CN110499095A - A kind of anti-fouling safety coating and its preparation process and application - Google Patents
A kind of anti-fouling safety coating and its preparation process and application Download PDFInfo
- Publication number
- CN110499095A CN110499095A CN201910748394.1A CN201910748394A CN110499095A CN 110499095 A CN110499095 A CN 110499095A CN 201910748394 A CN201910748394 A CN 201910748394A CN 110499095 A CN110499095 A CN 110499095A
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- Prior art keywords
- fouling agent
- coating
- parts
- fouling
- oxide
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of anti-fouling safety coating, it is characterized in that, by weight percentage, including following components: elastic resin 5%~40%, rosin 10%~30%, oxide 1%~35%, basalt fibre 0.2%~20%, dispersing agent 0.2%~20%, safety anti-fouling agent 3%~25%, microcapsules anti-fouling agent 4%~20%, storage light powder 0~5%, carbon black 0~5%, carbon fiber 0~10%, solvent 20%~60%.Coating quick-drying prepared by the present invention, it is good to material cohesions such as polyethylene, nylon resins, have a variety of antifouling mechanisms, good antifouling effect.By taking the fishing ground use in the North Sea and Haikou City as an example, after a span of breeding fish, biological attachment only has 40 grams/m, and it is before 3000 grams/m that the present invention, which is not used,.
Description
Technical field
The invention belongs to antifouling paint technical fields, and in particular to the system of the anti-fouling safety coating of one kind, the coating
The application of standby technique and the coating.
Background technique
During Fisheries Development, fishing net is indispensable a part in fish production, wherein traditional ropework production
Fishing net have been widely used for fishery fishing in, usually by ropework produce fishing net have the fishing nets kind such as seine, sticky net
Class, but after fishing net use, it is easy to a large amount of dirt can be adhered on its surface, the service performance of fishing net be influenced, in order to change
Kind such case resistance to is stained performance and mechanics is strong to improve its usually in the surface coating anti-pollution coating of raw material polyethylene
Degree, existing various nonpolluting coatings are with cuprous oxide using zinc acrylate resin, acrylic acid copper or acrylic silane as film forming matter
Main anti-fouling agent is suitable for rigid matrix surface, and will cause enrichment of the metallic copper in ocean, to marine environment and
Biozone therein is endangered.
For this purpose, the present invention comes into being.
Summary of the invention
In view of the foregoing, the present invention intends to provide a kind of safe and efficient antifouling paint and preparation method thereof work
Skill.
In order to solve the above technical problems, firstly, the present invention provides a kind of anti-fouling safety coating.The coating
Technical solution it is as follows:
A kind of anti-fouling safety coating, by weight percentage, including following components: elastic resin 5%~
40%, rosin 10%~30%, oxide 1%~35%, basalt fibre 0.2%~20%, dispersing agent 0.2%~20%,
Safety anti-fouling agent 3%~25%, microcapsules anti-fouling agent 4%~20%, storage light powder 0~5%, carbon black 0~5%, carbon fiber 0
~10%, solvent 20%~60%.
The technical program has the beneficial effect that
Coating quick-drying prepared by the present invention, it is good to material cohesions such as polyethylene, nylon resins, have a variety of antifouling machines
Reason, good antifouling effect.By taking the fishing ground use in the North Sea and Haikou City as an example, after a span of breeding fish, biological attachment only has 40
Gram/m, and it is before 3000 grams/m that the present invention, which is not used,.
Further, the elastic resin selection includes diethylene glycol, and waterborne polyester polyalcohol, fluorine richness polyester are more
One or more of first alcohol, propylene glycol, 1,4-butanediol polycarbonate resin and adipate polyester polyalcohol.
Further, the oxide includes one or more of magnesia, iron oxide and zinc oxide.
Further, the safety anti-fouling agent includes one of zinc pyrithione, 211 anti-fouling agent of Sea-Nine
Or it is a variety of.
Further, the dispersing agent includes one or more of soybean oil, OP-10, PVA, tween.
Further, the microcapsules anti-fouling agent includes anti-fouling agent dcoit, nano zine oxide, nano-titanium oxide, is received
One or more of rice silver wire.
Further, the storage light powder includes yellow green energy storage fluorescent powder, durable-acting rare-earth fluorescent powder and concealed fluorescent powder
One of or it is several.
Further, the solvent include water, ethyl acetate, dimethylbenzene, propylene glycol monomethyl ether, in dimethyl sulfoxide
It is one or more kinds of.
