CN110451919A - A kind of glass magnesium floor - Google Patents

A kind of glass magnesium floor Download PDF

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Publication number
CN110451919A
CN110451919A CN201910845866.5A CN201910845866A CN110451919A CN 110451919 A CN110451919 A CN 110451919A CN 201910845866 A CN201910845866 A CN 201910845866A CN 110451919 A CN110451919 A CN 110451919A
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China
Prior art keywords
parts
glass
slurry
magnesium chloride
floor
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CN201910845866.5A
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Chinese (zh)
Inventor
罗李华
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Zhejiang Jie On Jiexin Material Co Ltd
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Zhejiang Jie On Jiexin Material Co Ltd
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Priority to CN201910845866.5A priority Critical patent/CN110451919A/en
Publication of CN110451919A publication Critical patent/CN110451919A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00—Producing shaped prefabricated articles from the material
    • B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
    • B28B1/525—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement containing organic fibres, e.g. wood fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B23/00—Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects
    • B28B23/02—Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects wherein the elements are reinforcing members
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The present invention relates to a kind of glass magnesium floors, the glass magnesium floor, it is grouped as by following substance and weight: 50-80 parts of magnesia, 5-10 parts of glass fiber reticular cloth, 0.1-3 parts of silicon ash, 10-20 parts of magnesium chloride, 30-40 parts of wood powder, 6-8 parts of modifying agent, 0.1-3 parts of pigment, 30-50 parts of water.Glass magnesium floor of the invention has the characteristics of moisture-proof, rigidity is strong, comfortable foot feeling.

Description

A kind of glass magnesium floor
Technical field
The invention belongs to glass magnesium technical field of floor.
Background technique
Floor is a kind of floor decorative material.The classification on floor has very much, has by textural classification: natural landscape Plate, solid wooden floor board, reinforced composite wooden floor, solid wooden compound floor, bamboo-wood floor, cork flooring etc..
Wood plastic composite (Wood-Plastic Composites, WPC) is that domestic and international one kind being surging forward in recent years is new Type composite material, refers to using polyethylene, polypropylene and polyvinyl chloride etc., instead of common resin adhesive, and more than 50% or more The useless plant fiber such as wood powder, rice husk, stalk be mixed into new wood materials, then add through plastics such as extruding, molding, injection mouldings Work technique, the plate or profile produced.It is mainly used for the industries such as building materials, furniture, logistics packaging.Plastics and wooden powder are pressed Plate through hot extrusion molding after certain proportion mixing, referred to as extruding wood-plastic composite panel.The floor WPC has formaldehydeless and anti- Aqueous energy, but it in higher temperature there is very strong shrinking percentage to influence its application.
The floor SPC is the floor WPC a new generation floor, the certain proportion mainly combined by calcium powder, PVC stabilizer It is mixed to form compound shakedown material.The floor SPC is due to the calcium carbonate of its high-content, and making it, cost is relatively low, while relative to WPC Plate has very small shrinking percentage, is 100% Environmental protection floor for being free of formaldehyde, is real zero formaldehyde floor.But due to high Calcium carbonate content is so that its density is larger, and the comfort of foot is poor, and noise is larger when walking.Develop it is a kind of new have it is high-strength The floor for spending low-density, is conducive to meet people to floor comfort level increasingly higher demands.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of technical solutions: a kind of glass magnesium floor, glass magnesium floor It is grouped as by following substance and weight: 50-80 parts of magnesia, 5-10 parts of glass fiber reticular cloth, 0.1-3 parts of silicon ash, magnesium chloride 10-20 Part, 30-40 parts of wood powder, 6-8 parts of modifying agent, 0.1-3 parts of pigment, 30-50 parts of water.
As a preferred technical solution of the present invention, the glass fiber reticular cloth includes poly- selected from the glass fiber reticular cloth One or more of ester fiber grid cloth, crystalline glass fibre grid cloth and fluororesin grid cloth.
As a preferred technical solution of the present invention, the glass fiber reticular cloth preferably mainly becomes MgO-Al2O3-SiO2 Grid cloth。
As a preferred technical solution of the present invention, the weight part ratio of the magnesia and magnesium chloride is 8:1-4.
As a preferred technical solution of the present invention, it is to be process according to wood that the wood powder, which is selected from timber, the wood powder Partial size be 100-300 mesh.
As a preferred technical solution of the present invention, the modifying agent is polyisobutene and ferric sulfate by weight 10:1 Mixture, the weight average molecular weight of the polyisobutene is 80000-150000.
As a preferred technical solution of the present invention, the average grain diameter of the silicon ash is 0.1-0.3 μm.
As a preferred technical solution of the present invention, 80% < MgO of magnesia mass percent < 90%, surplus is miscellaneous Matter.
A kind of method preparing glass magnesium floor of the invention, prepares in accordance with the following steps:
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: by magnesia, pigment is uniformly mixed stirring 5-10 minutes, then will prepare magnesium chloride solution addition, It is uniformly mixed within stirring 8-20 minutes；Stirring 2-5 minutes is added in modifying agent；
3) it forms: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, glass fiber net is added Ge Bu continues the slurry for spreading 1/4 depth of mold on glass fiber reticular cloth, remaining slurry is layered on surface and is rolled with roller Molding, glass fiber reticular cloth are uniformly arranged on inside slurry, and silicon ash is sprayed at the top of every layer of slurry, keep 20-30 DEG C of temperature placement 24 hours, form half-finished product plate；
4) drying setting: half-finished product plate being dried, finally half-finished product plate cutting edge shapes, and forms glass magnesium floor.
As a preferred technical solution of the present invention, step 4) drying setting in the preparation process of glass magnesium floor, half The drying temperature of finished product is 35-50 DEG C.
Glass magnesium floor of the invention has the characteristics of moisture-proof, rigidity is strong, comfortable foot feeling.Used in inventive formulation wood powder for Filler, wood powder are the waste materials in timber processing, and the present invention efficiently uses waste material, can largely reduce production cost. It is MgO-Al present invention employs primary structure2O3-SiO2Glass fiber reticular cloth, be effectively increased the intensity on glass magnesium floor, together When present invention adds high polymer make glass magnesium floor as floor in use, will not be because of high rigidity and shoes issue ear-piercing sound Sound, high polymer are arbitrarily migrated to floor surface in ferric sulfate and under the action of other inorganic matters, thus play prevent it is ear-piercing The effect of sound.
