CN110498585A - A kind of in-situ immobilization black and odorous water bed mud medicament and its preparation method and application - Google Patents
A kind of in-situ immobilization black and odorous water bed mud medicament and its preparation method and application Download PDFInfo
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- CN110498585A CN110498585A CN201910834435.9A CN201910834435A CN110498585A CN 110498585 A CN110498585 A CN 110498585A CN 201910834435 A CN201910834435 A CN 201910834435A CN 110498585 A CN110498585 A CN 110498585A
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- medicament
- water
- gross mass
- bed mud
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/02—Biological treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/101—Sulfur compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Sludge (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The present invention relates to a kind of in-situ immobilization black and odorous water bed mud medicament and its preparation method and application, the weight percent of the primary chemical composition of the medicament is Zero-valent Iron 20-35%, mantoquita 5-10%, waterglass 10%, peroxidase 12 5-40%, carbohydrate 10-15%, NaY molecular sieve 5% and water 10-15%.The present invention also provides a kind of preparation methods of black and odorous water remedying sludge medicament, dissolve mantoquita with a small amount of water first, solution is poured into the beaker equipped with Zero-valent Iron, and mixed liquor A is made；Then a small amount of water is added into carbohydrate, and pours into the beaker for filling peroxide, mixed liquid B is made；Then, mixed liquor A and B are mixed, meanwhile, water glass solution and NaY molecular sieve is added, and be stirred continuously；Finally, being granulated by pelletizer, the medicament is made.The preparation process of the medicament is simple, and repairing effect is good, and the generation for the black odour such as can overcome hydrogen sulfide, has a good application prospect.
Description
Technical field
The present invention relates to the technical field of environment remediation, more particularly to a kind of in-situ immobilization black and odorous water bed mud medicament and
Preparation method and application.
Background technique
With the fast development of industrial or agricultural, more and more productions and sanitary wastewater excess emissions lead to river into river
Nutrient in flowing water body increases to be enriched with polluter, so that water quality deteriorates, generates black and odorous water.Black and odorous water is not
River crowd's living environment nearby is only influenced, and will lead to human health problems' appearance.Therefore, it is for black and odorous water improvement
The hot spot of aquatic ecological restoration.
Current black and odorous water recovery technique mainly includes external source Control Technology and endogenous Treatment process.With national policy and
The development of the relevant technologies, external source Control Technology repairing effect is significant, has prevented the discharge of xenobiotic pollutants substantially, therefore endogenous improvement
Technology is research hotspot instantly.According to the space-time boundary of recovery technique, endogenous Treatment process is divided into showering technology and original
Position recovery technique.It can destroy the aquatic environment of original water body relative to showering technology, rehabilitation cost height and be also easy to produce secondary
The problems such as pollution, based technique for in-situ remediation can effectively overcome problem above, and such as without a large amount of constructions, easy to operate, cost is relatively low,
It is smaller to the disturbance of original aquatic ecosystem, and be not easy to bring secondary pollution.Therefore, in-situ techniques are more paid close attention to.At present
Based technique for in-situ remediation mainly includes physical method, chemical method and three kinds of bioanalysis.Wherein physical method includes aeration oxygen replenishing, hidden covering
With riverbed landfill etc. technologies；Chemical method includes the technologies such as redox and passivation；Bioanalysis includes that phytoremediation and microorganism are repaired
Recovering technology.Because of bed mud diversity of organism and the complexity containing substance, using single physics, chemistry or biotechnology are all
It is difficult to repair black and odorous water, so how to be efficiently the weight of researcher's concern for the reparation of black and odorous water in conjunction with several technologies
Point.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of in-situ immobilization black and odorous water bed mud medicament and preparation method thereof
And application, it can effectively realize physical method, the combination of three kinds of technical methods of chemical method and bioanalysis and for black smelly water
Body is administered.
(2) technical solution
To achieve the above object, the invention provides the following technical scheme: a kind of in-situ immobilization black and odorous water bed mud medicament,
The weight percent of primary chemical composition is Zero-valent Iron 20-35%, mantoquita 5-10%, waterglass 10%, peroxidase 12 5-
40%, carbohydrate 10-15%, NaY molecular sieve 5% and water 10-15%.