The present invention also provides the preparation methods of above-mentioned coating, comprising:
The first step feeds intake stirring, investment oxide, basalt fibre, dispersing agent, safety anti-fouling agent, storage light powder, carbon
Black, carbon fiber and solvent mixing high-speed stirred dispersion；
Second step feeds intake stirring, adds elastic resin, rosin and solvent are mixed evenly；
Third step feeds intake stirring, adds safety anti-fouling agent and microcapsules anti-fouling agent stirs at low speed.
Using having the beneficial effect that for above-mentioned preparation method
This preparation method is the technique formed according to above-mentioned antifouling paint, and integrated artistic is simply pollution-free, process costs
Also more cheap, it is suitble to the industrialization of this antifouling paint.
The present invention also provides application of the above-mentioned coating on fishing net, which is characterized in that the fishing net is impregnated in institute
It states in coating, so that the coating is uniformly applied on the fishing net.
What this application had has the beneficial effect that
Uniformly smeared fishing net after coating of the invention, antifouling mechanism is prominent, efficient pollution-free, in the North Sea and
For the fishing ground use of Haikou City, after a span of breeding fish, biological attachment only has 40 grams/m, and is not used the present invention's
Before be 3000 grams/m.
Specific embodiment
Illustrate embodiments of the present invention below by way of specific specific example, those skilled in the art can be by this explanation
Other advantages and efficacy of the present invention can be easily understood for content disclosed by book.The present invention can also pass through in addition different tools
Body embodiment is embodied or practiced, and the various details in this specification can also not had based on different viewpoints and application
Various modifications or alterations are carried out under spirit of the invention.
Example 1:
By 29 parts of oxide, wherein 14 parts of magnesia, 15 parts of zinc oxide；1 part of basalt fibre, 2 parts of soybean oil, safety
Property anti-fouling agent: 5 parts of zinc pyrithione, 4 parts of yellow green energy storage fluorescent powder, 2 parts of carbon black, 1 part of carbon fiber and 15 parts of ethyl acetate it is mixed
It closes, 2500rmp high speed dispersion 50min, is sanded to 5 μm of fineness, adds 8 parts of diethylene glycol, 10 parts of rosin and ethyl acetate 15
Part mixing, stirs evenly, adds 211 5 parts of Sea-Nine and 3 parts of microcapsules anti-fouling agent: anti-fouling agent DCOIT,
600rmp, which is stirred at low speed, can be obtained antifouling paint.
Example 2:
By 30.5 parts of oxide: 14.5 parts of magnesia, 16 parts of zinc oxide, 0.5 part of basalt fibre, 1.8 parts of soybean oil,
Safety anti-fouling agent: 6 parts of zinc pyrithione, 5 parts of durable-acting rare-earth fluorescent powder, 1 part of carbon black, 1.2 parts of carbon fiber and propylene glycol monomethyl ether
35 parts of a meromict, 2000rmp high speed dispersion 80min are sanded to 16 μm of fineness, add fluorine richness polyester polyol 9
Part, 9 parts of rosin and residual acetic acid ethyl ester mix, and stir evenly, and add 211 4 parts of Sea-Nine and microcapsules anti-fouling agent 2
Part: anti-fouling agent is nano zine oxide, and 550rmp, which is stirred at low speed, can be obtained antifouling paint.
Example 3:
By 33 parts of oxide: 16 parts of magnesia, 17 parts of zinc oxide, 1.5 parts of basalt fibre, 1.3 parts of soybean oil, safety
Property anti-fouling agent: 11 parts of pyrithione, 6 parts of concealed fluorescent powder, 1.6 parts of carbon black, 0.8 part of carbon fiber and 38 parts of dimethyl sulfoxide
One meromict, 1800rmp high speed dispersion 90min are sanded to 22 μm of fineness, add 1,4-butanediol polycarbonate resin 26
Part, 13 parts of rosin and remaining dimethyl sulfoxide mixing stir evenly, add 211 7 parts of Sea-Nine and microcapsules are antifouling
2.6 parts of agent: anti-fouling agent is nano-titanium oxide, and 500rmp, which is stirred at low speed, can be obtained antifouling paint.
