CN110416573A - Cold module, fuel cell ICS intercooler system and its working method in one kind - Google Patents

Cold module, fuel cell ICS intercooler system and its working method in one kind Download PDF

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Publication number
CN110416573A
CN110416573A CN201910802376.7A CN201910802376A CN110416573A CN 110416573 A CN110416573 A CN 110416573A CN 201910802376 A CN201910802376 A CN 201910802376A CN 110416573 A CN110416573 A CN 110416573A
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China
Prior art keywords
fuel cell
cold
air
thermo
module
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CN201910802376.7A
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CN110416573B (en
Inventor
张伟明
杨春华
陶诗涌
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Sichuan Rong Innovation Power System Co Ltd
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Sichuan Rong Innovation Power System Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029Heat exchange using liquids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074Heat exchange unit structures specially adapted for fuel cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126Humidifying
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04701Temperature
    • H01M8/04708Temperature of fuel cell reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04701Temperature
    • H01M8/04738Temperature of auxiliary devices, e.g. reformer, compressor, burner
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The present invention provides module cold in one kind, fuel cell ICS intercooler system and its working methods.Cold module includes two thermo-electric generation chip arrays in described, and the hot face of thermo-electric generation chip arrays is oppositely arranged, and is provided with intercooler between hot face;The huyashi-chuuka (cold chinese-style noodles) of two thermo-electric generation chip arrays is provided with a water tank.In cold module can be applied in fuel cell system.The configuration of the present invention is simple, deft design, and Maintenance free, movement-less part, no medium leakage, small in size, light-weight, conveniently moving, long service life, environmental-friendly to wait remarkable advantages, the thermo-electric generation cold and hot surface temperature difference is bigger, and efficiency is higher.Therefore, the present invention has fabulous application prospect.

