CN110396697A - The hydrogen molecule of roudnel type electrolytic cell fuses method and device again - Google Patents

The hydrogen molecule of roudnel type electrolytic cell fuses method and device again Download PDF

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Publication number
CN110396697A
CN110396697A CN201810373191.4A CN201810373191A CN110396697A CN 110396697 A CN110396697 A CN 110396697A CN 201810373191 A CN201810373191 A CN 201810373191A CN 110396697 A CN110396697 A CN 110396697A
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water
anode
cathode
gas collection
hydrogen molecule
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CN110396697B (en
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徐文星
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/08Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • C25B9/73Assemblies comprising two or more cells of the filter-press type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

A kind of hydrogen molecule of roudnel type electrolytic cell fuses method and device again, especially the inside of pedestal and lid is respectively equipped with a gas collection water guide dish and an electrode plate, an ionic membrane is equipped between two electrode plates, the pedestal and lid, which correspond at two gas collection water guide dish, is respectively equipped with a gas collection water guide room, the center of two electrode plates is equipped with water inlet, the anode and cathode chamber that the corresponding position of two electrode plates is equipped with multiple hollow outs and radially configures, raw water radially flows into anode and cathode chamber from the water inlet of two electrode plates respectively, generated hydrogen molecule and oxygen molecule after electrolysis, anode and cathode chamber is taken away respectively by cathode water and anode water imports two gas collection water guide rooms, and it allows hydrogen molecule and cathode water to generate in gas collection water guide room and hands over molten effect, more hydrogen molecules are forced to be dissolved in cathode water once again with resultant pressure simultaneously, so as to increasing in cathode water Hydrogen molecule concentration is its feature.

Description

The hydrogen molecule of roudnel type electrolytic cell fuses method and device again
Technical field
The present invention relates to a kind of hydrogen molecules of roudnel type electrolytic cell to fuse method and device again, is mainly applied to promote electricity Solve the technical of total molten amount of hydrogen molecule in reductive water (including negative hydrogen ion).
Background technique
Hydrogen molecule medicine has become the new hot spot of preventive medicine research in recent years, has at present raw to suck hydrogen or injection hydrogen Li Shi salt water is in many animals disease pattern, it was demonstrated that it protects relieving effect, since hydrogen molecule is a kind of odorless, colourless, nothing The smallest antioxidant between taste, avirulent safe gas and universe, also because it has the energy for eliminating ten thousand old complaint source free radicals Power causes the numerous and confused input research of experts and scholars all over the world, and publishes thesis and clinical real example, confirmation hydrogen molecule for health care, Beauty and the prevention of disease have good result, the following new milestone that will open hydrogen molecule medicine of prediction!
Though the functional study of hydrogen molecule and its pathology machine turn gradually bright and clear, since above-mentioned suction-type hydrogen or injection hydrogen are raw Li Shi salt water needs professional technique and equipment, therefore will be a kind of not only economic but also side as can hydrogen molecule is imported in daily drinking-water Just health-care method, it is contemplated that Neoma Foam will be brought for people's health industry, also will bring new hope for hydrogen industry.
But there are still many urgent needs to overcome the problems, such as in terms of hardware at present, the existing electrolysis installation of tradition includes: to pass System flowing water type porous type electrolytic cell, static water element water electrolysis cup and porous type flowing water type electrolytic cell, in water due to hydrogen Solubility it is very low, causing in general electrolysis installation electrolytic reduction water generated hydrogen molecule, always molten amount is insufficient.Below with regard to needle The problem that above-mentioned three kinds of tradition existing electrolytic cell, is described as follows:
Traditional its electrode hole of flowing water type porous type electrolytic cell design is mostly with round, square, rectangle or mesh electrode It constitutes, since the runner of cathode water and anode water is all set in the surface of electrode plate, so that the electrode aperture vertical cross section occurs A large amount of recess portion and form " stagnant area ",
So-called " stagnant area " the i.e. region of sluggish flow.There is agglomeration in the hydrogen that the region will cause cathode generation, And then bigger bubble is generated, the hydrogen that in other words namely cathode has just generated can not dissolve in water rapidly, this phenomenon can pass Subtract the molten amount of hydrogen molecule in cathode water.
Electrolytic cell is set up for level to face main problem at present by taking static water element water electrolysis cup as an example and be: by It is lighter than water in the quality of gas, therefore no matter hydrogen or oxygen all have the physical property that less serious case raises up, therefore it is existing to will appear following points As:
One, firstly, the hydrogen (hydrogen molecule or negative hydrogen ion) generated above the cathode can form gas because of agglomeration Bubble, and rapidly increase to above cup, so that hydrogen caused by cathode is not completely dissolved into water actually, therefore cause the water Cup hydrogen molecule content generated is insufficient.
Two, the oxygen generated below the anode can not be successfully export because of top insufficient pressure, thus usually stagnate in Hole (vertical cross section), this phenomenon will cause electrode impedance and increase sharply below anode.
Three, below the anode electrolyte needed for (i.e. in anode chamber) be by pass through in cup above cathode hole or Hydrophilic ionic film imports in the anode chamber, and the described hole is practical to be intertwined anode and cathode chamber, therefore will appear following Contradictory phenomena, that is, when hole is too small, top electrolyte is not easy to import in lower anode chamber, if though hole is too big easy Water guide, but the oxygen of lower anode generation and ozone are also easy to raise up to be mixed into the cathode water of top and pollute.The described anode If electrode solution needed for chamber is by there is hydrophilic ionic film lead-in mode, since the impedance relationship of film may require that the long period Impregnate, the ionic membrane above the anode chamber can just obtain filling part it is enough wet, therefore when often resulting in cup and being electrolysed one section Between (about ten minutes or more) must just rest.This phenomenon makes cup that can not continuously generate Shui Sushui (hydrogen-rich water), for maximum disadvantage Disease.