Example 4:
By 36 parts of oxide: 36 parts of magnesia, 2.2 parts of basalt fibre, 0.9 part of soybean oil, safety anti-fouling agent: pyrrole
11 parts of pyridine thioketones, 6 parts of yellow green energy storage fluorescent powder, 3.4 parts of carbon black, the meromict that 2.3 parts and 42 parts of dimethylbenzene of carbon fiber,
1600rmp high speed dispersion 100min is sanded to 27 μm of fineness, adds 28 parts of adipate polyester polyalcohol, 15 parts of rosin and surplus
The mixing of remaining dimethylbenzene, stirs evenly, and adds 3.6 parts of microcapsules anti-fouling agent: anti-fouling agent DCOIT, and 560rmp is stirred at low speed
Antifouling paint uniformly can be obtained.
Example 5:
By 33 parts of oxide: 33 parts of zinc oxide, 2.7 parts of basalt fibre, 1.4 parts of soybean oil, safety anti-fouling agent: pyrrole
13 parts of pyridine thioketones, 7 parts of yellow green energy storage fluorescent powder, 3.1 parts of carbon black, the half that 2.6 parts and 46 parts of ethyl acetate of carbon fiber is mixed
It closes, 1500rmp high speed dispersion 120min, is sanded to 37 μm of fineness, adds 8 parts of adipate polyester polyalcohol, 1,4-butanediol
22 parts of polycarbonate resin, 17 parts of rosin and residual acetic acid ethyl ester mix, and stir evenly, add microcapsules anti-fouling agent 7.2
Part: anti-fouling agent is nano zine oxide and nano-titanium oxide, and 460rmp, which is stirred at low speed, can be obtained antifouling paint.
Example 6:
By 50 parts of oxide: 36 parts of magnesia, 14 parts of zinc oxide, 6.2 parts of basalt fibre, 2.6 parts of soybean oil, safety
Property anti-fouling agent: 11 parts of pyrithione, 6 parts of yellow green energy storage fluorescent powder, 3.4 parts of carbon black, 2.3 parts of carbon fiber and dimethyl sulfoxide
42 parts of a meromict, 1000rmp high speed dispersion 150min are sanded to 45 μm of fineness, add adipate polyester polyalcohol 17
Part, 18 parts of diethylene glycol, 25 parts of rosin and remaining dimethyl sulfoxide mixing, stir evenly, add Sea-Nine 211 12
8.6 parts of anti-fouling agent of microcapsules of part: anti-fouling agent DCOIT, 390rmp, which is stirred at low speed, can be obtained antifouling paint.
Application Example:
The fishing net is impregnated in the coating, so that the coating is uniformly applied to the work impregnated on the fishing net
Skill uses existing conventional impregnation technology.
Uniformly smeared fishing net after coating of the invention, antifouling mechanism is prominent, efficient pollution-free, in the North Sea and
For the fishing ground use of Haikou City, after a span of breeding fish, biological attachment only has 40 grams/m, and is not used the present invention's
Before be 3000 grams/m.
The key technical indexes is as follows:
Main effect comparison:
Beneficial effects of the present invention:
Advantage: quick-drying and polyethylene, nylon resin adhesive force are good；A variety of antifouling mechanisms, good antifouling effect, in the North Sea and
The fishing ground of Haikou City uses, and after a span of breeding fish, biological attachment only has 40 grams/m；It is originally 3000 grams/m.
It should be noted that structure depicted in this specification, ratio, size etc., only to cooperate specification to be taken off
The content shown is not intended to limit the invention enforceable qualifications so that those skilled in the art understands and reads,
Therefore not having technical essential meaning, the modification of any structure, the change of proportionate relationship or the adjustment of size are not influencing this
Under the effect of invention can be generated and the purpose that can reach, it should all still fall in disclosed technology contents and obtain and can contain
In the range of lid.Meanwhile cited such as "upper" in this specification, "lower", "left", "right", the use of " centre " and " one "
Language is merely convenient to being illustrated for narration, rather than to limit the scope of the invention, the change of relativeness or tune
It is whole, under the content of no substantial changes in technology, when being also considered as the enforceable scope of the present invention.
Those skilled in the art can make a variety of variations to the present invention according to the above description.Thus, it is not violating
Under the premise of claim objective of the invention, certain details in embodiment should not constitute limitation of the invention, the present invention
It will be using the range that the appended claims define as protection scope.
Claims (10)
1. a kind of anti-fouling safety coating, which is characterized in that by weight percentage, including following components: elastic resin
5%~40%, rosin 10%~30%, oxide 1%~35%, basalt fibre 0.2%~20%, dispersing agent 0.2%~
20%, safety anti-fouling agent 3%~25%, microcapsules anti-fouling agent 4%~20%, storage light powder 0~5%, carbon black 0~5%, carbon fiber
Tie up 0~10%, solvent 20%~60%.
