CN110400974A - A kind of valve-control sealed lead acid battery activator and usage mode - Google Patents

A kind of valve-control sealed lead acid battery activator and usage mode Download PDF

Info

Publication number
CN110400974A
CN110400974A CN201810376734.8A CN201810376734A CN110400974A CN 110400974 A CN110400974 A CN 110400974A CN 201810376734 A CN201810376734 A CN 201810376734A CN 110400974 A CN110400974 A CN 110400974A
Authority
CN
China
Prior art keywords
parts
valve
sealed lead
battery
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810376734.8A
Other languages
Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Zawa Energy Technology Co Ltd
Original Assignee
Shandong Zawa Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Zawa Energy Technology Co Ltd filed Critical Shandong Zawa Energy Technology Co Ltd
Priority to CN201810376734.8A priority Critical patent/CN110400974A/en
Publication of CN110400974A publication Critical patent/CN110400974A/en
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/06—Lead-acid accumulators
    • H01M10/12—Construction or manufacture
    • H01M10/121—Valve regulated lead acid batteries [VRLA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4242—Regeneration of electrolyte or reactants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)

Abstract

A kind of valve-control sealed lead acid battery activator and usage mode, it is characterized in that, according to weight percent, the content of each component is as follows: 0.01 part to 0.1 part of sodium sulphate, 2 parts to 2.5 parts of calcium sulfate, 0.2 part to 1 part of the bromo- 2- methyl -2- amylene of 5-, 1 part to 3 parts of polyoxyethylene sorbitan monolaurate, 0.5 part to 1 part of benzene sulfonic acid, 2 parts to 5 parts of vulcanized sodium, 0.1 part to 1 part of cobaltous sulfate, remaining is deionized water.The valve-regulated sealed lead-acid batteries activator that the present invention is configured and used can eliminate big crystal grain lead sulfate in battery, reinforce grid structure, restore cell active materials, restore battery capacity, increase its service life, have certain promotional value and environment protection significance.

Description

A kind of valve-control sealed lead acid battery activator and usage mode
Technical field
The present invention relates to lead-acid accumulator recovery technique field, specifically a kind of fixed valve-control sealed lead acid battery is living Agent and usage mode.
Background technique
Lead-acid accumulator has had 150 years history, is easy to get with raw material, cheap, safety and stability, is suitable for big electricity The advantages that banishing electricity and extensive ambient temperature range, the above advantage makes it have overwhelming superiority always in electrochmical power source.So And there are two major defects for open type lead-acid accumulator: 1. latter stage of charging liberations of hydrogen are serious, need continuous acid adding and Jia Shui, the later period Maintenance work is heavy；2. gas overflowing can generate acid mist, to the equipment seriously corroded of surrounding, and certain dirt is caused to environment Dye.Leaf after in twentieth century, valve control closed lead acid accumulator must develop on a large scale in order to solve the above problem, twentieth century end, and valve control is close Enclosed lead-acid accumulator obtains being widely recognized as user, is widely applied to electric system, dynamical system, backup power supply system System, communication system etc. become important direct current electrochemical power source.
However, even if reasonably using lead-acid battery, the decline that its capacity still can be different degrees of after a period of time, The shortening for causing battery life, the failure of sulfation problem and grid becomes most important reason in many reasons.Sulphur Hydrochlorate refers to, in the electrochemical reaction of battery, generates the vitriol of big crystal grain, is attached to polar board surface, make activity The phenomenon that substance failure, reduction battery capacity.Its main cause are as follows: in cell reaction, cotton-shaped lead sulfate is converted into lead or oxygen Change lead and is reversible process, and the cotton-shaped lead sulfate in solution can recrystallize, and form the lead sulfate of big crystal grain, these big crystal grains Lead sulfate, solubility is lower, cannot be spontaneous be changed into lead oxide or lead, cotton-shaped lead sulfate can not be converted into, with the time Continuous accumulation, big crystal grain lead sulfate constantly grows, and eventually leads to battery failure.Grid corrosion is also a kind of common failure mould Formula, the metallic lead on positive plate is thermodynamic instability, and under high oxidizing potential, i.e., battery is in floating charge or overcharges work Under state, in addition to sulfate becomes brown lead oxide active material, grid alloy can also be oxidized to brown lead oxide etc., accelerate battery Failure.
Common elimination sulfurization technology has:
Chemical method usually adds activator, such as nano carbon sol, all kinds of sulfate etc. to lead-acid accumulator.Activator can To reduce vulcanization, vulcanized sulfate, the activity of recovery and improvement electrode improve transfer efficiency for activation.But general addition Although activating agent can restore the state of lead-acid accumulator to a certain extent, the use of the substance is also changed simultaneously The ingredient of electrolyte generally influences whether the service life and other performances of battery.
Large current charge technology, the technology be using larger current to battery carry out charge and discharge it is electrically operated, although can be one Determine to dissolve hard sulfuric acid leading crystal in degree, but its counter productive is equally serious, in the charge and discharge middle and later periods, battery itself Electric current ability to accept is weaker, does not adapt to the charge status of high current generally, if continuing using high current charge-discharge, then can Grid and pole plate are adversely affected, in addition will cause serious battery polarization and liberation of hydrogen.
Using harmonic technology, which is the resonance using crystal, and there is also certain resonance frequencies for sulfuric acid leading crystal, should Resonance frequency is related to the size of crystal grain, and the size of general crystal grain is bigger, and resonance frequency is lower, to the certain frequency of feed-in in battery The resonance wave of rate then can produce resonance wave abundant, and then is eliminated the sulfide in battery.This resonance desulfuration Although the mode of change is smaller to the damage of battery, but its structure is complex, generally cannot thoroughly eliminate vulcanization, need to cooperate other Technology.
Pulse recovery technique mainly utilizes the Fourier transformation of impulse wave, and impulse wave has pop ingredient abundant, can To be crushed for different lead sulfate crystal grain, to achieve the purpose that eliminate vulcanization.However, this mode is for sulfate Change smaller situation to be relatively applicable in, for big crystal grain lead sulfate, produces little effect, and activation process is longer, be easy to cause temperature It rises.
Negative pulse recovery technique can reduce the temperature rise of lead-acid accumulator during the charging process from some degree, use Such technology can carry out charge and discharge combination to lead-acid accumulator, and the stability that works long hours is preferable, but its activation efficiency is same It is lower.
Summary of the invention
Technical problem to be solved by the present invention lies in, it is good to provide a kind of activation effect, it can effectively extend battery life, Improve the fixed valve-control sealed lead acid battery activator and usage mode of battery float ability.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of valve-control sealed lead acid battery activator and usage mode, which is characterized in that according to weight percent, each component Content is as follows: 0.01 part to 0.1 part of sodium sulphate, 2 parts to 2.5 parts of calcium sulfate, 0.2 part to 1 part of the bromo- 2- methyl -2- amylene of 5- gathers 1 part to 3 parts of ethylene oxide sorbitanmonolaureate, 0.5 part to 1 part of benzene sulfonic acid, 2 parts to 5 parts of vulcanized sodium, 0.1 part of cobaltous sulfate To 1 part, remaining is deionized water.
Further scheme of the invention by it is following account for different quality percentage at being grouped as: 0.1 part of sodium sulphate, calcium sulfate 2.5 parts, 0.5 part of the bromo- 2- methyl -2- amylene of 5-, 1 part of polyoxyethylene sorbitan monolaurate, 1 part of benzene sulfonic acid, vulcanized sodium 3 Part, 0.1 part of cobaltous sulfate, 91.8 parts of deionized water.
Further scheme of the invention by it is following account for different quality percentage at being grouped as: 0.1 part of sodium sulphate, calcium sulfate 2 parts, 1 part of the bromo- 2- methyl -2- amylene of 5-, 2 parts of polyoxyethylene sorbitan monolaurate, 1 part of benzene sulfonic acid, 4 parts of vulcanized sodium, 0.5 part of cobaltous sulfate, 89.4 parts of deionized water.
Further scheme of the invention by it is following account for different quality percentage at being grouped as: 0.1 part of sodium sulphate, calcium sulfate 2.5 parts, 1 part of the bromo- 2- methyl -2- amylene of 5-, 1 part of polyoxyethylene sorbitan monolaurate, 1 part of benzene sulfonic acid, vulcanized sodium 3 Part, 1 part of cobaltous sulfate, 90.4 parts of deionized water.
A kind of usage mode of valve-control sealed lead acid battery activator, which is characterized in that matched in the following way System and use:
(1) sodium sulphate, calcium sulfate, vulcanized sodium, cobaltous sulfate part are placed in the glass containers such as beaker, and 30-55 DEG C a certain amount of is added Deionized water, stir 15-30min, other impurity must not be added in configuration and whipping process, water temperature variation is kept to be no more than 1 DEG C, obtain mixed solution.
(2) the bromo- 2- methyl -2- amylene of 5- and benzene sulfonic acid is added in the mixed liquor, is then stirred 15-20min, utilized It needs to maintain water temperature between 45-65 DEG C during ultrasonic oscillation 25-30min, stirring and concussion.
(3) a certain amount of polyoxyethylene sorbitan monolaurate is added in above process acquired solution, was added Other impurities must not be introduced in journey, 150-180min is stirred to mixed solution, and the liquid after stirring is subjected to concussion 30- It is maintained the temperature between 10-35 DEG C in 50min, earthquake and whipping process.
(4) above-mentioned solution is put into glass reagent bottle and is kept in dark place, temperature is maintained at 25 DEG C hereinafter, when to be used It is drawn off.
(5) for 2V valve-control sealed lead acid battery, the 0.5-1.5ml solution is added in every ampere-hour；It is valve-control sealed for 6V The 1.5-4.5ml solution is added in lead-acid accumulator, every ampere-hour；12V valve-control sealed lead acid battery, 3-9ml is added in every ampere-hour should Solution.It needs to carry out battery 10 hour rate charge and discharge 3-5 times after solution is added, for 2V valve-control sealed lead acid battery, electric discharge Blanking voltage is set as 1.75V；For 6V valve-control sealed lead acid battery, discharge cut-off voltage is set as 5.25V；12V valve control Sealed lead acid storage battery, discharge cut-off voltage are set as 10.5V.After charge and discharge, surplus liquid liquid level has been drawn to just Do not cross pole plate.
Scheme is further used as activating agent of the present invention: step (1) sodium sulphate, calcium sulfate, vulcanized sodium, cobaltous sulfate part It is placed in the glass containers such as beaker, 40 DEG C of a certain amount of deionized water is added, stir 20min, in configuration and whipping process Other impurity must not be added, keep water temperature variation to be no more than 1 DEG C, obtain mixed solution.
Further use scheme as activating agent of the present invention: the bromo- 2- methyl -2- of 5- is added in the mixed liquor by step (2) Amylene and benzene sulfonic acid, are then stirred 20min, using ultrasonic oscillation 30min, need to keep water temperature during stirring and concussion At 50 DEG C.
Further use scheme as activating agent of the present invention: step (3) is by a certain amount of polyoxyethylene sorbitol acid anhydride list Laurate is added in above process acquired solution, and other impurities must not be introduced in adition process, are stirred to mixed solution Liquid after stirring is carried out concussion 30min, 25 DEG C is maintained the temperature in earthquake and whipping process by 180min.
Further use scheme as activating agent of the present invention: step (4) by above-mentioned solution be put into glass reagent bottle into Row is kept in dark place, and temperature is maintained at 20 DEG C of environment, is drawn off when to be used.
