CN110372954A - A kind of wear-resisting ageing-resistant Polywoven Bag formula - Google Patents
A kind of wear-resisting ageing-resistant Polywoven Bag formula Download PDFInfo
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- CN110372954A CN110372954A CN201910609920.6A CN201910609920A CN110372954A CN 110372954 A CN110372954 A CN 110372954A CN 201910609920 A CN201910609920 A CN 201910609920A CN 110372954 A CN110372954 A CN 110372954A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
- C08L2205/242—Beta spherulite nucleating agents
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
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Abstract
The present invention provides a kind of wear-resisting ageing-resistant Polywoven Bag formula, is grouped as by weight by following groups: 80-120 parts of isotactic polypropylene;0.01-0.2 parts of pimelic acid;0.4-1.2 parts of stearate;5-7 parts of imidacloprid;18-30 parts of ethylene propylene diene rubber;5-8 parts of wear-resistant component;Masterbatch 4-8 parts of addition;3-3.5 parts of auxiliary agent;4.5-12.5 parts of anti-cracking agent;5-13 parts of antiager;3-12 parts of UV resistant agent;8-19 parts of coupling agent.Using isotactic polypropylene as resin matrix, the calcium pimelate generated using pimelic acid and calcium stearate reaction, so that isotactic polypropylene mainly exists with beta crystal, has the effect of improving Polywoven Bag intensity the present invention as nucleating agent;The antiager and wear-resistant component of addition can effectively improve the anti-aging property and wear-resisting property of Polywoven Bag;The sepiolite being added in anti-cracking agent can also effectively improve the flame retardant property of Polywoven Bag.
Description
Technical field
The present invention relates to Polywoven Bag production technical fields, more particularly to a kind of wear-resisting ageing-resistant Polywoven Bag to match
Side.
Background technique
Polywoven Bag be using polypropylene as primary raw material, through extrusion, wire drawing, using weaving, braiding, bag making and
At;The scope of application of Polywoven Bag is very wide;For at present, Polywoven Bag is mainly used for agricultural product packaging, bag of cement packet
Dress, food packaging, geotechnical engineering, tourism traffic, flood fighting goods and materials etc.;But Polywoven Bag is in summer high temperature and ultraviolet light
Aging, peeling are easy to appear under radiation, the situations such as fracture not only influence the article in Polywoven Bag, have an effect on plastics
The using effect of woven bag.
Summary of the invention
The present invention exactly against the above technical problems, provides a kind of wear-resisting ageing-resistant Polywoven Bag formula.
The present invention to achieve the above object, using following technical scheme: a kind of wear-resisting ageing-resistant Polywoven Bag formula,
It is characterized in that, being grouped as by weight by following groups:
The wear-resistant component is composed of the following components by weight percentage: 50% filler, 15% bauxite powder, 20% phosphoric acid
Aluminum dihydrogen, 10% wollastonite in powder, 5% glass fibre;The filler is titanium dioxide, talcum powder, calcium carbonate, barium carbonate, calcium carbonate
The mixture of kaolin, molecular sieve powder.
The addition masterbatch is made from the ratio mixed grinding of nanometer calcium carbonate, barium monoxide, vermiculite by weight 3:2:1
Mixture.
The auxiliary agent is the mixing of one or more of coupling agent, antioxidant, lubricant, antistatic agent;And coupling agent
For vinyltriethoxysilane;Lubricant is stearic acid;Antioxidant is 2,6 di tert butyl 4 methyl phenol;Antistatic agent
For polyether ester amides.
The anti-cracking agent the preparation method comprises the following steps: take sepiolite, deionized water is added, ultrasonic disperse obtains sepiolite dispersion
Liquid;Under stirring condition, sodium alginate is added into sepiolite dispersion liquid, heats up, continues to be stirred to react, filters, dry, grinding,
Obtain anti-cracking agent.
The mass ratio of the sepiolite and sodium alginate is 1:0.3-1.4.
The antiager the preparation method comprises the following steps: (1) takes zirconium nitrate soluble in water, be added sodium hydrate aqueous solution, stirring,
Temperature reaction, cooling, suction filtration obtains filter cake, and filter cake is first dried, then roasts, is ground up, sieved, obtain Zirconia carrier;(2)
It takes lanthanum nitrate and catechin to be codissolved in water, Zirconia carrier, dipping is added, suction filtration obtains filter cake, filter cake first dried, then
Roasting, obtains antiager.
The zirconium nitrate, sodium hydroxide, lanthanum nitrate, catechin mass ratio be 1:1.5-2.5:0.3-0.7:0.4-0.9.
The UV resistant agent the preparation method comprises the following steps: take hollow aluminum oxide microspheres, be placed in cerous nitrate solution and tea polyphenols be molten
In the mixed liquor of liquid, dipping, suction filtration obtains filter cake, and filter cake is dried, and roasts, and obtains UV resistant agent, and aluminium oxide is empty
Heart microballoon, cerous nitrate, tea polyphenols weight ratio be 1:0.3-0.7:0.2-0.8.
The hollow aluminum oxide microspheres the preparation method comprises the following steps: take aluminum nitrate soluble in water, sodium hydrate aqueous solution is added, stirs
10-30min is mixed, is warming up to 150-165 DEG C, insulation reaction 20-35h, cooling, suction filtration obtains filter cake, by filter cake at 80-90 DEG C
Dry 25-45min, roasts 2-4.5h, ground 20-60 mesh obtains hollow aluminum oxide microspheres at 620-670 DEG C.
The beneficial effects of the present invention are: the present invention uses isotactic polypropylene as resin matrix, with pimelic acid and stearic acid
The calcium pimelate that calcium reaction generates is as nucleating agent, so that isotactic polypropylene mainly exists with beta crystal, has and improves plastics volume
Knit the effect of bag intensity;The antiager and wear-resistant component of addition can effectively improve the anti-aging property of Polywoven Bag and resistance to
Grind performance;The sepiolite being added in anti-cracking agent can also effectively improve the flame retardant property of Polywoven Bag, and using effect is preferable.
Specific embodiment
Below with reference to embodiment, the invention will be further described:
A kind of wear-resisting ageing-resistant Polywoven Bag formula, which is characterized in that be grouped as by weight by following groups:
The wear-resistant component is composed of the following components by weight percentage: 50% filler, 15% bauxite powder, 20% phosphoric acid
Aluminum dihydrogen, 10% wollastonite in powder, 5% glass fibre;The filler is titanium dioxide, talcum powder, calcium carbonate, barium carbonate, calcium carbonate
The mixture of kaolin, molecular sieve powder.
The addition masterbatch is made from the ratio mixed grinding of nanometer calcium carbonate, barium monoxide, vermiculite by weight 3:2:1
Mixture.
The auxiliary agent is the mixing of one or more of coupling agent, antioxidant, lubricant, antistatic agent;And coupling agent
For vinyltriethoxysilane;Lubricant is stearic acid;Antioxidant is 2,6 di tert butyl 4 methyl phenol;Antistatic agent
For polyether ester amides.
The anti-cracking agent the preparation method comprises the following steps: take sepiolite, deionized water is added, ultrasonic disperse obtains sepiolite dispersion
Liquid;Under stirring condition, sodium alginate is added into sepiolite dispersion liquid, heats up, continues to be stirred to react, filters, dry, grinding,
Obtain anti-cracking agent.
The mass ratio of the sepiolite and sodium alginate is 1:0.3-1.4.
The antiager the preparation method comprises the following steps: (1) takes zirconium nitrate soluble in water, be added sodium hydrate aqueous solution, stirring,
Temperature reaction, cooling, suction filtration obtains filter cake, and filter cake is first dried, then roasts, is ground up, sieved, obtain Zirconia carrier;(2)
It takes lanthanum nitrate and catechin to be codissolved in water, Zirconia carrier, dipping is added, suction filtration obtains filter cake, filter cake first dried, then
Roasting, obtains antiager.
The zirconium nitrate, sodium hydroxide, lanthanum nitrate, catechin mass ratio be 1:1.5-2.5:0.3-0.7:0.4-0.9.