Its electrode of existing porous type flowing water type electrolytic cell is mostly set up with vertical type, i.e., electrode design is in that a first from left is right Structure configuration, water flow mode are that from bottom to top, i.e. intake design is below electrolytic cell, and water outlet is designed above electrolytic cell, such as The above-mentioned physical property that after gas is detached from electrode there is less serious case to raise up can be not molten in the cathode chamber with water flow quickly from bottom to top Entering the hydrogen in water can quickly be taken out of, mainly receive headroom institute because the electrode left and right sides in electrolytic cell is not easy setting It causes, generally exports cathode water outside cell body, then import specially designed gas chamber of receiving so as to promoting hydrogen molecule capacity.On It states structure and mainly makes up the inborn deficiency of traditional electrolyte slot, however increase space problem on foot and increase infrastructure cost, both deposited still for it It is to be overcome to solve the problems, such as and defect.
Summary of the invention
The purpose of the present invention is to provide a kind of roudnel type electrolytic cell hydrogen molecule again fuse method and device, with solve At least one above-mentioned problem.
The present invention provides the hydrogen molecule of roudnel type electrolytic cell a kind of and fuses method again, mainly by raw water from two electrode plates The water inlet at center imports, and radially flows out along with the obverse anode and cathode chamber of two electrode plates, allow cathode water with The hydrogen molecule of nascent state generates solvation, is equipped with an ionic membrane between two electrode plates, avoids generated after being electrolysed Oxygen molecule is mixed into cathode water, while hydrogen molecule and oxygen molecule is taken away anode and cathode chamber by cathode water and anode water, and divide Upper and lower two gas collection water guides room is not imported, is allowed hydrogen molecule and cathode water to generate again in gas collection water guide room and is handed over molten effect, forces more More hydrogen molecules is dissolved in once again in cathode water, so as to increasing the hydrogen molecule concentration in cathode water.
The present invention provides the hydrogen molecule of roudnel type electrolytic cell a kind of and fuses device again, essentially consist in roudnel type electrolytic cell be by Pedestal and lid portion inside in the form of annular discs assembles two gas collection water guide dish, two anode and cathode electrode plates and an ionic membrane, the pedestal Outside is equipped with a disengaging water swivel;Wherein:
It is equipped with a gas collection water guide dish and an anode electrode plate at the top of the pedestal, extends downwardly and sets at the center of the pedestal There is a disengaging water swivel;A gas collection water guide dish and a cathode electrode plate are equipped at the lower section of the lid, at the center of the lid to Upper extend is equipped with a cathode water water outlet connector;Two gas collection water guide dish, which correspond to above pedestal, is equipped with two at lid lower section A gas collection water guide room;The center of two anode and cathode electrode plates is equipped with water inlet, the correspondence of two anode and cathode electrode plates The anode and cathode chamber that face is equipped with multiple hollow outs and radially configures;The ionic membrane is set between two anode and cathode electrode plates; The disengaging water swivel is equipped with a raw water water supply connector and an anode water water outlet connector;Water inlet difference of the raw water from two electrode plates Anode and cathode chamber is imported, generated hydrogen molecule and oxygen molecule after electrolysis are taken away with anode water by cathode water, and imported respectively Upper and lower two gas collection water guides room allows hydrogen molecule and cathode water to generate in gas collection water guide room and hands over molten effect, forces more hydrogen molecules It is dissolved in cathode water once again, so as to increasing the hydrogen molecule concentration in cathode water.
The present invention solve the problems, such as one applied by technological means and against existing technologies the effect of one be: first against It is not yet completely dissolved into the hydrogen molecule of electrolytic reduction water in cathode water, is pressed by handing over molten phenomenon to cooperate the molten hydrogen room of multiple ring-type and increase Power forces more hydrogen molecules to dissolve in water again.
The present invention solve the problems, such as two applied by technological means and against existing technologies the effect of two be: furthermore by ring Shape medium between anodic-cathodic plate is cut into radiant type hole and forms anode and cathode chamber, which also constitutes anode and cathode water flow passage, Therefore nascent state hydrogen can be taken away into rapidly cathode chamber rapidly, avoids generating hydrogen agglomeration and generating bigger bubble, Effectively promote the meltage of hydrogen.
The present invention solve the problems, such as three applied by technological means and against existing technologies the effect of three be: in anode electricity Gas collection water guide room is equipped with below pole plate, so as to quickly storing anode electrode plate oxygen generated and ozone, avoid the oxygen and Ozone is mixed into the cathode water of top, it is demonstrated experimentally that can effectively promote the molten amount of hydrogen molecule in cathode water through above-mentioned countermeasure, and ensures yin The purity of hydrogen molecule in the water of pole.
Detailed description of the invention
Fig. 1: being the bottom view Three-dimensional combination diagram of the embodiment of the present invention one.
Fig. 2: being the main view solid combination diagrammatic cross-section of the embodiment of the present invention one.
Fig. 3: being that the pedestal of the embodiment of the present invention one combines section with next part conductance water pond solid and shows
It is intended to.
Fig. 4: be the embodiment of the present invention one stereo decomposing and the portion A, the portion K, the portion G amplify
Schematic diagram.
Fig. 5: being the stereo decomposing and the portion S enlarged diagram of the embodiment of the present invention one.
Fig. 6: being the section combination diagram of one anode and cathode electrode plate conduction state of the embodiment of the present invention.
Fig. 7: being the section combination and the portion C, Y that raw water enters when the embodiment of the present invention one is electrolysed
Portion's enlarged diagram.
Fig. 8: being the E-E section combination diagram of Fig. 7.
Fig. 9: being that cathode water is combined with section derived from anode water when the embodiment of the present invention one is electrolysed
Schematic diagram.
Figure 10: being the J-J section combination diagram of Fig. 9.
Figure 11: being the F-F section combination diagram of Fig. 9.
Figure 12: being the R-R section combination diagram of Fig. 9.
Figure 13: being the perspective exploded view of the embodiment of the present invention two.
Figure 14: being section combination and the portion the H enlarged diagram of the embodiment of the present invention two.
Appended drawing reference is as follows:
10 pedestals
11 socket protrusions
111 grooves
112 tenons
12 demarcation plates
121 anode water flow paths
13 perforation
14 conductive pipes
141 internal screw threads
15 raw waters water inlet spacer ring
151 every rib
152 raw waters water inlet flow path
16 anode waters are discharged spacer ring
161 every rib
162 anode waters are discharged flow path
163 anode water water outlets
164 anode water apopores
17 flanges
171 engagement grooves
18 external screw threads
19 grooves
20 electric conductors
21 external screw threads
22 positioning terrace edges
23 external screw threads
24 positioning terrace edges
25 grooves
26 conductive parts
30 next part conductance water ponds
31 hole posts
311 fish eyelets
32 raw waters water inlet spacer ring
321 grooves
33 raw water inlets
34 raw water intake chambers
35 positioning embeded grooves
36 anode water water outlets
361 anode water outlet passages
362 bulge loops
37 grooves
38 flanges
39 block edges
391 gas collection water guide rooms
40 anode electrode plates
41 axis holes
42 anode chambers
43 water inlets
44 positioning regions
45 positive conductive portions
46 external screw threads
50 ionic membranes
51 circular holes
60 cathode electrode plates
61 axis holes
62 cathode chambers
63 water inlets
64 positioning regions
Gas collection water guide dish on 70
71 positioning abaculus
72 grooves
73 containing grooves
74 raw water intake chambers
75 cathode water water outlets
76 cathode water outlet passages
77 circular ring shape block edges
78 gas collection water guide rooms
79 notches
80 lids
81 internal screw threads
82 circular ring shape block edges
83 molten hydrogen rooms
84 notches
85 cathode water water outlet connectors
86 grooves
90 disengaging water swivels
91 hollow jack-posts
92 socket recess portions
93 tongue-and-grooves
94 anode water effluent troughs
95 raw water intake chambers
96 anode water water outlet connectors
97 raw water water supply connectors
98 negative conductive columns
99 cathode conductive films
S elastic element
R gasket
N nut
Q sealing washer
Specific embodiment
For the function and benefit for making those skilled in the art be easy to understand in depth construction content of the invention and can reach, A specific embodiment is now enumerated, and cooperates attached drawing to be discussed in detail and is described as follows:
A kind of hydrogen molecule of roudnel type electrolytic cell fuses method and device again, please be referring to FIG. 1 to 5.Main packet It includes: a pedestal 10, an electric conductor 20, once gas collection water guide dish 30, an anode electrode plate 40, an ionic membrane 50, a cathode electrode Gas collection water guide dish 70, a lid 80, one disengaging water swivel 90 and multiple sealing washer Q on plate 60, one.Wherein:
The pedestal 10 is in the form of annular discs, and the center of the pedestal 10 extends downwardly the socket protrusion 11 equipped with a hollow out, as set It connects a disengaging water swivel 90 to be used, be set outside the socket protrusion 11 there are two groove 111, and by two sealing washer Q sealings, it should The outside of socket protrusion 11 is set there are two tenon 112, is passed in and out water swivel 90 as fixing one and is used, the top surface of the pedestal 10 is equipped with The demarcation plate 12 that multiple equal parts radially configure, while anode water flow path 121, the seat are formed between every a piece of demarcation plate 12 It being set at the two sides of 10 top surface of body there are two perforation 13, two positive conductive portions 45 as an anode electrode plate 40, which are pierced by, to be used, And locked knot by two gasket R and two nut N and be fixed on pedestal 10, which is sequentially equipped with one from inside to outside Conductive pipe 14, raw water water inlet spacer ring 15 and an anode water are discharged spacer ring 16, and the inside of the conduction pipe 14 is equipped with spiral shell in one Line 141 is used as one electric conductor 20 of locking, is equipped between the inner wall and conductive pipe 14 of raw water water inlet spacer ring 15 multiple etc. Point every rib 151, intake flow path 152 so as to forming raw water in the inner wall of raw water water inlet spacer ring 15, which is discharged spacer ring Be equipped between 16 inner wall and raw water water inlet spacer ring 15 multiple equal parts every rib 161, so as in anode water water outlet spacer ring 16 Inner wall forms anode water and is discharged flow path 162, and anode water water outlet spacer ring 16 corresponds at anode water flow path 121 to go out equipped with anode water The mouth of a river 163, the anode water are discharged 162 bottom of flow path and correspond at the periphery of socket protrusion 11 anode for being equipped with multiple equal parts Water apopore 164, the top surface of the pedestal 10 corresponds to multiple 12 peripheries of demarcation plate and is equipped with a circle flange 17, so as in pedestal 10 An engagement groove 171 is formed between inner wall and flange 17, is combined and is used as gas collection water guide dish 30 once, the outer wall pair of the pedestal 10 An external screw thread 18 should be equipped at the inner wall of lid 80, mutually opposite lock is used with lid 80 as pedestal 10, and the pedestal 10 is right A circle groove 19 should be equipped at the top of external screw thread 18, it is mutual as pedestal 10 and lid 80 for pressed sealing washer Q Sealing is used when to lock;
