CN1104610A - Chlorine dioxide producing bag and its production - Google Patents
Chlorine dioxide producing bag and its production Download PDFInfo
- Publication number
- CN1104610A CN1104610A CN 93121244 CN93121244A CN1104610A CN 1104610 A CN1104610 A CN 1104610A CN 93121244 CN93121244 CN 93121244 CN 93121244 A CN93121244 A CN 93121244A CN 1104610 A CN1104610 A CN 1104610A
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- CN
- China
- Prior art keywords
- bag
- textone
- dioxide peroxide
- stearic acid
- paraffin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The bag for generating chlorine dioxide used to disinfect drinking water, fruit and vegetables is made up through such steps as melting Chinese wax, or stearic acid, or bees wax, or paraffin wax, addition of sodium chlorite to make up microcapsules, mixing with dry tartaric acid or oxalic acid particles, and loading mixture in cloth bag. The ratio of wax or stearic acid to sodium chlorite to acid is 0.2-0.6:1:2. Putting the bag in water can generate ClO2.
Description
The invention belongs to a kind of product disinfection agent of chlorine dioxide of what goods field.
Dioxide peroxide is a kind of strong oxidizer, and sterilization effect is better than free chlorine, does not produce organic carcinogens such as haloform after the sterilization drinking-water substantially.Begun to be widely used in disinfection of drinking water.At present, producing disinfection agent of chlorine dioxide is many with acidifying Textone method, in view of Textone very easily reacts with solid acidifier, and emit dioxide peroxide immediately, so present employed disinfection agent of chlorine dioxide all separates packing with Textone and solid acidifier, for example Chinese patent CN89100512 is exactly the way that adopts the plastics bag packing, face the time spent, open plastics bag, with less water dissolved solids souring agent, pour Textone again into and make its reaction generate dioxide peroxide, this method operation is cumbersome, and actual use is inconvenient.
The objective of the invention is to overcome the deficiency of above-mentioned technology, provide a kind of the need that Textone and solid acidifier are separated product dioxide peroxide bag packing, easy to use.
The present invention realizes like this; by weight Chinese wax or stearic acid or beeswax or paraffin: Textone: tartrate or oxalic acid are 0.2～0.6: 1: 2; the Chinese wax of Textone and thawing or stearic acid or beeswax or paraffin are mixed; make the Textone microcapsule granule with 20 eye mesh screens; again the Textone microcapsule granule is mixed with exsiccant solid acidifier tartrate or oxalic acid particle, pack to make with non-woven bag then and produce the dioxide peroxide bag.Only need during use that product dioxide peroxide bag is directly put into water and can produce dioxide peroxide.
The present invention has the following advantages:
1, the present invention adopts Chinese wax or stearic acid or beeswax or paraffin and Textone to make microcapsule granule, thereby Textone can directly be mixed with exsiccant solid acidifier particle and is difficult for reacting.
2, the present invention is easy to use, only needs during use product dioxide peroxide bag is dropped in the water, and the little reaction environment that utilizes non-woven bag suction back to form just can produce dioxide peroxide.
This disinfection agent of chlorine dioxide can be used for drinking water, the sterilization of tableware, fruit, vegetables and other article.Get the 1000ml natural river water, artificial contamination intestinal bacteria 1.6 * 10
7Individual/L or f
2Phage 3.4 * 10
7Individual plaque unit/L.Put into the product dioxide peroxide bag that can produce dioxide peroxide 2.0mg/L, after 5 minutes, the intestinal bacteria of pollution and the killing rate of phage reach 99.999%.
Get the surface and coat intestinal bacteria 1.34 * 10
7Individual/L or f
2Phage 9.3 * 10
7The apple of individual plaque unit/L or rice bowl airing.Can produce 15,30, the product dioxide peroxide bag of 50mg dioxide peroxide, put into a premium on currency respectively, again apple to be sterilized or rice bowl are put into water and clean, all do not check out intestinal bacteria and f after 5 minutes in apple, rice bowl and the water
2Phage.
