CN110409212A - A kind of tissue and its production technology of sandwich style - Google Patents
A kind of tissue and its production technology of sandwich style Download PDFInfo
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- CN110409212A CN110409212A CN201910656950.2A CN201910656950A CN110409212A CN 110409212 A CN110409212 A CN 110409212A CN 201910656950 A CN201910656950 A CN 201910656950A CN 110409212 A CN110409212 A CN 110409212A
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
- D21C5/025—De-inking
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
- D21C5/025—De-inking
- D21C5/027—Chemicals therefor
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/14—Secondary fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/10—Retention agents or drainage improvers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
- D21H21/20—Wet strength agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Paper (AREA)
- Sanitary Thin Papers (AREA)
Abstract
The invention belongs to field of papermaking, specifically disclose the tissue and its production technology of a kind of sandwich style, its production technology includes preparing primary slurry, prepare waste paper pulp, Top wire former and finished product prepare four steps, primary slurry whitewashing Top wire former is first formed into the first l Water Paper page, waste paper pulp is whitewashed to forming the second l Water Paper page on the first l Water Paper page, primary slurry is whitewashed again and forms third l Water Paper page to the second l Water Paper page, or Top wire former obtains the first primary l Water Paper page layer respectively, middle layer (waste sheet layer) and the second primary l Water Paper page layer, again successively by the first primary l Water Paper page layer, middle layer and the second primary l Water Paper page layer superposition;It obtains that centre is waste paper layer and two sides are the sandwich style tissue of primary paper layer, had not only met the performance requirement of tissue using tissue prepared by the production technology, but also recycled waste paper, energy is greatly saved.
Description
Technical field
The invention belongs to field of papermaking more particularly to the tissues and its production technology of a kind of sandwich style.
Background technique
Paper pulp is the base stock of papermaking and the main reason of papermaking consumptive material.Usually manufacture paper pulp raw material is with plant
It is main, four major class: stem fiber-like, bast fiber class, seed hair fiber class and lumber fibre class can be divided into according to its fiber feature, especially with
Lumber fibre class accounts for more, while lignocellulose quality is also best, and price is also most expensive;It is divided into wood pulp, straw pulp, bamboo by raw material variety
Slurry, cotton pulp, secondary stock etc.;It is divided into natural color pulp, partly bleach pulp, bleached pulp, refined stock etc. by working depth;These paper pulp were being worked overtime
The material and the energy that journey is consumed are not quite similar, while price also differs huge.
The paper for daily uses such as tissue, toilet paper account for very big ratio, and mentioning with living standard in paper industry
Height, demand of the people to paper for daily use are increasing, it is desirable that higher and higher.Tissue is mainly used for the places such as hotel, office building
It wipes and uses after washing one's hands, be a kind of expendable perishable consumer goods.The performance requirement of tissue are as follows: higher dry strength and
Wet strength, lesser dry and wet intensity difference, certain water imbibition, pliability and evenness etc..Although tissue is with higher dry strong
Degree and wet strength, but its water absorption is little, needs to consume more paper when absorbing a certain amount of water.
Common tissue, toilet paper are usually closed by several layers of letterweights on the market, and with 100% Original Pulp purification and
At tissue papery it is good, and microbiological indicator, physical index are superior to other raw materials, but such tissue need it is more
Tree resources, cause the waste of tree resources very serious.Also have in current paper technology and produces environmental protection using secondary stock
Type tissue.Be limited to the physical property of secondary stock, quality of finished paper will receive large effect, as stiffness or tensile strength without
Method reaches standard.Moreover, the utilization of secondary stock increases the content of microorganism, compared with the finished paper of Original Pulp manufacture also
There is microorganism to remain hidden danger.
Patent document CN107881829A discloses a kind of method of pulp from decoloured waste paper production tissue, carries out to waste paper broken
Solution, pulping again after filtering and impurity removing, use cellulase and hemicellulase to carry out size degradation, In to fiber again during pulping
Flocculant is added in filter process, using modified deinking agent in deinking step, improves regeneration tissue water absorbing properties, again
With certain stiff degree.
Patent document CN109667186A is added to the secondary stock of a part in the manufacturing process of tissue, has saved original
The usage amount of raw wood pulp, while the anti-of protonation chitosan is utilized by addition protonation chitosan in slurry in the fabrication process
Bacterium feature eliminates the excessively high hidden danger of secondary stock bring content of microorganisms, and wet to promote paper with AKD substitution PAE wet strength agent
Intensity.
