CN110466100A - A kind of preparation method of hollow rubber body - Google Patents

A kind of preparation method of hollow rubber body Download PDF

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Publication number
CN110466100A
CN110466100A CN201910762598.0A CN201910762598A CN110466100A CN 110466100 A CN110466100 A CN 110466100A CN 201910762598 A CN201910762598 A CN 201910762598A CN 110466100 A CN110466100 A CN 110466100A
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CN
China
Prior art keywords
rubber
hollow
preparation
hollow rubber
mould
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910762598.0A
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Chinese (zh)
Inventor
李磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yangzhou Qili New Energy Technology Co Ltd
Original Assignee
Yangzhou Qili New Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yangzhou Qili New Energy Technology Co Ltd filed Critical Yangzhou Qili New Energy Technology Co Ltd
Priority to CN201910762598.0A priority Critical patent/CN110466100A/en
Publication of CN110466100A publication Critical patent/CN110466100A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/002Component parts, details or accessories; Auxiliary operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/14Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/58Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/58Measuring, controlling or regulating
    • B29C2043/5816Measuring, controlling or regulating temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2022/00Hollow articles

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of preparation methods of hollow rubber body, including following preparation step: a kind of preparation method of hollow rubber body, including following preparation step: (1) carrying out ingredient according to rubber compounding;(2) rubber raw materials are subjected to mixing, mill, pre-formed sheet material;(3) prepare sulfurizing mould;(4) rubber mass is added by the charging aperture of upper and lower hollow mould, be molded in 150-160 DEG C 2 seconds it is preforming, be then opened, take out plate in hollow body, form the rubber bodies up and down of unvulcanized maturation;(5) it molds again, rubber bodies collide form pressure up and down, heat 20 seconds under the conditions of identical temperature;(6) sulfidization molding;(7) rubber rim charge is removed, it is body formed to obtain hollow rubber.Rubber molding vulcanization of the present invention is integrally formed, and processing step is simple, and greatly improves the intensity of rubber bodies.

Description

A kind of preparation method of hollow rubber body
Technical field
The present invention relates to rubber product technical field, specially a kind of preparation method of hollow rubber body.
Background technique
Rubber product is many kinds of, but production process is essentially identical.With general solid rubber --- raw rubber is original The basic craft course of the rubber product of material includes: 6 basic working procedures such as plasticate, be kneaded, rolling, extruding, forming, vulcanizing.It is logical Often, solid rubber product is molded by mold, is all relatively good processing, but the processing of hollow rubber bodies gets up and is not just It is easily worked obtained.The common preparation method of hollow rubber body mainly has: the inflatable molding practice, is blown at the liner type molding practice The glue formula practice, the filling plastic practice.In these methods, but it is most commonly seen with the liner type molding practice.
The conventional liner type molding practice generally includes following steps: rubber compounding ingredient;Rubber compounding is passed through into mixing; Mill, preforming rubber block;Design sulfurizing mould;Two halves rubber bodies are pressed and molded by mold, go extra leftover pieces, hollow rubber Colloid edging;Glue on rubber bodies edge;Two semi-closed of rubber bodies;Sulfidization molding takes out finished product hollow rubber body.Above-mentioned technique It needs two halfbody docking applying gluing knot, technique is cumbersome, and the product mechanical property prepared is affected by adhesive, by force Degree and performance are still to be improved.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of preparation method of hollow rubber body, this method rubber pattern Pressure vulcanization is integrally formed, and processing step is simple, and greatly improves the intensity of rubber bodies.
The technical solution of the application are as follows: a kind of preparation method of hollow rubber body, including following preparation step: (1) basis Rubber compounding carries out ingredient;(2) rubber raw materials are subjected to mixing, mill, pre-formed sheet material;(3) prepare sulfurizing mould;(4) lead to Cross upper and lower hollow mould charging aperture be added rubber mass, in 150-160 DEG C be molded 2 seconds it is preforming, be then opened, take out it is hollow Plate in body forms the rubber bodies up and down of unvulcanized maturation;(5) it molds again, rubber bodies collide form pressure up and down, in Xiang Tongwen It is heated 20 seconds under the conditions of degree;(6) sulfidization molding;(7) rubber rim charge is removed, it is body formed to obtain hollow rubber.
Preferably, sulfurizing mould includes plate in upper and lower hollow mould and hollow body.
Preferably, it is 140-160 DEG C that the process conditions of sulfidization molding, which are the temperature of vulcanization, in step (6), the pressure of vulcanization For 2.5-6MPa, the time of vulcanization is 0.5-3.5 hours.
The invention also discloses the hollow rubber body being prepared using the above method, which does not use additional glue Knot agent is bonded.
A kind of preparation method of hollow rubber body provided by the present application is molded vulcanization using rubber and is integrally formed, and reduces empty The processing step that heart body is formed increases the adhesive strength of two halves rubber bodies, greatly without using adhesive in product preparation engineering Production cost and production cycle are reduced greatly.After tested, tensile strength 15MPa is realized using the hollow rubber body of this method preparation Above, elongation rate of tensile failure (EB) 750% or more, shore hardness (HS) 50 ± 3A.
Detailed description of the invention
Fig. 1 is the mold structure diagram that the present invention uses;
In figure: the upper hollow mould of 1-, hollow mould under 2-, plate in 3- hollow body.
Specific embodiment
Present invention will be further explained below with reference to the attached drawings and examples.
Embodiment 1
A kind of preparation method of hollow rubber body, including following preparation step:
(1) ingredient is carried out according to rubber compounding, be formulated as 100 parts by weight of dience rubber, 40 parts by weight of carbon black, vulcanizing agent 1.5 parts by weight, the content of vulcanization accelerator are 0.5 parts by weight, 3 parts by weight of activator;
(2) rubber raw materials are subjected to mixing, mill, pre-formed sheet material;
(3) prepare sulfurizing mould, with reference to Fig. 1, sulfurizing mould includes in upper hollow mould 1, lower hollow mould 2 and hollow body Plate 3;
(4) rubber mass is added by the charging aperture of upper and lower hollow mould, be molded in 155 DEG C 2 seconds it is preforming, be then opened, Plate in hollow body is taken out, the rubber bodies up and down of unvulcanized maturation are formed;
(5) it molds again, rubber bodies collide form pressure up and down, heat 20 seconds under the conditions of identical temperature;
(6) sulfidization molding: curing temperature is 160 DEG C, sulfide stress 3MPa, and the time of vulcanization is 2.5 hours;
(7) rubber rim charge is removed, it is body formed to obtain hollow rubber.
Through detecting, hollow rubber body tensile strength 15.8MPa, elongation rate of tensile failure (EB) that the present embodiment is prepared 780% or more, shore hardness (HS) 51A.
Embodiment 2
A kind of preparation method of hollow rubber body, including following preparation step:
(1) ingredient is carried out according to rubber compounding, be formulated as EPDM85 parts by weight, 40 parts by weight of carbon black, 38 weight of paraffin oil Part prevents old 4 parts by weight, 3 parts by weight of promotor, 3 parts by weight of vulcanizing agent;
(2) rubber raw materials are subjected to mixing, mill, pre-formed sheet material;
(3) prepare sulfurizing mould, with reference to Fig. 1, sulfurizing mould includes in upper hollow mould 1, lower hollow mould 2 and hollow body Plate 3;
(4) rubber mass is added by the charging aperture of upper and lower hollow mould, be molded in 160 DEG C 2 seconds it is preforming, be then opened, Plate in hollow body is taken out, the rubber bodies up and down of unvulcanized maturation are formed;
(5) it molds again, rubber bodies collide form pressure up and down, heat 20 seconds under the conditions of identical temperature;
(6) sulfidization molding: curing temperature is 150 DEG C, sulfide stress 2.5MPa, and the time of vulcanization is 3 hours;
(7) rubber rim charge is removed, it is body formed to obtain hollow rubber.
Through detecting, hollow rubber body tensile strength 16.1MPa, elongation rate of tensile failure (EB) that the present embodiment is prepared 820% or more, shore hardness (HS) 50A.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (4)