The upper end of the electric conductor 20 is equipped with an external screw thread 21 and a positioning terrace edge 22, for a sealing washer Q and a nut N It is locked in the center position of cathode electrode plate 60, the lower end of the electric conductor 20 is equipped with an external screw thread 23 and a positioning terrace edge 24, A circle groove is formed for being locked in the internal screw thread 141 of 10 center conductive pipe 14 of pedestal, between two positioning terrace edges 22,24 25, for pressed sealing washer Q sealing, the lower end of the electric conductor 20 is equipped with a conductive part 26;
The next part conductance water pond 30 is in the form of annular discs, which, which corresponds at two of pedestal 10 perforation 13, sets There are two hole post 31, the outer diameter of two hole posts 31 is suitable with the internal diameter of two perforation 13, allows two hole posts 31 that can be arranged in two In a perforation 13, the inside of two hole posts 31 is equipped with perforative two fish eyelets 311, for two anodes of anode electrode plate 40 Conductive part 45 is pierced by, and the top of two fish eyelets 311 is set there are two sealing washer Q, is used as sealing, the next part conductance water pond At 30 center be equipped with a raw water intake spacer ring 32, the raw water intake 32 outer wall of spacer ring circumference equal dividing at be equipped with multiple raw waters into The mouth of a river 33 is equipped with a circle raw water intake chamber 34 at the periphery of the raw water inlet 33, allow raw water can from multiple raw waters into The mouth of a river 33 enters raw water intake chamber 34, then radially flows out from inside to outside from raw water intake chamber 34, the next part conductance water pond 30 The circumferential inner wall of top surface is equipped with the positioning embeded groove 35 of multiple equal parts, is embedded positioning as upper gas collection water guide dish 70 and is used, the next part The anode water water outlet 36 of multiple equal parts, the circumference of the anode water water outlet 36 are equipped at the periphery of 30 top surface of conductance water pond It inside encloses place and is equipped with multiple anode water outlet passages 361, a circle bulge loop is equipped at the periphery of multiple anode water water outlet 36 362, it is used as 50 sealing of ionic membrane, the lower section of raw water water inlet spacer ring 32 corresponds in the raw water water inlet spacer ring 15 of pedestal 10 A circle groove 321 is equipped at wall, for pressed sealing washer Q sealing, the outer wall of the next part conductance water pond 30 corresponds to pedestal It is equipped with a circle groove 37 at 10 17 inner wall of engagement groove, for pressed sealing washer Q sealing, prevents cathode water and anode water mixed It closes, which, which corresponds at the circumference of multiple anode water water outlets 36, is equipped with a circle flange 38, and utilization is convex Edge 38 improves the water level of anode water, and allowing ionic membrane 50 to obtain filling, part is enough wet, which corresponds to Place is enclosed in the circumference of multiple anode water water outlets 36 and is equipped with a circle block edge 39, so as to forming one in the bottom surface of next part conductance water pond 30 Gas collection water guide room 391, is used as oxygen molecule gas collection and anode water water guide, generated so as to quickly storing anode electrode plate 40 Oxygen and ozone avoid the oxygen and ozone from being mixed into the cathode water of top;
The anode electrode plate 40 is in the form of annular discs, and the center of the anode electrode plate 40 is equipped with an axis hole 41, the axis hole 41 it is interior Diameter is suitable with the raw water of next part conductance water pond 30 water inlet 32 outer diameter of spacer ring, and the periphery of the anode electrode plate 40 is equipped with multiple hollow outs And the anode chamber 42 radially configured, the shape of the anode chamber 42 can be V-shaped, so as to corresponding to next part conductance water Multiple water inlets 43 are formed at the raw water intake chamber 322 of disk 30, allow raw water that can import multiple anode cavities from multiple water inlets 43 Multiple positioning regions 44 for configuring in equal part and be in invaginated type are equipped in room 42, at the periphery of the anode electrode plate 40, as Correcting is used when aligning with cathode electrode plate 60, which corresponds to two perforation 13 and next part conductance of pedestal 10 It is set at two fish eyelets 311 of water pond 30 there are two positive conductive portion 45, two positive conductive portions 45 set that there are two outer spiral shells Line 46 is used as nut N locking;
The center of the ionic membrane 50 is equipped with a circular hole 51, and the internal diameter of the circular hole 51 and the raw water of next part conductance water pond 30 are intake 32 internal diameter of spacer ring is suitable, which can be proton exchange membrane, and the outer diameter of the ionic membrane 50 is greater than anode electrode plate 40 and yin The outer diameter of pole electrode plate 60, when electrolysis, allow hydrogen molecule that can penetrate ionic membrane 50, and oxygen molecule can not then penetrate ionic membrane 50, energy The oxygen generated of anode electrode plate 40 and ozone is avoided to be mixed into the cathode water of top;