But it is above-mentioned using secondary stock production tissue tensile strength it is lower, wipe hand using when easily fester, produce
The quality of product cannot be guaranteed.
Therefore, it is necessary to provide a kind of technology for making hand tissue of environmental protection, inhaled using the tissue of production technology production
Water is big, and not only dry strength and wet strength with higher, reduce the content of microorganisms in tissue, also with higher anti-
Zhang Qiangdu.
Summary of the invention
It is an object of the invention to combine the deficiencies in the prior art, a kind of production technology of sandwich style tissue is provided,
Solve the problems, such as that existing protoplasm tissue high production cost, secondary stock tissue tensile strength are low.
The present invention also provides a kind of tissue, the tissue tensile strength is higher, wipe hand using when be not easy rotten, Er Qiewei
Biological residual content is low, can satisfy the quality requirement of tissue.
In order to achieve the above objectives, technical scheme is as follows:
A kind of technology for making hand tissue of sandwich style, includes the following steps:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: being discongested and be beaten using mill, obtain the waste paper pulp that beating degree is 30-35 ° of SR;
(3) Top wire former:
Primary slurry whitewashing Top wire former is formed into the first l Water Paper page, waste paper pulp is whitewashed to being formed on the first l Water Paper page
Second l Water Paper page, then primary slurry is whitewashed and forms third l Water Paper page to the second l Water Paper page, three layers of l Water Paper page are made;
Or Top wire former obtains the first primary l Water Paper page layer, middle layer and the second primary l Water Paper page layer respectively;Wherein, described
Middle layer the preparation method comprises the following steps: waste paper pulp is sent into horizontal wind-tunnel from whitewashing material mouth, uniformly spread, whitewash to wire-cloth, paper
Slurry forms page, as middle layer on wire-cloth;
(4) prepared by finished product: by three layers of l Water Paper page dewatering press, being dried to obtain tissue finished product;
Or the first primary l Water Paper page layer and the second primary l Water Paper page layer are squeezed respectively it is dry after, it is former to obtain dry first
Raw page layer and the second primary page layer, then after the first primary page layer, middle layer and the second primary page layer are sequentially overlapped
Pressing obtains tissue finished product.
Preferably, the middle layer can be fabricated separately, and can also make on the wire-cloth for being covered with the first l Water Paper page;It is intermediate
Layer need to not need to dry, and depending on pulp case, if it is wet pulp, normal temperature air is changed to high temperature air, upper net filtration is cooled to
Shape water evaporation.
Preferably, when preparing waste paper pulp, first by waste paper oxidation, alkali carries, then carry out pulping, defibrination obtains waste paper pulp.
Preferably, chemicals used in the oxidation is at least one of hypochlorite, hydrogen peroxide, potassium peroxide.
Preferably, the additive amount of the chemicals is the 2-5% of slurry weight, handles 20- under the conditions of 45-100 DEG C
Then 100min is concentrated to get oxidation slurry.
Preferably, the operation of alkali carries are as follows: the pH of oxidation slurry is adjusted to 11-13 with sodium hydroxide, is handled at 45-100 DEG C
Then 20-100min is concentrated to get alkali carries slurry.
Preferably, alkali carries slurry carries out concentration again after breaing up.
Preferably, the slurry after alkali carries carries out pulping processing after washing.
Use clear water to being broken up the slurry washing of concentration to pH as 6-9 when washing, and to the addition in pulp after cleaning, it will
Obtained good slurry is used for the production of tissue.
The specific steps of pulping are as follows: size degradation under the conditions of 80-100 DEG C obtains waste paper by the waste paper of collection using drum unit
Slurry, pulping again after filtering and impurity removing, and hydrolysis enzymatic treatment is added, deinking agent is then added into obtained slurry and carries out at deinking
Reason.
Preferably, hydrolase is cellulase and hemicellulase, it is preferable that the cellulase and hemicellulase
Mass ratio is 1-3:1.The additive amount of hydrolase is the 0.4-0.8% of slurry weight.
Preferably, the additive amount of deinking agent is the 0.3-1% of slurry weight.
