CN110444700A - A kind of pack case and its ultra-thin lithium cell of ultra-thin lithium cell - Google Patents

A kind of pack case and its ultra-thin lithium cell of ultra-thin lithium cell Download PDF

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Publication number
CN110444700A
CN110444700A CN201910653645.8A CN201910653645A CN110444700A CN 110444700 A CN110444700 A CN 110444700A CN 201910653645 A CN201910653645 A CN 201910653645A CN 110444700 A CN110444700 A CN 110444700A
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CN
China
Prior art keywords
ultra
lithium
protective film
lithium cell
thin lithium
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Granted
Application number
CN201910653645.8A
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Chinese (zh)
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CN110444700B (en
Inventor
胡雪文
刘凯
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Jiangmen Jili Energy Co Ltd
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Jiangmen Jili Energy Co Ltd
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Priority to CN201910653645.8A priority Critical patent/CN110444700B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Secondary Cells (AREA)

Abstract

The invention discloses a kind of ultra-thin lithium cell pack case and its ultra-thin lithium cells; by the way that punching hole and protective film are arranged in composite membrane; and protective film is affixed on composite membrane for the one side of lithium cathode sheet to be arranged; the size of protective film is less than punching hole; it is advantageously implemented the cathode corresponding surface in pack case and directly passes through adhesive and stick protective film; it is effectively saved complicated film sticking equipment, drying shed and low dew point conditions is not necessarily to, greatly reduces production cost;Ultra-thin lithium cell is made using the pack case of this ultra-thin lithium cell, cathode injury of ear polypropylene layer in lithium battery processing or use process is effectively avoided, improves the yields and reliability of product.