1. a kind of preparation method of hollow rubber body, which is characterized in that including following preparation step: (1) according to rubber compounding into Row ingredient;(2) rubber raw materials are subjected to mixing, mill, pre-formed sheet material;(3) prepare sulfurizing mould;(4) by upper and lower hollow Rubber mass is added in the charging aperture of mold, be molded in 150-160 DEG C 2 seconds it is preforming, be then opened, take out plate in hollow body, formed The rubber bodies up and down of unvulcanized maturation;(5) it molds again, rubber bodies collide form pressure up and down, add under the conditions of identical temperature Heat 20 seconds;(6) sulfidization molding;(7) rubber rim charge is removed, it is body formed to obtain hollow rubber.
2. preparation method according to claim 1, which is characterized in that sulfurizing mould includes upper and lower hollow mould and hollow body Middle plate.
3. preparation method according to claim 1, it is characterised in that: the process conditions of sulfidization molding are sulphur in step (6) The temperature of change is 140-160 DEG C, and the pressure of vulcanization is 2.5-6MPa, and the time of vulcanization is 0.5-3.5 hours.
4. a kind of using the hollow rubber body being prepared such as any one of claim 1-3 preparation method, it is characterised in that: Adhesive is not used in the hollow rubber body, the tensile strength of hollow rubber body is 15MPa or more, elongation rate of tensile failure (EB) is 750% or more, shore hardness (HS) is 50 ± 3A.
CN201910762598.0A 2019-08-19 2019-08-19 A kind of preparation method of hollow rubber body Pending CN110466100A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910762598.0A CN110466100A (en) 2019-08-19 2019-08-19 A kind of preparation method of hollow rubber body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910762598.0A CN110466100A (en) 2019-08-19 2019-08-19 A kind of preparation method of hollow rubber body

Publications (1)

Publication Number Publication Date
CN110466100A true CN110466100A (en) 2019-11-19

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Family Applications (1)

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CN201910762598.0A Pending CN110466100A (en) 2019-08-19 2019-08-19 A kind of preparation method of hollow rubber body

Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10128760A (en) * 1996-10-29 1998-05-19 Molten Corp Production of elastic hollow member
CN1238173C (en) * 2000-01-11 2006-01-25 古尔拉顿高德里股份公司 Method for placing elestomer envelope around elongated body
CN108239306A (en) * 2017-12-11 2018-07-03 山东玲珑轮胎股份有限公司 Tire sidewall rubber composite material and preparation method thereof
CN109109352A (en) * 2018-08-22 2019-01-01 安徽世界村智能装备有限公司 A kind of rubber product disposably injects, hollow and sulfidization molding production method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10128760A (en) * 1996-10-29 1998-05-19 Molten Corp Production of elastic hollow member
CN1238173C (en) * 2000-01-11 2006-01-25 古尔拉顿高德里股份公司 Method for placing elestomer envelope around elongated body
CN108239306A (en) * 2017-12-11 2018-07-03 山东玲珑轮胎股份有限公司 Tire sidewall rubber composite material and preparation method thereof
CN109109352A (en) * 2018-08-22 2019-01-01 安徽世界村智能装备有限公司 A kind of rubber product disposably injects, hollow and sulfidization molding production method

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Application publication date: 20191119

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