Preferably, the deinking agent is made of each raw material of following parts by weight are as follows: dodecyl benzene sulfonic acid triethanolamine soap
3-5 parts of 10-20 parts, 10-18 parts of TX-10, polyethylene glycol oxide or polypropylene oxide, 5-15 parts of polyvinyl alcohol, 50-100 parts of water;
The temperature of deinking processing is 70-90 DEG C.
Preferably, antibacterial agent, wet strength agent, retention agent are added into slurry after mill defibrination for deinking treated slurry
Waste paper pulp is obtained with cationic starch;The antibacterial agent, wet strength agent, retention agent and cationic starch additive amount be described useless
0.02-0.1%, 0.1-0.4%, 0.2-0.5%, 0.2-0.5% of the weight of pulp material.
Preferably, the dosage of the cationic starch is more than the dosage of wet strength agent.
Preferably, the antibacterial agent is guanidine bactericides or quaternary ammonium salt antiseptic or sulfonic acid silver antibacterial agent.
Preferably, the retention agent is anionic polyacrylamide or aluminium polychloride.
Preferably, the retention agent is the anionic polyacrylamide that molecular weight is 400-800.
Preferably, the wet strength agent is Lauxite or polyethyleneimine.
The present invention also provides a kind of paper manufacturing systems that the production technology uses, including wet end, press section, drying portion,
Primary slurry is whitewashed and forms the to wet end by calender, driving section and primary head box and waste paper head box, primary head box
One l Water Paper page, under the action of driving section, waste paper pulp is whitewashed and forms middle layer, primary head box to wet end by waste paper head box
Primordial soup is whitewashed and forms the second l Water Paper page to middle layer, three layers of l Water Paper page are made;Three layers of l Water Paper page are through press section, drying portion
And calender handles to obtain tissue finished product.
The present invention also provides a kind of tissues of production technology production, and the tissue is by primary slurry and waste paper
De-watering of slurries squeezing is prepared, and the paper layer that the waste paper pulp is formed is set between the paper layer that the primary slurry is formed.
The invention has the benefit that
(1) primary slurry whitewashing Top wire former is formed the first l Water Paper by the technology for making hand tissue of sandwich style of the invention
Waste paper pulp is whitewashed to forming the second l Water Paper page on the first l Water Paper page, then primary slurry is whitewashed to the second l Water Paper page shape by page
At third l Water Paper page, three layers of l Water Paper page are made;Or Top wire former obtains the first primary l Water Paper page layer, middle layer (waste sheet respectively
Layer) and the second primary l Water Paper page layer, then be successively superimposed the first primary l Water Paper page layer, middle layer and the second primary l Water Paper page layer.
Waste paper pulp is high by the quality that processing obtains, and can be combined into one with primary slurry, increases the thickness of tissue;And it is former
Waste paper layer is set among raw paper layer, increases the intensity of tissue entirety, this makes the water imbibition of tissue, wipes when hand uses
Intensity is improved;
(2) middle layer can be fabricated separately, and can also make on the wire-cloth for being covered with the first l Water Paper page;Middle layer needs
It does not need to dry, depending on pulp case, if it is wet pulp, normal temperature air is changed to high temperature air, upper net filtration cooling forming water
Steam raising;The production used time can be shortened when middle layer is using dry paper pulp, improve productivity;Manufactured finished product more Gabon
Pine, feeling is better, and water absorbing properties are stronger.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail.
Embodiment 1
A kind of sandwich style technology for making hand tissue, includes the following steps:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: 3% potassium peroxide of waste paper its weight first being aoxidized into 40min under the conditions of 60 DEG C,
Then it is concentrated to get oxidation slurry;
The pH of oxidation slurry is adjusted at 12,70 DEG C with sodium hydroxide and handles 30min, alkali carries are concentrated to get after breaing up
Slurry;Use clear water to being broken up the slurry washing of concentration to pH as 8, and to the addition in pulp washing after cleaning after, at 90 DEG C
Under the conditions of size degradation, pulping again after filtering and impurity removing, and 0.6% hydrolase (cellulase and the hemicellulose of slurry weight is added
Plain enzyme 2:1) processing, the deinking agent (composition: dodecyl benzene sulfonic acid of slurry weight 0.6% is then added into obtained slurry
15 parts of triethanolamine soap, 16 parts of TX-10,4 parts of polyethylene glycol oxide, 10 parts of polyvinyl alcohol, 70 parts of water), at 80 DEG C of progress deinkings
0.06% sulfonic acid silver, 0.3% Lauxite, 0.3% are added into slurry after mill defibrination for reason, deinking treated slurry
Anionic polyacrylamide (M=400) and 0.4% cationic starch obtain the waste paper pulp that beating degree is 30-35 ° of SR;
(3) Top wire former: primary slurry whitewashing Top wire former is formed into the first l Water Paper page, waste paper pulp is whitewashed to first
The second l Water Paper page is formed on l Water Paper page, then primary slurry is whitewashed and forms third l Water Paper page to the second l Water Paper page, and obtained three layers wet
Page;
(4) prepared by finished product: by three layers of l Water Paper page dewatering press, being dried to obtain tissue finished product.
Embodiment 2
A kind of sandwich style technology for making hand tissue, includes the following steps:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: first aoxidizing 2% sodium hypochlorite of waste paper its weight under the conditions of 45 DEG C
Then 100min is concentrated to get oxidation slurry;
The pH of oxidation slurry is adjusted at 11,45 DEG C with sodium hydroxide and handles 100min, alkali is concentrated to get after breaing up
Warehouse material;Use clear water to being broken up the slurry washing of concentration to pH as 6, and to the addition in pulp washing after cleaning after, 80
Size degradation under the conditions of DEG C, pulping again after filtering and impurity removing, and 0.4% hydrolase (cellulase and the half fiber of slurry weight is added
Tie up element enzyme 1:1) processing, the deinking agent (composition: detergent alkylate sulphur of slurry weight 0.3% is then added into obtained slurry
10 parts of triethylenetetraminehexaacetic acid hydramine soap, 18 parts of TX-10,3 parts of polypropylene oxide, 15 parts of polyvinyl alcohol, 50 parts of water), in 70 DEG C of progress deinkings
0.02% quaternary ammonium salt antiseptic, 0.4% polyethylene are added into slurry after mill defibrination for processing, deinking treated slurry
Imines, 0.5% anionic polyacrylamide (M=800) and 0.5% cationic starch, obtaining beating degree is the useless of 30-35 ° of SR
Pulp material;
(3) Top wire former: by the whitewashing of primary slurry, Top wire former obtains the first primary l Water Paper page layer and second primary respectively
L Water Paper page layer;Waste paper pulp after drying is sent into horizontal wind-tunnel from whitewashing material mouth, uniformly spreads, whitewashes to wire-cloth, paper pulp
Page is formed on wire-cloth, and middle layer is made;
(4) prepared by finished product: after the first primary l Water Paper page layer and the second primary l Water Paper page layer are squeezed drying respectively, being done
The primary page layer of dry first and the second primary page layer, then by the first primary page layer, middle layer and the second primary page layer
Pressing obtains tissue finished product after being sequentially overlapped.
Embodiment 3
A kind of sandwich style technology for making hand tissue, includes the following steps:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: first the potassium peroxide of 2.5% hydrogen peroxide of waste paper its weight and 2.5% existing
20min is aoxidized under the conditions of 100 DEG C, is then concentrated to get oxidation slurry;
The pH of oxidation slurry is adjusted at 13,100 DEG C with sodium hydroxide and handles 20min, alkali is concentrated to get after breaing up
Warehouse material;Use clear water to being broken up the slurry washing of concentration to pH as 9, and to the addition in pulp washing after cleaning after, 100
Size degradation under the conditions of DEG C, pulping again after filtering and impurity removing, and 0.8% hydrolase (cellulase and the half fiber of slurry weight is added
Tie up element enzyme 3:1) processing, the deinking agent (composition: dodecyl benzene sulfonic acid of slurry weight 1% is then added into obtained slurry
20 parts of triethanolamine soap, 10 parts of TX-10,5 parts of polyethylene glycol oxide, 5 parts of polyvinyl alcohol, 100 parts of water), at 90 DEG C of progress deinkings
0.1% polyguanidine salt antibacterial agent, 0.1% polyethyleneimine are added into slurry after mill defibrination for reason, deinking treated slurry
Amine, 0.2% aluminium polychloride and 0.2% cationic starch obtain the waste paper pulp that beating degree is 30-35 ° of SR;
(3) Top wire former: primary slurry whitewashing Top wire former is formed into the first l Water Paper page, waste paper pulp is whitewashed to first
The second l Water Paper page is formed on l Water Paper page, then primary slurry is whitewashed and forms third l Water Paper page to the second l Water Paper page, and obtained three layers wet
Page;
(4) prepared by finished product: by three layers of l Water Paper page dewatering press, being dried to obtain tissue finished product.
