CN110467959A - Lubricating anticorrosive oil - Google Patents
Lubricating anticorrosive oil Download PDFInfo
- Publication number
- CN110467959A CN110467959A CN201810453582.7A CN201810453582A CN110467959A CN 110467959 A CN110467959 A CN 110467959A CN 201810453582 A CN201810453582 A CN 201810453582A CN 110467959 A CN110467959 A CN 110467959A
- Authority
- CN
- China
- Prior art keywords
- oil
- lubricating
- dodecenylsuccinic acid
- monoethanolamine
- antirust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention relates to a kind of lubricating and antirust oil products for being applicable in mechanical workpieces rust prevention during manufacture in the materials machining process such as the machinery manufacturing industry such as auto industry, aerospace stainless steel, cast iron, aluminium alloy, copper alloy, sealing antirust up for safekeeping and lubricating processing technology.Its innovative point is existing anti-rust action, and has lubricating action, can meet the rust prevention during manufacture requirement of machining, and also can satisfy workpiece seals antirust requirement up for safekeeping；The lubrication process for machining of machinery industry workpiece manufacturing process can also be met simultaneously, it can also be used to nursing is lubricated in mechanical equipment operation.
Description
Skill field art
The present invention relates to machinery manufacturing industry stainless steel, cast iron, aluminium alloy, the copper such as a kind of applicable auto industry, aerospace
Between the process of the mechanical workpieces of the materials machining process such as alloy and seal the lubricating and antirust oil product of antirust up for safekeeping.
Background technique
According to statistics, because burn into corrodes reason, non-serviceable steel product weight is about as much as gold every year in the world
Belong to the 10%~20% of annual output.The maintenance that metal erosion can result in machinery equipment increases and replaces in advance, metal product
Corrosion then reduces the accuracy and sensitivity of equipment, influences the use of equipment, or even cause scrapping for equipment.Therefore, metal becomes rusty
Erosion problem but annoyings always manufacturing product processing, transport, storage etc..It is quite huge to corrode bring economic loss,
So metal rust preventing is considerable.Corrosion of metal problem spreads national economy all trades and professions, and corrosion of metal can make made of metal
The performance and commodity value of product are greatly damaged, or even can be caused significant trouble and be made equipment scrapping.According to statistics, every year by
Direct economic loss caused by corrosion of metal accounts for about the 2%~4% of total value of production in national economy, complete with China GDP in 2011
Year 47156400000000 yuans of calculatings China's whole years of GDP due to corrosion caused by loss be at least up to 943,100,000,000 yuan with
On, it endangers very surprising.For the economic loss for avoiding corrosion bring direct or indirect, people take various sides
Method, it is one of current most common means of defence that metal product is protected with antirust oil.In recent years, with China's intermetallic composite coating
The raising of technological level, to antirust oil product quality, higher requirements are also raised, and China's antirust oil is in development, specification hair
Exhibition, the update of kind and application etc. achieve greater advance.
Traditional anti-rust lubricating additive is mainly following material: petroleum sulfonate, dodecyl succinate, zinc naphthenate,
Dinonyl naphthalene sulfonate barium, sarcosine and its octadecylamine salt, oxidized petrolatum barium soap, aluminum stearate, lanolin and its soaps, department are originally
One 80, what domestic existing antirust generallyd use at present is compound prescription to reach the requirement of antirust.
The antirust oil product in China has formed scale, and annual output alreadys exceed 20,000 tons, China antirust oil market year demand
Amount between 10~120,000 tons, rust-inhibiting additive year market demand also have 30,000 tons or more, but in terms of product quality and kind
All it is not met by the demand of user.Main problem existing for domestic antirust product is the antirust oil during steel product saves
Effect against corrosion is undesirable.
Summary of the invention
It is an object of the present invention to for spray easy to apply, easy required between machinery industry workpiece process, easily brush, rust-proof life
Long antirust requirement, and the lubricating requirement during device action can be met simultaneously, a kind of lubricating anticorrosive oil is provided.
The technical solution provided by the present invention is:
Lubricating anticorrosive oil, it is composed of the following components by mass percentage: barium mahogany sulfonate 15-30%, calcium mahogany sulfonate 10-
15%, petroleum sodium sulfonate 10-20%, turkey red oil 5-10%, dodecenylsuccinic acid monoethanolamine 5-10%, polyvinyl alcohol
10000 5-10%, 62# machine oil 10-45%.
The preparation method of the dodecenylsuccinic acid monoethanolamine includes the following steps: in 250 liters of reaction kettles,
A certain amount of dodecenylsuccinic acid and suitable monoethanolamine (dodecenylsuccinic acid: monoethanolamine=1: 2 moles is first added
Than), stirring is started, is then gradually heated to 120 DEG C -160 DEG C, is reacted 3 to 6 hours at this temperature, product is natural at room temperature
Cooling is to get dodecenylsuccinic acid monoethanolamine.
The present invention also provides the preparation method of lubricating anticorrosive oil, include the following steps: to put into 62# machine oil in reaction kettle,
It is warming up to 40-60 DEG C, puts into calcium mahogany sulfonate, barium mahogany sulfonate, petroleum sodium sulfonate, turkey red oil, laurylene base fourth again in proportion
The raw materials such as diacid monoethanolamine, polyvinyl alcohol 10000, stirring are warming up between 70-95 DEG C, hybrid reaction 2-4 hours to oil product
Transparent, as described lubricating anticorrosive oil.
Compared with prior art, the present invention has following innovative point:
Lubricating anticorrosive oil provided by the invention, that is, having anti-rust action again has lubricious effect, and rustless property is excellent, can expire simultaneously
The mach rust prevention during manufacture of foot requires and the antirust of sealing up for safekeeping of finished work-piece requires, and also meets machining process lubrication processing work
Skill.
Properties of product and test method
Specific embodiment
Below with reference to each embodiment, the present invention will be described in detail so that advantages and features of the invention can be easier to by
It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.But it should explanation
That these embodiments are not limitation of the present invention, those of ordinary skill in the art according to these embodiments made by function,
Equivalent transformation or substitution in method or structure, within category protection scope of the present invention.
Embodiment 1:
Lubricating anticorrosive oil of the present invention, it is composed of the following components by mass percentage: barium mahogany sulfonate 18%, calcium mahogany sulfonate
12%, petroleum sodium sulfonate 10%, turkey red oil 5%, dodecenylsuccinic acid monoethanolamine 5%, polyvinyl alcohol 10,000 5%, 62#
Machine oil 45%.
The dodecenylsuccinic acid monoethanolamine preparation method, includes the following steps: in 250 liters of reaction kettles, first
A certain amount of dodecenylsuccinic acid and suitable monoethanolamine (dodecenylsuccinic acid: monoethanolamine=1: 2 molar ratios) is added,
Start stirring, be then gradually heated to 120 DEG C, at this temperature react 6 hours, product at room temperature natural cooling to get 12
Alkenyl succinic acid monoethanolamine.
The preparation work method of the lubricating anticorrosive oil includes the following steps: to put into 62# machine oil in reaction kettle, be warming up to
50 DEG C, put into calcium mahogany sulfonate, barium mahogany sulfonate, petroleum sodium sulfonate, turkey red oil, one ethyl alcohol of dodecenylsuccinic acid again in proportion
The raw materials such as amine, polyvinyl alcohol 10000, stirring are warming up to 80 DEG C, and hybrid reaction 3 hours transparent to oil product, as the lubrication
Antirust oil.
Properties of product and test method
| Project | Quality index | Measured value | Experimental method |
| Oil base appearance | Black or brownish black | Brownish black | Range estimation |
| PH value | 6.5-8.0 | 7.0 | Extensive test paper |
| Moisture | Trace | It is qualified | GB/T265 |
| Kinematic viscosity (40 DEG C) mm2/s | Actual measurement | 91 | GB/T265 |
| Flash-point (opening agar diffusion method) DEG C | Actual measurement | 230 | GB/T267-88 |
| Damp heat test (cast iron) h | Actual measurement | 350 | GB/5938-86 |
| Salt spray test (cast iron) h | Actual measurement | 54 | GB/5938-86 |
The process for machining of product Mr. Yu's diesel engine manufacturing enterprise, using this product antirust oil, process on spraying method
Between rust-proof life up to three months or more.
Embodiment 2:
Lubricating anticorrosive oil of the present invention, it is composed of the following components by mass percentage: barium mahogany sulfonate 22%, calcium mahogany sulfonate
17%, petroleum sodium sulfonate 12%, turkey red oil 7%, dodecenylsuccinic acid monoethanolamine 7%, polyvinyl alcohol 10,000 7%, 62#
Machine oil 27%.
The dodecenylsuccinic acid monoethanolamine preparation method, includes the following steps: in 250 liters of reaction kettles, first
A certain amount of dodecenylsuccinic acid and suitable monoethanolamine (dodecenylsuccinic acid: monoethanolamine=1: 2 molar ratios) is added,
Start stirring, be then gradually heated to 120 DEG C, at this temperature react 6 hours, product at room temperature natural cooling to get 12
Alkenyl succinic acid monoethanolamine.
The preparation work method of the lubricating anticorrosive oil includes the following steps: to put into 62# machine oil in reaction kettle, be warming up to
50 DEG C, put into calcium mahogany sulfonate, barium mahogany sulfonate, petroleum sodium sulfonate, turkey red oil, one ethyl alcohol of dodecenylsuccinic acid again in proportion
The raw materials such as amine, polyvinyl alcohol 10000, stirring are warming up to 80 DEG C, and hybrid reaction 3 hours transparent to oil product, as the lubrication
Antirust oil.
Properties of product and test method
| Project | Quality index | Measured value | Experimental method |
| Oil base appearance | Black or brownish black | Brownish black | Range estimation |
| PH value | 6.5-8.0 | 7.0 | Extensive test paper |
| Moisture | Trace | It is qualified | GB/T265 |
| Kinematic viscosity (40 DEG C) mm2/s | Actual measurement | 97 | GB/T265 |
| Flash-point (opening agar diffusion method) DEG C | Actual measurement | 230 | GB/T267-88 |
| Damp heat test (cast iron) h | Actual measurement | 520 | GB/5938-86 |
| Salt spray test (cast iron) h | Actual measurement | 58 | GB/5938-86 |
Product seals antirust up for safekeeping with the finished product of Mr. Yu's Die & Mold Manufacturing Companies, and rust-proof life was up to 2 years or more.
Claims (3)
1. lubricating anticorrosive oil, which is characterized in that it is made of by weight percentage following component: barium mahogany sulfonate 15-30%,
Calcium mahogany sulfonate 10-15%, petroleum sodium sulfonate 10-20%, turkey red oil 5-10%, dodecenylsuccinic acid monoethanolamine 5-
10%, 10000 5-10%, 62# machine oil 10-45% of polyvinyl alcohol.
2. lubricating anticorrosive oil according to claim 1, which is characterized in that the dodecenylsuccinic acid monoethanolamine
Preparation method includes the following steps: that a certain amount of dodecenylsuccinic acid and suitable second is first added in 250 liters of reaction kettles
Hydramine (dodecenylsuccinic acid: monoethanolamine=1: 2 molar ratios), starts stirring, is then gradually heated to 120 DEG C -160 DEG C,
It reacts 3 to 6 hours at this temperature, natural cooling is at room temperature to get dodecenylsuccinic acid monoethanolamine.
3. the preparation method of lubricating anticorrosive oil according to claim 1 to 2, which comprises the steps of:
62# machine oil is put into reaction kettle, 40-60 DEG C is warming up to, puts into calcium mahogany sulfonate, barium mahogany sulfonate, mahogany acid again in proportion
The raw materials such as sodium, turkey red oil, dodecenylsuccinic acid monoethanolamine, polyvinyl alcohol 10000, stirring are warming up between 70-95 DEG C, are mixed
Conjunction reaction 2-4 hours transparent to oil product, as the lubricating anticorrosive oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810453582.7A CN110467959A (en) | 2018-05-11 | 2018-05-11 | Lubricating anticorrosive oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810453582.7A CN110467959A (en) | 2018-05-11 | 2018-05-11 | Lubricating anticorrosive oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110467959A true CN110467959A (en) | 2019-11-19 |
Family
ID=68504731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810453582.7A Pending CN110467959A (en) | 2018-05-11 | 2018-05-11 | Lubricating anticorrosive oil |
Country Status (1)
| Country | Link |
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| CN (1) | CN110467959A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112442415A (en) * | 2020-11-11 | 2021-03-05 | 长沙艾森设备维护技术有限公司 | Island equipment protective agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110237471A1 (en) * | 2004-03-26 | 2011-09-29 | Council Of Scientific & Industrial Research | Process for metalworking fluid from heavy alkylate |
| CN102344848A (en) * | 2010-07-29 | 2012-02-08 | 中国石油化工股份有限公司 | Bearing anti-corrosive oil composition |
| CN103131521A (en) * | 2011-11-29 | 2013-06-05 | 潘加锦 | Composition of rust-preventative oil |
| CN107903994A (en) * | 2017-11-20 | 2018-04-13 | 湖南金裕环保科技有限公司 | Cold rolled sheet factory leveling precision, preparation method and its application method |
-
2018
- 2018-05-11 CN CN201810453582.7A patent/CN110467959A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110237471A1 (en) * | 2004-03-26 | 2011-09-29 | Council Of Scientific & Industrial Research | Process for metalworking fluid from heavy alkylate |
| CN102344848A (en) * | 2010-07-29 | 2012-02-08 | 中国石油化工股份有限公司 | Bearing anti-corrosive oil composition |
| CN103131521A (en) * | 2011-11-29 | 2013-06-05 | 潘加锦 | Composition of rust-preventative oil |
| CN107903994A (en) * | 2017-11-20 | 2018-04-13 | 湖南金裕环保科技有限公司 | Cold rolled sheet factory leveling precision, preparation method and its application method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112442415A (en) * | 2020-11-11 | 2021-03-05 | 长沙艾森设备维护技术有限公司 | Island equipment protective agent and preparation method thereof |
| CN112442415B (en) * | 2020-11-11 | 2022-08-30 | 长沙艾森设备维护技术有限公司 | Island equipment protective agent and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20191119 |
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| WD01 | Invention patent application deemed withdrawn after publication |