Description

Cold module, fuel cell ICS intercooler system and its working method in one kind
Technical field
The invention belongs to fuel cells applications technical fields, more particularly to cold system in module cold in one kind, fuel cell System and its working method.
Background technique
The chemical energy being stored in fuel is directly changed into electric energy by electrochemical reaction by fuel battery energy, not by Kano The limitation of circulation, usual transfer efficiency is 50% or more, it is considered to be the generation technology of 21 century first choice.
High power fuel cell generallys use air compressor machine supply air, and the air after being pressurized is through overcompression, gas molecule Between gap become smaller, activity aggravation, process of this acting will generate heat, increase gas temperature sharply, and fuel The intake air temperature of battery is excessively high to may cause the system failure, or even damage battery pile, intake air temperature should control the work in battery pile Make near temperature, therefore in order to maintain reasonable intake air temperature, it is necessary to be cooled down to through the compressed air of air compressor machine.It is logical The compressed air cooling system being often used is intercooler, and traditional intercooler either air-cooled intercooler or water cooling intercooler are all It is to dissipate the heat of high temperature compressed air, is not used.It may be up to 150 by the compressed air themperature of air compressor machine DEG C, and the operating temperature of fuel cell is only 60-70 DEG C, there is the biggish temperature difference, but waste heat is not utilized, make At energy waste.
It will be very significant if a kind of technical solution for making full use of operation of fuel cells waste heat can be provided.
Summary of the invention
To solve the above problems, the present invention provides module cold in one kind, fuel cell ICS intercooler system and its working methods.
Cold module includes two thermo-electric generation chip arrays in described, and the hot face of thermo-electric generation chip arrays is oppositely arranged, hot face Between be provided with intercooler;The huyashi-chuuka (cold chinese-style noodles) of two thermo-electric generation chip arrays is provided with a water tank;The side of two water tanks is all provided with It is equipped with coolant inlet, the other side is provided with cooling liquid outlet;Intercooler side is provided with high temperature compressed air entrance, another Side is provided with low temperature compressed air outlet;The thermo-electric generation chip arrays are provided with electric energy output end.
Further, the hot face of the thermo-electric generation chip arrays and the heat-dissipating pipe and fin of intercooler fit closely.
Further, phase-change heat-storage material is filled between the heat-dissipating pipe and fin of intercooler.
Further, the thermoelectric generation film of thermo-electric generation chip arrays is made of semi-conductor thermoelectric material.
The fuel cell ICS intercooler system include fuel cell pack, air compressor machine, it is above-mentioned in cold module, air humidifier, Fuel cell cooling system, DC-DC power module, radiator, cooling circulating water pump;
Fuel cell pack has cooling liquid outlet, coolant inlet, air intake, air outlet slit, hydrogen inlet, hydrogen to go out Mouthful;Air humidifier is provided with dry gas inlet, humidification gas vent, air exit, cathode exhaust gas entrance.
Its connection relationship of each section are as follows:
The cooling liquid outlet of cold module, the coolant liquid of fuel cell pack go out in the coolant inlet connection of fuel cell pack Mouth connection radiator inlet;Radiator outlet connects cooling circulating water pump intake, cold mould in the outlet connection of cooling circulating water pump Block coolant inlet;The humidification gas vent of air humidifier connects fuel cell pack air intake, the connection of cathode exhaust gas entrance Fuel cell pack air outlet slit, air exit discharge exhaust gas.
The high temperature compressed air entrance connection air compressor machine outlet of ICS intercooler system, low temperature compressed air outlet connection air wetting The dry gas inlet of device;In cold module electric energy output end connect DC-DC power module.
Further, the system also includes the fuel cell hydrogen supplies for being provided with air supply outlet and hydrogen reflux inlet System, air supply outlet connect the hydrogen inlet of fuel cell pack, and hydrogen reflux inlet connects the hydrogen outlet of fuel cell pack.
Further, the system also includes further including energy-storage battery, it is electric that DC-DC power module output end connects energy storage Pond.
Further, the system controls DC-DC power module using CAN bus.
The working method of above-mentioned fuel cell ICS intercooler system, includes the following steps:
Step 1: fuel cell, cooling circulating water pump work, cooling circulating water pump Xiang Zhongleng module export coolant liquid;It is empty Press compression air, air by compression and temperature increase, high temperature compressed air by high temperature compressed air entrance be input in it is cold Module.
Step 2: high temperature compressed air flow through in cold module, transfer heat to thermo-electric generation chip arrays, cooled down; Coolant liquid flows through the heat that water tank takes away thermoelectric generation film array cold-end.
Step 3: the cold and hot both ends of thermo-electric generation chip arrays generate the temperature difference, and thermo-electric generation chip arrays export electric energy and give DC-DC electricity Source module.
Further, in step 2, heat transfer is to the phase-change heat-storage material in heat-dissipating pipe in intercooler and fin gap.
The invention has the benefit that
The present invention devises a kind of novel ICS intercooler system, can be preferably suitable for fuel cell system, can be preferable Generated electricity using the thermal energy of high temperature compressed air, and cool down after high temperature compressed air can be transferred directly to fuel cell into Row utilizes.
The configuration of the present invention is simple, deft design, and Maintenance free, movement-less part, no medium leakage, small in size, weight Gently, conveniently moving, long service life, environmental-friendly equal remarkable advantages, the thermo-electric generation cold and hot surface temperature difference is bigger, and efficiency is higher.Cause This, the present invention has fabulous application prospect.