The UV resistant agent the preparation method comprises the following steps: take hollow aluminum oxide microspheres, be placed in cerous nitrate solution and tea polyphenols be molten
In the mixed liquor of liquid, dipping, suction filtration obtains filter cake, and filter cake is dried, and roasts, and obtains UV resistant agent, and aluminium oxide is empty
Heart microballoon, cerous nitrate, tea polyphenols weight ratio be 1:0.3-0.7:0.2-0.8.
The hollow aluminum oxide microspheres the preparation method comprises the following steps: take aluminum nitrate soluble in water, sodium hydrate aqueous solution is added, stirs
10-30min is mixed, is warming up to 150-165 DEG C, insulation reaction 20-35h, cooling, suction filtration obtains filter cake, by filter cake at 80-90 DEG C
Dry 25-45min, roasts 2-4.5h, ground 20-60 mesh obtains hollow aluminum oxide microspheres at 620-670 DEG C.
A kind of wear-resisting ageing-resistant Polywoven Bag formula of embodiment 1, is grouped as by following groups by weight:
The wear-resistant component is composed of the following components by weight percentage: 50% filler, 15% bauxite powder, 20% phosphoric acid
Aluminum dihydrogen, 10% wollastonite in powder, 5% glass fibre;The filler is titanium dioxide, talcum powder, calcium carbonate, barium carbonate, calcium carbonate
The mixture of kaolin, molecular sieve powder.
The addition masterbatch is made from the ratio mixed grinding of nanometer calcium carbonate, barium monoxide, vermiculite by weight 3:2:1
Mixture.
The auxiliary agent is the mixing of one or more of coupling agent, antioxidant, lubricant, antistatic agent;And coupling agent
For vinyltriethoxysilane;Lubricant is stearic acid;Antioxidant is 2,6 di tert butyl 4 methyl phenol;Antistatic agent
For polyether ester amides.
The anti-cracking agent the preparation method comprises the following steps: take sepiolite, deionized water is added, ultrasonic disperse obtains sepiolite dispersion
Liquid;Under stirring condition, sodium alginate is added into sepiolite dispersion liquid, heats up, continues to be stirred to react, filters, dry, grinding,
Obtain anti-cracking agent.
The mass ratio of the sepiolite and sodium alginate is 1:0.3.
The antiager the preparation method comprises the following steps: (1) takes zirconium nitrate soluble in water, be added sodium hydrate aqueous solution, stirring,
Temperature reaction, cooling, suction filtration obtains filter cake, and filter cake is first dried, then roasts, is ground up, sieved, obtain Zirconia carrier;(2)
It takes lanthanum nitrate and catechin to be codissolved in water, Zirconia carrier, dipping is added, suction filtration obtains filter cake, filter cake first dried, then
Roasting, obtains antiager.
The zirconium nitrate, sodium hydroxide, lanthanum nitrate, catechin mass ratio be 1:1.5:0.3:0.4.
The UV resistant agent the preparation method comprises the following steps: take hollow aluminum oxide microspheres, be placed in cerous nitrate solution and tea polyphenols be molten
In the mixed liquor of liquid, dipping, suction filtration obtains filter cake, and filter cake is dried, and roasts, and obtains UV resistant agent, and aluminium oxide is empty
Heart microballoon, cerous nitrate, tea polyphenols weight ratio be 1:0.3:0.2.
The hollow aluminum oxide microspheres the preparation method comprises the following steps: take aluminum nitrate soluble in water, sodium hydrate aqueous solution is added, stirs
10min to be mixed, is warming up to 150 DEG C, insulation reaction 20h, is cooled down, suction filtration obtains filter cake, filter cake is dried into 25min at 80 DEG C,
2h is roasted at 620 DEG C, ground 20 mesh obtains hollow aluminum oxide microspheres.
A kind of wear-resisting ageing-resistant Polywoven Bag formula of embodiment 2, is grouped as by following groups by weight:
The wear-resistant component is composed of the following components by weight percentage: 50% filler, 15% bauxite powder, 20% phosphoric acid
Aluminum dihydrogen, 10% wollastonite in powder, 5% glass fibre;The filler is titanium dioxide, talcum powder, calcium carbonate, barium carbonate, calcium carbonate
The mixture of kaolin, molecular sieve powder.