Glass magnesium floor of the invention has high waterproof and meets the indeformable effect of water, it may be possible to because the present invention is preparing glass The silicon ash that average grain diameter is 0.1-0.3 μm is sprayed on surface when magnesium floor, the silicon ash of small particle can fill glass magnesium floor surface On smaller gap, prevent vapor from having haved the function that moisture-proof through glass magnesium floor.The present invention by control magnesia with The proportion of magnesium chloride enables magnesium chloride to react completely and does not influence the effect on glass magnesium floor, to solve glass magnesium floor due to mistake Anti- halogen phenomenon caused by the magnesium chloride of amount.
Specific embodiment
Unless otherwise defined, all technologies used herein and scientific term have and the common skill of fields of the present invention The normally understood identical meaning of art personnel.When there is a conflict, the definition in this specification shall prevail.
A kind of glass magnesium floor, is grouped as by following substance and weight: 50-80 parts of magnesia, 5-10 parts of glass fiber reticular cloth, silicon 0.1-3 parts grey, 10-20 parts of magnesium chloride, 30-40 parts of wood powder, 6-8 parts of modifying agent, 0.1-3 parts of pigment, 30-50 parts of water.
As a kind of preferred embodiment of the present invention, the glass fiber reticular cloth includes poly- selected from the glass fiber reticular cloth One or more of ester fiber, crystalline glass fibre and fluororesin.
As a kind of preferred embodiment of the present invention, as a preferred technical solution of the present invention, the glass fiber net Ge Bu is crystalline glass fibre, and the crystalline glass fibre main component is MgO-Al2O3-SiO2。
As a kind of preferred embodiment of the present invention, the weight part ratio of the magnesia and magnesium chloride is 8:1-4.
As a kind of preferred embodiment of the present invention, it is to be process according to wood that the wood powder, which is selected from timber, the wood powder Partial size be 100-300 mesh.
As a kind of preferred embodiment of the present invention, which is characterized in that the modifying agent is polyisobutene and ferric sulfate By weight the mixture of 10:1, the weight average molecular weight of the polyisobutene is 80000-150000.
As a kind of preferred embodiment of the present invention, which is characterized in that the average grain diameter of the silicon ash is 0.1-0.3 μ m。
As a kind of preferred embodiment of the present invention, which is characterized in that 80% < MgO of magnesia mass percent < 90%, surplus is impurity.
As a kind of preferred embodiment of the present invention, prepare in accordance with the following steps:
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment are uniformly mixed stirring 5-10 minutes, then will prepare magnesium chloride solution addition, It is uniformly mixed within stirring 8-20 minutes；Stirring 2-5 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 20-30 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: half-finished product plate being dried, finally half-finished product plate cutting edge shapes, and forms glass magnesium floor.
As a kind of preferred embodiment of the present invention, step 4) drying shapes in the preparation process of glass magnesium floor, and half The drying temperature of finished product is 35-50 DEG C.
The modifying agent of the following embodiments of the present invention is polyisobutene and ferric sulfate, and polyisobutene and sulfuric acid are by weight 10: 1, the source of polyisobutene:
45.00g low molecular weight polyisobutene, 0.20g acrylic acid, 0.05g azo-bis-iso-dimethyl are added in autoclave, Autoclave lid is tightened in the constant temperature oven for be put into 120 DEG C and reacted 24 hours, then cooled down, opened autoclave, product is used Acetone washing three times, obtains the polyisobutene of weight average molecular weight 130000 in dry 12 hours in 60 DEG C of vacuum drying ovens.
The measurement of glass magnesium floor waterproofness, the present invention in glass magnesium floor waterproof performance measurement be divided into two:
1. the waterproof on glass magnesium floor immerses ability, wherein waterproof immerses ability and is divided into A grades (glass magnesium floor surface is paved with water 72 hours Anhydrous immersion), B grades (glass magnesium floor surface is paved with water micro immersion in 72 hours), C grades (glass magnesium floor surface is paved with water 72 hours A small amount of water immerses), D grades (glass magnesium floor surface is paved with water 72 hours a large amount of water and immerses) E grades (it is small that glass magnesium floor surface is paved with water 12 Shi great Liang water immerses)；
Method therefor is conventional method unless otherwise instructed in following embodiments and experiment.
Embodiment 1
55 parts of magnesia, 5 parts of glass fiber reticular cloth, 0.1 part of silicon ash, 15 parts of magnesium chloride, 30 parts of wood powder, 6 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 40oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.3, intensity 35MPa.
Embodiment 2
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 15 parts of magnesium chloride, 30 parts of wood powder, 6 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 40oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.3, intensity 40MPa.
Embodiment 3
55 parts of magnesia, 10 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 15 parts of magnesium chloride, 30 parts of wood powder, 6 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 40oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.3, intensity 40MPa.
Embodiment 4
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 15 parts of magnesium chloride, 33 parts of wood powder, 6 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 40oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.2, intensity 42MPa.
Embodiment 5
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 15 parts of magnesium chloride, 38 parts of wood powder, 6 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 40oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.1, intensity 42MPa.
Embodiment 6
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 10 parts of magnesium chloride, 30 parts of wood powder, 6 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 40oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.3, intensity 38MPa.
Embodiment 7
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 20 parts of magnesium chloride, 30 parts of wood powder, 6 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 40oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is B grades, density 1.4, intensity 30MPa.
Embodiment 8
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 30 parts of magnesium chloride, 30 parts of wood powder, 6 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 80oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is B grades, density 1.5, intensity 35MPa.
Embodiment 9
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 15 parts of magnesium chloride, 30 parts of wood powder, 8 parts of modifying agent, pigment 0.6 Part, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 80oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.1, intensity 40MPa.
It is same as Example 1, silicon powder is added together with modifying agent, sprays what silicon ash was prepared at the top of every layer of slurry The waterproof performance on glass magnesium floor is greatly reduced, and measurement waterproof performance is C grades.
Comparative example 1
55 parts of magnesia, 15 parts of magnesium chloride, 0.6 part of pigment, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia being uniformly mixed with pigment, then will prepare magnesium chloride solution addition, stirs 10 minutes and mixes It closes uniform；Stirring 4 minutes is added in modifying agent；
3) it forms: slurry made of the 2) step being poured into mold roller roll forming, glass fiber reticular cloth is uniformly arranged on slurry Inside is kept for 28 DEG C of temperature place 24 hours, forms half-finished product plate；
4) drying setting: by half-finished product plate 40oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is C grades, density 1.5, intensity 15MPa.
Comparative example 2
55 parts of magnesia, 0.5 part of silicon ash, 15 parts of magnesium chloride, 30 parts of wood powder, 6 parts of modifying agent, 0.6 part of pigment, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 80oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.3, intensity 24MPa.
Comparative example 3
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 15 parts of magnesium chloride, 6 parts of modifying agent, 0.6 part of pigment, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) it forms: slurry made of the 2) step being poured into the slurry of 11/12 depth of die depth, remaining slurry is layered on table Face and with roller roll forming, glass fiber reticular cloth is uniformly arranged on inside slurry, and silicon ash is sprayed at the top of every layer of slurry, keeps temperature It spends 28 DEG C to place 24 hours, forms half-finished product plate；
4) drying setting: by half-finished product plate 80oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.5, intensity 22MPa.
Comparative example 4
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 0.5 part of silicon ash, 15 parts of magnesium chloride, 30 parts of wood powder, 0.6 part of pigment, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed;
3) form: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, on wood powder after The continuous slurry for spreading 1/4 depth of mold, is layered on surface for remaining slurry and with roller roll forming, and glass fiber reticular cloth is uniformly set It sets inside slurry, silicon ash is sprayed at the top of every layer of slurry, kept for 28 DEG C of temperature place 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 80oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is A grades, density 1.4, intensity 40MPa.
Comparative example 5
55 parts of magnesia, 6 parts of glass fiber reticular cloth, 15 parts of magnesium chloride, 30 parts of wood powder, 6 parts of modifying agent, 0.6 part of pigment, 40 parts of water.
1) it prepares magnesium chloride solution: first being uniformly mixed magnesium chloride to form magnesium chloride solution with water, for use；
2) prepared by slurry: magnesia and pigment being uniformly mixed stirring 6 minutes, magnesium chloride solution addition then will be prepared, and stir It mixes 10 minutes and is uniformly mixed；Stirring 4 minutes is added in modifying agent；
3) it forms: slurry made of the 2) step being poured at the 2/3 of die depth, wood powder is layered on slurry, it finally will be remaining Slurry be layered on surface and with roller roll forming, glass fiber reticular cloth is uniformly arranged on inside slurry, keeps 28 DEG C of temperature placements 24 hours, form half-finished product plate；
4) drying setting: by half-finished product plate 80oC drying, finally shapes half-finished product plate cutting edge, forms glass magnesium floor.
Measuring waterproof performance is C grades, density 1.2, intensity 40MPa.
In the present invention embodiment 1-9 foot relax all preferably, embodiment 9 it is best, the foot comfort level of comparative example 4 is poor, has Biggish sound.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention.It is all The equivalent changes and modifications that content is done according to the present invention are encompassed by the scope of the patents of the invention.