Preferably, the Zero-valent Iron derives from waste iron filing, industrial scum and business Zero-valent Iron, and control Zero-valent Iron partial size exists
10 microns or more.
Preferably, the mantoquita includes copper chloride, one of cupric salts such as copper sulphate and copper nitrate or a variety of.
Preferably, the peroxide includes sodium peroxide, potassium peroxide, one of calper calcium peroxide and peromag etc.
Or it is a variety of.
Preferably, the carbohydrate includes starch, one or more of the polysaccharide or monosaccharide such as cellulose and glucose.
A kind of preparation method of in-situ immobilization black and odorous water bed mud medicament, gross mass will be accounted for first by, which including the following steps:, is
The water of 2%-3% is mixed to get copper salt solution with the mantoquita that gross mass is 5-10% is accounted for, and then pours into copper salt solution equipped with accounting for
Gross mass is that mixed liquor A is made in the beaker of 20-35% Zero-valent Iron；Then to account for gross mass be 10-15% carbohydrate in be added
It accounts for the water that gross mass is 5% and is uniformly mixed, then the mixture of carbohydrate and water is poured into and to fill that account for gross mass be 25-40%
In the beaker of peroxide, mixed liquid B is made；Finally, mixed liquor A and B are mixed, while being added and accounting for gross mass 10-15%'s
Water glass solution and account for gross mass be 5% NaY molecular sieve, be stirred continuously, and by pelletizer be granulated, be made partial size be 150-
200 microns of the medicament.
Preferably, add the medicament according to the 0.5-5% of water body indsole mud mass fraction, reaction in an anaerobic environment into
Row.
(3) beneficial effect
Compared with prior art, the present invention provides a kind of in-situ immobilization black and odorous water bed mud medicament and preparation method thereof and
Using, have it is following the utility model has the advantages that
A kind of in-situ immobilization black and odorous water bed mud medicament and its preparation method and application first uses copper salt solution and Zero-valent Iron
It is mixed with mixed liquor A, the mixture of carbohydrate and water and peroxide are then mixed with mixed liquid B, then, by mixed liquor
A and mixed liquid B and water glass solution and NaY molecular sieve stir together and are added pelletizer granulation, and the medicament is made.It is described
Medicament can efficiently repair black and odorous water, effectively prevent the foul gas such as hydrogen sulfide to generate by controlling sulphur, by consuming hydrogen ion
It is adjustable the pH value of water body part, and passes through oxygenation and addition nutritive salt enhancement microbiological effect.
Detailed description of the invention
Fig. 1 is the effect picture that the medicament prepared by embodiment 1 administers black and odorous water bed mud；
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts
Example, shall fall within the protection scope of the present invention.
Embodiment 1:
Water that gross mass is 3% will be accounted for and account for the copper sulphate that gross mass is 10% and be mixed to get copper-bath, by sulfuric acid
Copper solution is poured into equipped with accounting in the beaker for the Zero-valent Iron that gross mass is 23%, and obtained mixed liquor A is stirred evenly；Then to the total matter of Zhan
Amount accounts for water that gross mass is 5% and is uniformly mixed to be added in 15% starch, and the mixture of starch and water is then poured into Sheng
Have and account in the beaker for the calper calcium peroxide that gross mass is 27%, obtained mixed liquid B is stirred evenly, finally, by mixed liquor A and mixed liquor
B is admixed together, meanwhile, water glass solution is added (water content is the 2% of gross mass, and waterglass content is the 10% of gross mass)
And the NaY molecular sieve that gross mass is 5% is accounted for, it is then constantly stirred, and be granulated by pelletizer, to obtain
The medicament that partial size is about 150 microns.
Add the medicament according to the 3% of water body indsole shale amount, reaction for 24 hours, bed mud volatile sulfide (AVS) from
475mg/kg drops to 71mg/kg, and removal rate is up to 85%；Ammonia-nitrogen content drops to 3mg/L from 15mg/L, and removal rate reaches
94%；Total phosphorus content drops to 0.09mg/L from 2mg/L, and removal rate reaches 96%；COD content drops to 13mg/ from 152mg/L
L, removal rate are up to 91%；The pH value of water body rises to 7.3 from 6.2.
Embodiment 2:
Water that gross mass is 3% will be accounted for and account for the copper sulphate that gross mass is 7% and be mixed to get copper-bath, by copper sulphate
Solution is poured into equipped with accounting in the beaker for the Zero-valent Iron that gross mass is 20%, stirs evenly obtained mixed liquor A；Then to accounting for gross mass
It accounts for water that gross mass is 5% to be added in 15% cellulose and is uniformly mixed, then pour into the mixture of cellulose and water
It fills and accounts in the beaker for the calper calcium peroxide that gross mass is 30%, obtained mixed liquid B is stirred evenly, finally, by mixed liquor A and mixing
Liquid B is admixed together, meanwhile, water glass solution is added, and (water content is the 5% of gross mass, and waterglass content is gross mass
10%) and the NaY molecular sieve that gross mass is 5% is accounted for, is then constantly stirred, and be granulated by pelletizer, from
And obtain the medicament that partial size is about 170 microns.
Add the medicament according to the 3% of water body indsole shale amount, reaction for 24 hours, bed mud volatile sulfide (AVS) from
475mg/kg drops to 96mg/kg, and removal rate is up to 80%；Ammonia-nitrogen content drops to 3.5mg/L from 15mg/L, and removal rate reaches
77%；Total phosphorus content drops to 0.15mg/L from 2mg/L, and removal rate reaches 93%；COD content drops to 19mg/ from 152mg/L
L, removal rate are up to 88%；The pH value of water body rises to 7.0 from 6.2.
Embodiment 3:
Water that gross mass is 2% will be accounted for and account for the copper sulphate that gross mass is 5% and be mixed to get copper-bath, by copper sulphate
Solution is poured into equipped with accounting in the beaker for the Zero-valent Iron that gross mass is 35%, stirs evenly obtained mixed liquor A；Then to accounting for gross mass
The obtained glucose solution of water that gross mass is 5% is accounted for be added in 19% glucose, then glucose solution is poured into and is filled
It accounts in the beaker for the potassium peroxide that gross mass is 25%, obtained mixed liquid B is stirred evenly, finally, by mixed liquor A and mixed liquid B
It is admixed together, meanwhile, water glass solution is added (water content is the 3% of gross mass, and waterglass content is the 10% of gross mass)
And the NaY molecular sieve that gross mass is 5% is accounted for, it is then constantly stirred, and be granulated by pelletizer, to obtain
The medicament that partial size is about 150 microns.
The medicament is added according to the 0.5% of water body indsole shale amount, is reacted for 24 hours, bed mud volatile sulfide (AVS)
Drop to 252mg/kg, removal rate 47% from 475mg/kg；Ammonia-nitrogen content drops to 12mg/L from 15mg/L, and removal rate reaches
20%；Total phosphorus content drops to 1.32mg/L from 2mg/L, and removal rate reaches 34%；COD content drops to 75mg/ from 152mg/L
L, removal rate 51%；The pH value of water body rises to 6.4 from 6.2.
Embodiment 4:
Water that gross mass is 2% will be accounted for and account for the copper sulphate that gross mass is 8% and be mixed to get copper-bath, by copper sulphate
Solution is poured into equipped with accounting in the beaker for the Zero-valent Iron that gross mass is 20%, stirs evenly obtained mixed liquor A, then to accounting for gross mass
It accounts for water that gross mass is 3% to be added in 10% starch and is uniformly mixed, then the mixture of starch and water is poured into and is filled
It accounts in the beaker for the calper calcium peroxide that gross mass is 40%, obtained mixed liquid B is stirred evenly, finally, by mixed liquor A and mixed liquid B
It is admixed together, meanwhile, water glass solution is added (water content is the 2% of gross mass, and waterglass content is the 10% of gross mass)
And the NaY molecular sieve that gross mass is 5% is accounted for, it is then constantly stirred, and be granulated by pelletizer, to obtain partial size
About 200 microns of the medicament.
Add the medicament according to the 3% of water body indsole shale amount, reaction for 24 hours, bed mud volatile sulfide (AVS) from
475mg/kg drops to 120mg/kg, and removal rate is up to 75%；Ammonia-nitrogen content drops to 2.7mg/L from 15mg/L, and removal rate reaches
To 82%；Total phosphorus content drops to 0.28mg/L from 2mg/L, and removal rate reaches 86%；COD content drops to from 152mg/L
35mg/L, removal rate are up to 77%；The pH value of water body rises to 7.0 from 6.2.
Embodiment 5:
Water that gross mass is 2% will be accounted for and account for the copper sulphate that gross mass is 8% and be mixed to get copper-bath, by copper sulphate
Solution is poured into equipped with accounting in the beaker for the Zero-valent Iron that gross mass is 20%, stirs evenly obtained mixed liquor A；Then to accounting for gross mass
It accounts for water that gross mass is 3% to be added in 10% starch and is uniformly mixed, then the mixture of starch and water is poured into and is filled
It accounts in the beaker for the calper calcium peroxide that gross mass is 40%, obtained mixed liquid B is stirred evenly, finally, by mixed liquor A and mixed liquid B
It is admixed together, meanwhile, water glass solution is added (water content is the 2% of gross mass, and waterglass content is the 10% of gross mass)
And the NaY molecular sieve that gross mass is 5% is accounted for, it is then constantly stirred, and be granulated by pelletizer, to obtain
The medicament that partial size is about 200 microns.
Add the medicament according to the 3% of water body indsole shale amount, reaction for 24 hours, bed mud volatile sulfide (AVS) from
475mg/kg drops to 120mg/kg, and removal rate is up to 75%；Ammonia-nitrogen content drops to 2.7mg/L from 15mg/L, and removal rate reaches
To 82%；Total phosphorus content drops to 0.28mg/L from 2mg/L, and removal rate reaches 86%；COD content drops to from 152mg/L
35mg/L, removal rate are up to 77%；The pH value of water body rises to 7.0 from 6.2.
It should be noted that, in this document, the terms "include", "comprise" or its any other variant are intended to non-row
His property includes, so that the process, method, article or equipment for including a series of elements not only includes those elements, and
And further include other elements that are not explicitly listed, or further include for this process, method, article or equipment institute it is intrinsic
Element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of in-situ immobilization black and odorous water bed mud medicament, which is characterized in that the weight percent of its primary chemical composition is zero
Valence iron 20-35%, mantoquita 5-10%, waterglass 10%, peroxidase 12 5-40%, carbohydrate 10-15%, 5% and of NaY molecular sieve
Water 10-15%.
2. a kind of in-situ immobilization black and odorous water bed mud medicament as described in claim 1, which is characterized in that Zero-valent Iron is from useless
Iron filings, industrial scum and business Zero-valent Iron control Zero-valent Iron partial size at 10 microns or more.
3. a kind of in-situ immobilization black and odorous water bed mud medicament as described in claim 1, which is characterized in that mantoquita includes chlorination
One of cupric salts such as copper, copper sulphate and copper nitrate are a variety of.
4. a kind of in-situ immobilization black and odorous water bed mud medicament as described in claim 1, which is characterized in that peroxide included
One of sodium oxide molybdena, potassium peroxide, calper calcium peroxide and peromag etc. are a variety of.
5. a kind of in-situ immobilization black and odorous water bed mud medicament as described in claim 1, which is characterized in that carbohydrate includes starch,
One or more of the polysaccharide or monosaccharide such as cellulose and glucose.
6. a kind of preparation method of in-situ immobilization black and odorous water bed mud medicament as described in claim 1, which is characterized in that including
Following steps: will account for water that gross mass is 2%-3% first and account for the mantoquita that gross mass is 5-10% and be mixed to get copper salt solution,
Then copper salt solution is poured into equipped with accounting in the beaker that gross mass is 20-35% Zero-valent Iron, mixed liquor A is made；Then Zhan is total
The water of quality 5% is added to account in the carbohydrate that gross mass is 10-15% and be uniformly mixed, and the mixture of carbohydrate and water is then poured into Sheng
Have and account in the beaker for the peroxide that gross mass is 25-40%, mixed liquid B is made；Finally, mixed liquor A and B are mixed, simultaneously
The water glass solution for accounting for gross mass 10-15% is added and accounts for the NaY molecular sieve that gross mass is 5%, is stirred continuously, and pass through granulation
Machine is granulated, and the medicament that partial size is 150-200 microns is made.
7. a kind of preparation method of in-situ immobilization black and odorous water bed mud medicament as claimed in claim 6, which is characterized in that according to
The 0.5-5% of water body indsole mud mass fraction adds the medicament, and reaction carries out in an anaerobic environment.
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