CN110499022A - A kind of corrosion-resistant plastic and preparation method thereof - Google Patents
A kind of corrosion-resistant plastic and preparation method thereof Download PDFInfo
- Publication number
- CN110499022A CN110499022A CN201910920979.7A CN201910920979A CN110499022A CN 110499022 A CN110499022 A CN 110499022A CN 201910920979 A CN201910920979 A CN 201910920979A CN 110499022 A CN110499022 A CN 110499022A
- Authority
- CN
- China
- Prior art keywords
- parts
- corrosion
- resistant plastic
- preparation
- glass fibre
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention discloses a kind of corrosion-resistant plastics and preparation method thereof, and in parts by weight, raw material composition includes: 60~70 parts of polyamide, 40~45 parts of glass fibre, 0.2~0.4 part of coupling agent, 6~10 parts of compatilizer, 0.3~0.6 part of antioxidant, 0.2~0.4 part of lubricant.Compared with prior art, the more traditional polyamide resin material of product of the present invention, corrosion resistance have obtained tremendous increase, can meet and use under corrosive environment, furthermore product of the present invention production stage is simple, easy to operate.In conclusion the composite can be widely applied to polymer material manufacture field.
Description
Technical field
The present invention relates to a kind of corrosion-resistant plastics and preparation method thereof, belong to polymer processing field.
Background technique
Polyamide itself good mechanical property, wearability and self-lubrication become using very extensive
One of engineering plastics, also just so result in polyamide and have and be greatly likely to be exposed Corrosive Materia, such as change
Learn industrial Corrosive Materia, the rainwater etc. in daily life.
Polyamide itself possesses a large amount of sour amino, and oxygen index (OI) is about 24%~26%, this also results in its change
It is slightly active to learn property, therefore polyamide corrosion resistance is not high, this also brings to industrial production and daily life larger
Hidden danger.
Summary of the invention
To solve the above technical problem, the present invention provides the preparation methods of a kind of corrosion-resistant plastic formula and the plastics.
A kind of corrosion-resistant plastic and preparation method thereof, the corrosion-resistant plastic includes following component:
Further, the polyamide is the mixture of PA66, PA6 or the two.
Further, the glass fibre is the alkali-free glass fibre that length is 0.4mm~0.6mm, and the coupling agent is
Coupling agent KH550.
Further, the compatilizer is maleic anhydride grafted polymer compatilizer.
Further, the antioxidant is antioxidant 626.
Further, the lubricant is silicone powder.
Further, 60 parts of the PA66,40 parts of the alkali-free glass fibre, 0.2 part of the coupling agent KH550, institute
State 6 parts of maleic anhydride grafted polymer compatilizer, 626 0.3 parts of the antioxidant, 0.2 part of the silicone powder.
Further, 65 parts of the PA66,42.5 parts of the alkali-free glass fibre, 0.3 part of the coupling agent KH550,
8 parts of the maleic anhydride grafted polymer compatilizer, 626 0.45 parts of the antioxidant, 0.3 part of the silicone powder.
Further, 70 parts of the PA66,45 parts of the alkali-free glass fibre, 0.4 part of the coupling agent KH550, institute
State 10 parts of maleic anhydride grafted polymer compatilizer, 626 0.6 parts of the antioxidant, 0.4 part of the silicone powder.
Further, the preparation method comprises the following steps:
(1) for investment into high-speed mixer, temperature is set as 30 DEG C~60 DEG C, holds after mixing glass fibre with coupling agent
The continuous time is 60min~120min；
(2) mixture obtained to step (1) launches polyamide, compatilizer, antioxidant, lubricant, continues to stir
40min~60min；
(3) mixture that step (2) obtains is put into double screw extruder, degree is set as 150 DEG C~200 DEG C, screw rod
Revolving speed is 60r/min~120r/min, squeezes out particle, and obtain corrosion-resistant plastic.
Compared with prior art, the more traditional polyamide resin material of product of the present invention, corrosion resistance have obtained huge
It is promoted, can meet and be used under corrosive environment.Furthermore product of the present invention production stage is simple, easy to operate, to possess preferable
Market prospects.
Specific embodiment
The present invention is described in further details below in conjunction with embodiment, but it is to be understood that, in following embodiment
Related number, scientific and technical terminology and process etc. are intended merely to preferably describe to explain the content of present invention, not
It is to limit the present invention, protection scope of the present invention is not limited only to this.
Embodiment one
The corrosion-resistant plastic of the present embodiment, Parts by Ingredients meter are as follows: 60 parts of PA66,40 parts of alkali-free glass fibre, even
0.2 part of agent KH550,6 parts of maleic anhydride grafted polymer compatilizer, 626 0.3 parts of antioxidant, 0.2 part of silicone powder of connection.