Description

A kind of pack case and its ultra-thin lithium cell of ultra-thin lithium cell
Technical field
The present invention relates to field of lithium, in particular to the pack case and its ultra-thin lithium cell of a kind of ultra-thin lithium cell.
Background technique
For existing ultra-thin flexible package lithium cell or thin polymer lithium battery, the material of pack case generallys use gold Category and composite plastic film, such as common nylon/aluminium/polypropylene, nylon/stainless steel/polypropylene, polyethylene terephthalate Ester/aluminium/polypropylene, polyethylene terephthalate/stainless steel/polypropylene etc., polypropylene layer are needed when being assembled into lithium battery It is coated on the one side that battery cathode of lithium is welded with negative electrode lug, and the thickness of the polypropylene layer of pack case only has 15-35 microns, directly It is coated on the one side that battery cathode of lithium is welded with negative electrode lug, subsequent processing or use process are needed to apply pressure, be may cause poly- Propylene layer is damaged, and battery is caused situations such as corrosion and inflatable occur;Existing way is to be welded with the one side of negative electrode lug in cathode of lithium Pasting protective film, and cathode of lithium is easy to become due to its soft, low and sticking characteristic of intensity when pressure welding negative electrode lug Out-of-flatness, it is at this time that protective film is smooth and be equably attached to cathode of lithium and need special equipment, and to tension control technology It is required that high, it is also necessary to -45 DEG C of dew point processing environments below, therefore, existing pack case and its method for manufacturing lithium battery High to the condition requirement of processing operation, difficulty of processing is big, even if having paid huge equipment cost, the yields of battery is also difficult To be protected.
Summary of the invention
It is an object of the invention at least solve one of the technical problems existing in the prior art, a kind of ultra-thin lithium electricity is provided The pack case and its ultra-thin lithium cell in pond enable to pack case to be avoided during installation by cathode injury of ear, difficult reducing construction The production of lithium battery is completed in the case where degree and equipment cost, and improves yields.
The first aspect of the present invention, provides a kind of pack case of ultra-thin lithium cell, including composite membrane, and the composite membrane includes Polypropylene layer, the composite membrane include rushing hole and protective film for protecting lithium cathode sheet surface, institute for be arranged lithium battery It states protective film to be affixed in the composite membrane for the one side of lithium battery lithium cathode sheet to be arranged, the protective film is set to the punching hole Downside or bottom surface, the size of the protective film cheats less than the punching, and the protection film surface is coated with adhesive.
Further, the composite membrane is that aluminum-plastic composite membrane or stainless steel mould composite membrane.
Further, the protective film is polyimide film, polypropylene screen or polyethylene terephthalate film.
Further, the adhesive of the protection film surface is the adhesive sticker of electrolyte resistance.
The second aspect of the present invention additionally provides a kind of ultra-thin lithium cell, one including battery and as described in any of the above-described The pack case of kind ultra-thin lithium cell, the battery include the anode rushed in hole for setting gradually the pack case from the inside to the outside Ear, positive plate, lithium cathode sheet and negative electrode lug, the protective film grow and be wider than the negative electrode lug it is described punching hole in length and It is wide.
Further, the battery further includes the diaphragm for separating positive plate and lithium cathode sheet, the diaphragm and anode Electrolyte is filled between piece and lithium cathode sheet;The length of the protective film and the wide length and width for being less than the diaphragm.
Further, the polypropylene layer and the sum of described protection film thickness with a thickness of the composite membrane of the negative electrode lug 35%~65%.
Further, the gel for bonding tab is additionally provided on the anode ear and negative electrode lug, the gel is set It is placed in the upside of punching hole top edge.
Further, the negative electrode lug pressure welding is in the lithium cathode sheet surface.
Further, lower side of the negative electrode lug pressure welding in the lithium cathode sheet part is arc-shaped edges or straight flange.
The pack case and its ultra-thin lithium cell for a kind of ultra-thin lithium cell that above-mentioned technical proposal provides, at least have has as follows Beneficial effect: by the way that punching hole and protective film are arranged in composite membrane, and protective film is affixed on composite membrane for lithium cathode sheet to be arranged On one side, the size of protective film is less than punching hole, is advantageously implemented the cathode corresponding surface in pack case and directly passes through adhesive and sticks guarantor Cuticula, is effectively saved complicated film sticking equipment, and the process of pasting protective film is not necessarily to drying shed and low dew point conditions, greatly reduces Production cost;Ultra-thin lithium cell is manufactured using the pack case of this ultra-thin lithium cell, lithium battery can effectively be avoided to process or make With cathode injury of ear polypropylene layer in the process, the yields and reliability of product are improved.
Detailed description of the invention
The present invention is further explained with reference to the accompanying drawings and examples;
Fig. 1 is a kind of main view of ultra-thin lithium cell pack case of the embodiment of the present invention;
Fig. 2 is a kind of right view of ultra-thin lithium cell pack case of the embodiment of the present invention;