Comparative example 1
(comparing with embodiment 1, pH value is different)
A kind of sandwich style technology for making hand tissue, includes the following steps:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: 3% potassium peroxide of waste paper its weight first being aoxidized into 40min under the conditions of 60 DEG C,
Then it is concentrated to get oxidation slurry;
The pH of oxidation slurry is adjusted at 9,70 DEG C with sodium hydroxide and handles 30min, alkali carries are concentrated to get after breaing up
Slurry;Use clear water to being broken up the slurry washing of concentration to pH as 5, and to the addition in pulp washing after cleaning after, at 90 DEG C
Under the conditions of size degradation, pulping again after filtering and impurity removing, and 0.6% hydrolase (cellulase and the hemicellulose of slurry weight is added
Plain enzyme 2:1) processing, the deinking agent (composition: dodecyl benzene sulfonic acid of slurry weight 0.6% is then added into obtained slurry
15 parts of triethanolamine soap, 16 parts of TX-10,4 parts of polyethylene glycol oxide, 10 parts of polyvinyl alcohol, 70 parts of water), at 80 DEG C of progress deinkings
0.06% sulfonic acid silver, 0.3% Lauxite, 0.3% are added into slurry after mill defibrination for reason, deinking treated slurry
Anionic polyacrylamide (M=400) and 0.4% cationic starch obtain the waste paper pulp that beating degree is 30-35 ° of SR;
(3) Top wire former: primary slurry whitewashing Top wire former is formed into the first l Water Paper page, waste paper pulp is whitewashed to first
The second l Water Paper page is formed on l Water Paper page, then primary slurry is whitewashed and forms third l Water Paper page to the second l Water Paper page;Obtained three layers wet
Page;
(4) prepared by finished product: by three layers of l Water Paper page dewatering press, being dried to obtain tissue finished product.
Comparative example 2
(comparing with embodiment 1, wet strength agent and cationic starch total amount are constant, and wet strengthening agent is more than cationic starch dosage)
A kind of sandwich style technology for making hand tissue, includes the following steps:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: 3% potassium peroxide of waste paper its weight first being aoxidized into 40min under the conditions of 60 DEG C,
Then it is concentrated to get oxidation slurry;
The pH of oxidation slurry is adjusted at 12,70 DEG C with sodium hydroxide and handles 30min, alkali carries are concentrated to get after breaing up
Slurry;Use clear water to being broken up the slurry washing of concentration to pH as 8, and to the addition in pulp washing after cleaning after, at 90 DEG C
Under the conditions of size degradation, pulping again after filtering and impurity removing, and 0.6% hydrolase (cellulase and the hemicellulose of slurry weight is added
Plain enzyme 2:1) processing, the deinking agent (composition: dodecyl benzene sulfonic acid of slurry weight 0.6% is then added into obtained slurry
15 parts of triethanolamine soap, 16 parts of TX-10,4 parts of polyethylene glycol oxide, 10 parts of polyvinyl alcohol, 70 parts of water), at 80 DEG C of progress deinkings
0.06% sulfonic acid silver, 0.5% Lauxite, 0.3% are added into slurry after mill defibrination for reason, deinking treated slurry
Anionic polyacrylamide (M=400) and 0.2% cationic starch obtain the waste paper pulp that beating degree is 30-35 ° of SR;
(3) Top wire former: primary slurry whitewashing Top wire former is formed into the first l Water Paper page, waste paper pulp is whitewashed to first
The second l Water Paper page is formed on l Water Paper page, then primary slurry is whitewashed and forms third l Water Paper page to the second l Water Paper page;Obtained three layers wet
Page;
(4) prepared by finished product: by three layers of l Water Paper page dewatering press, being dried to obtain tissue finished product.
