CN110424153A - A kind of production method of antibacterial waterproof textile - Google Patents
A kind of production method of antibacterial waterproof textile Download PDFInfo
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- CN110424153A CN110424153A CN201910691791.XA CN201910691791A CN110424153A CN 110424153 A CN110424153 A CN 110424153A CN 201910691791 A CN201910691791 A CN 201910691791A CN 110424153 A CN110424153 A CN 110424153A
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- textile
- antibacterial waterproof
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- 239000004753 textile Substances 0.000 title claims abstract description 51
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000000243 solution Substances 0.000 claims abstract description 75
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 35
- 238000003756 stirring Methods 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000008387 emulsifying waxe Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- 238000004945 emulsification Methods 0.000 claims abstract description 8
- 239000012670 alkaline solution Substances 0.000 claims abstract description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 150000002148 esters Chemical class 0.000 claims abstract description 6
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 6
- 239000012188 paraffin wax Substances 0.000 claims abstract description 6
- 239000003208 petroleum Substances 0.000 claims abstract description 6
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 20
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000012279 sodium borohydride Substances 0.000 claims description 10
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 10
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 6
- 229920002101 Chitin Polymers 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 5
- 229960004756 ethanol Drugs 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 239000001993 wax Substances 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 27
- 238000004078 waterproofing Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 239000003513 alkali Substances 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 238000009940 knitting Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000012797 qualification Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 241000238367 Mya arenaria Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000002633 protecting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/17—Halides of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of production methods of antibacterial waterproof textile, comprising the following steps: S1, the concentrated ammonia liquor that concentration is 26~31% is added in deionized water in the ratio of 0.5mL/L, then carries out at the uniform velocity stirring 5min by stirring rod and obtains solution A；S2, solution A is taken to be placed in graduated cylinder, then to alkaline solution is added inside graduated cylinder, until pH value adjustment adds 0.07~0.14mg reducing agent and 0.1~1.15mg silver nitrate, be protected from light stirring 25min and obtain solution B to 8~9；S3, it 5mg paraffin, microwax or petroleum ester is placed in blender mixes, 0.5L water is then added and carries out dissolving to obtain solution C, be placed in solution C and 3mg emulsifier together in ultrasonic emulsator and carry out emulsification procedure to get to emulsifying wax；By being blended in waterproofing agent inside textile fabric, to greatly increase the waterproof effect of textile fabric, while waterproofing agent is without departing from textile fabric, so that the waterproof effect of textile fabric is able to maintain the longer time.
Description
Technical field
The invention belongs to field of fabric producing technology, and in particular to a kind of production method of antibacterial waterproof textile.
Background technique
It is knitted fabric, by method for weaving point, there is two class of Weft knitted fabric and warp knitted fabric.Weft knitted fabric is normal
With low-elasticity terylene fibre or special-shaped dacron thread, Polyamide Yarns, cotton yarn, wool yarn etc. for raw material, using plain stitch, change plain stitch,
Rib-loop plain stitch, double rib plain stitch, figured texture weave, pile stitch etc. weave, soft type on various weft machines
Fabric is generally more frivolous, it is with a good drape effect to hang, and moulding lines are smooth, and clothes profile is unfolded naturally.Soft shell fabric mainly includes knitting
The knitting fabric and silk fabrics of the evacuation of object structure and soft thin dimity fabric etc..Soft knitting fabric is in dress designing
Human body grace curve is embodied frequently with the terse moulding of linear type；The fabrics such as silk, the dimity then common loose type and have rivel effect
Moulding, show fabric lines sense of movement.
Waterproofing agent is generally applied to the outside of textile fabric by existing water proof type textile fabric, and this coating method is easy
When wearing waterproofing agent is fallen off, thus the problem of causing textile fabric to lose waterproof effect, it is thus it is proposed that a kind of anti-
The production method of bacterium waterproof textile.
Summary of the invention
The purpose of the present invention is to provide a kind of production methods of antibacterial waterproof textile, to solve in above-mentioned background technique
The problem of waterproofing agent of proposition is easily separated from textile fabric.