Fig. 3 is a kind of main view of the battery of ultra-thin lithium cell of the embodiment of the present invention;
Fig. 4 is a kind of main view of ultra-thin lithium cell of the embodiment of the present invention.
Specific embodiment
This part will be described in specific embodiments of the present invention, and the preferred embodiments of the invention is shown in the accompanying drawings, attached The effect of figure be with figure remark additionally book word segment description, enable a person to intuitively, visually understand of the invention Each technical characteristic and overall technical architecture, but it should not be understood as limiting the scope of the invention.
In the description of the present invention, it is to be understood that, be related to orientation description, for example, above and below, front, rear, left and right etc. The orientation or positional relationship of instruction is to be based on the orientation or positional relationship shown in the drawings, and is merely for convenience of the description present invention and letter Change description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with specific orientation construct and Operation, therefore be not considered as limiting the invention.
In the description of the present invention, several to be meant that one or more, it is multiple to be meant that two or more, be greater than, Be less than, more than etc. be interpreted as not including this number, it is above, following, within etc. be interpreted as including this number.If there is being described to first, Second is only intended to for the purpose of distinguishing technical characteristic, is not understood to indicate or imply relative importance or implicitly indicates institute The quantity of the technical characteristic of instruction or the precedence relationship for implicitly indicating indicated technical characteristic.
In description of the invention, unless otherwise restricted clearly, the words such as setting, installation, connection be shall be understood in a broad sense, institute Above-mentioned word in the present invention specific can rationally be determined with the particular content of combination technology scheme by belonging to technical field technical staff Meaning.
- Fig. 2 referring to Fig.1, the embodiment provides a kind of pack case of ultra-thin lithium cell, including composite membrane 100, The composite membrane 100 includes polypropylene layer, and the composite membrane 100 includes cheating 120 and for protecting for rushing for lithium battery to be arranged The protective film 110 on 210 surface of lithium cathode sheet, the protective film 110 are affixed in the composite membrane 100 negative for lithium battery lithium to be arranged The one side of pole piece 210, the protective film 110 are set to the downside or bottom surface in the punching hole 120, the size of the protective film 110 Less than punching hole 120,110 surface of protective film is coated with adhesive.
Wherein, it should be noted that protective film 110 is affixed in the composite membrane (100) for lithium to be arranged in the present embodiment The one side of battery lithium cathode sheet can use cutter when using manual pad pasting using the method for manual pad pasting and machine pad pasting Protective film 110 is cut into suitably sized by tool, and the protective film 110 after cutting is affixed in the composite membrane 100 by craft It, can also be using rushing shell machine and automatic adhesive sticking machine is pasted automatically automatically for the one side of lithium battery lithium cathode sheet to be arranged Film is rushing placement composite membrane 100 on shell machine spool automatically, protective film 110 is placed in automatic adhesive sticking machine, is rushing the punching of shell machine automatically Out when pack case, protective film 110 is affixed on to the one side for being used to be arranged lithium battery lithium cathode sheet in the composite membrane 100, is punched into Ultra-thin lithium cell pack case is higher than the efficiency of manual pad pasting using the efficiency of automatic coating, and specific pad pasting mode is according to practical item Part is chosen, and can be realized and protective film 110 is affixed in the composite membrane (100) for the one side of lithium battery lithium cathode sheet to be arranged i.e. It can.
Wherein, it should be noted that setting punching hole 120 is only the preferred of the present embodiment in composite membrane 100, can not also be set Punching hole 120 is set, if being not provided with punching hole 120, battery 200 is directly arranged in the position in punching hole 120 in Fig. 1, then passes through rubberizing Machine sticks protective film 110, and punching hole 120 specifically whether is arranged and is adjusted according to the demand of actual production.
Wherein it is possible to understand, the composite membrane 100 in the present embodiment be can be in existing 100 structure of composite membrane Any one, it can be ensured that innermost layer is polypropylene layer, and details are not described herein.
Wherein it is possible to understand, the airbag 130 of exhaust can be also used on the composite membrane 100 in the present embodiment, it can The gas of generation is discharged in the fabrication process, it is ensured that production smoothly completes, and the airbag 130 in the present embodiment is lithium battery system Common airbag in making, details are not described herein.
Wherein, it should be noted that the protective film 110 is set to the downside or bottom surface in the punching hole 120, depends on It is the bottom side that lithium cathode sheet 210 is set to the downside in punching hole 120 or lithium cathode sheet 210 is set to punching hole 120;Lithium is born Pole piece 210 be set to punching hole 120 downside then protective film 110 be set to it is described punching hole 120 downside, turn down packaging film, protection Film 110 is just covered with lithium cathode sheet 210;By lithium cathode sheet 210 be set to punching hole 120 then protective film 110 is set to institute for bottom surface State the bottom surface in punching hole 120,110 face lithium cathode sheet 210 of protective film.