The present invention is further elaborated below by embodiment:
Example 1
Take by weighing Chinese wax or stearic acid or beeswax or paraffin 0.2 gram; Textone 1 gram; tartrate or oxalic acid 2 grams; Chinese wax or stearic acid or beeswax or paraffin: Textone: tartrate or oxalic acid are 0.2: 1: 2; with Chinese wax or stearic acid or beeswax or the mixing of paraffin thawing back adding Textone; make the Textone microcapsule granule with 20 purpose screen clothes, the Textone microcapsule granule is mixed with exsiccant tartrate or oxalic acid particle again, the non-woven bag of packing into is made and is produced the dioxide peroxide bag.During use, will produce the dioxide peroxide bag and put into water, just can produce dioxide peroxide, after 5 minutes, wherein use the tartaric dioxide peroxide 213.68mg that produces; Use oxalic acid, can produce dioxide peroxide 235.94mg.Time spent not, will produce the dioxide peroxide bag and put into waterproof composite film and seal.Produce of the acute storage experiment of dioxide peroxide bag, preserve dioxide peroxide loss 20～40% in 3 months through 37 ℃ of temperature, relative humidity 100%; And promptly do not lose 100% in 3 days with the sample of Chinese wax.
Example 2
Take by weighing Chinese wax or stearic acid or beeswax or paraffin 0.4 gram, Textone 1 gram, tartrate or oxalic acid 2 grams, Chinese wax or stearic acid or beeswax or paraffin: Textone: tartrate or oxalic acid are 0.4: 1: 2, the method for use-case 1 is made and is produced the dioxide peroxide bag.To produce the dioxide peroxide bag and put into water, just can produce dioxide peroxide, after 10 minutes, wherein use the tartaric dioxide peroxide 213.68mg that produces; Use oxalic acid, can produce dioxide peroxide 235.94mg.Produce of the acute storage experiment of dioxide peroxide bag, preserve dioxide peroxide loss 20～30% in 3 months through 37 ℃ of temperature, relative humidity 100%; And promptly do not lose 100% in 3 days with the sample of Chinese wax.
Example 3
Take by weighing Chinese wax or stearic acid or beeswax or paraffin 0.6 gram, Textone 1 gram, tartrate or oxalic acid 2 grams, Chinese wax or stearic acid or beeswax or paraffin: Textone: tartrate or oxalic acid are 0.6: 1: 2, the method for use-case 1 is made and is produced the dioxide peroxide bag.To produce the dioxide peroxide bag and put into water, just can produce dioxide peroxide, after 15 minutes, wherein use the tartaric dioxide peroxide 213.68mg that produces; Use oxalic acid, can produce dioxide peroxide 235.94mg.Produce of the acute storage experiment of dioxide peroxide bag, preserve dioxide peroxide loss 10～20% in 3 months through 37 ℃ of temperature, relative humidity 100%; And promptly do not lose 100% in 3 days with the sample of Chinese wax.
Claims (2)
1, a kind of product dioxide peroxide bag, comprise Textone, tartrate or oxalic acid, it is characterized in that comprising the Chinese wax or stearic acid or beeswax or the paraffin that are used to make the Textone microcapsule granule, by weight Chinese wax or stearic acid or beeswax or paraffin: Textone: tartrate or oxalic acid are 0.2～0.6: 1: 2, also comprise the non-woven bag that is used to accommodate said mixture.
2, a kind of production method of producing the dioxide peroxide bag; it is characterized in that the Chinese wax of Textone and thawing or stearic acid or beeswax or paraffin are mixed; make the Textone microcapsule granule with 20 eye mesh screens; again the Textone microcapsule granule is mixed with exsiccant tartrate or oxalic acid particle, pack with non-woven bag then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93121244 CN1104610A (en) | 1993-12-30 | 1993-12-30 | Chlorine dioxide producing bag and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93121244 CN1104610A (en) | 1993-12-30 | 1993-12-30 | Chlorine dioxide producing bag and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1104610A true CN1104610A (en) | 1995-07-05 |
Family
ID=4993634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93121244 Pending CN1104610A (en) | 1993-12-30 | 1993-12-30 | Chlorine dioxide producing bag and its production |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1104610A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999024356A1 (en) * | 1997-11-07 | 1999-05-20 | Engelhard Corporation | Method and device for the production of an aqueous solution containing chlorine dioxide |