2. coating according to claim 1, it is characterised in that: the elastic resin selection includes diethylene glycol, aqueous
In polyester polyol, fluorine richness polyester polyol, propylene glycol, 1,4-butanediol polycarbonate resin and adipate polyester polyalcohol
One or more.
3. coating according to claim 1, it is characterised in that: the oxide includes magnesia, iron oxide and oxidation
One or more of zinc.
4. coating according to claim 1, it is characterised in that: the safety anti-fouling agent include zinc pyrithione,
One or more of 211 anti-fouling agent of Sea-Nine.
5. coating according to claim 1, it is characterised in that: the dispersing agent includes soybean oil, OP-10, PVA, spits
One or more of temperature.
6. coating according to claim 1, it is characterised in that: the microcapsules anti-fouling agent includes anti-fouling agent dcoit, receives
Rice zinc oxide, nano-titanium oxide, one or more of nano-silver thread.
7. coating according to claim 1, it is characterised in that: the storage light powder includes yellow green energy storage fluorescent powder, dilute
One of the long-acting fluorescent powder of soil and concealed fluorescent powder are several.
8. coating according to claim 1, it is characterised in that: the solvent includes water, ethyl acetate, dimethylbenzene, third
One or more of glycol methyl ether, dimethyl sulfoxide.
9. a kind of preparation method of coating described in any of the above-described claim characterized by comprising
The first step feeds intake stirring, investment oxide, basalt fibre, dispersing agent, safety anti-fouling agent, storage light powder, carbon black, carbon fiber
Peacekeeping solvent mixes high-speed stirred dispersion；
Second step feeds intake stirring, adds elastic resin, rosin and solvent are mixed evenly；
Third step feeds intake stirring, adds safety anti-fouling agent and microcapsules anti-fouling agent stirs at low speed.
10. a kind of application according to coating according to any one of claims 1 to 8 on fishing net, which is characterized in that by the fishing
Net is impregnated in the coating, so that the coating is uniformly applied on the fishing net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910748394.1A CN110499095A (en) | 2019-08-14 | 2019-08-14 | A kind of anti-fouling safety coating and its preparation process and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910748394.1A CN110499095A (en) | 2019-08-14 | 2019-08-14 | A kind of anti-fouling safety coating and its preparation process and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110499095A true CN110499095A (en) | 2019-11-26 |
Family
ID=68587444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910748394.1A Pending CN110499095A (en) | 2019-08-14 | 2019-08-14 | A kind of anti-fouling safety coating and its preparation process and application |
Country Status (1)
| Country | Link |
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| CN (1) | CN110499095A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112680012A (en) * | 2020-12-24 | 2021-04-20 | 海南大学 | Degradable antifouling coating containing basalt fiber, flake powder and copper metal powder and preparation process thereof |
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| WO2010133548A2 (en) * | 2009-05-19 | 2010-11-25 | Capeco Ab | Slow releasing microcapsules and microspheres comprising an active substance |
| CN106883758A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of environment-friendly type fishing net is without copper antifouling paint |
| CN107474715A (en) * | 2017-07-25 | 2017-12-15 | 宁波盾科新材料有限公司 | A kind of antifouling paint peculiar to vessel and preparation method thereof |
| CN110003703A (en) * | 2019-04-25 | 2019-07-12 | 海南大学 | A kind of antifouling microcapsules, preparation method and application |
-
2019
- 2019-08-14 CN CN201910748394.1A patent/CN110499095A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010133548A2 (en) * | 2009-05-19 | 2010-11-25 | Capeco Ab | Slow releasing microcapsules and microspheres comprising an active substance |
| CN106883758A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of environment-friendly type fishing net is without copper antifouling paint |
| CN107474715A (en) * | 2017-07-25 | 2017-12-15 | 宁波盾科新材料有限公司 | A kind of antifouling paint peculiar to vessel and preparation method thereof |
| CN110003703A (en) * | 2019-04-25 | 2019-07-12 | 海南大学 | A kind of antifouling microcapsules, preparation method and application |
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| Title |
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| KIM, BONG-JU等: "《Self-Polishing Properties of Antifouling Paint Resins Based on Polyurethanes According to the Types of Polyol》", 《POLYMER-KOREA》 * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112680012A (en) * | 2020-12-24 | 2021-04-20 | 海南大学 | Degradable antifouling coating containing basalt fiber, flake powder and copper metal powder and preparation process thereof |
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