Further, in another embodiment of the present invention, the composite membrane 100 is that aluminum-plastic composite membrane or stainless steel modeling are multiple Close film.
Wherein, it should be noted that the thickness of composite membrane 100 can be any number, and the present embodiment is preferably 0.04~ 0.09mm, specific value are chosen according to actual production demand.
Further, in another embodiment of the present invention, the protective film 110 be polyimide film, polypropylene screen or Polyethylene terephthalate film.
Wherein it is possible to understand, the thickness of protective film 110 can arbitrary value between 0.005~0.05mm, this reality Applying example is more preferably the value within the scope of 0.01~0.03mm, and specific value is chosen according to actual production demand.
Further, in another embodiment of the present invention, the adhesive on 110 surface of protective film is electrolyte resistance Adhesive sticker.
Wherein, it should be noted that adhesive can be any type, can be realized and protective film 110 is bonded to lithium bears 210 surface of pole piece, the adhesive sticker of the preferred electrolyte resistance of the present embodiment, it can be ensured that the feelings of electrolyte leakage occur in battery Sealing is kept under condition, avoids the leakage that electrolyte occurs.
With reference to Fig. 3-Fig. 4, in addition, another embodiment of the invention additionally provides a kind of ultra-thin lithium cell, including battery The pack case of core 200 and a kind of ultra-thin lithium cell as described in any of the above-described, the battery 200 include successively setting from the inside to the outside Set anode ear 232, positive plate, lithium cathode sheet 210 and the negative electrode lug 233 of the pack case rushed in hole 120, the protective film The length and width cheated in 120 are being rushed in 110 grow and be wider than the negative electrode lug 233.
Wherein it is possible to understand, the thickness of the ultra-thin lithium cell can be the arbitrary value within the scope of 0.2~0.9mm, The present embodiment is more preferably the value between 0.3~0.6mm, and specific value is chosen according to actual production demand.
Wherein it is possible to understand, length and width of the negative electrode lug 233 in punching hole 120 are grown and be wider than to protective film 110 can Ensure that protective film 110 can be completely covered by 233 surface of negative electrode lug, realizes protecting effect, specific long and width is according to practical life Situation adjustment is produced, battery seal is not influenced.
Wherein, it should be noted that the lithium battery in the present embodiment can be lithium primary battery, be also possible to chargeable Lithium battery, details are not described herein.It is understood that lithium primary battery can be ultra-thin flexible-packaged lithium one-shot battery or ultra-thin poly- Object lithium primary battery is closed, positive active material can be manganese dioxide, fluorocarbons, fluorographite, molybdenum trioxide, five oxidations two One of vanadium, siliver chromate, copper fluoride, copper chloride, copper oxide, copper sulfide, iron sulfide, ferrous disulfide or two kinds or more mix Object, cathode are lithium or lithium alloy, and specific material is chosen according to actual production demand.
Further, in another embodiment of the present invention, the battery 200 further includes for separating positive plate and lithium The diaphragm 220 of negative electrode tab 210 is filled with electrolyte between the diaphragm 220 and positive plate and lithium cathode sheet 210;The protection The length of film 110 and wide length and width less than the diaphragm 220.
Wherein, it should be noted that protective film 110 is due to needing to be affixed in the composite membrane 100 for cathode of lithium to be arranged The surface of piece 210, therefore its length and the wide length for being necessarily less than diaphragm 220 and width, avoid the too big influence battery seal of protective film.
Further, in another embodiment of the present invention, the negative electrode lug 233 with a thickness of the composite membrane 100 The 35%~65% of the sum of polypropylene layer and 110 thickness of protective film.
Wherein, it should be noted that negative electrode lug thickness can be the arbitrary value within the scope of 0.01~0.1mm, the present embodiment Arbitrary value within the scope of further preferably 0.015~0.025mm, specific value are chosen according to actual production demand.
Further, in another embodiment of the present invention, use is additionally provided on the anode ear 232 and negative electrode lug 233 In the gel 231 of bonding tab, the gel 231 is set to the upside of 120 top edges of the punching hole.
Further, in another embodiment of the present invention, 233 pressure welding of negative electrode lug is in 210 table of lithium cathode sheet Face.
Further, in another embodiment of the present invention, 233 pressure welding of negative electrode lug is in the lithium cathode sheet 210 The lower side divided is arc-shaped edges or straight flange.
Wherein, it should be noted that for 233 pressure welding of negative electrode lug on cathode of lithium, pressure welding length can be 1~100mm range Interior arbitrary value, the present embodiment are more preferably the arbitrary value within the scope of 2~20mm, can be while ensuring weld strength It is easy to produce.It should be noted that the lower side of negative electrode lug 233 is the burr that arc-shaped advantageously reduces 233 port of negative electrode lug, Straight flange is conducive to the production and reconditioning of 233 cutter of negative electrode lug, and concrete shape is adjusted according to actual production demand.
The embodiment of the present invention is explained in detail above in conjunction with attached drawing, but the present invention is not limited to the above embodiments, In The technical field those of ordinary skill within the scope of knowledge, can also make without departing from the purpose of the present invention Various change out.