The corrosion-resistant plastic preparation process is as follows:
(1) for investment into high-speed mixer, temperature is set as 30 DEG C after mixing alkali-free glass fibre with coupling agent KH550
~60 DEG C, the duration is 60min~120min；
(2) mixture that is obtained to step (1) launch PA66, maleic anhydride grafted polymer compatilizer, antioxidant 626,
Silicone powder continues to stir 40min~60min；
(3) mixture that step (2) obtains is put into double screw extruder, degree is set as 150 DEG C~200 DEG C, screw rod
Revolving speed is 60r/min~120r/min, squeezes out particle, and obtain corrosion-resistant plastic.
Embodiment two
The corrosion-resistant plastic of the present embodiment, Parts by Ingredients meter are as follows: 65 parts of PA66,42.5 parts of alkali-free glass fibre,
0.3 part of coupling agent KH550,8 parts of maleic anhydride grafted polymer compatilizer, 626 0.45 parts of antioxidant, 0.3 part of silicone powder.
The corrosion-resistant plastic preparation process is as follows:
(1) for investment into high-speed mixer, temperature is set as 30 DEG C after mixing alkali-free glass fibre with coupling agent KH550
~60 DEG C, the duration is 60min~120min；
(2) mixture that is obtained to step (1) launch PA66, maleic anhydride grafted polymer compatilizer, antioxidant 626,
Silicone powder continues to stir 40min~60min；
(3) mixture that step (2) obtains is put into double screw extruder, degree is set as 150 DEG C~200 DEG C, screw rod
Revolving speed is 60r/min~120r/min, squeezes out particle, and obtain corrosion-resistant plastic.
Embodiment three
The corrosion-resistant plastic of the present embodiment, Parts by Ingredients meter are as follows: 70 parts of PA66,45 parts of alkali-free glass fibre, even
0.4 part of agent KH550,10 parts of maleic anhydride grafted polymer compatilizer, 626 0.6 parts of antioxidant, 0.4 part of silicone powder of connection.
The corrosion-resistant plastic preparation process is as follows:
(1) for investment into high-speed mixer, temperature is set as 30 DEG C after mixing alkali-free glass fibre with coupling agent KH550
~60 DEG C, the duration is 60min~120min；
(2) mixture that is obtained to step (1) launch PA66, maleic anhydride grafted polymer compatilizer, antioxidant 626,
Silicone powder continues to stir 40min~60min；
(3) mixture that step (2) obtains is put into double screw extruder, degree is set as 150 DEG C~200 DEG C, screw rod
Revolving speed is 60r/min~120r/min, squeezes out particle, and obtain corrosion-resistant plastic.
The above is all a specific embodiment of the invention, any without creativeness in claim of the invention
The variations and alternatives of labour belong in protection scope of the present invention.
Claims (10)
1. a kind of corrosion-resistant plastic and preparation method thereof, it is characterised in that: the corrosion-resistant plastic includes following component:
2. a kind of corrosion-resistant plastic as described in claim 1 and preparation method thereof, it is characterised in that: the polyamide is
The mixture of PA66, PA6 or the two.
3. a kind of corrosion-resistant plastic as described in claim 1 and preparation method thereof, it is characterised in that: the glass fibre is length
Degree is the alkali-free glass fibre of 0.4mm~0.6mm, and the coupling agent is coupling agent KH550.
4. a kind of corrosion-resistant plastic as described in claim 1 and preparation method thereof, it is characterised in that: the compatilizer is Malaysia
Anhydride-grafted polymers compatilizer.
5. a kind of corrosion-resistant plastic as described in claim 1 and preparation method thereof, it is characterised in that: the antioxidant is antioxygen
Agent 626.
6. a kind of corrosion-resistant plastic as described in claim 1 and preparation method thereof, it is characterised in that: the lubricant is silicone
Powder.
7. a kind of corrosion-resistant plastic as described in any one of claims 1 to 6 and preparation method thereof, it is characterised in that: described
60 parts of PA66,40 parts of the alkali-free glass fibre, 0.2 part of the coupling agent KH550, the maleic anhydride grafted polymer phase
6 parts of agent of appearance, 626 0.3 parts of the antioxidant, 0.2 part of the silicone powder.
8. a kind of corrosion-resistant plastic as described in any one of claims 1 to 6 and preparation method thereof, it is characterised in that: described
65 parts of PA66,42.5 parts of the alkali-free glass fibre, 0.3 part of the coupling agent KH550, the maleic anhydride grafted polymer
8 parts of compatilizer, 626 0.45 parts of the antioxidant, 0.3 part of the silicone powder.