The cathode electrode plate 60 is in the form of annular discs, and the center of the cathode electrode plate 60 is equipped with an axis hole 61, the axis hole 61 it is interior Diameter is suitable with 21 outer diameter of external screw thread of 20 upper end of electric conductor, and the external screw thread 21 of 20 upper end of electric conductor is allowed to be pierced by cathode electrode plate 60 Axis hole 61 after, be locked in the center position of cathode electrode plate 60 for a sealing washer Q and a nut N, cathode electricity The cathode chamber 62 that the periphery of pole plate 60 is equipped with multiple hollow outs and radially configures, the shape of the cathode chamber 62 can be V Font, the anode chamber 42 of the anode electrode plate 40 and 62 shape of cathode chamber, the size and location of the cathode electrode plate 60 are complete Exactly the same, which is being equipped with multiple water inlets in equal part configuration between axis hole 61 and multiple cathode chambers 62 Mouth 63, raw water can be imported in multiple cathode chambers 62 from multiple water inlets 63, at the periphery of the cathode electrode plate 60 Equipped with multiple positioning regions 64 for configuring in equal part and be in invaginated type, as with the positioning region 44 of anode electrode plate 40 align correcting it With the anode chamber 42 of the anode electrode plate 40 and the cathode chamber 62 of the cathode electrode plate 60 can be fitted like a glove;
Gas collection water guide dish 70 is in the form of annular discs on this, and gas collection water guide dish 70 corresponds to the multiple fixed of next part conductance water pond 30 on this Multiple positioning abaculus 71 are equipped at the caulking groove 35 of position, positioning is embedded with next part conductance water pond 30 as upper gas collection water guide dish 70 and is used, Gas collection water guide dish 70, which corresponds at the bulge loop 362 of next part conductance water pond 30, on this is equipped with a circle groove 72, for a pressed sealing Washer Q makes the ionic membrane 50 bulge loop 362 of the sealing washer Q of gas collection water guide dish 70 and next part conductance water pond 30 on this mutual One sealing effect of pressed lower formation, is avoided that cathode water and anode water mixed flow, sets at center of 70 bottom surface of gas collection water guide dish on this There is a containing groove 73, is used as the external screw thread 21 and nut N for accommodating 20 upper end of electric conductor, the bottom of gas collection water guide dish 70 on this Face, which corresponds at multiple water inlets 63 of cathode electrode plate 60, is equipped with a circle raw water intake chamber 74, allows raw water can be from multiple raw waters Water inlet 63 enters raw water intake chamber 74, then radially flows out from inside to outside from raw water intake chamber 74, gas collection water guide dish on this The cathode water water outlet 75 of multiple equal parts is equipped at 70 periphery, 70 bottom surface of gas collection water guide dish corresponds to multiple yin on this Place is enclosed in the circumference of pole water water outlet 75 and is equipped with multiple equal part cathode water outlet passages 76, and 70 top surface of gas collection water guide dish is corresponding on this Multiple circular ring shape block edges 77 are equipped in enclosing place in the circumference of multiple cathode water water outlets 75, so as on the top of upper gas collection water guide dish 70 Face forms multiple gas collection water guides room 78, and the top surface of multiple circular ring shape block edge 77 is equipped with multiple notches 79, as hydrogen molecule gas collection It is used with cathode water water guide, so as to quickly storing the hydrogen generated of cathode electrode plate 60;
The inner wall of the lid 80, which corresponds to, is equipped with an internal screw thread 81 at the external screw thread 18 of pedestal 10, as lid 80 and pedestal 10 mutual opposite locks are used, which is in mutual corresponding to being equipped at multiple circular ring shape block edges 77 of upper gas collection water guide dish 70 multiple Interconnected circular ring shape block edge 82, so as to forming multiple molten hydrogen rooms 83, multiple circle at the top position inside lid 80 The top surface of annular block edge 82 is equipped with multiple notches 84, is used as hydrogen molecule gas collection and cathode water water guide, allows cathode water can be Multiple gas collection water guides room 78 and multiple molten about 83 hydrogen rooms are in that continuous S-shaped flows up and down, are risen using hydrogen and are dropped under water with cathode It is generated mutually to hand over molten phenomenon so that more hydrogen molecule dissolves in water, be equipped at the center of the lid 80 one upwardly extend and The cathode water water outlet connector 85 of perforation, the outside of the cathode water water outlet connector 85 is equipped with a circle groove 86, for a pressed sealing Washer Q is used as a cathode water delivery hose (not shown) is connected, allows the cathode water rich in reactive hydrogen can be from cathode water Water outlet connector 85 and cathode water delivery hose (not shown) export;
The center of the disengaging water swivel 90, which corresponds to, is equipped with a hollow jack-post 91 at the conductive pipe 14 of pedestal 10, this is hollow It is equipped with an elastic element S and a negative conductive column 98 (please be refering to shown in Fig. 6) in jack-post 91, utilizes the bullet of elastic element S Power allows the upper end of the negative conductive column 98 that can be closely contacted the conductive part 26 in electric conductor 20, the lower end of the conductive column 98 For connecting negative electrical wire (not shown), two anodes that the top surface of the disengaging water swivel 90 corresponds to anode electrode plate 40 are led Electric portion 45 is equipped with flexible two cathode conductive films 99 (please be refering to shown in Fig. 6), allows two of the anode electrode plate 40 45 lower end of positive conductive portion can be closely contacted in two cathode conductive films 99, and the lower end of two cathode conductive films 99 can For connecting positive electrical wire (not shown), which corresponds to recessed equipped with a socket at the socket protrusion 11 of pedestal 10 Socket 11 outer diameter of protrusion in portion 92, the pedestal 10 is suitable with disengaging 92 internal diameter of socket recess portion of water swivel 90, the socket recess portion 92 Corresponding to being set at two tenons 112 there are two tongue-and-groove 93, two tenons 112 can be threaded in or out in two tongue-and-grooves 93, makees Water swivel 90 is passed in and out for quick assembly and disassembly to be used, the inside of the socket recess portion 92 be coaxially provided with an anode water effluent trough 94 with The internal diameter of one raw water intake chamber 95, the anode water effluent trough 94 is greater than raw water intake chamber 95, and the outside of the disengaging water swivel 90 is right An anode water water outlet connector 96 should be equipped at anode water effluent trough 94, the anode water water outlet connector 96 is for connecting an anode water Delivery hose (not shown), the outside of the disengaging water swivel 90, which corresponds to, is equipped with a raw water water supply connector at raw water intake chamber 95 97。