Detailed description of the invention
Fig. 1 be in cold modular structure schematic diagram.
Fig. 2 is fuel cell ICS intercooler system structural schematic diagram.
In figure: 1: fuel cell pack;2: air compressor machine;3: in cold module;31: intercooler;32: thermo-electric generation chip arrays;33: Cold end water tank;34: coolant inlet;35: cooling liquid outlet;36: high temperature compressed air entrance;37: low temperature compressed air outlet; 4: humidifier;5: hydrogen supply system;6: fuel cell cooling system;61: radiator;62: cooling circulating water pump;7:DC-DC Power module;8: energy-storage battery;9 electrical equipments.
Specific embodiment
The invention discloses modules 3 cold in one kind, the ICS intercooler system and its working method of a kind of fuel cell pack 1.
Cold module 3 in introducing first.As shown in Figure 1, the module is in layer structure, including two thermo-electric generation chip arrays 32, the hot face of thermo-electric generation chip arrays 32 is oppositely arranged, and intercooler 31 is provided between hot face;Two thermo-electric generation chip arrays 32 Huyashi-chuuka (cold chinese-style noodles) be provided with a water tank 33;The side of two water tanks 33 is provided with coolant inlet 34, and the other side is provided with cold But liquid outlet 35;31 side of intercooler is provided with high temperature compressed air entrance 36, and the other side is provided with low temperature compressed air outlet 37。
32 array of thermoelectric generation film is the array that multiple thermoelectric generation films are concatenated and compose in parallel.
The present invention recycles waste heat using semiconductor thermoelectric power generation technology, while cooling down for compressed air.Semiconductor temperature difference hair Thermal energy can be directly changed into electric energy by electric heating electric material, have structure simple, Maintenance free, movement-less part, no medium leakage, Small in size, light-weight, conveniently moving, long service life, environmental-friendly equal remarkable advantages.The bigger effect of the thermo-electric generation cold and hot surface temperature difference Rate is higher.Thermoelectric generation film is made of that semiconductor thermoelectric material is provided with electric energy output end.The electric energy of output is converted After can be carried out storage or use.
Preferably, the hot face of the thermo-electric generation chip arrays 32 is fitted closely with the heat-dissipating pipe and fin of intercooler 31.In Phase-change heat-storage material is filled between the heat-dissipating pipe and fin of cooler 31.Guarantee heating conduction.
Preferably, the huyashi-chuuka (cold chinese-style noodles) of two groups of thermo-electric generation chip arrays 32 is connected by heat conductive silica gel with two water tanks 33.Thermal conductive silicon Glue is high-end thermally conductive compound, will not solidification, will not be conductive characteristic, can be to avoid risks such as short circuits.
Preferably, two water tanks 33 share 34, cooling liquid outlets 35 of a coolant inlet.
The fuel cell ICS intercooler system using cold module 3 among the above is illustrated below with reference to Fig. 2.
The system include fuel cell pack 1, air compressor machine 2, in cold module 3, air humidifier 4, fuel cell cooling system 6, DC-DC power module 7, radiator 61, cooling circulating water pump 62.1 coolant liquid of fuel cell pack has cooling liquid outlet 35, cooling Liquid entrance 34, air intake, air outlet slit, hydrogen inlet, hydrogen outlet;Air humidifier 4 is provided with dry gas inlet, adds Humid gas outlet, air exit, cathode exhaust gas entrance.Radiator 61, cooling circulating water pump 62 belong to fuel cell heat dissipation system System.
Its connection relationship of each section are as follows:
Fuel cell pack 1 coolant inlet connection in cold module 3 cooling liquid outlet 35, fuel cell pack 1 it is cold But liquid outlet connection 61 entrance of radiator;The outlet of radiator 61 connection 62 entrance of cooling circulating water pump, cooling circulating water pump 62 Cold 3 coolant inlet 34 of module in outlet connection;Humidification gas vent connection 1 air of fuel cell pack of air humidifier 4 enters Mouthful, cathode exhaust gas entrance connects 1 air outlet slit of fuel cell pack, and air exit discharges exhaust gas.
The high temperature compressed air entrance 36 of ICS intercooler system connects air compressor machine 2 and exports, and 37 connection of low temperature compressed air outlet is empty The dry gas inlet of gas humidifier 4;In cold 3 electric energy output end of module connect DC-DC power module 7.
Further, it is also provided with the fuel cell hydrogen supply system 5 of air supply outlet and hydrogen reflux inlet, is supplied Gas outlet connection 1 hydrogen inlet of fuel cell pack, hydrogen reflux inlet connect 1 hydrogen outlet of fuel cell pack.
It further, further include energy-storage battery 8,7 output end of DC-DC module connects energy-storage battery 8 and/or electrical equipment 9. DC-DC power module realizes constant current and constant voltage output, and is controlled by CAN bus, can be instructed by CAN and different output electricity are arranged Press grade (such as 12V, 24V, 48V etc.) and current value.
The workflow of above system is illustrated below.
Step 1: system starting, fuel cell, cooling circulating water pump 62, air humidifier 4, in cold module 3 work, it is cold But 62 Xiang Zhongleng module 3 of water circulating pump exports coolant liquid;2 compressed air of air compressor machine, air temperature raising by compression become high Warm compressed gas, high temperature compressed air by high temperature compressed air entrance 36 be input in cold module 3.
Step 2: high temperature compressed air flow through in cold module 3, transfer heat to thermo-electric generation chip arrays 32, dropped Temperature;Coolant liquid flows through water tank 33, takes away the heat of 32 cold end of thermo-electric generation chip arrays.
Step 3: the cold and hot both ends of thermo-electric generation chip arrays 32 generate the temperature difference, and thermo-electric generation chip arrays 32 export electric energy to DC- DC power module 7.
It certainly, include its inputting hydrogen to fuel cell pack 1, and fire when fuel cell hydrogen supply system 5 is set Expect that battery pile 1 exports the step of hydrogen is to 5 hydrogen reflux inlet of hydrogen supply system.
When energy-storage battery 8 is set, include the steps that DC-DC power module 7 exports electric energy and stored to energy-storage battery 8.

Claims (10)

1. cold module in one kind, which is characterized in that including two thermo-electric generation chip arrays, the hot face of thermo-electric generation chip arrays is opposite It is arranged, is provided with intercooler between hot face;The huyashi-chuuka (cold chinese-style noodles) of two thermo-electric generation chip arrays is provided with a water tank;Two water tanks Side is provided with coolant inlet, and the other side is provided with cooling liquid outlet;Intercooler side is provided with high temperature compressed air Entrance, the other side are provided with low temperature compressed air outlet;The thermo-electric generation chip arrays are provided with electric energy output end.
2. cold module in as described in claim 1, which is characterized in that the hot face of the thermo-electric generation chip arrays and dissipating for intercooler Heat pipe and fin fit closely.
3. cold module in as claimed in claim 2, which is characterized in that stored up between the heat-dissipating pipe and fin of intercooler filled with phase transformation Hot material.
4. cold module in as described in claim 1, which is characterized in that the thermoelectric generation film of thermo-electric generation chip arrays is semiconductor temperature Poor power generation sheet.
5. device for cooling in a kind of fuel cell, which is characterized in that any including fuel cell pack, air compressor machine, such as claim 1-4 Cold module, air humidifier, fuel cell cooling system, DC-DC power module, radiator, cooling circulating water in described in Pump;
Fuel cell pack has cooling liquid outlet, coolant inlet, air intake, air outlet slit, hydrogen inlet, hydrogen outlet;It is empty Gas humidifier is provided with dry gas inlet, humidification gas vent, air exit, cathode exhaust gas entrance;
Its connection relationship of each section are as follows:
The cooling liquid outlet of cold module, the cooling liquid outlet of fuel cell pack connect in the coolant inlet connection of fuel cell pack Connect radiator inlet;Radiator outlet connects cooling circulating water pump intake, and cold module is cold in the outlet connection of cooling circulating water pump But liquid entrance;The humidification gas vent of air humidifier connects fuel cell pack air intake, and cathode exhaust gas entrance connects fuel Battery pile air outlet slit, air exit discharge exhaust gas;
The high temperature compressed air entrance connection air compressor machine outlet of ICS intercooler system, low temperature compressed air outlet connection air humidifier Dry gas inlet;In cold module electric energy output end connect DC-DC power module.
6. device for cooling in a kind of fuel cell as claimed in claim 5, which is characterized in that further include be provided with air supply outlet and The fuel cell hydrogen supply system of hydrogen reflux inlet, air supply outlet connect the hydrogen inlet of fuel cell pack, hydrogen reflux The hydrogen outlet of entrance connection fuel cell pack.
7. device for cooling in a kind of fuel cell as claimed in claim 5, which is characterized in that further include energy-storage battery, DC-DC electricity Source module output end connects energy-storage battery.
8. device for cooling in a kind of fuel cell as claimed in claim 6, which is characterized in that utilize CAN bus control DC-DC electricity Source module.
9. such as the working method of device for cooling in a kind of described in any item fuel cells of claim 5-8, which is characterized in that including Following steps:
Step 1: fuel cell, cooling circulating water pump work, cooling circulating water pump Xiang Zhongleng module export coolant liquid;Air compressor machine Compressed air, air by compression and temperature increase, high temperature compressed air by high temperature compressed air entrance be input in cold module;
Step 2: high temperature compressed air flow through in cold module, transfer heat to thermo-electric generation chip arrays, cooled down;It is cooling Liquid stream takes away the heat of thermoelectric generation film array cold-end through water tank;
Step 3: the cold and hot both ends of thermo-electric generation chip arrays generate the temperature difference, and thermo-electric generation chip arrays export electric energy and give DC-DC power source mould Block.
10. the working method of device for cooling in a kind of fuel cell as claimed in claim 9, which is characterized in that in step 2, heat Amount passes to the phase-change heat-storage material in intercooler in heat-dissipating pipe and fin gap.
CN201910802376.7A 2019-08-28 2019-08-28 Intercooler module, fuel cell intercooler system and working method of fuel cell intercooler system Active CN110416573B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006024418A (en) * 2004-07-07 2006-01-26 Nissan Motor Co Ltd Fuel cell system
CN106848496A (en) * 2017-02-10 2017-06-13 西南交通大学 A kind of fuel cell tramcar residual neat recovering system based on thermo-electric generation
CN107901772A (en) * 2017-10-27 2018-04-13 江苏理工学院 A kind of fuel cell temperature difference electricity generation device applied to automobile combines energy supplying system
CN109159657A (en) * 2018-07-24 2019-01-08 中国第汽车股份有限公司 Fuel cell thermal management system of whole
CN209129735U (en) * 2018-10-18 2019-07-19 上海汽车集团股份有限公司 Temperature difference power generation type charge inter cooling system
CN210272553U (en) * 2019-08-28 2020-04-07 四川荣创新能动力系统有限公司 Inter-cooling module and inter-cooling system of fuel cell

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006024418A (en) * 2004-07-07 2006-01-26 Nissan Motor Co Ltd Fuel cell system
CN106848496A (en) * 2017-02-10 2017-06-13 西南交通大学 A kind of fuel cell tramcar residual neat recovering system based on thermo-electric generation
CN107901772A (en) * 2017-10-27 2018-04-13 江苏理工学院 A kind of fuel cell temperature difference electricity generation device applied to automobile combines energy supplying system
CN109159657A (en) * 2018-07-24 2019-01-08 中国第汽车股份有限公司 Fuel cell thermal management system of whole
CN209129735U (en) * 2018-10-18 2019-07-19 上海汽车集团股份有限公司 Temperature difference power generation type charge inter cooling system
CN210272553U (en) * 2019-08-28 2020-04-07 四川荣创新能动力系统有限公司 Inter-cooling module and inter-cooling system of fuel cell

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