Claims (10)

1. a kind of pack case of ultra-thin lithium cell, including composite membrane, the composite membrane include polypropylene layer, it is characterised in that: institute Stating composite membrane includes rushing hole and protective film for protecting lithium cathode sheet surface for be arranged lithium battery, and the protective film is affixed on For the one side of lithium battery lithium cathode sheet to be arranged in the composite membrane, the protective film is set to the downside or bottom in the punching hole The size in face, the protective film is cheated less than the punching, and the protection film surface is coated with adhesive.
2. a kind of pack case of ultra-thin lithium cell according to claim 1, it is characterised in that: the composite membrane is multiple for plastic-aluminum It closes film or stainless steel moulds composite membrane.
3. a kind of pack case of ultra-thin lithium cell according to claim 1, it is characterised in that: the protective film is that polyamides is sub- Amine film, polypropylene screen or polyethylene terephthalate film.
4. a kind of pack case of ultra-thin lithium cell according to claim 1, it is characterised in that: the protection film surface is glued Mixture is the adhesive sticker of electrolyte resistance.
5. a kind of ultra-thin lithium cell, it is characterised in that: a kind of ultra-thin lithium including battery and as described in claim 1-4 is any The pack case of battery, the battery include set gradually from the inside to the outside the pack case rush hole in anode ear, positive plate, Length and width of the negative electrode lug in the punching hole are grown and are wider than to lithium cathode sheet and negative electrode lug, the protective film.
6. a kind of ultra-thin lithium cell according to claim 5, it is characterised in that: the battery further includes for separating just The diaphragm of pole piece and lithium cathode sheet is filled with electrolyte between the diaphragm and positive plate and lithium cathode sheet;The protective film The long and wide length and width for being less than the diaphragm.
7. a kind of ultra-thin lithium cell according to claim 5, it is characterised in that: the negative electrode lug with a thickness of described compound The polypropylene layer of film and the 35%~65% of the sum of described protection film thickness.
8. a kind of ultra-thin lithium cell according to claim 7, it is characterised in that: also set up on the anode ear and negative electrode lug There is the gel for bonding tab, the gel is set to the upside of punching hole top edge.
9. a kind of ultra-thin lithium cell according to claim 5, it is characterised in that: the negative electrode lug pressure welding is in the cathode of lithium Piece surface.
10. a kind of ultra-thin lithium cell according to claim 9, it is characterised in that: the negative electrode lug pressure welding is negative in the lithium The lower side of pole piece part is arc-shaped edges or straight flange.
CN201910653645.8A 2019-07-19 2019-07-19 Packaging shell of ultrathin lithium battery and ultrathin lithium battery Active CN110444700B (en)

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CN110444700B CN110444700B (en) 2022-07-22

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JP2011044332A (en) * 2009-08-21 2011-03-03 Jm Energy Corp Laminated outer package power storage device
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CN202094228U (en) * 2011-05-26 2011-12-28 东莞市利赛奥新能源科技有限公司 Flexible package lithium ion battery with bump recovery device
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US20150288029A1 (en) * 2013-12-27 2015-10-08 Eve Energy Co., Ltd. Lithium battery and the preparation method thereof
JP2017069107A (en) * 2015-09-30 2017-04-06 大日本印刷株式会社 Adhesive protection film
CN106972189A (en) * 2017-03-07 2017-07-21 惠州亿纬锂能股份有限公司 The preparation method and slimline battery of a kind of slimline battery
CN207587771U (en) * 2017-11-30 2018-07-06 广东安电能源科技有限公司 A kind of polymer Li-ion battery of anti-short circuit
CN208433424U (en) * 2018-05-24 2019-01-25 湖南立方新能源科技有限责任公司 A kind of Soft Roll laminated batteries encapsulating structure

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000235845A (en) * 1998-12-16 2000-08-29 Japan Storage Battery Co Ltd Thin battery
CN101083344A (en) * 2006-05-31 2007-12-05 比亚迪股份有限公司 Lithium ion secondary battery and mfg. method of same
JP2011044332A (en) * 2009-08-21 2011-03-03 Jm Energy Corp Laminated outer package power storage device
CN102024995A (en) * 2009-09-22 2011-04-20 深圳市比克电池有限公司 Novel lithium ion power battery
CN202094228U (en) * 2011-05-26 2011-12-28 东莞市利赛奥新能源科技有限公司 Flexible package lithium ion battery with bump recovery device
CN102891334A (en) * 2011-07-18 2013-01-23 比亚迪股份有限公司 Lithium ion battery and preparation method thereof
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CN106972189A (en) * 2017-03-07 2017-07-21 惠州亿纬锂能股份有限公司 The preparation method and slimline battery of a kind of slimline battery
CN207587771U (en) * 2017-11-30 2018-07-06 广东安电能源科技有限公司 A kind of polymer Li-ion battery of anti-short circuit
CN208433424U (en) * 2018-05-24 2019-01-25 湖南立方新能源科技有限责任公司 A kind of Soft Roll laminated batteries encapsulating structure

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