It is that a kind of hydrogen molecule of roudnel type electrolytic cell is being provided by the present invention made of combined by above-mentioned each component structure Method and device is fused again, in practical operation using upper:
Please be refering to shown in Fig. 7: the section combination that raw water enters when the embodiment of the present invention one is electrolysed be shown with the portion C, the amplification of the portion Y It is intended to.With shown in Fig. 8: the E-E section combination diagram of Fig. 7.Raw water flow into when, by raw water from disengaging water swivel 90 raw water Water supply connector 97 imports raw water intake chamber 95, is first formed by raw water water inlet flow path by raw water water inlet 15 inner wall of spacer ring of pedestal 10 152 flow into from lower to upper, and most water is imported the original of upper gas collection water guide dish 70 by multiple water inlets 63 of cathode electrode plate 60 Water intake chamber 74, then multiple cathode chambers 62 that cathode electrode plate 60 radially configures, small portion are flowed into from raw water intake chamber 74 The water divided then flows into raw water intake chamber by multiple raw water inlets 33 of 30 its raw water of next part conductance water pond water inlet spacer ring, 32 periphery 34, then the multiple anode cavities radially configured are flowed into from raw water intake chamber 34 via multiple water inlets 43 of anode electrode plate 40 Room 42.
Please be refering to shown in Fig. 9: cathode water combines signal with section derived from anode water when the embodiment of the present invention one is electrolysed Figure.With shown in Figure 10, Figure 11 and Figure 12: J-J, F-F and R-R section combination diagram of Fig. 9.When raw water is electrolysed, raw water point It is not electrolysed in multiple cathode chambers 62 of cathode electrode plate 60 and multiple anode chambers 42 of anode electrode plate 40, so as to dividing Hydrogen and cathode water are not generated in multiple cathode chambers 62, and generates oxygen, ozone and anode water in multiple anode chambers 42, Due between cathode electrode plate 60 and anode electrode plate 40 across one layer of ionic membrane 50, so when electrolysis hydrogen molecule can penetrate from Sub- film 50, and oxygen molecule can not then penetrate ionic membrane 50, be avoided that the oxygen generated of anode electrode plate 40, ozone are mixed into top In cathode water.The nascent state hydrogen generated of cathode chamber 62 is fused rapidly and taken away by cathode water, first by upper collection conductance The cathode water outlet passage 76 of water pond 70 flows into cathode water water outlet 75, then by cathode water water outlet 75 from lower to upper from circular ring shape The notch 79 of block edge 77 imports the gas collection water guide room 78 of top, and hydrogen molecule can be allowed simultaneously in gas collection above molten hydrogen room 83 Cathode water is flowed in multiple gas collection water guides room 78 with multiple molten about 83 hydrogen rooms, up and down in continuous S-shaped, utilizes hydrogen rising and yin Molten phenomenon is mutually handed over caused by extremely underwater drop, so that more hydrogen molecules dissolve in water, forces more hydrogen molecules with resultant pressure It is dissolved in cathode water once again, so as to increasing the hydrogen molecule concentration in cathode water, finally allows the cathode water rich in hydrogen molecule can be from Cathode water water outlet connector 85 and cathode water delivery hose (not shown) export, and the institute's oxygen generated of anode chamber 42, smelly Oxygen is then taken away rapidly by anode water, first flows into anode water water outlet by the anode water outlet passage 361 of next part conductance water pond 30 36, then import by anode water water outlet 36 the gas collection water guide room 391 of lower section from block edge 39 from top to bottom, allow oxygen and can be with ozone It is quickly accommodated in the top of gas collection water guide room 391, the oxygen and ozone is avoided to be mixed into the cathode water of top, using anode water by oxygen And ozone from the anode water catch basin 94 and anode water water outlet connector 96 and anode water delivery hose of disengaging water swivel 90 (in figure not Show) discharge, while the water level of anode water is improved using flange 38, allow ionic membrane 50 to obtain filling part enough wet.
The hydrogen molecule of roudnel type electrolytic cell provided by the present invention fuses device again, please be refering to fig. 1 shown in 3: the present invention The perspective exploded view of embodiment two.With shown in Figure 14: the section of the embodiment of the present invention two combine with the portion H enlarged diagram. Wherein: the anode chamber 42 of the anode electrode plate 40 and the cathode chamber 62 of cathode electrode plate 60 can also be equipped in porous type, The next part conductance water pond 30 and upper gas collection water guide dish 70 correspond to anode chamber 42 and cathode chamber 62 in porous type equipped with more A separation rib 341,741 radially configured, so as to forming multiple anode water flows between multiple separation ribs 341,741 respectively Road 342 and cathode water flow channels 742, allow the oxygen generated of anode chamber 42, ozone in porous type, can be fast by anode water Speed belt from, while using cathode water by cathode chamber 62 will in porous type the nascent state hydrogen generated of cathode chamber 62 it is rapid It fuses and takes away.
In conclusion the hydrogen molecule of roudnel type electrolytic cell provided by the present invention fuses method and device again, it is already practical Complete, and confirm can effectively to be promoted in cathode water hydrogen molecule always molten amount up to 30 or more percent.It is again of the invention by molten hydrogen Room and collection chamber in addition to that can reduce cost, while can have conveniently combined into thorough modularization together with quick assembly and disassembly Sell the advantages of taking, it is contemplated that future will contribute to hydrogen industry.It is again simultaneously the creation first that in the streets there is no information at present, has Utility value in industry has really met the establishment main idea of patent of invention practicability and progressive, according to the regulation of Patent Law, The application of patent of invention is proposed to an ancient unit of weight office.

Claims (18)

1. a kind of hydrogen molecule of roudnel type electrolytic cell fuses method again, mainly by raw water from the water inlet of two electrode plate centers It imports, and is radially flowed out along with the obverse anode and cathode chamber of two electrode plates, cathode water and the hydrogen of nascent state is allowed to divide Son generates solvation, is equipped with an ionic membrane between two electrode plates, generated oxygen molecule after electrolysis is avoided to be mixed into yin In the water of pole, while hydrogen molecule and oxygen molecule are taken away by anode and cathode chamber by cathode water and anode water, and import upper and lower two respectively A gas collection water guide room allows hydrogen molecule and cathode water to generate again in gas collection water guide room and hands over molten effect, forces more hydrogen molecules again Degree dissolves in cathode water, so as to increasing the hydrogen molecule concentration in cathode water.
2. the hydrogen molecule of roudnel type electrolytic cell as described in claim 1 fuses method again, in which: two anode and cathode electrodes The polarity of plate can be interchanged.
3. a kind of hydrogen molecule of roudnel type electrolytic cell fuses device again, essentially consisting in roudnel type electrolytic cell is by seat in the form of annular discs Body and lid portion inside assemble two gas collection water guide dish, two anode and cathode electrode plates and an ionic membrane, outside the pedestal equipped with one into Water outlet connector;Wherein:
It is equipped with a gas collection water guide dish and an anode electrode plate at the top of the pedestal, extends downwardly at the center of the pedestal equipped with one Pass in and out water swivel;
It is equipped with a gas collection water guide dish and a cathode electrode plate at the lower section of the lid, upwardly extends at the center of the lid equipped with one Cathode water water outlet connector;
There are two gas collection water guide rooms corresponding to setting above pedestal and at lid lower section for two gas collection water guide dish;
The center of two anode and cathode electrode plates is equipped with water inlet, and the corresponding surface of two anode and cathode electrode plates is equipped with multiple Hollow out and the anode and cathode chamber radially configured;
The ionic membrane is set between two anode and cathode electrode plates;
The disengaging water swivel is equipped with a raw water water supply connector and an anode water water outlet connector;
Raw water is directed respectively into anode and cathode chamber from the water inlet of two electrode plates, generated hydrogen molecule and oxygen molecule after electrolysis, It is taken away by cathode water with anode water, and imports upper and lower two gas collection water guides room respectively, allow hydrogen molecule and cathode water in collection conductance Water chamber, which generates, hands over molten effect, and more hydrogen molecules is forced to be dissolved in cathode water once again, dense so as to increasing the hydrogen molecule in cathode water Degree.
4. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: two anode and cathode electrodes The polarity of plate can be interchanged.
5. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: the top surface of the pedestal is equipped with more The demarcation plate that a equal part radially configures, while anode water flow path, the center of the pedestal are formed between every a piece of demarcation plate Locate sequentially to be equipped with a conductive pipe, raw water water inlet spacer ring and anode water water outlet spacer ring, raw water water inlet spacer ring from inside to outside Inner wall and conductive pipe between be equipped with multiple equal parts every rib, so as to forming raw water water inlet in the inner wall of raw water water inlet spacer ring Flow path, the anode water be discharged spacer ring inner wall and raw water water inlet spacer ring between be equipped with multiple equal parts every rib, so as in the anode The inner wall that water is discharged spacer ring forms anode water and is discharged flow path, and anode water water outlet spacer ring, which corresponds to, is equipped with anode at anode water flow path Water water outlet, the anode water are discharged the anode water apopore that multiple equal parts are equipped at the periphery of flow path bottom.
6. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: enclose circle in the pedestal top surface A circle flange is equipped at week to combine so as to forming an engagement groove between the inner wall and flange of pedestal as a gas collection water guide dish It is used, the outer wall of the gas collection water guide dish, which corresponds to, prevents cathode equipped with a circle groove at engagement groove for pressed sealing washer water Water is mixed with anode water.
7. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: downward at the center of the pedestal Extend and be equipped with a socket protrusion, the center of the disengaging water swivel is equipped with a socket recess portion, pair of the socket protrusion and socket recess portion It should locate to be equipped with tenon and tongue-and-groove, allow disengaging water swivel that can quickly be connected in pedestal.
8. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: the pedestal and lid are equipped with pair The external screw thread and internal screw thread answered, as pedestal, mutually opposite lock is used with lid.
9. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: the circle of two electrode plates All periphery places are equipped with multiple positioning regions in equal part configuration, align correctings as two electrode plates and are used, and allow two electrodes The anode and cathode chamber of plate can correspond to completely to coincide.
10. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: the lid and gas collection water guide Multiple circular ring shape block edges in interlaced configuration are equipped between disk, it is multiple molten so as to being formed at the top position of lid portion inside Hydrogen room, multiple circular ring shape block edge are equipped with multiple notches, are used as hydrogen molecule gas collection and cathode water water guide, allow cathode water can be with It is flowed above and below multiple gas collection water guides room and multiple molten hydrogen rooms, up and down in continuous S-shaped, is risen using hydrogen and drop institute under water with cathode The molten phenomenon of mutually friendship generated, so that more hydrogen molecules dissolve in water.
11. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: the ionic membrane can be proton Exchange membrane, the outer diameter of the ionic membrane are greater than the outer diameter of two electrode plates, are equipped at the peripheral circumferential of two gas collection water guide dish Corresponding bulge loop and groove, the groove for pressed sealing washer, allow the ionic membrane two gas collection water guide dish bulge loop with Sealing washer one sealing effect of mutual pressed lower formation, is avoided that cathode water and anode water mixed flow.
12. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: two gas collection water guides The circumference corresponding position of disk is equipped with multiple positioning embeded grooves and positioning abaculus, is embedded positioning mutually as two gas collection water guide dish and is used.
13. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: in the cathode electrode plate An electric conductor is equipped at the heart, the lower end of the electric conductor is equipped with a conductive part, a conductive pipe is equipped at the center of the pedestal, this is led The inside of electric pipe is equipped with internal screw thread, sets for the electric conductor lock of cathode electrode plate, and the two sides of the pedestal are set there are two perforation, can It is pierced by for two conductive parts of anode electrode plate two sides, the center of the disengaging water swivel corresponds to hollow equipped with one at conductive pipe Jack-post is equipped with an elastic element and a conductive column in the hollow jack-post, using the elastic force of the elastic element, allows the upper of the conductive column End can be closely contacted the conductive part in electric conductor, and the lower end of the conductive column is for connecting negative electrical wire, the disengaging water swivel Top surface correspond to anode electrode plate two positive conductive portions be equipped with flexible two cathode conductive films, two it is described just The lower end of pole conductive sheet is for connecting positive electrical wire.
14. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: two anode and cathode electricity The anode and cathode chamber of pole plate is in V-shape.
15. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: two anode and cathode electricity The anode and cathode chamber of pole plate is in porous type, and two gas collection water guide dish, which correspond to anode and cathode chamber and are equipped with, radially to be configured Separation rib, so as to multiple anode and cathode water flow passages are formed between multiple separation ribs respectively.
16. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 3 fuses device again, in which: two gas collection water guides The water inlet that disk corresponds to two electrode plates is set there are two raw water intake chamber, at the circumference of two gas collection water guide dish peripheries Anode and cathode water water outlet equipped with multiple equal parts is equipped with the yin-yang of multiple equal parts in the anode and cathode water water outlet at the circumference that encloses Pole water outlet passage, allow raw water can be separately flowed into from the water inlet of two electrode plates two raw waters of two gas collection water guide dish into Sink, then radially flow into the anode and cathode chamber of two electrode plates from inside to outside from two water inlets respectively, finally distinguish again It is flowed out from anode and cathode water outlet passage by anode and cathode water water outlet.
17. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 16 fuses device again, in which: should be corresponding to the collection of pedestal Conductance water pond bottom surface is equipped with a circle block edge corresponding to place is enclosed in the circumference of multiple anode water water outlets, so as in gas collection water guide dish Bottom surface forms a gas collection water guide room, is used as oxygen molecule gas collection and anode water water guide, so as to quickly storing anode electrode plate institute The oxygen and ozone of generation avoid the oxygen and ozone from being mixed into the cathode water of top.
18. the hydrogen molecule of roudnel type electrolytic cell as claimed in claim 16 fuses device again, in which: should be corresponding to the collection of pedestal Conductance water pond top surface is equipped with a circle flange corresponding to place is enclosed in the circumference of multiple anode water water outlets, and flange is utilized to improve anode water Water level, allow ionic membrane to obtain filling part enough wet.
CN201810373191.4A 2018-04-24 2018-04-24 Hydrogen molecule re-fusion method and device for disk type electrolytic cell Active CN110396697B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113789532A (en) * 2020-05-26 2021-12-14 徐文星 Device capable of storing and improving hydrogen molecule concentration in cathode water

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JPH1161472A (en) * 1997-08-08 1999-03-05 Shinko Pantec Co Ltd Electrolytic cell of hydrogen/oxygen generator and electrode therefor
CN101054682A (en) * 2006-04-14 2007-10-17 徐文星 Horizontal radiation type electrolysis method and device
CN101386992A (en) * 2007-09-11 2009-03-18 徐文星 Radial type electrolytic apparatus
CN106995233A (en) * 2017-05-09 2017-08-01 胡巍 It is a kind of to be conducive to the device that gas fully dissolves

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JPH1161472A (en) * 1997-08-08 1999-03-05 Shinko Pantec Co Ltd Electrolytic cell of hydrogen/oxygen generator and electrode therefor
CN101054682A (en) * 2006-04-14 2007-10-17 徐文星 Horizontal radiation type electrolysis method and device
CN101386992A (en) * 2007-09-11 2009-03-18 徐文星 Radial type electrolytic apparatus
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CN106995233A (en) * 2017-05-09 2017-08-01 胡巍 It is a kind of to be conducive to the device that gas fully dissolves

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113789532A (en) * 2020-05-26 2021-12-14 徐文星 Device capable of storing and improving hydrogen molecule concentration in cathode water

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