To achieve the above object, the invention provides the following technical scheme: a kind of production method of antibacterial waterproof textile, packet
Include following steps:
S1, the concentrated ammonia liquor that concentration is 26~31% is added in deionized water in the ratio of 0.5mL/L, then passes through stirring
Stick carries out at the uniform velocity stirring 5min and obtains solution A；
S2, solution A is taken to be placed in graduated cylinder, then to alkaline solution is added inside graduated cylinder, until pH value adjustment is to 8~9, then plus
Enter 0.07~0.14mg reducing agent and 0.1~1.15mg silver nitrate, is protected from light stirring 25min and obtains solution B；
S3,5mg paraffin, microwax or petroleum ester are placed in blender mix, be then added 0.5L water carry out it is molten
Solution C is solved, solution C and 3mg emulsifier is placed in together in ultrasonic emulsator and carries out emulsification procedure to get cream is arrived
Change wax；
S4,26~32% emulsifying waxs, polyurethane 16~22%, 20~33% deca-BDEs and 17 are taken by weight percentage
~25% aluminium chloride is dissolved in dehydrated alcohol, and at the uniform velocity 10~15min of stirring obtains solution D；
S5, solution B and solution D are taken while being placed in blender and stirs 15min, then carry out 6~12min of ultrasonic disperse, obtained
Solution E；
S6, textile is completely immersed in solution E, ultrasonic vibration 2.5h, the ethanol washing used for textiles 2 after taking out dipping
Secondary, product can be obtained by further taking out textile naturally dry.
Preferably, the S2 step neutral and alkali solution can be one of sodium hydroxide, potassium hydroxide and aluminium hydroxide
Or it is several.
Preferably, emulsifier selects compound emulsifying agent in the S3 step, is made of oleophilic emulsifier and hydrophilic emulsifying agent,
And the weight ratio of the oleophilic emulsifier and hydrophilic emulsifying agent is 2:2.5.
Preferably, in the S2 step reducing agent be potassium borohydride and sodium borohydride mixture, and the potassium borohydride
It is by weight 2:3 with sodium borohydride.
Preferably, textile selects chitin fiber in the S6 step.
Preferably, in the S4 step emulsifying wax, polyurethane, deca-BDE and aluminium chloride mixture and dehydrated alcohol
Weight ratio be 2:8.
Preferably, the weight ratio of solution B and solution D is 2:3 in the S5 step.
Compared with prior art, the beneficial effects of the present invention are:
1, in the present invention, by being blended in waterproofing agent inside textile fabric, to greatly increase the waterproof of textile fabric
Effect, while waterproofing agent is without departing from textile fabric, so that the waterproof effect of textile fabric is able to maintain the longer time.
2, in the present invention, by increasing anti-biotic material in waterproofing agent, so that textile fabric can enhance antibacterial effect
Fruit enables textile fabric to play better protecting effect.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
The present invention provides a kind of technical solution: a kind of production method of antibacterial waterproof textile, comprising the following steps:
S1, by concentration be 28% concentrated ammonia liquor by 0.5mL/L ratio be added deionized water in, then pass through stirring rod into
Row at the uniform velocity stirring 5min obtains solution A；
S2, solution A is taken to be placed in graduated cylinder, then to alkaline solution is added inside graduated cylinder, until pH value adjustment is to 8.2, then plus
Enter 0.09mg reducing agent and 0.12mg silver nitrate, is protected from light stirring 25min and obtains solution B；
S3,5mg paraffin, microwax or petroleum ester are placed in blender mix, be then added 0.5L water carry out it is molten
Solution C is solved, solution C and 3mg emulsifier is placed in together in ultrasonic emulsator and carries out emulsification procedure to get cream is arrived
Change wax；
S4, take by weight percentage 27% emulsifying wax, polyurethane 17%, 32% deca-BDE and 24% aluminium chloride it is molten
For solution in dehydrated alcohol, at the uniform velocity stirring 12min obtains solution D；
S5, solution B and solution D are taken while being placed in blender and stirs 15min, then carry out ultrasonic disperse 8min, obtain solution
E；
S6, textile is completely immersed in solution E, ultrasonic vibration 2.5h, the ethanol washing used for textiles 2 after taking out dipping
Secondary, product can be obtained by further taking out textile naturally dry.
Wherein, S2 step neutral and alkali solution can be one of sodium hydroxide, potassium hydroxide and aluminium hydroxide or several
Kind.
Wherein, emulsifier selects compound emulsifying agent in S3 step, is made of oleophilic emulsifier and hydrophilic emulsifying agent, and oleophylic
The weight ratio of emulsifier and hydrophilic emulsifying agent is 2:2.5.
Wherein, in S2 step reducing agent be potassium borohydride and sodium borohydride mixture, and potassium borohydride and sodium borohydride
It is by weight 2:3.
Wherein, textile selects chitin fiber in S6 step.
Wherein, the weight of the mixture of emulsifying wax in S4 step, polyurethane, deca-BDE and aluminium chloride and dehydrated alcohol
Than for 2:8.
Wherein, the weight ratio of solution B and solution D is 2:3 in S5 step.
Embodiment 2
The present invention provides a kind of technical solution: a kind of production method of antibacterial waterproof textile, comprising the following steps:
S1, by concentration be 30% concentrated ammonia liquor by 0.5mL/L ratio be added deionized water in, then pass through stirring rod into
Row at the uniform velocity stirring 5min obtains solution A；
S2, solution A is taken to be placed in graduated cylinder, then to alkaline solution is added inside graduated cylinder, until pH value adjustment is to 8.4, then plus
Enter 0.1mg reducing agent and 0.13mg silver nitrate, is protected from light stirring 25min and obtains solution B；
S3,5mg paraffin, microwax or petroleum ester are placed in blender mix, be then added 0.5L water carry out it is molten
Solution C is solved, solution C and 3mg emulsifier is placed in together in ultrasonic emulsator and carries out emulsification procedure to get cream is arrived
Change wax；
S4, take by weight percentage 28% emulsifying wax, polyurethane 18%, 32% deca-BDE and 22% aluminium chloride it is molten
For solution in dehydrated alcohol, at the uniform velocity stirring 14min obtains solution D；
S5, solution B and solution D are taken while being placed in blender and stirs 15min, then carry out ultrasonic disperse 10min, obtain solution
E；
S6, textile is completely immersed in solution E, ultrasonic vibration 2.5h, the ethanol washing used for textiles 2 after taking out dipping
Secondary, product can be obtained by further taking out textile naturally dry.
Wherein, S2 step neutral and alkali solution can be one of sodium hydroxide, potassium hydroxide and aluminium hydroxide or several
Kind.
Wherein, emulsifier selects compound emulsifying agent in S3 step, is made of oleophilic emulsifier and hydrophilic emulsifying agent, and oleophylic
The weight ratio of emulsifier and hydrophilic emulsifying agent is 2:2.5.
Wherein, in S2 step reducing agent be potassium borohydride and sodium borohydride mixture, and potassium borohydride and sodium borohydride
It is by weight 2:3.
Wherein, textile selects chitin fiber in S6 step.
Wherein, the weight of the mixture of emulsifying wax in S4 step, polyurethane, deca-BDE and aluminium chloride and dehydrated alcohol
Than for 2:8.
Wherein, the weight ratio of solution B and solution D is 2:3 in S5 step.
Embodiment 3
The present invention provides a kind of technical solution: a kind of production method of antibacterial waterproof textile, comprising the following steps:
S1, by concentration be 31% concentrated ammonia liquor by 0.5mL/L ratio be added deionized water in, then pass through stirring rod into
Row at the uniform velocity stirring 5min obtains solution A；
S2, solution A is taken to be placed in graduated cylinder, then to alkaline solution is added inside graduated cylinder, until pH value adjustment to 9, adds
0.14mg reducing agent and 1.15mg silver nitrate are protected from light stirring 25min and obtain solution B；
S3,5mg paraffin, microwax or petroleum ester are placed in blender mix, be then added 0.5L water carry out it is molten
Solution C is solved, solution C and 3mg emulsifier is placed in together in ultrasonic emulsator and carries out emulsification procedure to get cream is arrived
Change wax；
S4, take by weight percentage 29% emulsifying wax, polyurethane 19%, 33% deca-BDE and 19% aluminium chloride it is molten
For solution in dehydrated alcohol, at the uniform velocity stirring 15min obtains solution D；
S5, solution B and solution D are taken while being placed in blender and stirs 15min, then carry out ultrasonic disperse 12min, obtain solution
E；
S6, textile is completely immersed in solution E, ultrasonic vibration 2.5h, the ethanol washing used for textiles 2 after taking out dipping
Secondary, product can be obtained by further taking out textile naturally dry.
Wherein, S2 step neutral and alkali solution can be one of sodium hydroxide, potassium hydroxide and aluminium hydroxide or several
Kind.
Wherein, emulsifier selects compound emulsifying agent in S3 step, is made of oleophilic emulsifier and hydrophilic emulsifying agent, and oleophylic
The weight ratio of emulsifier and hydrophilic emulsifying agent is 2:2.5.
Wherein, in S2 step reducing agent be potassium borohydride and sodium borohydride mixture, and potassium borohydride and sodium borohydride
It is by weight 2:3.
Wherein, textile selects chitin fiber in S6 step.
Wherein, the weight of the mixture of emulsifying wax in S4 step, polyurethane, deca-BDE and aluminium chloride and dehydrated alcohol
Than for 2:8.
Wherein, the weight ratio of solution B and solution D is 2:3 in S5 step.
