CN110455012A - A kind of vapor compression types absorption heat pump - Google Patents

A kind of vapor compression types absorption heat pump Download PDF

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Publication number
CN110455012A
CN110455012A CN201910850822.1A CN201910850822A CN110455012A CN 110455012 A CN110455012 A CN 110455012A CN 201910850822 A CN201910850822 A CN 201910850822A CN 110455012 A CN110455012 A CN 110455012A
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CN
China
Prior art keywords
refrigerant
solution
circulating pump
heat
vapor compression
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Pending
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CN201910850822.1A
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Chinese (zh)
Inventor
孙健
霍成
马世财
戈志华
杜小泽
杨勇平
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North China Electric Power University
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North China Electric Power University
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Priority to CN201910850822.1A priority Critical patent/CN110455012A/en
Publication of CN110455012A publication Critical patent/CN110455012A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B25/00Machines, plants or systems, using a combination of modes of operation covered by two or more of the groups F25B1/00 - F25B23/00
    • F25B25/02Compression-sorption machines, plants, or systems

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Sorption Type Refrigeration Machines (AREA)

Abstract

The present invention proposes that a kind of heat of efficient recycling industrial exhaust heat is used for the heat pump unit of heat hot water, the inner exchanging of refrigerant is realized using two kinds of cycle fluids in inside, and the solution assimilation effect of absorber is promoted using compressor simultaneously, wherein compressor uses multistage blade mode, for existing heat pump techniques, the significantly promotion of heating temperature, more sufficient recycling industrial exhaust heat may be implemented, and then there is significant energy-conserving and emission-cutting technology advantage.