Comparative example 3
(compared with Example 1, hydrolase is different)
A kind of sandwich style technology for making hand tissue, includes the following steps:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: 3% potassium peroxide of waste paper its weight first being aoxidized into 40min under the conditions of 60 DEG C,
Then it is concentrated to get oxidation slurry;
The pH of oxidation slurry is adjusted at 12,70 DEG C with sodium hydroxide and handles 30min, alkali carries are concentrated to get after breaing up
Slurry;Use clear water to being broken up the slurry washing of concentration to pH as 8, and to the addition in pulp washing after cleaning after, at 90 DEG C
Under the conditions of size degradation, pulping again after filtering and impurity removing, and the 0.6% cellulase processing of slurry weight is added, then to obtaining
Slurry in be added slurry weight 0.6% deinking agent (composition: 15 parts of dodecyl benzene sulfonic acid triethanolamine soap, TX-10 16
Part, 4 parts of polyethylene glycol oxide, 10 parts of polyvinyl alcohol, 70 parts of water), in 80 DEG C of progress deinking processing, deinking treated slurry is through grinding
After mill slurry, 0.06% sulfonic acid silver, 0.3% Lauxite, 0.3% anionic polyacrylamide (M=400) are added into slurry
With 0.4% cationic starch, the waste paper pulp that beating degree is 30-35 ° of SR is obtained;
(3) Top wire former: primary slurry whitewashing Top wire former is formed into the first l Water Paper page, waste paper pulp is whitewashed to first
The second l Water Paper page is formed on l Water Paper page, then primary slurry is whitewashed and forms third l Water Paper page to the second l Water Paper page;Obtained three layers wet
Page;
(4) prepared by finished product: by three layers of l Water Paper page dewatering press, being dried to obtain tissue finished product.
Comparative example 4
(compared with Example 1, the molecular weight of anionic polyacrylamide is different)
A kind of sandwich style technology for making hand tissue, includes the following steps:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: 3% potassium peroxide of waste paper its weight first being aoxidized into 40min under the conditions of 60 DEG C,
Then it is concentrated to get oxidation slurry;
The pH of oxidation slurry is adjusted at 12,70 DEG C with sodium hydroxide and handles 30min, alkali carries are concentrated to get after breaing up
Slurry;Use clear water to being broken up the slurry washing of concentration to pH as 8, and to the addition in pulp washing after cleaning after, at 90 DEG C
Under the conditions of size degradation, pulping again after filtering and impurity removing, and 0.6% hydrolase (cellulase and the hemicellulose of slurry weight is added
Plain enzyme 2:1) processing, the deinking agent (composition: dodecyl benzene sulfonic acid of slurry weight 0.6% is then added into obtained slurry
15 parts of triethanolamine soap, 16 parts of TX-10,4 parts of polyethylene glycol oxide, 10 parts of polyvinyl alcohol, 70 parts of water), at 80 DEG C of progress deinkings
0.06% sulfonic acid silver, 0.3% Lauxite, 0.3% are added into slurry after mill defibrination for reason, deinking treated slurry
Anionic polyacrylamide (M=1200) and 0.4% cationic starch obtain the waste paper pulp that beating degree is 30-35 ° of SR;
(3) Top wire former: primary slurry whitewashing Top wire former is formed into the first l Water Paper page, waste paper pulp is whitewashed to first
The second l Water Paper page is formed on l Water Paper page, then primary slurry is whitewashed and forms third l Water Paper page to the second l Water Paper page, and obtained three layers wet
Page;
(4) prepared by finished product: by three layers of l Water Paper page dewatering press, being dried to obtain tissue finished product.
Effect example
According to the experimental method that national standard GB/T " 24455-2009 tissue " is recorded, to embodiment 1-3 and comparative example 1-3 system
The tissue finished product obtained is tested for the property, and obtained performance parameter is as shown in table 1 below.
The performance parameter of 1 tissue of table
It can be seen that tissue provided by the invention has the performance parameters such as preferable water imbibition, tensile strength, antibacterial.
Above-mentioned detailed description is illustrating for one of them possible embodiments of the present invention, the embodiment not to
The scope of the patents of the invention is limited, all equivalence enforcements or change without departing from carried out by the present invention are intended to be limited solely by the technology of the present invention
In the range of scheme.