The addition masterbatch is made from the ratio mixed grinding of nanometer calcium carbonate, barium monoxide, vermiculite by weight 3:2:1
Mixture.
The auxiliary agent is the mixing of one or more of coupling agent, antioxidant, lubricant, antistatic agent;And coupling agent
For vinyltriethoxysilane;Lubricant is stearic acid;Antioxidant is 2,6 di tert butyl 4 methyl phenol;Antistatic agent
For polyether ester amides.
The anti-cracking agent the preparation method comprises the following steps: take sepiolite, deionized water is added, ultrasonic disperse obtains sepiolite dispersion
Liquid;Under stirring condition, sodium alginate is added into sepiolite dispersion liquid, heats up, continues to be stirred to react, filters, dry, grinding,
Obtain anti-cracking agent.
The mass ratio of the sepiolite and sodium alginate is 1:1.4.
The antiager the preparation method comprises the following steps: (1) takes zirconium nitrate soluble in water, be added sodium hydrate aqueous solution, stirring,
Temperature reaction, cooling, suction filtration obtains filter cake, and filter cake is first dried, then roasts, is ground up, sieved, obtain Zirconia carrier;(2)
It takes lanthanum nitrate and catechin to be codissolved in water, Zirconia carrier, dipping is added, suction filtration obtains filter cake, filter cake first dried, then
Roasting, obtains antiager.
The zirconium nitrate, sodium hydroxide, lanthanum nitrate, catechin mass ratio be 1:2.5:0.7:0.9.
The UV resistant agent the preparation method comprises the following steps: take hollow aluminum oxide microspheres, be placed in cerous nitrate solution and tea polyphenols be molten
In the mixed liquor of liquid, dipping, suction filtration obtains filter cake, and filter cake is dried, and roasts, and obtains UV resistant agent, and aluminium oxide is empty
Heart microballoon, cerous nitrate, tea polyphenols weight ratio be 1:0.7:0.8.
The hollow aluminum oxide microspheres the preparation method comprises the following steps: take aluminum nitrate soluble in water, sodium hydrate aqueous solution is added, stirs
30min to be mixed, is warming up to 165 DEG C, insulation reaction 35h, is cooled down, suction filtration obtains filter cake, filter cake is dried into 45min at 90 DEG C,
4.5h is roasted at 670 DEG C, ground 60 mesh obtains hollow aluminum oxide microspheres.
The present invention is exemplarily described above, it is clear that present invention specific implementation is not subject to the restrictions described above,
As long as using the various improvement that the inventive concept and technical scheme of the present invention carry out, or not improved directly apply to other fields
It closes, it is within the scope of the present invention.
Claims (10)
1. a kind of wear-resisting ageing-resistant Polywoven Bag formula, which is characterized in that be grouped as by weight by following groups:
2. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 1, which is characterized in that described resistance to wear into
Divide composed of the following components by weight percentage: 50% filler, 15% bauxite powder, 20% aluminium dihydrogen phosphate, 10% wollastonite
Powder, 5% glass fibre;The filler is titanium dioxide, talcum powder, calcium carbonate, barium carbonate, calcium carbonate kaolin, molecular sieve powder
Mixture.
3. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 1, which is characterized in that the addition is female
Material is mixture made from the ratio mixed grinding of nanometer calcium carbonate, barium monoxide, vermiculite by weight 3:2:1.
4. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 1, which is characterized in that the auxiliary agent is
The mixing of one or more of coupling agent, antioxidant, lubricant, antistatic agent;And coupling agent is vinyl triethoxyl silicon
Alkane;Lubricant is stearic acid;Antioxidant is 2,6 di tert butyl 4 methyl phenol;Antistatic agent is polyether ester amides.
5. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 1, which is characterized in that the anti-cracking agent
The preparation method comprises the following steps: take sepiolite, deionized water is added, ultrasonic disperse obtains sepiolite dispersion liquid;Under stirring condition, Xiang Hai
Sodium alginate is added in afrodite dispersion liquid, heats up, continues to be stirred to react, filters, dry, grinding obtains anti-cracking agent.
6. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 5, which is characterized in that the sepiolite
Mass ratio with sodium alginate is 1:0.3-1.4.
7. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 1, which is characterized in that described ageing-resistant
Agent the preparation method comprises the following steps: (1) takes zirconium nitrate soluble in water, sodium hydrate aqueous solution is added, stirring, temperature reaction is cooling, filters
Filter cake is obtained, filter cake is first dried, then roasts, is ground up, sieved, obtain Zirconia carrier;(2) take lanthanum nitrate and catechin total
It is soluble in water, Zirconia carrier, dipping is added, suction filtration obtains filter cake, filter cake is first dried, then roasts, obtains antiager.
8. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 7, which is characterized in that the nitric acid
Zirconium, sodium hydroxide, lanthanum nitrate, catechin mass ratio be 1:1.5-2.5:0.3-0.7:0.4-0.9.
9. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 1, which is characterized in that the uvioresistant
Line agent the preparation method comprises the following steps: take hollow aluminum oxide microspheres, be placed in the mixed liquor of cerous nitrate solution and tea polyphenols solution, impregnate,
Suction filtration obtains filter cake, and filter cake is dried, and roasting obtains UV resistant agent, and hollow aluminum oxide microspheres, cerous nitrate, tea are more
The weight ratio of phenol is 1:0.3-0.7:0.2-0.8.
10. the wear-resisting ageing-resistant Polywoven Bag formula of one kind according to claim 9, which is characterized in that the oxidation
Aluminium tiny balloon the preparation method comprises the following steps: take aluminum nitrate soluble in water, sodium hydrate aqueous solution is added, stirs 10-30min, heating
To 150-165 DEG C, insulation reaction 20-35h, cooling down, suction filtration obtains filter cake, filter cake is dried into 25-45min at 80-90 DEG C,
2-4.5h is roasted at 620-670 DEG C, ground 20-60 mesh obtains hollow aluminum oxide microspheres.
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Cited By (2)
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CN111099139A (en) * | 2020-01-08 | 2020-05-05 | 宿迁市中塑实业有限公司 | Preparation process of anti-skid and anti-purple plastic woven bag |
CN114959993A (en) * | 2022-06-28 | 2022-08-30 | 界首市宏利塑料股份有限公司 | Wear-resistant woven bag and preparation method thereof |
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CN108841083A (en) * | 2018-06-25 | 2018-11-20 | 天津市久大塑料制品有限公司 | A kind of antiultraviolet Polywoven Bag composition of raw materials |
CN108976563A (en) * | 2018-08-09 | 2018-12-11 | 安徽义林塑业有限公司 | A kind of uvioresistant Polywoven Bag |
CN109251391A (en) * | 2018-08-09 | 2019-01-22 | 安徽义林塑业有限公司 | A kind of anti-cracking Polywoven Bag |
CN109337193A (en) * | 2018-08-09 | 2019-02-15 | 安徽义林塑业有限公司 | A kind of ageing-resistant Polywoven Bag |
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CN107936381A (en) * | 2017-12-25 | 2018-04-20 | 安徽省临泉县万隆塑料包装有限公司 | A kind of wear-resistant plastic woven bag |
CN108841083A (en) * | 2018-06-25 | 2018-11-20 | 天津市久大塑料制品有限公司 | A kind of antiultraviolet Polywoven Bag composition of raw materials |
CN108976563A (en) * | 2018-08-09 | 2018-12-11 | 安徽义林塑业有限公司 | A kind of uvioresistant Polywoven Bag |
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CN114959993A (en) * | 2022-06-28 | 2022-08-30 | 界首市宏利塑料股份有限公司 | Wear-resistant woven bag and preparation method thereof |
CN114959993B (en) * | 2022-06-28 | 2024-03-22 | 界首市宏利塑料股份有限公司 | Wear-resistant woven bag and preparation method thereof |
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Application publication date: 20191025 |
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