Description

A kind of vapor compression types absorption heat pump
Technical field
The invention belongs to technical field of energy utilization, are used to be promoted the heat of hot water temperature more particularly to recycling industrial exhaust heat Pump technology.
Background technique
It is widely present heat exchange process in field of energy utilization, the transmittance process of heat can be summarized as from high temperature fluid It transmits to cryogen or is transmitted from cryogen to high temperature fluid.According to Newton's second law, heat can it is spontaneous from High temp objects are transmitted to cryogenic object, can be realized using only ordinary heat exchanger;If necessary to which heat is transmitted to height from cryogenic object Warm object then needs to consume certain cost, generally requires to consume a certain amount of high-grade energy, such as the steaming of electric power, high-temperature Vapour or hot water etc. are needed using heat pump, induction apparatus etc..In the prior art, using heat pump techniques due to its higher effect Rate and reliability have obtained the approval and application in market.It is divided into absorption heat pump or compression heat pump by principle in heat pump techniques Mode, wherein absorption heat pump is divided into first-class absorption type heat pump and second-kind absorption-type heat pump, first-class absorption type heat pump again It needs to consume high-grade energy and the heat of cryogenic object is largely transferred to high temp objects, also referred to as increasing heating type heat pump, and second Class heat pump does not need consumption high-grade energy, and needs the cold source than cryogenic object lower temperature, extracts a small amount of of cryogenic object High temp objects are continued to heat up by heat, also referred to as warming heat pump.Second-kind absorption-type heat pump needs more low-grade cold water, into And the temperature difference between waste heat and cold water is utilized to complete internal circulation with heat hot water.But with regard to the second kind absorption type of existing report heat It for pump technology, is influenced by internal thermodynamic cycle and working medium physical property, the limited extent of hot water heating, and then is difficult to meet heat Water obtains the demand of " big temperature rise ".
In order to solve the technical problem, which proposes a kind of using refrigerant vapour exchange and refrigerant vapor compression Absorption type heat pump assembly, be obviously improved the outlet temperature of hot water side.
Summary of the invention
For the heat exchange purpose for recycling industrial exhaust heat to realize hot water side " big temperature rise ", the invention heat pump uses system The process of refrigerant vapour exchanger and refrigerant vapor compression blower.It include absorber 1, evaporator 2, refrigerant inside the heat pump Gasification section 3, generator 5, condenser 6, compressor 7, solution heat exchanger 8, solution heat exchanger 9, is followed at refrigerant condensation segment 4 Ring pump 10, circulating pump 11, circulating pump 12, circulating pump 13, circulating pump 14, hot water inlet 15, hot water outlet 16, waste heat entrance 17, Waste heat outlet 18, cold water inlet 19 and cooling water outlet 20.
A kind of vapor compression types absorption heat pump, hot water are heated in absorber 1, and waste heat fluid is successively by steaming Hair device 2, refrigerant vapor section 3 and generator 5 are cooled down step by step, and cold water successively passes through refrigerant condensation segment 4 and condenser 6 is added It is left after heat.
A kind of vapor compression types absorption heat pump, absorber 1 and solution heat exchanger 8, hot water inlet 15 and hot water Outlet 16 is connected;Evaporator 2 is connected with waste heat entrance 17, circulating pump 10 and refrigerant vapor section 3;Refrigerant vapor section 3 with it is molten Liquid heat exchanger 8, circulating pump 11, evaporator 2 are connected with generator 5;Refrigerant condensation segment 4 and solution heat exchanger 9, circulating pump 12, cold water inlet 19 is connected with condenser 6;Condenser 6 is connected with cooling water outlet 20, refrigerant condensation segment 4 and circulating pump 14;Hair Raw device 5 is connected with solution heat exchanger 9, circulating pump 13, refrigerant vapor section 3 and waste heat outlet 18.
A kind of vapor compression types absorption heat pump, while two kinds of cycle fluids pair are used, two kinds of working medium centerings absorb Agent is different, and refrigerant is identical.Medium A and medium B constitute solution C, and medium A and medium D constitute solution E, and wherein medium A is refrigeration Agent, medium B and medium C are absorbent, and solution C is circulated between absorber 1 and refrigerant vapor section 3, and solution E is circulated in refrigeration Agent condensation segment 4 and generator 5.
A kind of vapor compression types absorption heat pump, the solution C of high concentration absorbs in absorber 1 carrys out flash-pot 2 Refrigerant A steam after discharge heat hot water, and the solution C for becoming low concentration enters after solution heat exchanger 8 The solution C of refrigerant vapor section 3, low concentration is generated refrigerant A steam, system after the waste heat fluid heating from waste heat entrance 17 Refrigerant vapour A enters refrigerant condensation segment 4, while the solution C of low concentration becomes the solution C of high concentration and successively passes through circulating pump 11 With after solution heat exchanger 8 enter absorber 1;Refrigerant A steam enters high concentration after being condensed into liquid in refrigerant condensation segment 4 Solution E, the solution E being diluted, which sequentially enters, enters generator 5 after circulating pump 12 and solution heat exchanger 9, low concentration it is molten Liquid E boils after being heated by waste heat fluid to be concentrated, and the solution E of the high concentration of generation successively passes through circulating pump 13 and solution heat exchanger Enter refrigerant condensation segment 4 after 9, at the same the refrigerant vapour A that generates of the solution enter after condenser 6 cooled down by cold water after condense For liquid, the refrigerant A of liquid enters evaporator 2 using circulating pump 14, and realizes that spraying and sprinkling evaporation becomes by circulating pump 10 Refrigerant vapour.
A kind of vapor compression types absorption heat pump, absorber 1 and evaporator 2 share a cavity, and compressor 7 is installed In the cavity middle position, the refrigerant vapour that evaporator 2 generates boost in pressure after compressor 7, subsequently into absorber 1。
A kind of vapor compression types absorption heat pump, refrigerant vapor section 3 and refrigerant condensation segment 4 share a chamber Body, the steam that refrigerant vapor section 3 generates condense after entering refrigerant condensation segment 4.
A kind of vapor compression types absorption heat pump, condenser 6 and generator 5 share a cavity.
A kind of vapor compression types absorption heat pump, compressor 7 realize the effect of refrigerant vapour adherence pressure, in turn Enhance solution absorption process in absorber 1 and realizes that higher hot water outlet temperature, compressor 7 use motor driven.
A kind of vapor compression types absorption heat pump, hot water is from domestic heating pipeline or technique production hot water Or steam pipework, cold water production technology in cooling tower, underground water, rivers,lakes and seas or industry are discharged.
The invention heat pump uses refrigerant vapour exchange and refrigerant vapor compression, can be obviously improved hot water Increasing extent of temperature and waste heat fluid cooling extent, while promoting efficiency of heat exchanger.Refrigerant vapour is used first to exchange Mode improves the solution concentration of 1 entrance of absorber, and then enhances the effect of the absorption refrigerant vapour of solution;Secondly it is evaporating Compressor 7 is set among device 2 and absorber 1, and the pressure by promoting refrigerant vapour is obviously improved the solution in absorber and inhales It produces effects fruit.To sum up, the heat exchange amount of absorber 1 significantly rises, so the outlet temperature of hot water is promoted.
Detailed description of the invention
Fig. 1 is a kind of vapor compression types absorption heat pump flow chart.
Appended drawing reference: 1- absorber, 2- evaporator, 3- refrigerant vapor section, 4- refrigerant condensation segment, 5- generator, 6- Condenser, 7- compressor, 8- solution heat exchanger, 9- solution heat exchanger, 10- circulating pump, 11- circulating pump, 12- circulating pump, 13- circulating pump, 14- circulating pump, 15- hot water inlet, 16- hot water outlet, 17- waste heat entrance, the outlet of 18- waste heat, 19- cold water enter Mouthful, 20- cooling water outlet.
Specific embodiment
To keep the purposes, technical schemes and advantages of the invention implemented clearer, below in conjunction in the embodiment of the present invention Attached drawing 1, technical solution in the embodiment of the present invention is further described in more detail.In fig. 1, identical from beginning to end or Similar label indicates same or similar element or element with the same or similar functions.Described embodiment is this hair Bright a part of the embodiment, instead of all the embodiments.The embodiments described below with reference to the accompanying drawings are exemplary, it is intended to It is used to explain the present invention, and is not considered as limiting the invention.Based on the embodiments of the present invention, ordinary skill Personnel's every other embodiment obtained without creative efforts, shall fall within the protection scope of the present invention.
The heat pump uses lithium bromide water solution and calcium chloride water, and lithium bromide is absorbent, water in lithium bromide water solution For refrigerant;Calcium chloride is absorbent in calcium chloride water, and water is refrigerant.It include absorber 1, evaporator inside the heat pump 2, refrigerant vapor section 3, refrigerant condensation segment 4, generator 5, condenser 6, compressor 7, solution heat exchanger 8, solution heat are handed over Parallel operation 9, circulating pump 10, circulating pump 11, circulating pump 12, circulating pump 13, circulating pump 14, hot water inlet 15, hot water outlet 16, waste heat Entrance 17, waste heat outlet 18, cold water inlet 19 and cooling water outlet.
The heat pump is used to heat hot water and cold water by the heat of recovery waste heat, and wherein hot water carrys out autothermal operation system return pipe Road, cold water are discharged from cooling tower, remaining hot water from production technology.Wherein hot water is heated in absorber 1, waste heat fluid It is successively left after evaporator 2, refrigerant vapor section 3 and generator 5 are cooled down step by step, cold water successively passes through refrigerant condensation Section 4 and condenser 6 leave after being heated.
The heat pump various components inside connection type are as follows: absorber 1 and solution heat exchanger 8, hot water inlet 15 and hot water Outlet 16 is connected;Evaporator 2 is connected with waste heat entrance 17, circulating pump 10 and refrigerant vapor section 3;Refrigerant vapor section 3 with it is molten Liquid heat exchanger 8, circulating pump 11, evaporator 2 are connected with generator 5;Refrigerant condensation segment 4 and solution heat exchanger 9, circulating pump 12, cold water inlet 19 is connected with condenser 6;Condenser 6 is connected with cooling water outlet 20, refrigerant condensation segment 4 and circulating pump 14;Hair Raw device 5 is connected with solution heat exchanger 9, circulating pump 13, refrigerant vapor section 3 and waste heat outlet 18.
The working method of the heat pump are as follows: lithium bromide concentrated solution is released after absorbing the water vapour for carrying out flash-pot 2 in absorber 1 Thermal discharge heat hot water, and become lithium bromide weak solution and enter refrigerant vapor section 3, bromination after solution heat exchanger 8 Lithium weak solution is generated water vapour after the waste heat fluid heating from waste heat entrance 17, and water vapour enters refrigerant condensation segment 4, together When lithium bromide weak solution become lithium bromide concentrated solution successively after circulating pump 11 and solution heat exchanger 8 enter absorber 1;System Water vapour causes calcium chloride solution concentration therein to decline after being condensed into liquid in cryogen condensation segment 4, and the calcium chloride of generation is dilute molten Liquid enters generator 5 after sequentially entering circulating pump 12 and solution heat exchanger 9, and calcium chloride weak solution is boiled after being heated by waste heat fluid Concentration is risen, the calcium chloride concentrated solution of generation successively enters refrigerant condensation segment 4 after circulating pump 13 and solution heat exchanger 9, The water vapour that calcium chloride solution boiling simultaneously generates enters after condenser 6 cooled down by cold water after be condensed into liquid, the cryogen of liquid Water enters evaporator 2 using circulating pump 14, and realizes that spraying and sprinkling evaporation becomes water vapour by circulating pump 10.
A kind of vapor compression types absorption heat pump, absorber 1 and evaporator 2 share a cavity, wherein absorber 1 Positioned at top, evaporator 2 is located at lower part, and compressor 7 is installed on the cavity middle position, the refrigerant vapour that evaporator 2 generates The boost in pressure after compressor 7, subsequently into absorber 1.
A kind of vapor compression types absorption heat pump, refrigerant vapor section 3 and refrigerant condensation segment 4 share a chamber Body, the steam that refrigerant vapor section 3 generates, which enters after refrigerant condensation segment 4 to condense, to be continued cycling through.
A kind of vapor compression types absorption heat pump, condenser 6 and generator 5 share a cavity.
A kind of vapor compression types absorption heat pump, compressor 7 realizes the effect of water vapour adherence pressure, and then enhances Lithium bromide concentrated solution absorbs the higher hot water outlet temperature of water vapor process realization in absorber 1, and compressor 7 is driven using motor It is dynamic, and using the cissoid shape blade of three pieces.
Finally it is noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations.To the greatest extent Present invention has been described in detail with reference to the aforementioned embodiments for pipe, those skilled in the art should understand that: it is still It is possible to modify the technical solutions described in the foregoing embodiments, or part of technical characteristic is equally replaced It changes;And these are modified or replaceed, the essence for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution Mind and range.

Claims (5)

1. a kind of vapor compression types absorption heat pump, it is characterised in that: inside includes absorber (1), evaporator (2), refrigerant Gasification section (3), refrigerant condensation segment (4), generator (5), condenser (6), compressor (7), solution heat exchanger (8), solution Heat exchanger (9), circulating pump (10), circulating pump (11), circulating pump (12), circulating pump (13), circulating pump (14), hot water inlet (15), hot water outlet (16), waste heat entrance (17), waste heat outlet (18), cold water inlet (19) and cooling water outlet (20).
A kind of vapor compression types absorption heat pump, absorber (1) and solution heat exchanger (8), hot water inlet (15) and heat Water out (16) is connected;Evaporator (2) is connected with waste heat entrance (17), circulating pump (10) and refrigerant vapor section (3);Refrigerant Gasification section (3) is connected with solution heat exchanger (8), circulating pump (11), evaporator (2) and generator (5);Refrigerant condensation segment (4) it is connected with solution heat exchanger (9), circulating pump (12), cold water inlet (19) and condenser (6);Condenser (6) goes out with cold water Mouth (20), refrigerant condensation segment (4) are connected with circulating pump (14);Generator (5) and solution heat exchanger (9), circulating pump (13), Refrigerant vapor section (3) is connected with waste heat outlet (18).
A kind of vapor compression types absorption heat pump, hot water are heated in absorber (1), and waste heat fluid is successively through pervaporation Device (2), refrigerant vapor section (3) and generator (5) are cooled down step by step, and cold water successively passes through refrigerant condensation segment (4) and condensation Device (6) leaves after being heated.
A kind of vapor compression types absorption heat pump, while two kinds of cycle fluids pair are used, two kinds of working medium centering absorbents are not Together, refrigerant is identical.Medium A and medium B constitute solution C, and medium A and medium D constitute solution E, and wherein medium A is refrigerant, Medium B and medium C is absorbent, and solution C is circulated between absorber (1) and refrigerant vapor section (3), and solution E is circulated in system Cryogen condensation segment (4) and generator (5).
A kind of vapor compression types absorption heat pump, the solution C of high concentration absorbs in absorber (1) carrys out flash-pot (2) Refrigerant A steam after discharge heat hot water, and it is laggard by solution heat exchanger (8) to become the solution C of low concentration Enter refrigerant vapor section (3), the solution C of low concentration is generated refrigerant A after the waste heat fluid heating from waste heat entrance (17) Steam, refrigerant vapour A enter refrigerant condensation segment (4), while the solution C of low concentration becomes the solution C of high concentration and successively passes through It crosses circulating pump (11) and solution heat exchanger (8) and enters absorber (1) afterwards;Refrigerant A steam condenses in refrigerant condensation segment (4) For, by the solution E of high concentration, the solution E of the low concentration of generation sequentially enters circulating pump (12) and solution heat exchanger after liquid (9) enter generator (5) afterwards, the solution E of low concentration is boiled after the heating of waste heat fluid to be concentrated, the solution E of the high concentration of generation Successively enter refrigerant condensation segment (4) after circulating pump (13) and solution heat exchanger (9), while the refrigeration that the solution generates Agent steam A enters after condenser (6) cooled down by cold water after be condensed into liquid, the refrigerant A of liquid using circulating pump (14) into Enter evaporator (2), and realizes that spraying and sprinkling evaporation becomes refrigerant vapour by circulating pump (10).A kind of vapor compression types absorb Formula heat pump, absorber (1) and evaporator (2) share a cavity, and wherein absorber (1) is located at top, under evaporator (2) is located at Portion, compressor (7) are installed on the cavity middle position, the refrigerant vapour that evaporator (2) generates pressure after compressor (7) It is promoted, subsequently into absorber (1).
A kind of vapor compression types absorption heat pump, refrigerant vapor section (3) and refrigerant condensation segment (4) share a chamber Body, the steam that refrigerant vapor section (3) generates, which enters refrigerant condensation segment (4) and condenses afterwards, to be continued cycling through.
A kind of vapor compression types absorption heat pump, condenser (6) and generator (5) share a cavity.
2. a kind of vapor compression types absorption heat pump according to claim 1, it is characterised in that: in refrigerant vapor section (3) it realizes and is exchanged in the refrigerant of different cycle fluids pair with refrigerant condensation segment (4).
3. a kind of vapor compression types absorption heat pump according to claim 1, it is characterised in that: absorbent is nothing in working medium Machine salt, alcohols and freon.
4. a kind of vapor compression types absorption heat pump according to claim 1, it is characterised in that: compressor uses multiple-blade (2 or more) blower.
5. a kind of vapor compression types absorption heat pump according to claim 1, it is characterised in that: hot water is from civilian confession Heat pipeline or technique production hot water or steam pipework, cold water is in cooling tower, underground water, rivers,lakes and seas or industry Production technology discharge.
CN201910850822.1A 2019-09-10 2019-09-10 A kind of vapor compression types absorption heat pump Pending CN110455012A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108592444A (en) * 2018-02-06 2018-09-28 华北电力大学 A kind of electric heat pump and the compound heat-exchange unit of absorption heat pump

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Publication number Priority date Publication date Assignee Title
JPH0688652A (en) * 1992-09-07 1994-03-29 Tokyo Gas Co Ltd Low temperature heat source utilizing absorption heat pump
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CN101832681A (en) * 2009-03-13 2010-09-15 上海青浦工业园区热电有限公司 Lithium bromide refrigerating machine capable of recycling heat energy by utilizing heat pump
JP2010249356A (en) * 2009-04-13 2010-11-04 Daikin Ind Ltd Refrigerating device
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CN102788446A (en) * 2012-08-30 2012-11-21 华北电力大学(保定) Adsorption type auxiliary heat pump refrigerating system driven by condensation heat
CN105004095A (en) * 2015-07-03 2015-10-28 浙江大学 Compound heat pump system for co-production by adopting trans-critical circle and two-stage absorption type heat pump cycle
WO2017071106A1 (en) * 2015-10-26 2017-05-04 王超颖 Multi-purpose pump system
CN108088074A (en) * 2017-12-03 2018-05-29 天津大学 Novel oil smoke heat recovery system and method based on absorption heat pump
CN109654638A (en) * 2019-01-30 2019-04-19 华北电力大学 A kind of efficient industrial afterheat recovery varying duty water chiller-heater unit

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0688652A (en) * 1992-09-07 1994-03-29 Tokyo Gas Co Ltd Low temperature heat source utilizing absorption heat pump
DE102008013585A1 (en) * 2008-03-11 2009-09-17 Josef Lehnertz Single- or multi-stage absorption refrigerator/absorption heat pump, has drive control reaching pressure/temperature reference values of heat exchanger outlet, and control valve adjusting mass flow of heat exchanger circuit
CN101832681A (en) * 2009-03-13 2010-09-15 上海青浦工业园区热电有限公司 Lithium bromide refrigerating machine capable of recycling heat energy by utilizing heat pump
JP2010249356A (en) * 2009-04-13 2010-11-04 Daikin Ind Ltd Refrigerating device
CN102230686A (en) * 2011-06-12 2011-11-02 浙江理工大学 Lithium bromide absorption-compression type series boosting refrigeration/heating pump system
CN102788446A (en) * 2012-08-30 2012-11-21 华北电力大学(保定) Adsorption type auxiliary heat pump refrigerating system driven by condensation heat
CN105004095A (en) * 2015-07-03 2015-10-28 浙江大学 Compound heat pump system for co-production by adopting trans-critical circle and two-stage absorption type heat pump cycle
WO2017071106A1 (en) * 2015-10-26 2017-05-04 王超颖 Multi-purpose pump system
CN108088074A (en) * 2017-12-03 2018-05-29 天津大学 Novel oil smoke heat recovery system and method based on absorption heat pump
CN109654638A (en) * 2019-01-30 2019-04-19 华北电力大学 A kind of efficient industrial afterheat recovery varying duty water chiller-heater unit

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108592444A (en) * 2018-02-06 2018-09-28 华北电力大学 A kind of electric heat pump and the compound heat-exchange unit of absorption heat pump
CN108592444B (en) * 2018-02-06 2023-10-31 华北电力大学 Heat exchange unit combining electric heat pump and absorption heat pump

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