CN110485164A - A kind of production technology of nice and cool pashm worsted plus material - Google Patents

A kind of production technology of nice and cool pashm worsted plus material Download PDF

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Publication number
CN110485164A
CN110485164A CN201910815994.5A CN201910815994A CN110485164A CN 110485164 A CN110485164 A CN 110485164A CN 201910815994 A CN201910815994 A CN 201910815994A CN 110485164 A CN110485164 A CN 110485164A
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CN
China
Prior art keywords
cool
nice
pashm
plus material
worsted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910815994.5A
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Chinese (zh)
Inventor
何良
陆晓明
韩晨晨
何慧
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Jiangsu Sunshine Co Ltd
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Jiangsu Sunshine Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Sunshine Co Ltd filed Critical Jiangsu Sunshine Co Ltd
Priority to CN201910815994.5A priority Critical patent/CN110485164A/en
Publication of CN110485164A publication Critical patent/CN110485164A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • D06M13/148Polyalcohols, e.g. glycerol or glucose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192Polycarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • D06M2101/12Keratin fibres or silk

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of production technologies of nice and cool pashm worsted plus material, comprising the following steps: S1 configures nice and cool finishing agent, and the Main Components for finishing agent of feeling nice and cool are Waterborne Polyurethane Prepolymer, multicomponent organic acid, the agent of polyalcohol cool feeling, hydramine and water;Pashm worsted plus material is placed in the nice and cool finishing agent of S1 by S2, pads processing, takes out the pashm worsted plus material with liquid;Worsted fabric obtained by S2 is placed at 85~95 DEG C and is dried to drying in advance by S3, then imports at 110~130 DEG C and bake, and obtains nice and cool pashm worsted plus material.Using Waterborne Polyurethane Prepolymer as film forming agent, multicomponent organic acid is added and is crosslinked with cool feeling agent, it is ensured that the persistence of cool feeling reduces fabric xanthochromia degree.

Description

A kind of production technology of nice and cool pashm worsted plus material
Technical field
The present invention relates to fleece fabrics production technical fields, and in particular to a kind of production work of nice and cool pashm worsted plus material Skill.
Background technique
Worsted cashmere fabric has the advantages that smooth, frivolous, penetrating, slim and graceful, fine and smooth etc. take.It is original with top cashmere Material, after combing is spun into combed yarn, is made into fleece fabrics in Seiko.The number of worsted cashmere yarn generally from 28 to 120.Worsted cashmere is very suitable to spring and summer dress, when being used for summer clothes, usually by cashmere fiber and coolmax, outlast Deng the yarn adjusted with excellent moisture absorption sweat discharging functions or temperature, to improve wearing comfort.
For full pashm worsted plus material, cool feeling agent is applied on fabric by the method for generalling use final finishing. A kind of finishing fluid is disclosed in CN107523993A, wherein including cool feeling agent and crosslinking agent, further, cool feeling agent is COOLM6036, crosslinking agent AF3600, but above-mentioned AF series crosslinking agent usually requires to bake to 160 DEG C or more, and above-mentioned bake Under the conditions of temperature, the strength of cashmere fiber can decline, and different journeys can integrally occur because of the difference of use condition, cashmere fabric The irreversible xanthochromia of degree.
Therefore, it is necessary to which the nice and cool finishing technique to pashm worsted plus material in the prior art optimizes.
Summary of the invention
It is an object of the invention to overcome defect existing in the prior art, a kind of life of nice and cool pashm worsted plus material is provided Production. art is added multicomponent organic acid and crosslinks with cool feeling agent, it is ensured that cool feeling using Waterborne Polyurethane Prepolymer as film forming agent Persistence.
To achieve the above object, the technical solution of the present invention is as follows: a kind of production technology of nice and cool pashm worsted plus material, special Sign is, comprising the following steps:
S1: configuring nice and cool finishing agent, and the Main Components for finishing agent of feeling nice and cool are Waterborne Polyurethane Prepolymer, multicomponent organic acid, polynary The agent of alcohol cool feeling, hydramine and water;
S2: pashm worsted plus material is placed in the nice and cool finishing agent of S1, pads processing, takes out the pashm worsted plus material with liquid;
S3: worsted fabric obtained by S2 is placed at 85~95 DEG C and is dried to drying in advance, then imports at 110~130 DEG C and bakes, is obtained nice and cool Pashm worsted plus material.
Preferred technical solution is that the polyalcohol cool feeling agent is xylitol and/or red sugar alcohol.
Preferred technical solution is the concentration of main component in nice and cool finishing agent are as follows: Waterborne Polyurethane Prepolymer 50~ 130g/L, 0.5~4 g/L of multicomponent organic acid, 5~30g/L of polyalcohol cool feeling agent, 0.1~2 g/L of hydramine.
Preferred technical solution is that the organic multicomponent acid is one or both of citric acid, ethanedioic acid and tartaric acid Above combination.
Preferred technical solution is that hydramine is selected from monoethanolamine, diethanol amine, triethanolamine, diglycolamine, diisopropyl The combination of one or more of hydramine, N methyldiethanol amine.
Preferred technical solution is that the pick-up of processing is padded in S2 is 60~70%.
The advantages and beneficial effects of the present invention are:
The production technology of the nice and cool pashm worsted plus material using Waterborne Polyurethane Prepolymer as film forming agent, it is multicomponent organic acid, more The surface group of first alcohol cool feeling agent and hydramine and wool fiber crosslinking, help to improve pashm worsted plus material cool feeling persistence and Washability;
The preliminary drying and baking temperature of above-mentioned arrangement process are lower, and fabric entirety xanthochromia and influence to fiber strength are smaller.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Embodiment 1
Embodiment 1 feel nice and cool pashm worsted plus material production technology the following steps are included:
S1: configuring nice and cool finishing agent, and the Main Components for finishing agent of feeling nice and cool are Waterborne Polyurethane Prepolymer, multicomponent organic acid, polynary The agent of alcohol cool feeling, hydramine and water;
S2: pashm worsted plus material is placed in the nice and cool finishing agent of S1, pads processing, takes out the pashm worsted plus material with liquid;
S3: worsted fabric obtained by S2 is placed at 85 DEG C and is dried to drying in advance, then imports at 130 DEG C and bakes, it is spinning to obtain nice and cool cashmere Fabric.
Polyalcohol cool feeling agent is xylitol.
Embodiment 1 uses the Waterborne Polyurethane Prepolymer of 1000 magnitudes;The concentration of main component in nice and cool finishing agent are as follows: water Property base polyurethane prepolymer for use as 50g/L, 4 g/L of multicomponent organic acid, polyalcohol cool feeling agent 30g/L, 2 g/L of hydramine.
Organic multicomponent acid is citric acid;Hydramine is monoethanolamine.
The pick-up that processing is padded in S2 is 80%.
Embodiment 2
Embodiment 2 is based on embodiment 1, and difference is:
S3: worsted fabric obtained by S2 is placed at 95 DEG C and is dried to drying in advance, then imports at 110 DEG C and bakes 3min;Polyalcohol cool feeling Agent is that xylitol and red sugar alcohol 1:1 weight ratio are composed.
The concentration of main component in nice and cool finishing agent are as follows: Waterborne Polyurethane Prepolymer 130g/L, 5 g/L of multicomponent organic acid, 3 g/L of polyalcohol cool feeling agent, 0.1 g/L of hydramine.
Organic multicomponent acid is tartaric acid;Hydramine is diethanol amine.
The pick-up that processing is padded in S2 is 60%.
Embodiment 3
Embodiment 3 is based on embodiment 2, and difference is:
S3: worsted fabric obtained by S2 is placed at 90 DEG C and is dried to drying in advance, then imports at 120 DEG C and bakes;Polyalcohol cool feeling agent is Red sugar alcohol.
The concentration of main component in nice and cool finishing agent are as follows: Waterborne Polyurethane Prepolymer 80g/L, 2 g/L of multicomponent organic acid, more First 18 g/L of alcohol cool feeling agent, 1 g/L of hydramine.
Organic multicomponent acid is citric acid;Hydramine is triethanolamine.
The pick-up that processing is padded in S2 is 70%.
Comparative example
Comparative example 1: comparative example 1 is based on embodiment 1 using the world He Te AF3600 disclosed in CN107523993A as crosslinking agent, The xylitol cool feeling agent of the world He Te AF3600 and 20 g/L in finishing fluid containing 20 g/L, the preliminary drying baking temperature of post-processing With embodiment 1.
Cool feeling test:
1, there is refrigerant sense compared to the pashm worsted plus material arranged without cool feeling, comparative example 1 and embodiment gained sample, due to Be cool feeling agent in the finishing fluid of embodiment 1 and comparative example 1 content it is larger, test arrange front and back the temperature difference be -2 DEG C;
2, after cleaning fabric 50 times, the coolness of fabric is still remained, and it is -1.4 DEG C that embodiment 1, which arranges the front and back temperature difference, and is compared The temperature difference is -0.6 DEG C before and after the arrangement of example 1;
3, compared to the pashm worsted plus material arranged without cool feeling, the fabric of comparative example 1 omits xanthochromia, yellow since baking temperature is low Change degree is smaller, and embodiment 1 is without xanthochromia.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (6)

1. a kind of production technology of nice and cool pashm worsted plus material, which comprises the following steps:
S1: configuring nice and cool finishing agent, and the Main Components for finishing agent of feeling nice and cool are Waterborne Polyurethane Prepolymer, multicomponent organic acid, polynary The agent of alcohol cool feeling, hydramine and water;
S2: pashm worsted plus material is placed in the nice and cool finishing agent of S1, pads processing, takes out the pashm worsted plus material with liquid;
S3: worsted fabric obtained by S2 is placed at 85~95 DEG C and is dried to drying in advance, then imports at 110~130 DEG C and bakes, is obtained nice and cool Pashm worsted plus material.
2. the production technology of nice and cool pashm worsted plus material according to claim 1, which is characterized in that the polyalcohol cool feeling Agent is xylitol and/or red sugar alcohol.
3. the production technology of nice and cool pashm worsted plus material according to claim 1, which is characterized in that main in nice and cool finishing agent Want the concentration of component are as follows: 50~130g/L of Waterborne Polyurethane Prepolymer, 0.5~4 g/L of multicomponent organic acid, polyalcohol cool feeling agent 5 ~30g/L, 0.1~2 g/L of hydramine.
4. the production technology of nice and cool pashm worsted plus material according to claim 3, which is characterized in that the organic multicomponent acid For the combination of one or more of citric acid, ethanedioic acid and tartaric acid.
5. the production technology of nice and cool pashm worsted plus material according to claim 1, which is characterized in that hydramine is selected from single second One or more of hydramine, diethanol amine, triethanolamine, diglycolamine, diisopropanolamine (DIPA), N methyldiethanol amine Combination.
6. the production technology of nice and cool pashm worsted plus material according to claim 1, which is characterized in that pad processing in S2 Pick-up is 60~70%.
CN201910815994.5A 2019-08-30 2019-08-30 A kind of production technology of nice and cool pashm worsted plus material Pending CN110485164A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113651925A (en) * 2021-09-24 2021-11-16 深圳市创想三帝科技有限公司 Cool-feeling resin, photosensitive resin composition, and preparation method and application thereof
CN114657778A (en) * 2022-05-18 2022-06-24 广东洪兴实业股份有限公司 Cooling agent composition containing plant sugar alcohol and application of cooling agent composition in preparation of cool pure cotton fabric

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CN102912501A (en) * 2012-10-04 2013-02-06 山东济宁如意毛纺织股份有限公司 Production method of cool and comfortable worsted fabric
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CN109137500A (en) * 2018-08-15 2019-01-04 宁波萌恒花边有限公司 A kind of mosquito proof has the processing method of the cloth of cool feeling

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CN1704523A (en) * 2004-05-27 2005-12-07 香港理工大学 Reactive aqueous polyurethane fabric finishing agent, its preparation method and application
CN101821445A (en) * 2007-10-15 2010-09-01 蓝宝迪有限公司 Method for treating wool
CN101994254A (en) * 2009-08-31 2011-03-30 香港纺织及成衣研发中心 Wool knitted fabrics shape-remembering finishing agent as well as preparation method and application thereof
CN102912501A (en) * 2012-10-04 2013-02-06 山东济宁如意毛纺织股份有限公司 Production method of cool and comfortable worsted fabric
CN104420224A (en) * 2013-09-11 2015-03-18 青岛三秀新科技复合面料有限公司 Functional finishing method of wool fabrics
CN109137500A (en) * 2018-08-15 2019-01-04 宁波萌恒花边有限公司 A kind of mosquito proof has the processing method of the cloth of cool feeling

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113651925A (en) * 2021-09-24 2021-11-16 深圳市创想三帝科技有限公司 Cool-feeling resin, photosensitive resin composition, and preparation method and application thereof
CN114657778A (en) * 2022-05-18 2022-06-24 广东洪兴实业股份有限公司 Cooling agent composition containing plant sugar alcohol and application of cooling agent composition in preparation of cool pure cotton fabric

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