Further use scheme as activating agent of the present invention: step (5) is for 2V valve-control sealed lead acid battery, every peace When be added the 1ml solution；For 6V valve-control sealed lead acid battery, the 3ml solution is added in every ampere-hour；12V valve-control sealed lead acid The 6ml solution is added in battery, every ampere-hour.It needs to carry out battery 10 hour rate charge and discharge 5 times after solution is added, for 2V valve control Sealed lead acid storage battery, discharge cut-off voltage are set as 1.75V；For 6V valve-control sealed lead acid battery, discharge cut-off voltage It is set as 5.25V；12V valve-control sealed lead acid battery, discharge cut-off voltage are set as 10.5V.It, will be extra after charge and discharge Liquid is drawn to liquid level and did not had pole plate just.
It is brilliant that the valve-regulated sealed lead-acid batteries activator that the present invention is configured and used can dissolve big crystal grain lead sulfate Body eliminates battery sulfurization, the capacity of battery can be enable to restore, meanwhile, which can improve battery conductive net Network restores the ratio of battery-active ingredient, can also play solidification to grid, slow down the corrosion to grid, thus from root Extend battery life on this, improves its circulation ability.The activating agent raw material is easy to get, and prepares and usage mode is simple, can be preferable Solution battery vulcanization and slow down grid corrosion, increase the service life of battery, have certain promotional value and environment protection significance.
Specific embodiment:
In order to fully show main feature of the invention, handling characteristics and good using effect, below with reference to specific reality Example is applied, the present invention is specifically addressed.
Embodiment one
A kind of valve-regulated sealed lead-acid batteries activator, is prepared from the following raw materials in parts by weight: 0.1 part of sodium sulphate, sulfuric acid 2.5 parts of calcium, 0.5 part of the bromo- 2- methyl -2- amylene of 5-, 1 part of polyoxyethylene sorbitan monolaurate, 1 part of benzene sulfonic acid, vulcanization 3 parts of sodium, 0.1 part of cobaltous sulfate, 91.8 parts of deionized water.
A kind of application method of valve-regulated sealed lead-acid batteries activator: by sodium sulphate, calcium sulfate, vulcanized sodium, sulfuric acid Cobalt part is placed in the glass containers such as beaker, and 40 DEG C of a certain amount of deionized water is added, and stirs 20min, in configuration and stirred Other impurity must not be added in journey, keep water temperature variation to be no more than 1 DEG C, obtain mixed solution.The bromo- 2- of 5- is added in the mixed liquor Methyl -2- amylene and benzene sulfonic acid, are then stirred 20min, using ultrasonic oscillation 30min, need during stirring and concussion Maintain water temperature at 50 DEG C.A certain amount of polyoxyethylene sorbitan monolaurate is added in above process acquired solution, is added Other impurities must not be introduced during entering, 180min is stirred to mixed solution, and the liquid after stirring is shaken 25 DEG C are maintained the temperature in 30min, earthquake and whipping process.Above-mentioned solution is put into and carries out being protected from light guarantor in glass reagent bottle It deposits, temperature is maintained at 20 DEG C of environment, is drawn off when to be used.
To Laiwu City energy company, Shandong Province for six of energy-storage system it is quasi- scrap valve-regulated sealed lead-acid battery into Row activation, the battery are the production of Shandong Province's battery enterprise, and the production time is 2013, nominal capacity 2V500Ah.According to electricity Pool capacity quantity measuring method, 25 DEG C are at room temperature, fully charged to battery progress, charge electricity and carry out 50A constant-current discharge to battery later, Ending discharge voltage is set as 1.8V, its capacity is measured and is respectively as follows: 150Ah, 163Ah, 173Ah, 142Ah, 187Ah and 164Ah. Tear lid tool open using profession and tear open lid operation to battery, after then unloading bottom flange, this activator of 500ml is added, to battery into 5 charge and discharge of row, charging and discharging currents are disposed as 50A, and discharge cut-off voltage is set as 1.75V.Then surplus liquid is extracted out, It charges the battery, is discharged with 50A, blanking voltage 1.8V is set, record discharge time respectively and calculates capacity and is respectively as follows: 475Ah, 482Ah, 479Ah, 493 Ah, 510Ah and 495Ah, all batteries are restored to 95% or more of rated capacity.
Embodiment two
A kind of valve-regulated sealed lead-acid batteries activator, is prepared from the following raw materials in parts by weight: 0.1 part of sodium sulphate, sulfuric acid 2 parts of calcium, 1 part of the bromo- 2- methyl -2- amylene of 5-, 2 parts of polyoxyethylene sorbitan monolaurate, 1 part of benzene sulfonic acid, vulcanized sodium 4 Part, 0.5 part of cobaltous sulfate, 89.4 parts of deionized water.
