CN110368772A - The processing method and its device of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle - Google Patents

The processing method and its device of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle Download PDF

Info

Publication number
CN110368772A
CN110368772A CN201910088390.5A CN201910088390A CN110368772A CN 110368772 A CN110368772 A CN 110368772A CN 201910088390 A CN201910088390 A CN 201910088390A CN 110368772 A CN110368772 A CN 110368772A
Authority
CN
China
Prior art keywords
gas
tail gas
dichloropropane
propylene oxide
heat exchanger
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910088390.5A
Other languages
Chinese (zh)
Inventor
李民堂
王增礼
张媛华
耿立芳
张崇森
王秀明
冯鑫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG BEFAR GROUP DONGRUI CHEMICAL Co Ltd
BEFAR GROUP CO LTD
Original Assignee
SHANDONG BEFAR GROUP DONGRUI CHEMICAL Co Ltd
BEFAR GROUP CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANDONG BEFAR GROUP DONGRUI CHEMICAL Co Ltd, BEFAR GROUP CO LTD filed Critical SHANDONG BEFAR GROUP DONGRUI CHEMICAL Co Ltd
Priority to CN201910088390.5A priority Critical patent/CN110368772A/en
Publication of CN110368772A publication Critical patent/CN110368772A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/02Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

Abstract

The invention discloses a kind of processing methods of tail gas during propylene oxide, dichloropropane loading-unloading vehicle, which comprises the following steps: propylene oxide, dichloropropane handling tail gas enter surge tank through tail gas;Propylene oxide, dichloropropane handling tail gas by buffering are pressurized through the logical Roots blower that enters of tail gas;Pressurized propylene oxide, dichloropropane handling tail gas are entered into heat exchanger channels through tail gas again;Enter cold box system through tail gas by the propylene oxide of heat exchanger channels, dichloropropane handling tail gas;Propylene oxide, dichloropropane handling tail gas first pass through big channel plate-fin heat exchanger and are condensed into -100 DEG C, wherein trace water is frozen in the channel after tail gas enters cold box system;Cooled tail gas enters the first gas-liquid separator, isolates the condensate liquid of the components such as VOCs;The present invention meets the requirement of the recycling of valuable material and environment protection standard discharge in tail gas.

Description

During a kind of propylene oxide, dichloropropane loading-unloading vehicle the processing method of tail gas and its Device
Technical field
The present invention relates to the loading-unloading vehicle tail gas treatment process of organic matter, and in particular to a kind of propylene oxide, dichloropropane dress The processing method and its device of tail gas during unloading.
Background technique
The chlorohydrination tail gas that country's propylene oxide chlorohydrination method production technology generates at present is using the method being vented.Emptying group Divide predominantly ethylene, ethane, propylene, propane, dichloropropane etc., does not meet environmental requirement.Some enterprises are with incinerator by tail gas Burn-up, but hydrogen chloride can be generated when burning, serious corrosion is caused to incinerator, influences safety in production operation.In order to change This status, my company independently have developed the technique that a set of deep cooling adds carbon fiber adsorption and catalytic combustion processing chlorohydrination tail gas, increase The added value of device, thoroughly solves the problems, such as exhaust emissions.
Summary of the invention
To achieve the goals above, the invention provides the following technical scheme:
The present invention provides the processing method and its device of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle, Meet the requirement of the recycling of valuable material and environment protection standard discharge in tail gas.
The processing method of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle, which is characterized in that including following step It is rapid:
(1) propylene oxide, dichloropropane handling tail gas enter surge tank through tail gas;
(2) propylene oxide by buffering, dichloropropane handling tail gas are pressurized through the logical Roots blower that enters of tail gas;
(3) pressurized propylene oxide, dichloropropane handling tail gas are entered into heat exchanger channels through tail gas again;
(4) enter cold box system through tail gas by the propylene oxide of heat exchanger channels, dichloropropane handling tail gas;
(5) propylene oxide, dichloropropane handling tail gas first pass through big channel plate-fin after tail gas enters cold box system Heat exchanger is condensed into -100 DEG C, and wherein trace water is frozen in the channel;
(6) cooled tail gas enters the first gas-liquid separator, isolates the condensate liquid of the components such as VOCs;
(7) heat exchanger is removed from the gas that the first gas-liquid separator separates come out, it is multiple as the hydrolysis analysis gas that channel is freezed Wen Hou, using being gone out-of-bounds after ice chest;
(8) liquid come out from the first gas-liquid separator separates is after heat exchanger rewarming to room temperature, into the second gas-liquid Separator, the liquid come out from the second gas-liquid separator are gone out-of-bounds;
(9) blower inlet surge tank circular treatment is gone from the gas of the second gas-liquid separator separates;
(10) when VOCs content superelevation in the gas after separating, by the gas after separation from the inlet valve of adsorption tower lower end It into adsorption tower, is adsorbed using the active carbon on bed, the tail gas after absorption passes through the emptying on adsorption tower top again Valve is discharged into atmosphere.
Optionally, for the adsorption tower close to when reaching saturation, system automatically switches to the absorption of another adsorption tower, and right Close to the adsorption tower of saturation, then its active-carbon bed pressure is reduced.
Optionally, the hydrocarbon for the high concentration adsorbed on the active carbon is by vacuum pump, from the hole of active carbon It is detached in structure, and reenters condenser system and become liquid.
A kind of processing unit of tail gas during propylene oxide, dichloropropane loading-unloading vehicle, which is characterized in that the epoxy third The processing unit of tail gas is skid structure during alkane, dichloropropane loading-unloading vehicle;The skid structure includes that Roots blower increases Pressure and heat exchanger channels;Wherein the heat exchanger channels entrance is connect with activated carbon fiber absorber, drain respectively communicates, described Heat exchanger channels outlet is connect with the first gas-liquid separator feed inlet to be communicated;The first gas-liquid separator liquid-phase outlet and the second gas The connection of liquid/gas separator feed inlet communicates;The second gas-liquid separator gaseous phase outlet is filled with the carbon fiber adsorption and catalytic combustion respectively Set, drain connection communicate, the second gas-liquid separator liquid phase discharge port is connect with condensate tank to be communicated;The active carbon Fiber absorber is in parallel with the drain;The skid structure also wraps expansion unit, and the expansion unit refrigerant is air Or nitrogen;The expansion unit includes ice chest heat exchange module, and the ice chest heat exchange module is multichannel finned heat exchanger.
Optionally, the tail gas pressurization by tail gas buffer buffering is sent into heat exchanger channels module by the Roots blower In.
Optionally, the heat exchanger channels module is multichannel finned heat exchanger, can be described to change by tail gas condensing to -110 DEG C Passage of heat module be two groups can the heat exchange module that changes of two-way autogenous cutting, the heat exchanger channels module wherein one group it is deep as tail gas Cold condensation pass connects the first gas-liquid separator feed inlet, and another group of the heat exchanger channels module is used as gas-liquid separator gas phase Condensation pass connection activated carbon fiber absorber and drain again.
Optionally, two groups of the heat exchanger channels module can mutually switch.
Optionally, first gas-liquid separator, the second gas-liquid separator form gas-liquid separator, first gas-liquid Separator carries out gas-liquid separation to by -110 DEG C of tail gas of heat exchange module, and it is cold that the gas phase isolated returns to heat exchange module continuation After solidifying, cooling capacity is recycled through heat exchange module into connection activated carbon fiber absorber and drain access, the liquid phase isolated Heating enters the second gas-liquid separator afterwards;Its gas phase isolated of second gas-liquid separator is connected to tail gas buffer entrance, Its liquid phase isolated is sent into external condensation liquid storage tank by pipeline.
Optionally, the activated carbon fiber absorber is by two activated carbon fibre tanks and vacuum pump group at described two Activated carbon fibre tank is provided with active carbon fiber felt, can free switching access between two tanks;The vacuum pump is used in desorption.
Optionally, the activated carbon fibre tank has one working always, another is in desorption and stand-by state, when The activated carbon fibre tank of cut-in stand-by state takes over work, the work after saturation after the activated carbon fibre tank adsorption saturation of working condition Property Carbon fibe tank enters desorption and stand-by state.
The beneficial effects of the present invention are: tail gas during propylene oxide provided by the invention, dichloropropane loading-unloading vehicle Propylene oxide, dichloropropane handling tail gas are integrated pipeline by tail gas and sent to tail by processing method and processing device, present apparatus design Gas surge tank send to the air inlet of Roots blower through tail gas buffer top exit, send through Roots blower gas outlet to two It is a it is in parallel, alternately can open one of complete channel of heat exchanger channels entrance, heat exchange is carried out in heat exchanger channels and is cooled to -110 DEG C Left and right, after organic matter most in tail gas is condensed into liquid phase, feeding the first gas-liquid separator progress gas-liquid separation, first The gas phase that gas-liquid separator separates come out through upper gaseous phase outlet send to it is above-mentioned two it is in parallel, can alternately open complete heat exchanger channels Another channel, activated carbon fiber absorber and drain, the first gas-liquid point are sent into after heat exchanger channels exchange heat condensation again Enter heat exchange module through bottom liquid phases outlet from the liquid phase that device is separated to heat up, while recycling cooling capacity and improving cryogenic energy utilization Rate, liquid phase enters the second gas-liquid separator after heating, and the gas phase that the second gas-liquid separator separates come out is sent through upper gaseous phase outlet To tail gas buffer inlet, the liquid phase that the second gas-liquid separator separates come out is through sending pipeline outside into external reservoir;Tail gas is slow Rushing tank entrance has the changeable tail gas of emergency pipeline to send to carbon fiber adsorption and catalytic combustion entrance and tail gas drain;First gas-liquid separator The feeding activated carbon fiber absorber after second of heat exchange condensation of gas phase out is adsorbed, and the gas after absorption, which enters, to be put It eats dishes without rice or wine qualified discharge.
Detailed description of the invention
Fig. 1 be during a kind of propylene oxide provided by the invention, dichloropropane loading-unloading vehicle the processing method of tail gas and its Device figure.
Each label indicates in Fig. 1: 1- propylene oxide, dichloropropane loading-unloading vehicle exhaust pipe, 2- tail gas buffer, 3- Roots Air blower, 4- ice chest heat exchange module, the first gas-liquid separator of 5-, the second gas-liquid separator of 6-, 7- condensate liquid remove external reservoir pipe Road, 8- activated carbon fibre tank, 9- drain, two groups of 10- can two-way switching heat exchange module, 11- gas buffer tank, 12- compressor, 13- heat exchanger, 14- expanding machine, 15- vacuum pump.
Specific embodiment
The following are better embodiments of the invention, but are not intended to limit the scope of the present invention.
Embodiment 1:
The processing method of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle, which is characterized in that including following step It is rapid:
(1) propylene oxide, dichloropropane handling tail gas enter surge tank through tail gas;
(2) propylene oxide by buffering, dichloropropane handling tail gas are pressurized through the logical Roots blower that enters of tail gas;
(3) pressurized propylene oxide, dichloropropane handling tail gas are entered into heat exchanger channels through tail gas again;
(4) enter cold box system through tail gas by the propylene oxide of heat exchanger channels, dichloropropane handling tail gas;
(5) propylene oxide, dichloropropane handling tail gas first pass through big channel plate-fin after tail gas enters cold box system Heat exchanger is condensed into -100 DEG C, and wherein trace water is frozen in the channel;
(6) cooled tail gas enters the first gas-liquid separator, isolates the condensate liquid of the components such as VOCs;
(7) heat exchanger is removed from the gas that the first gas-liquid separator separates come out, it is multiple as the hydrolysis analysis gas that channel is freezed Wen Hou, using being gone out-of-bounds after ice chest;
(8) liquid come out from the first gas-liquid separator separates is after heat exchanger rewarming to room temperature, into the second gas-liquid Separator, the liquid come out from the second gas-liquid separator are gone out-of-bounds;
(9) blower inlet surge tank circular treatment is gone from the gas of the second gas-liquid separator separates;
(10) when VOCs content superelevation in the gas after separating, by the gas after separation from the inlet valve of adsorption tower lower end It into adsorption tower, is adsorbed using the active carbon on bed, the tail gas after absorption passes through the emptying on adsorption tower top again Valve is discharged into atmosphere.
Optionally, for the adsorption tower close to when reaching saturation, system automatically switches to the absorption of another adsorption tower, and right Close to the adsorption tower of saturation, then its active-carbon bed pressure is reduced.
Optionally, the hydrocarbon for the high concentration adsorbed on the active carbon is by vacuum pump, from the hole of active carbon It is detached in structure, and reenters condenser system and become liquid.
Refering to what is shown in Fig. 1, during propylene oxide provided in this embodiment, dichloropropane loading-unloading vehicle tail gas processing method And its device, including tail gas buffer 2, Roots blower 3, ice chest heat exchange module 4, the first gas-liquid separator 5, the second gas-liquid point From device 6, activated carbon fibre tank 8, drain 9, two groups can two-way switching heat exchange module 10, vacuum pump 15,.Wherein, tail gas buffers The entrance of the outlet of tank 2 connection Roots blower 3, Roots blower is frequency control, adjusts blower headend equipment gas in pipelines Pressure is in slight positive pressure state, and the outlet of Roots blower 3 can first gas-liquid separation of the two-way connection of switching heat exchange module 10 through two groups 5 feed inlet of device, two groups can two-way switching heat exchange module 10 be resistance sense should automatically switch, guarantee 10 access of heat exchange module in freeze Another access is switched to when blocking to work on;The gas phase that first gas-liquid separator 5 is separated is exported through upper gaseous phase through changing Another channel connection 8 entrance of carbon fiber adsorption and catalytic combustion tank and drain 9, the first gas-liquid separator 5 of thermal modules 10 are separated Liquid phase through bottom liquid phases export through heat exchange module 10 carry out rising temperature reclamation cooling capacity after enter the second gas-liquid separator 6, the second gas The gas phase that liquid/gas separator 6 is separated enters 2 inlet of tail gas buffer, and the liquid phase that the second gas-liquid separator 6 is separated is sent Enter in external reservoir.
Embodiment 2:
As shown in Figure 1, during the propylene oxide provided for the present embodiment 2, dichloropropane loading-unloading vehicle tail gas processing side Method and device design, have all components of the refining plant of the offer of embodiment 1, are not illustrating herein.It is different from embodiment 1 , it further include gas buffer tank 11 in the refining plant of the present embodiment 2, compressor 12, heat exchanger 13, expanding machine 14, In, the outlet of gas buffer tank 11 connects 13 entrance of heat exchanger through compressor 12, and heat exchanger 13 exports expanded machine 14 and connects gas 11 entrance of surge tank, temperature increases after gas is pressurized from gas buffer tank 11 to compressor 12, is cooled down at heat exchanger 13, It depressurizes and does work to expanding machine 14, finally into gas buffer tank 11, complete a down cycles.
The beneficial effects of the present invention are: tail gas during propylene oxide provided by the invention, dichloropropane loading-unloading vehicle Propylene oxide, dichloropropane handling tail gas are integrated pipeline by tail gas and sent to tail by processing method and processing device, present apparatus design Gas surge tank send to the air inlet of Roots blower through tail gas buffer top exit, send through Roots blower gas outlet to two It is a it is in parallel, alternately can open one of complete channel of heat exchanger channels entrance, heat exchange is carried out in heat exchanger channels and is cooled to -110 DEG C Left and right, after organic matter most in tail gas is condensed into liquid phase, feeding the first gas-liquid separator progress gas-liquid separation, first The gas phase that gas-liquid separator separates come out through upper gaseous phase outlet send to it is above-mentioned two it is in parallel, can alternately open complete heat exchanger channels Another channel, activated carbon fiber absorber and drain, the first gas-liquid point are sent into after heat exchanger channels exchange heat condensation again Enter heat exchange module through bottom liquid phases outlet from the liquid phase that device is separated to heat up, while recycling cooling capacity and improving cryogenic energy utilization Rate, liquid phase enters the second gas-liquid separator after heating, and the gas phase that the second gas-liquid separator separates come out is sent through upper gaseous phase outlet To tail gas buffer inlet, the liquid phase that the second gas-liquid separator separates come out is through sending pipeline outside into external reservoir;Tail gas is slow Rushing tank entrance has the changeable tail gas of emergency pipeline to send to carbon fiber adsorption and catalytic combustion entrance and tail gas drain;First gas-liquid separator The feeding activated carbon fiber absorber after second of heat exchange condensation of gas phase out is adsorbed, and the gas after absorption, which enters, to be put It eats dishes without rice or wine qualified discharge.
The above is only the preferred embodiment of the present invention, it is noted that those skilled in the art are come It says, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (10)

1. the processing method of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle, which is characterized in that including following step It is rapid:
(1) propylene oxide, dichloropropane handling tail gas enter surge tank through tail gas;
(2) propylene oxide by buffering, dichloropropane handling tail gas are pressurized through the logical Roots blower that enters of tail gas;
(3) pressurized propylene oxide, dichloropropane handling tail gas are entered into heat exchanger channels through tail gas again;
(4) enter cold box system through tail gas by the propylene oxide of heat exchanger channels, dichloropropane handling tail gas;
(5) propylene oxide, dichloropropane handling tail gas first pass through big channel plate fin heat-exchanging after tail gas enters cold box system Device is condensed into -100 DEG C, and wherein trace water is frozen in the channel;
(6) cooled tail gas enters the first gas-liquid separator, isolates the condensate liquid of the components such as VOCs;
(7) heat exchanger is removed from the gas that the first gas-liquid separator separates come out, as the hydrolysis analysis gas that channel is freezed, rewarming Afterwards, using being gone out-of-bounds after ice chest;
(8) liquid come out from the first gas-liquid separator separates is after heat exchanger rewarming to room temperature, into the second gas-liquid separation Device, the liquid come out from the second gas-liquid separator are gone out-of-bounds;
(9) blower inlet surge tank circular treatment is gone from the gas of the second gas-liquid separator separates;
(10) separate after gas in VOCs content superelevation when, by the gas after separation from the inlet valve of adsorption tower lower end enter It in adsorption tower, is adsorbed using the active carbon on bed, the tail gas after absorption passes through the blow valve row on adsorption tower top again It is put into atmosphere.
2. the processing method of tail gas during a kind of propylene oxide according to claim 1, dichloropropane loading-unloading vehicle, special Sign is: for the adsorption tower close to when reaching saturation, system automatically switches to the absorption of another adsorption tower, and to close saturation Adsorption tower, then reduce its active-carbon bed pressure.
3. the processing method of tail gas during a kind of propylene oxide according to claim 1, dichloropropane loading-unloading vehicle, special Sign is: the hydrocarbon for the high concentration adsorbed on the active carbon is taken off from the pore structure of active carbon by vacuum pump It separates out and, and reenter condenser system and become liquid.
4. the processing unit of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle, which is characterized in that the epoxy third The processing unit of tail gas is skid structure during alkane, dichloropropane loading-unloading vehicle;The skid structure includes that Roots blower increases Pressure and heat exchanger channels;Wherein the heat exchanger channels entrance is connect with activated carbon fiber absorber, drain respectively communicates, described Heat exchanger channels outlet is connect with the first gas-liquid separator feed inlet to be communicated;The first gas-liquid separator liquid-phase outlet and the second gas The connection of liquid/gas separator feed inlet communicates;The second gas-liquid separator gaseous phase outlet is filled with the carbon fiber adsorption and catalytic combustion respectively Set, drain connection communicate, the second gas-liquid separator liquid phase discharge port is connect with condensate tank to be communicated;The active carbon Fiber absorber is in parallel with the drain;The skid structure also wraps expansion unit, and the expansion unit refrigerant is air Or nitrogen;The expansion unit includes ice chest heat exchange module, and the ice chest heat exchange module is multichannel finned heat exchanger.
5. the processing unit of tail gas during a kind of propylene oxide according to claim 4, dichloropropane loading-unloading vehicle, special Sign is: the tail gas pressurization buffered by tail gas buffer is sent into heat exchanger channels module by the Roots blower.
6. the processing unit of tail gas during a kind of propylene oxide according to claim 5, dichloropropane loading-unloading vehicle, special Sign is: the heat exchanger channels module is multichannel finned heat exchanger, can be extremely -110 DEG C by tail gas condensing, the heat exchanger channels mould Block be two groups can the heat exchange module that changes of two-way autogenous cutting, the heat exchanger channels module wherein one group it is logical as tail gas cryogenic condensation Road connects the first gas-liquid separator feed inlet, and another group of the heat exchanger channels module condenses logical again as gas-liquid separator gas phase Road connects activated carbon fiber absorber and drain.
7. the processing unit of tail gas during a kind of propylene oxide according to claim 6, dichloropropane loading-unloading vehicle, special Sign is: two groups of the heat exchanger channels module can mutually switch.
8. the processing unit of tail gas during a kind of propylene oxide according to claim 4, dichloropropane loading-unloading vehicle, special Sign is: first gas-liquid separator, the second gas-liquid separator form gas-liquid separator, first gas-liquid separator pair Gas-liquid separation is carried out by -110 DEG C of tail gas of heat exchange module, after the gas phase return heat exchange module isolated continues condensation, into Enter to connect activated carbon fiber absorber and drain access, the liquid phase isolated heat up after heat exchange module recycles cooling capacity into Enter the second gas-liquid separator;Its gas phase isolated of second gas-liquid separator is connected to tail gas buffer entrance, isolates Liquid phase pass through pipeline be sent into external condensation liquid storage tank.
9. the processing unit of tail gas during a kind of propylene oxide according to claim 4, dichloropropane loading-unloading vehicle, special Sign is: the activated carbon fiber absorber is by two activated carbon fibre tanks and vacuum pump group at described two active carbon fibres Dimension tank is provided with active carbon fiber felt, can free switching access between two tanks;The vacuum pump is used in desorption.
10. the processing unit of tail gas during a kind of propylene oxide according to claim 9, dichloropropane loading-unloading vehicle, Be characterized in that: the activated carbon fibre tank has one working always, another is in desorption and stand-by state, when work shape The activated carbon fibre tank of cut-in stand-by state takes over work, the active carbon fibre after saturation after the activated carbon fibre tank adsorption saturation of state Dimension tank enters desorption and spare shape.
CN201910088390.5A 2019-01-31 2019-01-31 The processing method and its device of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle Pending CN110368772A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910088390.5A CN110368772A (en) 2019-01-31 2019-01-31 The processing method and its device of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910088390.5A CN110368772A (en) 2019-01-31 2019-01-31 The processing method and its device of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle

Publications (1)

Publication Number Publication Date
CN110368772A true CN110368772A (en) 2019-10-25

Family

ID=68248408

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910088390.5A Pending CN110368772A (en) 2019-01-31 2019-01-31 The processing method and its device of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle

Country Status (1)

Country Link
CN (1) CN110368772A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100107685A1 (en) * 2006-12-05 2010-05-06 Praxair Technology, Inc. Refinery gas upgrading via partial condensation and psa
US20140343341A1 (en) * 2011-12-20 2014-11-20 Sumitomo Seika Chemicals Co., Ltd. Purification method and purification system for propane
CN107469550A (en) * 2017-08-22 2017-12-15 刘祖虎 A kind of integrated condensing and the VOCs emission control systems and its processing method of absorption
CN207126329U (en) * 2017-08-25 2018-03-23 北京沃太斯环保科技发展有限公司 A kind of sledge fills oil extraction-generated waste water VOC waste gas pollution control and treatment complete set of equipments
CN107875668A (en) * 2017-12-18 2018-04-06 张伟华 A kind of cryogenic condensation separation method of C2 C5 alkene tail gas
CN108339369A (en) * 2018-03-16 2018-07-31 浙江大学 A kind of device and method of PVC device exhausts component separation and recycling

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100107685A1 (en) * 2006-12-05 2010-05-06 Praxair Technology, Inc. Refinery gas upgrading via partial condensation and psa
US20140343341A1 (en) * 2011-12-20 2014-11-20 Sumitomo Seika Chemicals Co., Ltd. Purification method and purification system for propane
CN107469550A (en) * 2017-08-22 2017-12-15 刘祖虎 A kind of integrated condensing and the VOCs emission control systems and its processing method of absorption
CN207126329U (en) * 2017-08-25 2018-03-23 北京沃太斯环保科技发展有限公司 A kind of sledge fills oil extraction-generated waste water VOC waste gas pollution control and treatment complete set of equipments
CN107875668A (en) * 2017-12-18 2018-04-06 张伟华 A kind of cryogenic condensation separation method of C2 C5 alkene tail gas
CN108339369A (en) * 2018-03-16 2018-07-31 浙江大学 A kind of device and method of PVC device exhausts component separation and recycling

Similar Documents

Publication Publication Date Title
CN101929788B (en) Device for preparing liquefied natural gas by oxygen-bearing coal mine methane
CN108826831B (en) Device and process for cryogenic separation of carbon monoxide gas by nitrogen circulation refrigeration
CN105004140A (en) Polypropylene tail gas recovery device and recovery method
CN102441310A (en) Method for recovering oil gas and device
CN211302556U (en) Polyolefin exhaust gas recovery system
CN101723338A (en) Method for extracting krypton-xenon from liquid oxygen
CN111578620A (en) Vehicle-mounted mobile system and process method for recovering hydrocarbon mixture and liquefied natural gas in oil field vent gas
CN107062798A (en) Atmospheric carbon dioxide liquefaction system and method
CN104110940A (en) Efficient air separation device utilizing liquefied natural gas cold energy
CN106524666B (en) Integrated mobile natural gas liquefaction device
CN206276186U (en) A kind of polyolefin tail recovery system
CN204830683U (en) Polypropylene tail gas recovery unit
CN114518016A (en) Carbon dioxide capturing, liquefying and recycling device and method
CN103073378B (en) Low-temperature methanol washing and alkane dehydrogenation combination system and coupling system of low-temperature methanol washing and alkane dehydrogenation combination system and alkene separation system
CN100365101C (en) Method for removing heavy hydrocarbon in natural gas by adsorption of heavy hydrocarbon
CN110368772A (en) The processing method and its device of tail gas during a kind of propylene oxide, dichloropropane loading-unloading vehicle
CN103589550A (en) Carbon dioxide balanced system for beer brewing technology
CN217330413U (en) System for retrieve argon gas and high-purity methane in hydrogen system
CN204240703U (en) A kind of efficient air separation unit utilizing cold energy of liquefied natural gas
CN114440551B (en) Device and method for recycling mixed hydrocarbon of associated gas of oil field rich in nitrogen and liquefying dry gas at low temperature
CN114377513B (en) Mobile train system and method for recovering and treating oilfield associated gas
CN208990491U (en) The processing system of tail gas during a kind of industrial chemicals is unloaded
CN206858511U (en) BOG recovery liquefaction removing Nitrogen in Natural Gases gas process systems
CN212467608U (en) Purification unit in vehicle-mounted movable oilfield emptying gas recovery system
CN111004082A (en) System and method for removing carbon dioxide from C2 fraction

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20191025