9. a kind of corrosion-resistant plastic as described in any one of claims 1 to 6 and preparation method thereof, it is characterised in that: described
70 parts of PA66,45 parts of the alkali-free glass fibre, 0.4 part of the coupling agent KH550, the maleic anhydride grafted polymer phase
10 parts of agent of appearance, 626 0.6 parts of the antioxidant, 0.4 part of the silicone powder.
10. a kind of corrosion-resistant plastic as described in claim 1 and preparation method thereof, it is characterised in that: the preparation method packet
Include following steps:
(1) for investment into high-speed mixer, temperature is set as 30 DEG C~60 DEG C after mixing glass fibre with coupling agent, when continuing
Between be 60min~120min；
(2) mixture obtained to step (1) launches polyamide, compatilizer, antioxidant, lubricant, continues to stir 40min
~60min；
(3) mixture that step (2) obtains is put into double screw extruder, degree is set as 150 DEG C~200 DEG C, screw speed
For 60r/min~120r/min, particle is squeezed out, and obtains corrosion-resistant plastic.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910920979.7A CN110499022A (en) | 2019-09-27 | 2019-09-27 | A kind of corrosion-resistant plastic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910920979.7A CN110499022A (en) | 2019-09-27 | 2019-09-27 | A kind of corrosion-resistant plastic and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110499022A true CN110499022A (en) | 2019-11-26 |
Family
ID=68592894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910920979.7A Pending CN110499022A (en) | 2019-09-27 | 2019-09-27 | A kind of corrosion-resistant plastic and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110499022A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804416A (en) * | 2015-03-17 | 2015-07-29 | 南京利华工程塑料有限公司 | Colorful photoaging-resistant glass fiber reinforced polyamide and preparation method thereof |
-
2019
- 2019-09-27 CN CN201910920979.7A patent/CN110499022A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804416A (en) * | 2015-03-17 | 2015-07-29 | 南京利华工程塑料有限公司 | Colorful photoaging-resistant glass fiber reinforced polyamide and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103275448B (en) | Preparation method of modified packing ion enhanced polytetrafluoroethylene composite | |
| CN103333442B (en) | TiO 2the preparation method of-SiC-fibre filling polytetrafluoroethyland matrix material | |
| CN109535327A (en) | A kind of maleic anhydride-grafted polypropylene material and preparation method thereof of low smell high fusion index | |
| CN107915933B (en) | Preparation method of special toughening type nano calcium carbonate for PVC (polyvinyl chloride) plastics | |
| CN104177719B (en) | Special material for cross-flow fan reinforced AS with high heat resistance and preparation method of material | |
| CN106220997A (en) | PP composite material and preparation method thereof | |
| CN110499022A (en) | A kind of corrosion-resistant plastic and preparation method thereof | |
| CN102558711B (en) | Wood plastic composite material and production method thereof | |
| CN103013034B (en) | Modified ABS (Acrylonitrile Butadiene Styrene) resin capable of being firmly bonded by epoxy resin and preparation method of modified ABS resin | |
| CN112500700A (en) | Blow-moldable weather-resistant nylon composition and preparation method thereof | |
| CN105017526B (en) | A kind of bulking agent of plasticizing enhancement nylon 6 and its production and use | |
| CN106046785A (en) | High-temperature-resistant synthetic resin and preparation method thereof | |
| CN110789213A (en) | Polyurethane and polytetrafluoroethylene compounding process | |
| CN106349689B (en) | Toughening enhances PA6 materials and preparation method thereof | |
| CN106189216B (en) | A kind of PEI and PA66 alloy and preparation method thereof | |
| CN105131587B (en) | A kind of nylon 6 Blends containing bulking agent | |
| CN103289385B (en) | Composite material of nylon 66/aramid fibres and preparation method of same | |
| CN113667254A (en) | High-stability broad-spectrum antibacterial PMMA \ ASA alloy material based on molecular on-line self-assembly technology and preparation method thereof | |
| CN106398205A (en) | Preparation method of conductive nylon material | |
| CN111171473A (en) | Large-diameter PVC-U water supply accessory injection molding granules and preparation method thereof | |
| CN108530859A (en) | A kind of preparation method of particle strengthening rubber reinforcement composite material | |
| CN109627757A (en) | A kind of PA66-ACS composite material | |
| CN112679873B (en) | Heat-resistant pressure-resistant PVC (polyvinyl chloride) pipe composition and preparation method thereof | |
| CN101701104A (en) | Environment-friendly self-lubricating wearable injection-molded nylon 66 and preparing process thereof | |
| CN104927349B (en) | A kind of preparation method of packing rope PA composites |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |