CN110369447A - A kind of device and processing method of biomass in-situ carburization processing mining wastes - Google Patents

A kind of device and processing method of biomass in-situ carburization processing mining wastes Download PDF

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Publication number
CN110369447A
CN110369447A CN201910635145.1A CN201910635145A CN110369447A CN 110369447 A CN110369447 A CN 110369447A CN 201910635145 A CN201910635145 A CN 201910635145A CN 110369447 A CN110369447 A CN 110369447A
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reactor
biomass
mining wastes
mixed material
reaction
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CN110369447B (en
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田森林
黄建洪
赵群
胡学伟
李英杰
李波
陈杰
宁平
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Kunming Engineering & Research Institute Of Nonferrous Metallurgy Co ltd
Kunming University of Science and Technology
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Kunming University of Science and Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses the devices and processing method of a kind of biomass in-situ carburization processing mining wastes.Described device includes reactor, blower, deduster, pressometer, temperature meter, flow valve;The conveniently adjusted combustion air flow of apparatus of the present invention has the advantages that regulation is flexible to regulate and control reactor endogenous substance carbonizing degree.The method includes the steps: mixed material preparation, charging, the carburizing reagent of mixed material, discharge.The present invention is by mixing carbonization with biomass for mining wastes, the fertility of mining wastes can be effectively improved after processing and improves pH, and accelerate the physical weathering of mining wastes, chemical weathering, thermal decomposition reduces metal sulfide content in mining wastes, and realization improves mining wastes upgrading.

Description

A kind of device and processing method of biomass in-situ carburization processing mining wastes
Technical field
The invention belongs to mining wastes processing technology fields, and in particular to a kind of biomass in-situ carburization processing mining industry is useless The device and processing method of gurry.
Background technique
Mining wastes refer to the waste and contaminated soil generated during Mining Market, as tailing, roach stone, Contaminated soil etc..Mining wastes are largely stored up, and the clast that some weathering are formed can be washed away by water into after waters, or even dissolution Permeate the ground water, and environment is seriously polluted in blown by wind into atmosphere also.And in these wastes, some contains harmful element, right Human health threatens.It is serious also to will cause the disasters such as landslide, mud-rock flow and in mining wastes banking process.
Banking up is the traditional method of disposal of mining wastes, and barren rock is transported to waste-rock yard, and removing rock is sent into refuse dump, tailing Input Tailings Dam.Secondary pollution in order to prevent, the 1970s, the harmless treatment of solid waste was set about in China.Common place Reason method has physical method, chemical method, plant method and land reconversion method.The preparation that more direction is construction material is studied at present, Such as prepared by a kind of green construction material-biology cement preparation method (CN106587681B), a kind of low price calcium ion that is based on The production method and application (CN107176798A), a kind of foamed cement composite self-insulating brick and its processing technology of biological cement (CN104446193B) etc., these methods are a kind of relatively good resource utilization directions, but can have some potential hazards, such as The oxidation of tailing produces whether acid will lead to the damage of construction material, and whether contaminated soil can make pollutant exudation endanger environment or people Body health etc. can not solve its potential safety issue, and stealthy harm easily occurs.
For this purpose, researching and developing a kind of device of biomass in-situ carburization processing mining wastes and processing method is very necessary 's.
Summary of the invention
The first object of the present invention is to provide a kind of device of biomass in-situ carburization processing mining wastes.
The second object of the present invention is to provide a kind of processing of the device of biomass in-situ carburization processing mining wastes Method.
The first object of the present invention is achieved in that be surveyed including reactor, blower, deduster, pressometer, temperature Measuring device, flow valve, the reactor are in the form of a column structure, and reactor head is equipped with feed opening, and bottom is discharge air grid structure, The measurement end of the temperature meter is set in reactor, the reactor side surface upper part air-vent by pipeline and blower into Gas end, and pipeline is equipped with pressometer, flow valve, the outlet side of the blower is connected by the inlet end of pipeline and deduster It connects.
The second object of the present invention be achieved in that the following steps are included:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, crushing and be uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of reactor volume;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower, helps Combustion air enters in reactor from discharge air grid structure and uplink, the flue gas of generation of burning by blower import in deduster into Row dedusting is 15L/min, reaction to reactor by the combustion air flow that flow valve control enters reactor during reaction Interior temperature declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor.
Beneficial effects of the present invention: the present invention can have after processing by the way that mining wastes are mixed carbonization with biomass Effect improves the fertility of mining wastes and improves pH, and accelerates the physical weathering of mining wastes, chemical weathering, thermally decomposes Reduce metal sulfide content in mining wastes, realization improves mining wastes upgrading;Apparatus of the present invention can facilitate tune Combustion air flow is saved, to regulate and control reactor endogenous substance carbonizing degree, has the advantages that regulation is flexible.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention;
Fig. 2 be further include in Fig. 1 dispenser, broken blending bunker, lower hopper, removal device, igniter structural schematic diagram;
In figure: 1- reactor, 2- blower, 3- deduster, 4- pressometer, 5- temperature meter, 6- flow valve, 7- feed Device, 8- are crushed blending bunker, 9- lower hopper, 10- removal device, 11- igniter, and 12- has air inlet.
Specific embodiment
The present invention will be further described below with reference to the drawings, but the present invention is limited in any way, base In present invention teach that it is made it is any transform or replace, all belong to the scope of protection of the present invention.
The present invention as shown in 1 ~ Fig. 2 of attached drawing includes reactor 1, blower 2, deduster 3, pressometer 4, temperature meter 5, flow valve 6, the reactor 1 are in the form of a column structure, and feed opening is equipped at the top of reactor 1, and bottom is discharge air grid structure, The measurement end of the temperature meter 5 is set in reactor 1, and the 1 side surface upper part air-vent of reactor passes through pipeline and blower 2 Inlet end, and pipeline is equipped with pressometer 4, flow valve 6, the outlet side of the blower 2 by pipeline and deduster 3 into The connection of gas end.
Preferably, further include air hermetic dispenser 7, broken blending bunker 8, the discharge end of the air hermetic dispenser 7 with The connection of 1 feed opening of reactor, the feed end of the air hermetic dispenser 7 are connect with broken 8 bottom of blending bunker.
Preferably, crushing mixer structure is equipped in the broken blending bunker 8.
It preferably, further include lower hopper 9, air hermetic removal device 10, igniter 11, the lower hopper 9 is set to reactor 1 The feed end of bottom, the air hermetic removal device 10 is connect with 9 bottom of lower hopper, and 9 side of lower hopper is equipped with air inlet 12, The igniter 11 is set to 1 side lower of reactor.
Preferably, the deduster 3 is cyclone dust collectors, sack cleaner, electric precipitator or gravitational precipitator.
Preferably, the blower 2 is water ring vacuum pump or centrifugal blower.
Preferably, the temperature meter 5 has multiple, is set in turn in 1 side of reactor from top to bottom.
Preferably, the air hermetic dispenser 7 is screw feeder.
Preferably, the air hermetic removal device 10 is discharge with endless screw device or star-like discharging device.
Apparatus of the present invention working principle and the course of work: material is crushed and is uniformly mixed in broken blending bunker 8 first, It is sent into reactor 1 by air hermetic dispenser 7 again, mixed material from top to bottom moves under the effect of gravity;Mixed material dress After filling out, mixed material is lighted from discharge air grid structure by igniter 11, while starting blower 2, combustion is empty Gas enters in reactor 1 from discharge air grid structure and uplink, the flue gas of generation of burning by blower 2 import in deduster 3 into Row dedusting;By temperature meter 5, when the temperature in observing response device 1 declines after no longer rising or rise, i.e. end of reaction; Then the material after reaction is discharged by air hermetic removal device 10.
Preferably, the processing method of the device of the biomass in-situ carburization processing mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, crushing and be uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1.
Preferably, in step S1, the biomass powder particle diameter is greater than 50 mesh.
Preferably, in step S1, the mining wastes powder particle diameter is 80 mesh.
Preferably, the mining wastes are contaminated soil, roach stone or tailing.
Preferably, the mining wastes are contaminated soil, roach stone, mass ratio 5:1.
Preferably, the mining wastes are contaminated soil, tailing, mass ratio 5:2.
Preferably, the mining wastes are roach stone, tailing, mass ratio 2:1.
Preferably, the mining wastes are contaminated soil, roach stone and tailing, mass ratio 5:1:2.
Preferably, the water content of the biomass is 15%.
Preferably, the water content of the mining wastes is 20 ~ 40%.
Below with reference to 1 ~ embodiment of embodiment 9, the invention will be further described.
Embodiment 1
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, crushing and be uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1.
Embodiment 2
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, wherein mining wastes be contaminated soil, Roach stone, mass ratio 5:1 are crushed and are uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1.
Embodiment 3
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, wherein mining wastes be contaminated soil, Tailing, mass ratio 5:2 are crushed and are uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1.
Embodiment 4
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, wherein mining wastes are roach stone, tail Mine, mass ratio 2:1 are crushed and are uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1.
Embodiment 5
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, wherein mining wastes be contaminated soil, Roach stone and tailing, mass ratio 5:1:2 are crushed and are uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1.
Embodiment 6
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, wherein mining wastes be contaminated soil, Roach stone and tailing, mass ratio 5:1:2 are crushed and are uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1;
The water content of the biomass is 15%.
Embodiment 7
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, wherein mining wastes be contaminated soil, Roach stone and tailing, mass ratio 5:1:2 are crushed and are uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1;
The water content of the biomass is 15%;
The water content of the mining wastes is 20%.
Embodiment 8
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, wherein mining wastes be contaminated soil, Roach stone and tailing, mass ratio 5:1:2 are crushed and are uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1;
The water content of the biomass is 15%;
The water content of the mining wastes is 40%.
Embodiment 9
Biomass in-situ carburization handles the processing method of the device of mining wastes, comprising the following steps:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, wherein mining wastes be contaminated soil, Roach stone and tailing, mass ratio 5:1:2 are crushed and are uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor 1, and feed rate is 50 ~ 150kg/min, Feeding quantity is the 2/3 of 1 volume of reactor;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower 2, Combustion air enters in reactor 1 from discharge air grid structure and uplink, and the flue gas for generation of burning imports deduster by blower 2 It is dusted in 3, is 15L/min by the combustion air flow that the control of flow valve 6 enters reactor 1, reaction is extremely during reaction Temperature in reactor 1 declines after no longer rising or rise, i.e. end of reaction;
S4, discharge: the material of end of reaction is discharged from reactor 1;
The water content of the biomass is 15%;
The water content of the mining wastes is 30%.