A kind of application method of valve-regulated sealed lead-acid batteries activator: by sodium sulphate, calcium sulfate, vulcanized sodium, sulfuric acid Cobalt part is placed in the glass containers such as beaker, and 40 DEG C of a certain amount of deionized water is added, and stirs 20min, in configuration and stirred Other impurity must not be added in journey, keep water temperature variation to be no more than 1 DEG C, obtain mixed solution.The bromo- 2- of 5- is added in the mixed liquor Methyl -2- amylene and benzene sulfonic acid, are then stirred 20min, using ultrasonic oscillation 30min, need during stirring and concussion Maintain water temperature at 50 DEG C.A certain amount of polyoxyethylene sorbitan monolaurate is added in above process acquired solution, is added Other impurities must not be introduced during entering, 180min is stirred to mixed solution, and the liquid after stirring is shaken 25 DEG C are maintained the temperature in 30min, earthquake and whipping process.Above-mentioned solution is put into and carries out being protected from light guarantor in glass reagent bottle It deposits, temperature is maintained at 20 DEG C of environment, is drawn off when to be used.
To Laiwu City energy company, Shandong Province for six of energy-storage system it is quasi- scrap valve-regulated sealed lead-acid battery into Row activation, the battery are the production of Shandong Province's battery enterprise, and the production time is 2013, nominal capacity 2V500Ah.According to electricity Pool capacity quantity measuring method, 25 DEG C are at room temperature, fully charged to battery progress, charge electricity and carry out 50A constant-current discharge to battery later, Ending discharge voltage is set as 1.8V, its capacity is measured and is respectively as follows: 142Ah, 137Ah, 121Ah, 168Ah, 154Ah and 191Ah. Tear lid tool open using profession and tear open lid operation to battery, after then unloading bottom flange, this activator of 500ml is added, to battery into 5 charge and discharge of row, charging and discharging currents are disposed as 50A, and discharge cut-off voltage is set as 1.75V.Then redundant cell liquid is taken out Out, it charges the battery, is discharged with 50A, blanking voltage 1.8V is set, record discharge time respectively and calculate capacity difference Are as follows: 471Ah, 468Ah, 476Ah, 492 Ah, 485Ah and 513Ah, all batteries are restored to 90% or more of rated capacity.
Embodiment three
A kind of valve-regulated sealed lead-acid batteries activator, is prepared from the following raw materials in parts by weight: 0.1 part of sodium sulphate, sulfuric acid 2.5 parts of calcium, 1 part of the bromo- 2- methyl -2- amylene of 5-, 1 part of polyoxyethylene sorbitan monolaurate, 1 part of benzene sulfonic acid, vulcanized sodium 3 Part, 1 part of cobaltous sulfate, 90.4 parts of deionized water.
A kind of application method of valve-regulated sealed lead-acid batteries activator: by sodium sulphate, calcium sulfate, vulcanized sodium, sulfuric acid Cobalt part is placed in the glass containers such as beaker, and 40 DEG C of a certain amount of deionized water is added, and stirs 20min, in configuration and stirred Other impurity must not be added in journey, keep water temperature variation to be no more than 1 DEG C, obtain mixed solution.The bromo- 2- of 5- is added in the mixed liquor Methyl -2- amylene and benzene sulfonic acid, are then stirred 20min, using ultrasonic oscillation 30min, need during stirring and concussion Maintain water temperature at 50 DEG C.A certain amount of polyoxyethylene sorbitan monolaurate is added in above process acquired solution, is added Other impurities must not be introduced during entering, 180min is stirred to mixed solution, and the liquid after stirring is shaken 25 DEG C are maintained the temperature in 30min, earthquake and whipping process.Above-mentioned solution is put into and carries out being protected from light guarantor in glass reagent bottle It deposits, temperature is maintained at 20 DEG C of environment, is drawn off when to be used.
To four of Jinan City, Shandong Province point communication company it is quasi- scrap valve-regulated sealed lead-acid battery and activate, the electricity Pond is the production of Jiangsu Province's battery enterprise, and the production time is 2012, nominal capacity 2V300Ah.According to battery capacity measuring Method, 25 DEG C at room temperature, fully charged to battery progress, charges electricity and carries out 30A constant-current discharge to battery later, setting cut-off is put Piezoelectric voltage is 1.8V, measures its capacity and is respectively as follows: 97Ah, 107Ah, 86Ah and 91Ah.Using profession tear open lid tool to battery into Row tears lid operation open, and after then unloading bottom flange, this activator of 300ml is added, and carries out 5 charge and discharge to battery, charging and discharging currents are equal It is set as 50A, discharge cut-off voltage is set as 1.75V.Then surplus liquid is extracted out, is charged the battery, is put with 50A Electricity, is arranged blanking voltage 1.8V, and record discharge time respectively and calculates capacity and is respectively as follows: 281Ah, 302Ah, 305Ah, 294Ah, All batteries are restored to 90% or more of rated capacity.
The preferred embodiment of the patent is described in detail above, what one skilled in the relevant art had It is to be appreciated that above description and embodiment description are the explaination to the principle of the invention in knowledge, but this patent is simultaneously It is not limited to above embodiment, without departing from the spirit and scope of the present invention, the present invention also has various change and changes Into these changes and improvements all should be within the scope of the present invention.