Claims (10)
1. a kind of technology for making hand tissue of sandwich style, which comprises the steps of:
(1) it prepares primary slurry: the Original Pulp mill after scattered slurry slagging-off is beaten;
(2) it prepares waste paper pulp: being discongested and be beaten using mill, obtain the waste paper pulp that beating degree is 30-35 ° of SR;
(3) Top wire former: primary slurry whitewashing Top wire former is formed into the first l Water Paper page, waste paper pulp is whitewashed to the first l Water Paper
The second l Water Paper page is formed on page, then primary slurry is whitewashed and forms third l Water Paper page to the second l Water Paper page, and three layers of l Water Paper page are made;
Or Top wire former obtains the first primary l Water Paper page layer, middle layer and the second primary l Water Paper page layer respectively;Wherein, the centre
Layer the preparation method comprises the following steps: waste paper pulp is sent into horizontal wind-tunnel from whitewashing material mouth, uniformly spread, whitewash to wire-cloth, paper pulp exists
Page, as middle layer are formed on wire-cloth;
(4) prepared by finished product: by three layers of l Water Paper page dewatering press, being dried to obtain tissue finished product;
Or the first primary l Water Paper page layer and the second primary l Water Paper page layer are squeezed respectively it is dry after, obtain the first dry primary paper
Page layer and the second primary page layer, then pressed after the first primary page layer, middle layer and the second primary page layer are sequentially overlapped
Obtain tissue finished product.
2. the technology for making hand tissue of sandwich style as described in claim 1, which is characterized in that when preparing waste paper pulp, first
By waste paper oxidation, alkali carries, then carry out pulping, defibrination obtains waste paper pulp.
3. the technology for making hand tissue of sandwich style as claimed in claim 2, which is characterized in that chemistry used in the oxidation
Product are at least one of hypochlorite, hydrogen peroxide, potassium peroxide;The additive amount of the chemicals is the 2- of slurry weight
5%, 20-100min is handled under the conditions of 45-100 DEG C, is then concentrated to get oxidation slurry.
4. the technology for making hand tissue of sandwich style as claimed in claim 2, which is characterized in that the specific steps of the alkali carries
Are as follows: the pH of oxidation slurry is adjusted to 11-13 with sodium hydroxide, 20-100min is handled at 45-100 DEG C, is then concentrated to get alkali carries
Slurry;Slurry after alkali carries carries out pulping processing again after washing.
5. the technology for making hand tissue of sandwich style as claimed in claim 2, which is characterized in that the specific steps of the pulping
Are as follows: using drum unit, by the waste paper of collection, size degradation under the conditions of 80-100 DEG C obtains secondary stock, pulping again after filtering and impurity removing, and
Hydrolysis enzymatic treatment is added, deinking agent is then added into obtained slurry and carries out deinking processing.
6. the technology for making hand tissue of sandwich style as claimed in claim 5, which is characterized in that the deinking agent is by following heavy
Measure each raw material composition of part are as follows: 10-20 parts of dodecyl benzene sulfonic acid triethanolamine soap, TX-10-18 parts, polyethylene glycol oxide or oxygen
Change propylene 3-5 parts, 5-15 parts of polyvinyl alcohol, 50-100 parts of water;The additive amount of deinking agent is the 0.3-1% of slurry weight;Deinking
The temperature of processing is 70-90 DEG C.
7. the technology for making hand tissue of sandwich style as claimed in claim 5, which is characterized in that deinking treated slurry warp
After mill defibrination, antibacterial agent, wet strength agent, retention agent and cationic starch is added into slurry and obtains waste paper pulp;The antibacterial
Agent, wet strength agent, retention agent and cationic starch additive amount be the waste paper pulp weight 0.02-0.1%, 0.1-
0.4%, 0.2-0.5%, 0.2-0.5%.
8. the technology for making hand tissue of sandwich style as claimed in claim 7, which is characterized in that the antibacterial agent is anti-for guanidine
Microbial inoculum or quaternary ammonium salt antiseptic or sulfonic acid silver antibacterial agent.
9. paper manufacturing systems used in a kind of production technology as described in claim 1-8 is any, which is characterized in that including wet end, pressure
Squeezing portion, drying portion, calender, driving section and primary head box and waste paper head box, primary head box whitewash primary slurry
The first l Water Paper page is formed to wet end, under the action of driving section, waste paper head box, which whitewashes waste paper pulp, forms centre to wet end
Protoplasm is whitewashed and forms the second l Water Paper page to middle layer by layer, primary head box, and three layers of l Water Paper page are made;Three layers of l Water Paper page are through pressing
Squeezing portion, drying portion and calender handle to obtain tissue finished product.
10. a kind of tissue of the production technology as described in claim 1-8 is any production, which is characterized in that the tissue by
Primary slurry and waste paper pulp dewatering press are prepared, and the paper layer that the waste paper pulp is formed is set to the primary slurry shape
At paper layer between.
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