Claims (10)

1. a kind of device of biomass in-situ carburization processing mining wastes, including reactor (1), blower (2), deduster (3), Pressometer (4), temperature meter (5), flow valve (6), it is characterised in that the reactor (1) is in the form of a column structure, reaction Feed opening is equipped at the top of device (1), bottom is discharge air grid structure, and the measurement end of the temperature meter (5) is set to reaction In device (1), reactor (1) the side surface upper part air-vent passes through the inlet end of pipeline and blower (2), and pipeline is surveyed equipped with pressure The outlet side of measuring device (4), flow valve (6), the blower (2) is connect by pipeline with the inlet end of deduster (3).
2. the device of biomass in-situ carburization processing mining wastes according to claim 1, it is characterised in that further include gas Close formula dispenser (7), broken blending bunker (8), the discharge end and reactor (1) feed opening of the air hermetic dispenser (7) connect It connects, the feed end of the air hermetic dispenser (7) is connect with broken blending bunker (8) bottom.
3. the device of biomass in-situ carburization processing mining wastes according to claim 2, it is characterised in that described broken Crushing mixer structure is equipped in blending bunker (8).
4. the device of biomass in-situ carburization processing mining wastes according to claim 1 or claim 2, it is characterised in that further include Lower hopper (9), air hermetic removal device (10), igniter (11), the lower hopper (9) are set to reactor (1) bottom, the gas The feed end of close formula removal device (10) is connect with lower hopper (9) bottom, and lower hopper (9) side is equipped with air inlet (12), institute Igniter (11) are stated set on reactor (1) side lower.
5. the device of biomass in-situ carburization processing mining wastes according to claim 1, it is characterised in that the temperature Measuring appliance (5) has multiple, is set in turn in reactor (1) side from top to bottom.
6. the device of biomass in-situ carburization processing mining wastes according to claim 2, it is characterised in that described airtight Formula dispenser (7) is screw feeder.
7. the device of biomass in-situ carburization processing mining wastes according to claim 4, it is characterised in that described airtight Formula removal device (10) is discharge with endless screw device or star-like discharging device.
8. a kind of processing side of the device of the biomass in-situ carburization processing mining wastes any according to claim 1 ~ 7 Method, it is characterised in that the following steps are included:
S1, mixed material prepare: by biomass, mining wastes 3:7 in mass ratio, crushing and be uniformly mixed;
S2, charging: the mixed material that S1 step is prepared is added in reactor (1), and feed rate is 50 ~ 150kg/ Min, feeding quantity are the 2/3 of reactor (1) volume;
The carburizing reagent of S3, mixed material: lighting a fire from discharge air grid structure, mixed material lighted, and starts blower (2), combustion air enters in reactor (1) from discharge air grid structure and uplink, the flue gas for generation of burning are led by blower (2) Enter and be dusted in deduster (3), during reaction, is by the combustion air flow that flow valve (6) control enters reactor (1) 15L/min, reaction decline after no longer rising or rise to the temperature in reactor (1), i.e. end of reaction;
S4, discharge: the discharge from reactor (1) by the material of end of reaction.
9. the device of biomass in-situ carburization processing mining wastes according to claim 8, it is characterised in that the mining industry Waste is contaminated soil, roach stone or tailing.
10. the device of biomass in-situ carburization processing mining wastes according to claim 8, it is characterised in that the biology The water content of matter is 15%.
CN201910635145.1A 2019-07-15 2019-07-15 Device and method for treating mining waste through in-situ carbonization of biomass Active CN110369447B (en)

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CN114672329A (en) * 2022-04-08 2022-06-28 昆明理工大学 Device and method for reducing heavy metal polluted soil environment risk in smoldering mode
CN114672329B (en) * 2022-04-08 2023-12-12 昆明理工大学 Device and method for reducing environmental risk of heavy metal polluted soil in smoldering mode
CN115197727A (en) * 2022-08-12 2022-10-18 昆明理工大学 Treatment method and treatment device for repairing contaminated soil through biomass pyrolysis and carbonization
CN115197727B (en) * 2022-08-12 2024-01-16 昆明理工大学 Treatment method and treatment device for restoring polluted soil by biomass pyrolysis and carbonization

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