| US6602466B2 (en) | 2000-02-18 | 2003-08-05 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US6607696B1 (en) | 2000-02-18 | 2003-08-19 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| WO2005019101A3 (en) * | 2003-08-04 | 2006-08-31 | Engelhard Corp | Chlorine dioxide releasing composite article |
| CN101803610A (en) * | 2010-03-22 | 2010-08-18 | 北京欧凯纳斯科技有限公司 | Self regulation and control type chlorine dioxide combination and application thereof in tobacco warehouse storage |
| US7922984B2 (en) | 2000-02-18 | 2011-04-12 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| CN101812803B (en) * | 2009-12-21 | 2013-02-27 | 北京欧凯纳斯科技有限公司 | Degradable non-woven fabric for disinfection and preparation method thereof |
| CN101716362B (en) * | 2009-12-08 | 2013-07-24 | 北京欧凯纳斯科技有限公司 | Bactericidal disinfectant material containing chlorine dioxide, and application thereof |
| CN104480792A (en) * | 2014-11-11 | 2015-04-01 | 东北林业大学 | Preparation method of chlorine dioxide slow-release fresh-keeping paper and obtained product |
| CN107136206A (en) * | 2017-03-22 | 2017-09-08 | 京博农化科技股份有限公司 | A kind of anti-corrosive fresh-keeping composition containing chlorine dioxide and preparation method thereof |
| CN108295642A (en) * | 2018-03-18 | 2018-07-20 | 国润生物科技（深圳）有限公司 | A kind of efficiently removal sulfur-bearing contamination gas build air purifying preparation composition |
| CN111066814A (en) * | 2019-11-23 | 2020-04-28 | 南阳市天华制药有限公司 | Novel slow-release gas disinfectant and preparation method thereof |
| CN111392831A (en) * | 2020-04-15 | 2020-07-10 | 广东爱锝医药技术研究院有限公司 | Method for purifying and disinfecting domestic water |
| US12036525B2 (en) | 2021-10-27 | 2024-07-16 | Selective Micro Technologies, Llc | Gas micro reactor utilizing membrane packaging |
-
1993
- 1993-12-30 CN CN 93121244 patent/CN1104610A/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999024356A1 (en) * | 1997-11-07 | 1999-05-20 | Engelhard Corporation | Method and device for the production of an aqueous solution containing chlorine dioxide |
| US7160484B2 (en) * | 1997-11-07 | 2007-01-09 | Engelhard Corporation | Method and device for the production of an aqueous solution containing chlorine dioxide |
| US7922984B2 (en) | 2000-02-18 | 2011-04-12 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US6602466B2 (en) | 2000-02-18 | 2003-08-05 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US6607696B1 (en) | 2000-02-18 | 2003-08-19 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US8137581B2 (en) | 2003-08-04 | 2012-03-20 | Basf Corporation | Chlorine dioxide releasing composite article |
| AU2004267046B2 (en) * | 2003-08-04 | 2010-03-25 | Engelhard Corporation | Chlorine dioxide releasing composite article |
| WO2005019101A3 (en) * | 2003-08-04 | 2006-08-31 | Engelhard Corp | Chlorine dioxide releasing composite article |
| CN101716362B (en) * | 2009-12-08 | 2013-07-24 | 北京欧凯纳斯科技有限公司 | Bactericidal disinfectant material containing chlorine dioxide, and application thereof |
| CN101812803B (en) * | 2009-12-21 | 2013-02-27 | 北京欧凯纳斯科技有限公司 | Degradable non-woven fabric for disinfection and preparation method thereof |
| CN101803610A (en) * | 2010-03-22 | 2010-08-18 | 北京欧凯纳斯科技有限公司 | Self regulation and control type chlorine dioxide combination and application thereof in tobacco warehouse storage |
| CN101803610B (en) * | 2010-03-22 | 2012-07-18 | 北京欧凯纳斯科技有限公司 | Self regulation and control type chlorine dioxide combination and application thereof in tobacco warehouse storage |
| CN104480792A (en) * | 2014-11-11 | 2015-04-01 | 东北林业大学 | Preparation method of chlorine dioxide slow-release fresh-keeping paper and obtained product |
| CN107136206A (en) * | 2017-03-22 | 2017-09-08 | 京博农化科技股份有限公司 | A kind of anti-corrosive fresh-keeping composition containing chlorine dioxide and preparation method thereof |
| CN108295642A (en) * | 2018-03-18 | 2018-07-20 | 国润生物科技（深圳）有限公司 | A kind of efficiently removal sulfur-bearing contamination gas build air purifying preparation composition |
| CN108295642B (en) * | 2018-03-18 | 2021-11-30 | 国润生物科技（深圳）有限公司 | Air purifying agent composition for efficiently removing sulfur-containing polluted gas |
| CN111066814A (en) * | 2019-11-23 | 2020-04-28 | 南阳市天华制药有限公司 | Novel slow-release gas disinfectant and preparation method thereof |
| CN111392831A (en) * | 2020-04-15 | 2020-07-10 | 广东爱锝医药技术研究院有限公司 | Method for purifying and disinfecting domestic water |
| US12036525B2 (en) | 2021-10-27 | 2024-07-16 | Selective Micro Technologies, Llc | Gas micro reactor utilizing membrane packaging |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |