CN110452548A - A kind of novel thermoplastic elastomer composition - Google Patents
A kind of novel thermoplastic elastomer composition Download PDFInfo
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
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- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
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- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
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- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2453/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
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- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/10—Block- or graft-copolymers containing polysiloxane sequences
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Abstract
The invention discloses a kind of novel composition for thermoplastic elastomer, are made of the following components by mass fraction the composition:
Description
Technical field
The invention belongs to Macroscopic single crystal and modified fields, and in particular to a kind of novel composition for thermoplastic elastomer.
Background technique
Thermoplastic elastomer (TPE) abbreviation TPE/TPR, also known as artificial rubber or synthetic rubber, including phenylethylene (SBS, SIS,
SEBS, SEPS), olefines (TP0, TPV), diene class (TPB, TPI), polyvinyl chloride-base (TPVC, TCPE), urethane class (TPU),
Esters (TPEE), amides (TPAE), organic fluoride class (TPF), organic silicon and vinyl etc..There is tradition under its product room temperature
The excellent properties such as the high resiliency of cross-linking vulcanized rubber, ageing-resistant, plasticization molding again, can be used injection molding, extrusion, blow molding under high temperature
Equal processing methods production, leftover pieces crush after can directly secondary use, and while processing, does not have niff, is a kind of environmental protection
New material.Not only simplify process, but also reduce processing cost, therefore thermoplastic elastomer (TPE) TPE/TPR material has become substitution
The Latest Materials of traditional rubber, environmentally friendly, nontoxic, comfortable feel, exquisite appearance, make product have more intention.It is widely used in day
The fields such as articles, automobile parts, sealing strip, wire and cable, medical instrument, industrial castor.Wherein styrene block copolymer by
In haveing excellent performance and at low cost, use is most extensive.
The viscose glue of present adhesive hair rolling, binding dust rolling is made of the mode of gluing, there is part silica gel.Gluing
Mode to pollute environment serious, and can not reuse.Silica gel production may be reused, but silica gel is at high cost, production
Complex process falls behind.Pass through quadric injection mould with the resulting thermoplastic elastomer (TPE) adhesive layer of styrene block copolymer blending and modifying
Mode is directly injection-moulded on roller, and simple process may be reused, not only environmental protection but also reduce costs.But due to ordinary hot
Plastic resilient bulk viscosity is inadequate, can not reuse.
Summary of the invention
Environment-friendly type styrene block thermoplastic that is high the object of the present invention is to provide a kind of viscosity and can reusing
Property elastomer, the mechanical performance of resulting materials is excellent and processing fluidity is good, be very suitable to adhesive hair rolling etc. products.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical scheme:
A kind of novel composition for thermoplastic elastomer, is made of the following components by mass fraction the composition:
Preferably, styrene block copolymer is Styrene-Butadiene-Styrene Block Copolymer (SBS) or its hydrogenation
At least one of object (SEBS), styrene-isoprene-styrene block copolymer (SIS) or its hydride (SEPS).
Preferably, filling oil is at least one of linear saturation alkane oil, naphthenic oil.
Preferably, tackifying resin is at least one of natural resin, synthetic resin.Tackifying resin is for improving thermoplasticity
The viscosity of elastic composition increases its adhesive hair.
Preferably, natural resin includes rosin, rosin derivative, and the synthetic resin includes terpene resin, C5, C9 and
C5/C9 Petropols, dicyclopentadiene novolacs, coumarone-indene resin, styrene series resin and condensation resin.Rosin is preferred
Gum rosin, toll oil rosin, wood rosin；The preferred hydrogenated rosin of rosin derivative, disproportionated rosin, newtrex, esterified rosin, horse
To be acidified rosin；Preferred α-the terpene resin of terpene resin, β-terpene resin, terpene phenolic resin；Condensation resin optimizing alkyl
Phenolic resin, xylene resin.
Preferably, stabilizer is at least one of benzophenone, Hinered phenols, phosphorous acid esters.Stabilizer prevents
Composition for thermoplastic elastomer decomposition, aging.
Preferably, titanium dioxide is at least one of anatase titanium dioxide, rutile-type.Titanium dioxide increases thermoplastic elastomer (TPE)
The mechanical performance of composition.
Preferably, foaming agent is at least one of AC type chemical foaming agent, microballoon mechanical foaming agent.Foaming agent increases viscous
Property duration increase viscous rolling surface area since surface blister forms subtle pore, increase viscosity.
Preferably, PE wax powder is polyethylene wax powder of the partial size in 3-15um.PE wax powder can be rolled in styrene block copolymer
Particle surface sticks together after preventing particle from packing.
Preferably, organic silicon polyether copolymer be hydroxy silicon oil and both ends be hydroxyl polyethers copolymer；
Wherein, hydroxy silicon oil is the dimethyl polysiloxane and first that both ends are the dimethicone of hydroxyl, both ends are hydroxyl
The copolymer of base phenyl polysiloxane, both ends be hydroxyl dimethyl polysiloxane and diphenylpolysiloxane copolymer, two
End is the dimethyl polysiloxane of hydroxyl and at least one of the copolymer of methyl trifluoro propyl polysiloxanes；
Both ends are that the polyethers of hydroxyl is in Pluronic F-127 ether, polycyclic oxypropylene ether, oxireme ether and propylene oxide ether
At least one.
Hydroxy silicon oil molecular weight preferably 1000~40000mPas, both ends be hydroxyl pfpe molecule amount preferably 200~
2000mPa·s。
Organic silicon polyether copolymer can form diaphragm in styrene block copolymer particle surface, prevent to be bonded between particle
Together, make it easy to be granulated.
Due to the adoption of the above technical scheme, the invention has the following advantages:
The present invention is high by the resulting thermoplastic elastic bulk viscosity of styrene block copolymer blending and modifying, and can weigh
Multiple to use, viscosity nothing is decreased obviously after being used for multiple times.The thermoplastic elastomer (TPE) mechanical performance is excellent and processing fluidity is good.Thickening
Resin is used to improve the viscosity of composition for thermoplastic elastomer, increases its adhesive hair.Foaming agent increases the duration of viscosity, due to
Surface blister forms subtle pore, increases viscous rolling surface area, increases viscosity.PE wax powder can be rolled in styrene
Object particle surface sticks together after preventing particle from packing.Organic silicon polyether copolymer can be in styrene block copolymer particle table
Face forms diaphragm, prevents to be bonded together between particle, makes it easy to be granulated.
Specific embodiment
Below according to embodiment, the invention will be further described.
Block styrene copolymer in embodiment is styrene-ethylene-butylene-styrene block copolymer (SEBS),
Styrene ethylene-propylene-styrene type block copolymer (SEPS) at least one.Specific such as U.S. Ke Teng company
(KRATON) G1651, G1654, G1633, the 4055 of Kuraray, 4044, TaiWan, China rubber limited liability company
6151,6154,6159, the 2315,2314 of Italian eni company, the CH-6170 of Spain Dynasol.
Linear paraffin oil of the filling oil for saturation, at least one of naphthenic oil, such as sun-stone company, the U.S. (SUNPAR)
150, the 150SN of Shuan Long company, South Korea, the KN4010 etc. of Karamay, Xinjiang oil plant.
Tackifying resin is natural resin, synthetic resin, specially rosin (gum rosin, toll oil rosin, wood rosin), rosin
Derivative (hydrogenated rosin, disproportionated rosin, newtrex, esterified rosin, maleated rosin) and terpene resin (α-terpenes tree
Rouge, β-terpene resin, terpene phenolic resin), C5, C9 and C5/C9 Petropols, bicyclopentadiene (DCPD) resin, ancient horse
Grand-indene resin, styrene series resin] and condensation resin (alkyl phenolic resin, xylene resin) at least one, such as beauty
The Kristalex 5140 of state Yi Siman, Kristalex 1120, abitol-e hydroabietyl alcohol, Plastolyn 240,
Plastolyn 290, Piccotex 100, Piccotex 120 etc..
Stabilizer is benzophenone, phosphorous acid esters, Hinered phenols, hindered amines or the mixing formed by a certain percentage
Object.The Irganox 1010, Irganox 168, Irganox1076, UV531 of specific such as Ciba, UV327 etc..
Titanium dioxide is at least one of anatase titanium dioxide, rutile-type, such as the R960 of Du Pont, R706 etc..
PE wax powder is synthetic polyethylene waxes, and partial size is in 3um-15um, such as the A-C series wax of Honeywell.
Foaming agent is at least one of AC type chemical foaming agent, microballoon mechanical foaming agent, such as AC of the bright Sheng of Germany, day
Microballoon foaming agent of Ben Songben etc..
The self-control of organosilicon polyalkylene polyether copolymer.
Embodiment 1
The preparation (referred to as: SiOC-1) of organic silicon polyether copolymer: preparation method is first by the hydroxyl of molecular weight 1000
The terminal hydroxy group polyoxyethylene ether 1000g of sealing end polydimethyl siloxane fluid 100g and molecular weight 1000 is warming up to 100 at 120mmHg
DEG C, after removing moisture content 2h, it is cooled to room temperature, obtains organic silicon polyether copolymer.
The preparation of thermoplastic elastomer (TPE): by block styrene copolymer, filling oil, tackifying resin, titanium dioxide, stabilizer
Etc. components be uniformly mixed as following weight percent in high-speed mixer and mixing 30min, then 20min is mixed in low speed mixer,
Uniformly mixed material is added twin-screw extrude by metering feeding machine, and temperature is set in 180 DEG C -210 DEG C, engine speed setting
In 320rpm/min, feeding unit frequency is set in 28 hertz.Mixed raw material melts modeling by the shear at high temperature of double screw extruder
Change, mixing, underwater cutpellet and obtain, PE wax powder, foaming agent pass through in proportion weighing balance from pelleter discharge port be added, pelletizing
Organic silicon polyether copolymer is added in machine water tank.
Its material composition is as shown in table 1 by mass fraction:
Table 1: the mass percent of each ingredient in embodiment 1.
Embodiment 2
The preparation (referred to as: SiOC-2) of organic silicon polyether copolymer: preparation method is first by the two of molecular weight 40000
End is poly- for the terminal hydroxy group of the dimethyl polysiloxane of hydroxyl and the copolymer 400g of methyl phenyl silicone and molecular weight 200
Oxypropylene ether 200g is warming up to 100 DEG C at 120mmHg, after removing moisture content 2h, is cooled to room temperature and obtains organic silicon polyether copolymerization
Object.
The preparation process of thermoplastic elastomer (TPE) such as embodiment 1, material composition are as shown in table 2 by mass fraction:
Table 2: the mass percent of each ingredient in embodiment 2.
Embodiment 3
The preparation (referred to as: SiOC-3) of organic silicon polyether copolymer: preparation method is first by the both ends of molecular weight 5000
For the terminal hydroxy group polyoxy of the dimethyl polysiloxane of hydroxyl and the copolymer 5000g of diphenylpolysiloxane and molecular weight 2000
Ethylene and polyethenoxy ether 2000g are warming up to 100 DEG C at 120mmHg, after removing moisture content 2h, are cooled to room temperature and obtain organosilicon
Copolyether.
The preparation process of thermoplastic elastomer (TPE) such as embodiment 1, material composition are as shown in table 3 by mass fraction:
Table 3: the mass percent of each ingredient in embodiment 3.
Comparative example 1
The preparation process of thermoplastic elastomer (TPE) such as embodiment 1, material composition are as shown in table 4 by mass fraction:
Table 4: the mass percent of each ingredient in comparative example 1.
Comparative example 2
The preparation process of thermoplastic elastomer (TPE) such as embodiment 1, material composition are as shown in table 5 by mass fraction:
Table 5: the mass percent of each ingredient in comparative example 2.
Comparative example 3
The preparation process of thermoplastic elastomer (TPE) such as embodiment 1, material composition are as shown in table 6 by mass fraction:
Table 6: the mass percent of each ingredient in comparative example 3.
Test the mechanical performance and adhesive hair of thermoplastic elastomer (TPE) obtained in above-described embodiment 1 to 3 and comparative example 1 to 3
Property, the results are shown in Table 7.
Table 7: the mechanical performance and adhesive hair of thermoplastic elastomer (TPE).
It can be concluded that according to table 7 and embodiment 1-3 compares with comparative example 1, thickening is not added in thermoplastic elastomer (TPE)
It is very poor that resin will lead to adhesive hair.Embodiment 1-3 is compared with comparative example 2, it is poly- that organosilicon is not added in the water tank of underwater pelletizer
Ether copolymer and PE wax is not added in pelleter exit, raw material can not be granulated.Embodiment 1-3 is compared with comparative example 3, it is former
There is no foaming agent in material, thermoplastic elastomer (TPE) reuse number is few, and viscosity decline is fast.It is a high proportion of due to adding in blend
Tackifying resin, styrene block copolymer particle are easy to stick together, after adding organosilicon copolyether in water tank, have
Machine silicon copolyether can form diaphragm in styrene block copolymer particle surface, prevent to be bonded together between particle, cut
PE wax powder is added in grain machine exit, and PE wax powder can be rolled in styrene block copolymer particle surface, prevent styrene
It is sticked together after object particle packaging.Be added a small amount of foaming agent will increase viscosity duration, due to surface blister formed it is subtle
Pore increases viscous rolling surface area, increases viscosity.
The above is only specific embodiments of the present invention, but technical characteristic of the invention is not limited thereto.It is any with this hair
Based on bright, to solve essentially identical technical problem, essentially identical technical effect is realized, made ground simple change, etc.
With replacement or modification etc., all it is covered by among protection scope of the present invention.
Claims (10)
1. a kind of novel composition for thermoplastic elastomer, which is characterized in that have following components group by mass fraction the composition
At:
2. the novel composition for thermoplastic elastomer of one kind according to claim 1, it is characterised in that: the styrene is embedding
Section copolymer is Styrene-Butadiene-Styrene Block Copolymer or its hydride, styrene-isoprene-phenylethene block
At least one of copolymer or its hydride.
3. the novel composition for thermoplastic elastomer of one kind according to claim 1, it is characterised in that: the filling oil is
At least one of linear saturation alkane oil, naphthenic oil.
4. the novel composition for thermoplastic elastomer of one kind according to claim 1, it is characterised in that: the tackifying resin
For at least one of natural resin, synthetic resin.
5. the novel composition for thermoplastic elastomer of one kind according to claim 4, it is characterised in that: the natural resin
Including rosin, rosin derivative, the synthetic resin includes terpene resin, C5, C9 and C5/C9 Petropols, bicyclopentadiene
Resin, coumarone-indene resin, styrene series resin and condensation resin.
6. the novel composition for thermoplastic elastomer of one kind according to claim 1, it is characterised in that: the stabilizer is
At least one of benzophenone, Hinered phenols, phosphorous acid esters.
7. the novel composition for thermoplastic elastomer of one kind according to claim 1, it is characterised in that: the titanium dioxide
For at least one of anatase titanium dioxide, rutile-type.
8. the novel composition for thermoplastic elastomer of one kind according to claim 1, it is characterised in that: the foaming agent is
At least one of AC type chemical foaming agent, sphere physical foaming agent.
9. the novel composition for thermoplastic elastomer of one kind according to claim 1, it is characterised in that: the PE wax powder is
Polyethylene wax powder of the partial size in 3-15um.
10. the novel composition for thermoplastic elastomer of one kind according to claim 1, it is characterised in that: the organosilicon
Copolyether be hydroxy silicon oil and both ends be hydroxyl polyethers copolymer；
Wherein, the hydroxy silicon oil is the dimethyl polysiloxane and first that both ends are the dimethicone of hydroxyl, both ends are hydroxyl
The copolymer of base phenyl polysiloxane, both ends be hydroxyl dimethyl polysiloxane and diphenylpolysiloxane copolymer, two
End is the dimethyl polysiloxane of hydroxyl and at least one of the copolymer of methyl trifluoro propyl polysiloxanes；
The both ends are that the polyethers of hydroxyl is in Pluronic F-127 ether, polycyclic oxypropylene ether, oxireme ether and propylene oxide ether
At least one.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110669278A (en) * | 2019-11-17 | 2020-01-10 | 斯莱达医疗用品（惠州）有限公司 | Pipe for effectively reducing condensate water of breathing pipeline |
| CN110951220A (en) * | 2019-11-19 | 2020-04-03 | 宁波市青湖弹性体科技有限公司 | High-performance thermoplastic elastomer capable of injection-molding and bonding polyformaldehyde and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183897A (en) * | 2013-04-11 | 2013-07-03 | 无锡市万力粘合材料有限公司 | Coating film combination for hot melt adhesive and preparation method thereof |
| CN103554819A (en) * | 2013-10-28 | 2014-02-05 | 深圳市科聚新材料有限公司 | Thermoplastic elastomer (TPE) alloy for nylon adhesive encapsulation and preparation method thereof |
| CN104817754A (en) * | 2015-03-27 | 2015-08-05 | 常州大学 | High hardness, high elasticity and wear resistance composite foam material and preparation method thereof |
| CN106046735A (en) * | 2015-04-10 | 2016-10-26 | 中国石油化工股份有限公司 | Polycarbonate resin composition with high haze and high light transmittance, and preparation method thereof |
| CN107459954A (en) * | 2016-06-06 | 2017-12-12 | 欧瑞喜(福州)塑胶科技有限公司 | A kind of thermosol adhesive rich in thermoplastic elastomer (TPE) |
| CN109504104A (en) * | 2018-11-02 | 2019-03-22 | 浙江耀隆塑业有限公司 | A kind of thermoplastic elastomer blending material of high adherence and preparation method thereof |
| CN109796731A (en) * | 2019-01-28 | 2019-05-24 | 盛嘉伦橡塑(深圳）股份有限公司 | Thermoplastic Elastic Material Used and preparation method thereof |
-
2019
- 2019-07-22 CN CN201910659030.6A patent/CN110452548A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183897A (en) * | 2013-04-11 | 2013-07-03 | 无锡市万力粘合材料有限公司 | Coating film combination for hot melt adhesive and preparation method thereof |
| CN103554819A (en) * | 2013-10-28 | 2014-02-05 | 深圳市科聚新材料有限公司 | Thermoplastic elastomer (TPE) alloy for nylon adhesive encapsulation and preparation method thereof |
| CN104817754A (en) * | 2015-03-27 | 2015-08-05 | 常州大学 | High hardness, high elasticity and wear resistance composite foam material and preparation method thereof |
| CN106046735A (en) * | 2015-04-10 | 2016-10-26 | 中国石油化工股份有限公司 | Polycarbonate resin composition with high haze and high light transmittance, and preparation method thereof |
| CN107459954A (en) * | 2016-06-06 | 2017-12-12 | 欧瑞喜(福州)塑胶科技有限公司 | A kind of thermosol adhesive rich in thermoplastic elastomer (TPE) |
| CN109504104A (en) * | 2018-11-02 | 2019-03-22 | 浙江耀隆塑业有限公司 | A kind of thermoplastic elastomer blending material of high adherence and preparation method thereof |
| CN109796731A (en) * | 2019-01-28 | 2019-05-24 | 盛嘉伦橡塑(深圳）股份有限公司 | Thermoplastic Elastic Material Used and preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 孔萍等主编: "《塑料材料》", 31 July 2017, 广东高等教育出版社 * |
| 朱洪法主编: "《精细化工常用原材料手册》", 31 December 2003, 金盾出版社 * |
| 汪菊英等编著: "《塑料助剂品种及选用速查手册》", 31 January 2017, 文化发展出版社 * |
| 王霞等编著: "《现代建筑涂料-树脂合成与配方设计》", 30 September 2005, 上海交通大学出版社 * |
| 白晓艳著: "《PVC木塑复合材料》", 30 April 2014, 北京交通大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110669278A (en) * | 2019-11-17 | 2020-01-10 | 斯莱达医疗用品（惠州）有限公司 | Pipe for effectively reducing condensate water of breathing pipeline |
| CN110669278B (en) * | 2019-11-17 | 2022-04-26 | 斯莱达医疗用品（惠州）有限公司 | Pipe for effectively reducing condensate water of breathing pipeline |
| CN110951220A (en) * | 2019-11-19 | 2020-04-03 | 宁波市青湖弹性体科技有限公司 | High-performance thermoplastic elastomer capable of injection-molding and bonding polyformaldehyde and preparation method thereof |
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Application publication date: 20191115 |