Claims (8)

1. a kind of glass magnesium floor, which is characterized in that glass magnesium floor is grouped as: magnesia 50-80 by following substance and weight Part, 5-10 parts of glass fiber reticular cloth, 0.1-3 parts of silicon ash, 10-20 parts of magnesium chloride, 30-40 parts of wood powder, 6-8 parts of modifying agent, pigment 0.1-3 parts, 30-50 parts of water.
2. a kind of glass magnesium floor according to claim 1, which is characterized in that the glass fiber reticular cloth is selected from the glass fiber net Ge Bu includes one or more of polyester fiber grid cloth, crystalline glass fibre grid cloth and fluororesin grid cloth.
3. a kind of glass magnesium floor according to claim 1, which is characterized in that the glass fiber reticular cloth is crystalline glass fibre net Ge Bu, the crystalline glass fibre main component are MgO-Al2O3-SiO2。
4. a kind of glass magnesium floor according to claim 1, which is characterized in that the weight part ratio of the magnesia and magnesium chloride is 8:1-4。
5. a kind of glass magnesium floor according to claim 1, which is characterized in that the wood powder be selected from timber be according to wood processing and At the partial size of the wood powder is 100-300 mesh.
6. a kind of glass magnesium floor according to claim 1, which is characterized in that the modifying agent is that polyisobutene is pressed with ferric sulfate The mixture of weight ratio 10:1, the weight average molecular weight of the polyisobutene are 80000-150000.
7. a kind of glass magnesium floor according to claim 1, which is characterized in that the average grain diameter of the silicon ash is 0.1-0.3 μm.
8. a kind of glass magnesium floor according to claim 1, which is characterized in that 80% < MgO of magnesia mass percent < 90%, surplus is impurity.
CN201910845866.5A 2019-09-09 2019-09-09 A kind of glass magnesium floor Pending CN110451919A (en)

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Publication number Priority date Publication date Assignee Title
CN111892377A (en) * 2020-07-06 2020-11-06 财纳福诺木业(中国)有限公司 Waterproof glass magnesium floor base material and manufacturing method thereof
CN113719062A (en) * 2020-05-26 2021-11-30 财纳福诺木业(中国)有限公司 Panel and method for manufacturing a panel
US11724537B2 (en) 2020-05-26 2023-08-15 Champion Link International Corporation Panel and method for producing a panel

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CN1361844A (en) * 1999-07-31 2002-07-31 克隆纳斯板技术有限公司 Laminate flooring comprising tread sound-proofing
CN101564922A (en) * 2009-05-25 2009-10-28 南京佳汇新型建材制造有限公司 Multi-use composite reinforcing board and production process thereof
CN102633487A (en) * 2012-03-23 2012-08-15 刘丰 Disposable glass magnesium cement building mould plate and method for preparing same
CN104310922A (en) * 2014-10-08 2015-01-28 上海鹰必讯再生资源科技发展有限公司 Fiber-reinforced red-mud-modified magnesium oxide plate and preparation method thereof

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CN1361844A (en) * 1999-07-31 2002-07-31 克隆纳斯板技术有限公司 Laminate flooring comprising tread sound-proofing
CN101564922A (en) * 2009-05-25 2009-10-28 南京佳汇新型建材制造有限公司 Multi-use composite reinforcing board and production process thereof
CN102633487A (en) * 2012-03-23 2012-08-15 刘丰 Disposable glass magnesium cement building mould plate and method for preparing same
CN104310922A (en) * 2014-10-08 2015-01-28 上海鹰必讯再生资源科技发展有限公司 Fiber-reinforced red-mud-modified magnesium oxide plate and preparation method thereof

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CN113719062A (en) * 2020-05-26 2021-11-30 财纳福诺木业(中国)有限公司 Panel and method for manufacturing a panel
US11624192B2 (en) 2020-05-26 2023-04-11 Champion Link International Corporation Panel and method for producing a panel
US11724537B2 (en) 2020-05-26 2023-08-15 Champion Link International Corporation Panel and method for producing a panel
CN111892377A (en) * 2020-07-06 2020-11-06 财纳福诺木业(中国)有限公司 Waterproof glass magnesium floor base material and manufacturing method thereof

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