The detection of antibacterial waterproof performance is carried out to 1,2,3 products obtained therefrom of embodiment respectively, data is obtained and is as follows:
| Serial number | Antibacterial waterproof effectiveness duration |
| Embodiment 1 | 24 months (qualification) |
| Embodiment 2 | 25 months (qualification) |
| Embodiment 3 | 26 months (qualification) |
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of production method of antibacterial waterproof textile, which comprises the following steps:
S1, by concentration be 26~31% concentrated ammonia liquor by 0.5mL/L ratio be added deionized water in, then pass through stirring rod into
Row at the uniform velocity stirring 5min obtains solution A；
S2, solution A is taken to be placed in graduated cylinder, then to alkaline solution is added inside graduated cylinder, until pH value adjustment to 8~9, adds
0.07~0.14mg reducing agent and 0.1~1.15mg silver nitrate are protected from light stirring 25min and obtain solution B；
S3, it 5mg paraffin, microwax or petroleum ester is placed in blender mixes, 0.5L water is then added and dissolve
Solution C is placed in solution C and 3mg emulsifier together in ultrasonic emulsator and carries out emulsification procedure to get emulsification is arrived
Wax；
S4, take by weight percentage 26~32% emulsifying waxs, polyurethane 16~22%, 20~33% deca-BDEs and 17~
25% aluminium chloride is dissolved in dehydrated alcohol, and at the uniform velocity 10~15min of stirring obtains solution D；
S5, solution B and solution D are taken while being placed in blender and stirs 15min, then carry out 6~12min of ultrasonic disperse, obtain solution
E；
S6, textile is completely immersed in solution E, ultrasonic vibration 2.5h, ethanol washing used for textiles 2 times after taking out dipping,
Product can be obtained by further taking out textile naturally dry.
2. a kind of production method of antibacterial waterproof textile according to claim 1, it is characterised in that: in the S2 step
Alkaline solution can be one of sodium hydroxide, potassium hydroxide and aluminium hydroxide or several.
3. a kind of production method of antibacterial waterproof textile according to claim 1, it is characterised in that: in the S3 step
Emulsifier selects compound emulsifying agent, is made of oleophilic emulsifier and hydrophilic emulsifying agent, and the oleophilic emulsifier and hydrophilic emulsification
The weight ratio of agent is 2:2.5.
4. a kind of production method of antibacterial waterproof textile according to claim 1, it is characterised in that: in the S2 step
Reducing agent is the mixture of potassium borohydride and sodium borohydride, and the potassium borohydride and sodium borohydride are 2:3 by weight.
5. a kind of production method of antibacterial waterproof textile according to claim 1, it is characterised in that: in the S6 step
Textile selects chitin fiber.
6. a kind of production method of antibacterial waterproof textile according to claim 1, it is characterised in that: in the S4 step
Emulsifying wax, polyurethane, deca-BDE and the mixture of aluminium chloride and the weight ratio of dehydrated alcohol are 2:8.
7. a kind of production method of antibacterial waterproof textile according to claim 1, it is characterised in that: in the S5 step
The weight ratio of solution B and solution D is 2:3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910691791.XA CN110424153A (en) | 2019-07-30 | 2019-07-30 | A kind of production method of antibacterial waterproof textile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910691791.XA CN110424153A (en) | 2019-07-30 | 2019-07-30 | A kind of production method of antibacterial waterproof textile |
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| Publication Number | Publication Date |
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| CN110424153A true CN110424153A (en) | 2019-11-08 |
Family
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| CN201910691791.XA Pending CN110424153A (en) | 2019-07-30 | 2019-07-30 | A kind of production method of antibacterial waterproof textile |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114687220A (en) * | 2021-03-09 | 2022-07-01 | 上海爱尔企业发展股份有限公司 | Cool feeling finishing agent and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN105369602A (en) * | 2014-08-28 | 2016-03-02 | 青岛鑫润土苗木专业合作社 | Antibacterial flame-retardant textile producing method |
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| CN106498706A (en) * | 2016-10-25 | 2017-03-15 | 苏州维度丝绸有限公司 | A kind of processing technique of water proof type silk fabrics |
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| CN1388223A (en) * | 2002-06-04 | 2003-01-01 | 华东理工大学 | Emulsified microcrystalline wax and its prepn |
| CN105369602A (en) * | 2014-08-28 | 2016-03-02 | 青岛鑫润土苗木专业合作社 | Antibacterial flame-retardant textile producing method |
| CN106479303A (en) * | 2016-08-31 | 2017-03-08 | 秦瑶 | A kind of water-proof antibiotic coating |
| CN106498706A (en) * | 2016-10-25 | 2017-03-15 | 苏州维度丝绸有限公司 | A kind of processing technique of water proof type silk fabrics |
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| CN114687220A (en) * | 2021-03-09 | 2022-07-01 | 上海爱尔企业发展股份有限公司 | Cool feeling finishing agent and preparation method and application thereof |
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