-08-18 | 华能国际电力股份有限公司 | Low-loss organic amine solution purification device and application method thereof |
-
2019
- 2019-09-19 CN CN201910889282.8A patent/CN110508331B/en active Active
-
2020
- 2020-09-17 JP JP2021600151U patent/JP3238723U/en active Active
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- 2020-09-17 WO PCT/CN2020/115961 patent/WO2021052432A1/en active Application Filing
-
2021
- 2021-09-29 US US17/488,693 patent/US20220016616A1/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011161303A (en) * | 2010-02-04 | 2011-08-25 | Kurita Engineering Co Ltd | Method for regenerating ion exchange resin having been used for regeneration of amine liquid |
| CN102125803A (en) * | 2010-12-10 | 2011-07-20 | 北京科技大学 | Method for purifying degraded amine solution |
| CN104192946A (en) * | 2014-08-12 | 2014-12-10 | 江西瑞林电气自动化有限公司 | Amine liquid purification control method and device |
| CN105366766A (en) * | 2014-08-25 | 2016-03-02 | 中石化洛阳工程有限公司 | Resin bed thermal stabilization salt removing method |
| CN205019965U (en) * | 2015-09-29 | 2016-02-10 | 成都赛普瑞兴科技有限公司 | Amine liquid purifier |
| CN210875372U (en) * | 2019-09-19 | 2020-06-30 | 华能国际电力股份有限公司 | Low-loss organic amine solution purification device |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021052432A1 (en) * | 2019-09-19 | 2021-03-25 | 华能国际电力股份有限公司 | Low-loss organic amine solution purification device and use method thereof |
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| DE202020005624U1 (en) | 2021-11-03 |
| WO2021052432A1 (en) | 2021-03-25 |
| US20220016616A1 (en) | 2022-01-20 |
| AU2020347721A1 (en) | 2021-10-28 |
| CN110508331B (en) | 2023-08-18 |
| JP3238723U (en) | 2022-08-16 |
| AU2020347721B2 (en) | 2023-01-12 |
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