Claims (7)

1. a kind of valve-control sealed lead acid battery activator, which is characterized in that according to weight percent, the content of each component is such as Under: 0.01 part to 0.1 part of sodium sulphate, 2 parts to 2.5 parts of calcium sulfate, 0.2 part to 1 part of the bromo- 2- methyl -2- amylene of 5-, polyoxyethylene 1 part to 3 parts of sorbitanmonolaureate, 0.5 part to 1 part of benzene sulfonic acid, 2 parts to 5 parts of vulcanized sodium, 0.1 part to 1 part of cobaltous sulfate, Remaining is deionized water.
2. a kind of valve-control sealed lead acid battery activator according to claim 1, which is characterized in that according to weight percent Than being formulated by following component: 0.1 part of sodium sulphate, 2.5 parts of calcium sulfate, 0.5 part of the bromo- 2- methyl -2- amylene of 5-, polyoxy second 1 part of alkene sorbitanmonolaureate, 1 part of benzene sulfonic acid, 3 parts of vulcanized sodium, 0.1 part of cobaltous sulfate, 91.8 parts of deionized water.
3. a kind of valve-control sealed lead acid battery activator according to claim 1, which is characterized in that according to weight percent Than being formulated by following component: 0.1 part of sodium sulphate, 2 parts of calcium sulfate, 1 part of the bromo- 2- methyl -2- amylene of 5-, polyoxyethylene mountain 2 parts of monolaurate of pears alcohol acid anhydride, 1 part of benzene sulfonic acid, 4 parts of vulcanized sodium, 0.5 part of cobaltous sulfate, 89.4 parts of deionized water.
4. a kind of valve-control sealed lead acid battery activator according to claim 1, which is characterized in that according to weight percent Than being formulated by following component: 0.1 part of sodium sulphate, 2.5 parts of calcium sulfate, 1 part of the bromo- 2- methyl -2- amylene of 5-, polyoxyethylene 1 part of sorbitanmonolaureate, 1 part of benzene sulfonic acid, 3 parts of vulcanized sodium, 1 part of cobaltous sulfate, 90.4 parts of deionized water.
5. a kind of a kind of valve-control sealed lead acid battery activator as described in claim 1, configuration and usage mode feature It is, is configured and used in the following way:
(1) sodium sulphate, calcium sulfate, vulcanized sodium, cobaltous sulfate part are placed in the glass containers such as beaker, and 30-55 DEG C a certain amount of is added Deionized water, stir 15-30min, other impurity must not be added in configuration and whipping process, water temperature variation is kept to be no more than 1 DEG C, obtain mixed solution.
(2) the bromo- 2- methyl -2- amylene of 5- and benzene sulfonic acid is added in the mixed liquor, is then stirred 15-20min, utilizes ultrasound Wave shakes 25-30min, needs to maintain water temperature between 45-65 DEG C during stirring and concussion.
(3) a certain amount of polyoxyethylene sorbitan monolaurate is added in above process acquired solution, in adition process Other impurities must not be introduced, 150-180min is stirred to mixed solution, the liquid after stirring is subjected to concussion 30-50min, It is maintained the temperature between 10-35 DEG C in earthquake and whipping process.
(4) above-mentioned solution is put into glass reagent bottle and is kept in dark place, temperature is maintained at 25 DEG C hereinafter, by it when to be used It takes out.
(5) for 2V valve-control sealed lead acid battery, the 0.5-1.5ml solution is added in every ampere-hour；For 6V valve-control sealed lead acid The 1.5-4.5ml solution is added in battery, every ampere-hour；The 3-9ml solution is added in 12V valve-control sealed lead acid battery, every ampere-hour.
6. needing to carry out battery 10 hour rate charge and discharge 3-5 times after solution is added, for 2V valve-control sealed lead acid battery, electric discharge Blanking voltage is set as 1.75V；For 6V valve-control sealed lead acid battery, discharge cut-off voltage is set as 5.25V；12V valve control Sealed lead acid storage battery, discharge cut-off voltage are set as 10.5V.
7. after charge and discharge, surplus liquid being drawn to liquid level and did not had pole plate just.
CN201810376734.8A 2018-04-25 2018-04-25 A kind of valve-control sealed lead acid battery activator and usage mode Pending CN110400974A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810376734.8A CN110400974A (en) 2018-04-25 2018-04-25 A kind of valve-control sealed lead acid battery activator and usage mode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810376734.8A CN110400974A (en) 2018-04-25 2018-04-25 A kind of valve-control sealed lead acid battery activator and usage mode

Publications (1)

Publication Number Publication Date
CN110400974A true CN110400974A (en) 2019-11-01

Family

ID=68322075

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810376734.8A Pending CN110400974A (en) 2018-04-25 2018-04-25 A kind of valve-control sealed lead acid battery activator and usage mode

Country Status (1)

Country Link
CN (1) CN110400974A (en)

Similar Documents

Publication Publication Date Title
CN105024103B (en) The restorative procedure of waste and old lead acid accumulator
CN101022181A (en) Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method
CN105870530A (en) Waste lead storage battery repair and activation method
CN109616702A (en) A kind of alternative expression pulse formation charge technology
CN109037666A (en) Metal hydride graphene battery and graphene battery
CN103633332A (en) Anode active material for high-temperature valve-regulated sealed lead-acid storage battery
CN108417778A (en) A kind of lithium ion battery SnS hybrid energy-storing negative plates and preparation method thereof
CN108470949B (en) A kind of lead-acid accumulator is with high-efficiency activated dose and preparation method thereof
CN105048001B (en) A kind of lead-acid accumulator
CN101958417A (en) Anode additive of lead acid storage battery
CN110400974A (en) A kind of valve-control sealed lead acid battery activator and usage mode
CN103311587B (en) The preparation method of liquid repaired by lead acid accumulator
CN104993178A (en) Lead-acid storage battery capacity-increase exciting agent, capacity-increase system and capacity-increase method thereof
CN113078376B (en) Biological macromolecule repairing agent for lead-acid storage battery and preparation method thereof
CN1175506C (en) Preparation method of positive plate lead paste of lead-acid battery
CN107123835B (en) A kind of electrochemical method and system of lead-acid accumulator desulfurization
CN112259812B (en) Lead storage battery repairing agent and repairing method
CN112086639B (en) Nuclear power station fixed acid-proof lead acid storage battery activator and preparation method thereof
CN108598602A (en) A kind of lead-acid accumulator repairs activator and preparation method thereof
WO2015068979A1 (en) Method for operating redox flow battery
CN109148992B (en) Tubular colloidal battery rapid internalization is at technique
CN111342149B (en) Lead storage battery cathode devulcanization repairing method
CN102646855A (en) Lead-acid battery repair agent
CN117276708B (en) Repairing agent for lead-acid storage battery and repairing method for lead-acid storage battery
CN201490289U (en) Micro-control nano liquid crystal storage battery restore device

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20191101