CN110369123A - A kind of deironing apparatus and technique of refractory material fine powder - Google Patents

A kind of deironing apparatus and technique of refractory material fine powder Download PDF

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Publication number
CN110369123A
CN110369123A CN201910802256.7A CN201910802256A CN110369123A CN 110369123 A CN110369123 A CN 110369123A CN 201910802256 A CN201910802256 A CN 201910802256A CN 110369123 A CN110369123 A CN 110369123A
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CN
China
Prior art keywords
fine powder
refractory material
distribution plate
air distribution
material fine
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CN201910802256.7A
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Chinese (zh)
Inventor
薛钟安
黄海明
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Shanxi Weitai Safety And Environmental Protection Engineering Technology Co Ltd
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Shanxi Weitai Safety And Environmental Protection Engineering Technology Co Ltd
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Priority to CN201910802256.7A priority Critical patent/CN110369123A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/005Pretreatment specially adapted for magnetic separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/005Pretreatment specially adapted for magnetic separation
    • B03C1/015Pretreatment specially adapted for magnetic separation by chemical treatment imparting magnetic properties to the material to be separated, e.g. roasting, reduction, oxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/02Magnetic separation acting directly on the substance being separated
    • B03C1/16Magnetic separation acting directly on the substance being separated with material carriers in the form of belts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Furnace Details (AREA)

Abstract

The invention discloses the deironing apparatus and technique of a kind of refractory material fine powder, the device includes fluidized bed furnace, fluidized bed furnace is equipped with the smoke outlet for excluding furnace gas from top to bottom, for receiving the feed inlet of refractory material fine powder, and the discharge port excluded for the refractory material fine powder after restoring, air distribution plate is equipped in fluidized bed furnace, air distribution plate is located at below discharge port, fluidized bed furnace part on air distribution plate and air distribution plate surrounds boiling cavity, fluidized bed furnace part under air distribution plate and air distribution plate surrounds inlet chamber, the gas inlet for conveying hot fume into boiling cavity is equipped on inlet chamber;It is successively arranged the first conveying mechanism, cooling body, second conveyor structure, ball mill after discharge port and removes ferromagnetic roller.Refractory material fine powder of the present invention by iron content higher than 5% is placed in fluidized bed furnace, and the flue gas being passed through in fluidized bed furnace not less than 750 DEG C forms reducing atmosphere, makes to be reduced to can be used the fe that magnetic roller is removed except iron mode under the iron oxide reducing atmosphere in refractory material fine powder.

Description

A kind of deironing apparatus and technique of refractory material fine powder
Technical field
The invention belongs to technical field of refractory materials, are related to the deironing apparatus and technique of a kind of refractory material fine powder.
Background technique
It is well known that it is all ferro-aluminum mineral intergrowth that the bauxite ore in China is most of, and in the calcination process of entire aluminium alum mine In, current technique is completed in oxidation environment, this allows for iron exists in the form of iron oxide always in aluminium alum mine, This allows for be completed in the way of magnetic deironing except iron, this allows for finished product --- the iron tramp in refractory material fine powder It not can be removed, once the iron-content in refractory material fine powder is more than 5%, will seriously affect the performance of refractory material fine powder.If sharp The mode of iron oxide in refractory material fine powder is impregnated with pickling to complete to remove iron, not only complex process, increased costs, cause it is serious Blowdown, it is often more important that its effective component changes after most of refractory material fine powder pickling, loses refractory material itself Attribute.This allows for the higher mining raw material of iron-content in the mining raw material of refractory material and is unable to get effective use, causes A large amount of wastes of production of resources.
Summary of the invention
It is higher in order to solve iron content in existing refractory material fine powder, it is difficult to the problem of removing and utilizing, the present invention The deironing apparatus and technique of a kind of refractory material fine powder are disclosed, the refractory material fine powder by iron content in finished product higher than 5-8% is set In fluidized bed furnace, and the flue gas being passed through in fluidized bed furnace not less than 750 DEG C forms reducing atmosphere, makes the oxidation in refractory material fine powder It is reduced to fe under iron reducing atmosphere, iron is removed so as to remove iron mode using magnetic roller.
The technical scheme of the present invention is realized as follows:
On the one hand, the invention discloses a kind of deironing apparatus of refractory material fine powder, including fluidized bed furnace, the fluidized bed furnace from upper and Have the smoke outlet for excluding furnace gas, the feed inlet for receiving refractory material fine powder and for resistance to after restoring The discharge port that fiery fine material powder excludes is equipped with air distribution plate in the fluidized bed furnace, and the air distribution plate is located at below discharge port, described Fluidized bed furnace part on air distribution plate and air distribution plate surrounds boiling cavity, and the air distribution plate is enclosed with the fluidized bed furnace part under air distribution plate At inlet chamber, the gas inlet for conveying hot fume into boiling cavity is equipped on the inlet chamber;After the discharge port It is successively arranged the first conveying mechanism, cooling body, second conveyor structure, ball mill and removes ferromagnetic roller.
As a further improvement, in order to make that the refractory material fine powder in fluidized bed furnace boils more sufficiently, the smoke outlet and Discharge port is located at opposite side that is ipsilateral, and being located at feed inlet, and further, the gas inlet and feed inlet are ipsilateral.
It is further improved, striker plate is staggeredly equipped in the fluidized bed furnace, for preventing the material in fluidized bed furnace with cigarette Gas discharge.
The smoke outlet is connected to by smoke exhaust pipe with gravitational precipitator as a preferred implementation manner, the cigarette after dedusting Gas burns for heating furnace to be used.Further, the gas inlet is connected to the gas outlet of heating furnace, the air inlet of the heating furnace Mouth is connected to booster fan, and the flue gas after dedusting is introduced into heating furnace burning by booster fan, is not less than 750 DEG C to generate Hot fume restore the iron oxide in refractory material fine powder, realize recycling for flue gas.
Preferably, the feed inlet is connected to the discharge port of star-shaped dust-discharging valve, naturally it is also possible to can be realized by other Any doffer of powder material conveying is realized.
Further, first and second conveying mechanism is screw conveyor or conveyor belt, naturally it is also possible to be other energy Enough realize any conveying mechanism of solid-state high-temperature material conveying;The cooling body be water cooling tank, be also possible to it is other can Realize the cooling other any cooling bodies of solid-state high-temperature material.
On the other hand, the invention also discloses a kind of deferrization process of refractory material fine powder, to the upper of fluidized bed furnace air distribution plate Refractory material fine powder is added in side, the hot fume not less than 750 DEG C is passed through below air distribution plate, by the refractory material above air distribution plate Iron oxide in fine powder is reduced to fe, and the refractory material fine powder for then transporting out boiling fire grate is through cooling, crushing, magnetic Blanking iron obtains finished product.
Since a small amount of impurity iron in mining raw material is oxidized to iron oxide together during calcining, iron oxide will be mixed It is miscellaneous not can be removed in finished product so that its iron content is exceeded, seriously affect the quality of finished product, it is of the invention except iron operation be by by The unqualified refractory material fine powder of excessive iron calcining into raw iron oxide is calcined in fluidized bed furnace in mining raw material, by fire resisting The iron oxide that not can be removed originally in fine material powder is reduced into fe again.
The hot fume temperature that heating furnace is supplied to fluidized bed furnace in the present invention is controlled at 750 DEG C or more, logical in air distribution plate lower part Enter hot fume, makes reducibility gas CO and H in the flue gas in boiling cavity2Temperature at 700 DEG C or more, air distribution plate top it is resistance to Fiery fine material powder hot fume advertise effect under, make Fe2O3It can be with CO, H2Reaction generates Fe, and entire reduction process Fe2O3 Reaction complete under reducing atmosphere.Fe will not be oxidized during sealing water is cooling, make to produce the middle and later periods always The ingredient of fe is kept, the iron in refractory material fine powder can be removed conducive to magnetic roller, and ball mill grinds thinner, taken off Except effect is better, in refractory material fine powder 95% or more iron can be removed substantially, can satisfy in refractory material iron content not Effect more than 1%.
Compared with prior art, the present invention having the following beneficial effects:
(1) present invention can will be because of the excessively high and underproof refractory material fine powder of iron-content next life according to the technical solution of the present invention Qualified refractory material finished product is produced, without considering the iron-content of raw mineral materials, the higher raw mineral materials of Fe content can also be exploited It uses, greatly reduces the cost of raw material, reduce cost of winning and difficulty comprising the raw mineral materials including aluminium alum mine, save About extraction value is the technological revolution and breakthrough of refractory material production;
(2) it is exactly that transformation can be completed using original process conditions and equipment that technique of the invention and equipment, which are improved, invest at This is low, more environmentally friendly using safe and effective, and using closing production;
(3) present invention is not only used in fire resisting material field, impurity iron can also be generated iron oxide in other calcination process And carry out operating except iron in the industry that do not can be removed, the program is easy to operate, is particularly suitable for China's raw mineral materials complicated component, product Characteristic more than kind has great dissemination.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention without any creative labor, may be used also for those of ordinary skill in the art To obtain other drawings based on these drawings.
Fig. 1 is the process flow chart of the embodiment of the present invention.
In figure: 1, fluidized bed furnace;2, air distribution plate;3, gravitational precipitator;4, heating furnace;5, booster fan;6, star-like to unload ash Valve;7, screw conveyor;8, water cooling tank;9, conveyor belt;10, ball mill;11, ferromagnetic roller is removed;12, striker plate.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Embodiment
The deironing apparatus of refractory material fine powder as shown in Figure 1, including fluidized bed furnace 1, the fluidized bed furnace 1 are equipped with from top to bottom For excluding the smoke outlet of furnace gas, the feed inlet for receiving refractory material fine powder and for the refractory material after restoring The discharge port that fine powder excludes is equipped with air distribution plate 2 in the fluidized bed furnace 1, and the air distribution plate 2 is located at below discharge port, the cloth 1 part of fluidized bed furnace on aerofoil 2 and air distribution plate 2 surrounds boiling cavity, the air distribution plate 2 and the fluidized bed furnace portion under air distribution plate 2 Divide and surround inlet chamber, the gas inlet for conveying hot fume into boiling cavity is equipped on the inlet chamber;The air distribution plate 2 It is obliquely installed, highest point is located at below feed inlet, and the minimum point of the air distribution plate is located at below discharge port;In order to make boiling cavity Interior refractory material fine powder reaction more sufficiently efficiently, and prevent refractory material fine powder hot fume advertise boiling under not from charging Mouth and discharge port are rushed out, and the smoke outlet is connected to by smoke exhaust pipe with gravitational precipitator 3, and the flue gas after dedusting is for heating furnace 4 Burning uses.The gas inlet is connected to the gas outlet of heating furnace 4, and the air inlet and booster fan 5 of the heating furnace 4 connect It is logical, the flue gas after dedusting is introduced by heating furnace 4 by booster fan 5 and is burnt, is gone back with generating the hot fume not less than 750 DEG C Iron oxide in former refractory material fine powder, realizes recycling for flue gas;The discharge port of the feed inlet and star-shaped dust-discharging valve 6 connects It is logical;
It is equipped with the screw conveyor 7 for receiving and conveying material at the discharge port rear, is discharged in the screw conveyor 7 The lower section of mouth is equipped with the water cooling tank 8 for cooling down material, is equipped with conveyor belt 9 below the discharge port of the water cooling tank 8, leads to It crosses conveyor belt 9 material is transported to ball mill 10 and material is crushed, then smashed material is placed in except ferromagnetic roller It is carried out on 11 except iron.
As a further improvement, in order to prevent in fluidized bed furnace material year flue gas discharge, in the fluidized bed furnace be equipped with hand over The striker plate 12 of mistake distribution;In order to make that the refractory material fine powder in fluidized bed furnace boils more sufficiently, the smoke outlet and discharge port Positioned at ipsilateral, the gas inlet and feed inlet are ipsilateral, and discharge port is located at the opposite side of feed inlet.
Its technical process are as follows: refractory material fine powder is added to the top of 1 air distribution plate 2 of fluidized bed furnace, the lower section of air distribution plate 2 is passed through Iron oxide in the refractory material fine powder of 2 top of air distribution plate is reduced to fe, then will by the hot fume not less than 750 DEG C The refractory material fine powder that 1 row of fluidized bed furnace transports out obtains finished product through cooling, crushing, iron removal by magnetic separation.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of deironing apparatus of refractory material fine powder, it is characterised in that: including fluidized bed furnace, the fluidized bed furnace is equipped with from top to bottom For excluding the smoke outlet of furnace gas, the feed inlet for receiving refractory material fine powder and for the refractory material after restoring The discharge port that fine powder excludes is equipped with air distribution plate in the fluidized bed furnace, and the air distribution plate is located at below discharge port, the air distribution plate Boiling cavity is surrounded with the fluidized bed furnace part on air distribution plate, the fluidized bed furnace part under the air distribution plate and air distribution plate surrounds air inlet Chamber is equipped with the gas inlet for conveying hot fume into boiling cavity on the inlet chamber;It is successively set after the discharge port There are the first conveying mechanism, cooling body, second conveyor structure, ball mill and removes ferromagnetic roller.
2. the deironing apparatus of refractory material fine powder as described in claim 1, it is characterised in that: the air distribution plate is obliquely installed, The highest point of the air distribution plate is located at below feed inlet, and the minimum point of the air distribution plate is located at below discharge port.
3. the deironing apparatus of refractory material fine powder as described in claim 1, it is characterised in that: staggeredly set in the fluidized bed furnace It is equipped with striker plate.
4. the deironing apparatus of refractory material fine powder as described in claim 1, it is characterised in that: the smoke outlet passes through smoke exhaust pipe It is connected to gravitational precipitator.
5. the deironing apparatus of refractory material fine powder as described in claim 1, it is characterised in that: the feed inlet unloads ash with star-like The discharge port of valve is connected to.
6. the deironing apparatus of refractory material fine powder as described in claim 1, it is characterised in that: the gas inlet and heating furnace Gas outlet connection, the air inlet of the heating furnace is connected to booster fan.
7. the deironing apparatus of refractory material fine powder as described in claim 1, it is characterised in that: first and second conveying mechanism For screw conveyor or conveyor belt.
8. the deironing apparatus of refractory material fine powder as described in claim 1, it is characterised in that: the cooling body is cooling for water Slot.
9. a kind of deferrization process of refractory material fine powder, it is characterised in that: refractory material is added to the top of fluidized bed furnace air distribution plate Fine powder is passed through the hot fume not less than 750 DEG C below air distribution plate, by the iron oxide in the refractory material fine powder above air distribution plate It is reduced to fe, the refractory material fine powder that fire grate transports out that then will boil is obtained into through cooling, crushing, iron removal by magnetic separation Product.
CN201910802256.7A 2019-08-28 2019-08-28 A kind of deironing apparatus and technique of refractory material fine powder Pending CN110369123A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114408980A (en) * 2022-02-11 2022-04-29 长沙有色冶金设计研究院有限公司 Preparation method and equipment of demanganizing agent

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB922019A (en) * 1960-01-11 1963-03-27 Exxon Research Engineering Co Iron ore magnetic roast process
GB1288252A (en) * 1969-03-25 1972-09-06
CN102653821A (en) * 2012-04-27 2012-09-05 洛阳栾川钼业集团股份有限公司 Fluidized bed furnace device for circularly roasting molybdenum concentrates and method for using same
CN203718760U (en) * 2014-02-28 2014-07-16 大理州大维肥业有限责任公司 Boiling furnace
CN107460307A (en) * 2017-07-19 2017-12-12 东北大学 A kind of high-iron bauxite suspension roasting utilization system and method
CN108588406A (en) * 2018-06-15 2018-09-28 甘肃酒钢集团宏兴钢铁股份有限公司 A kind of refractory iron ore suspension heating-coal base magnetic roasting process
CN210585357U (en) * 2019-08-28 2020-05-22 山西惟泰安全环保工程技术有限公司 Deironing device of refractory material fine powder

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB922019A (en) * 1960-01-11 1963-03-27 Exxon Research Engineering Co Iron ore magnetic roast process
GB1288252A (en) * 1969-03-25 1972-09-06
CN102653821A (en) * 2012-04-27 2012-09-05 洛阳栾川钼业集团股份有限公司 Fluidized bed furnace device for circularly roasting molybdenum concentrates and method for using same
CN203718760U (en) * 2014-02-28 2014-07-16 大理州大维肥业有限责任公司 Boiling furnace
CN107460307A (en) * 2017-07-19 2017-12-12 东北大学 A kind of high-iron bauxite suspension roasting utilization system and method
CN108588406A (en) * 2018-06-15 2018-09-28 甘肃酒钢集团宏兴钢铁股份有限公司 A kind of refractory iron ore suspension heating-coal base magnetic roasting process
CN210585357U (en) * 2019-08-28 2020-05-22 山西惟泰安全环保工程技术有限公司 Deironing device of refractory material fine powder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114408980A (en) * 2022-02-11 2022-04-29 长沙有色冶金设计研究院有限公司 Preparation method and equipment of demanganizing agent
CN114408980B (en) * 2022-02-11 2024-06-04 长沙有色冶金设计研究院有限公司 Preparation method and equipment of demanganizing agent

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