CN100365101C - Method for removing heavy hydrocarbon in natural gas by heavy hydrocarbon absorption - Google Patents
Method for removing heavy hydrocarbon in natural gas by heavy hydrocarbon absorption Download PDFInfo
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- CN100365101C CN100365101C CNB2005100180344A CN200510018034A CN100365101C CN 100365101 C CN100365101 C CN 100365101C CN B2005100180344 A CNB2005100180344 A CN B2005100180344A CN 200510018034 A CN200510018034 A CN 200510018034A CN 100365101 C CN100365101 C CN 100365101C
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- heavy hydrocarbon
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- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 149
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 149
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 147
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 239000003345 natural gas Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 32
- 238000010521 absorption reaction Methods 0.000 title description 3
- 239000007788 liquid Substances 0.000 claims abstract description 32
- 239000012071 phase Substances 0.000 claims abstract description 16
- 239000007791 liquid phase Substances 0.000 claims abstract description 13
- 235000009508 confectionery Nutrition 0.000 claims description 42
- 239000007789 gas Substances 0.000 claims description 24
- 241000282326 Felis catus Species 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000003507 refrigerant Substances 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 4
- 239000002737 fuel gas Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 230000001737 promoting effect Effects 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims 1
- 238000005265 energy consumption Methods 0.000 abstract description 5
- 238000003795 desorption Methods 0.000 abstract 1
- 239000007792 gaseous phase Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000003949 liquefied natural gas Substances 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
Heavy hydrocarbon absorbs the method of heavy hydrocarbon in the desorption natural gas, belong to a natural gas and take off the heavy hydrocarbon technique, in the invention, the natural gas that contains the heavy hydrocarbon gets into the bottom of taking off the heavy hydrocarbon tower, after removing most heavy hydrocarbon wherein in taking off the heavy hydrocarbon tower, discharge from the top of taking off the heavy hydrocarbon tower and be cooled off for gas-liquid two-phase, gaseous phase gets into next process, liquid phase is sent into the top of taking off the heavy hydrocarbon tower after the heavy hydrocarbon pump pressure boost and makes heavy hydrocarbon and natural gas contact against the current, thereby wash most heavy hydrocarbon in the natural gas, owing to adopt the invention, the natural gas takes off the heavy hydrocarbon flow and is simplified, device energy consumption greatly reduced, it is effectual to take off the heavy hydrocarbon, heavy hydrocarbon mole content can fall to below 10ppm in the natural gas after purifying, can satisfy.
Description
One, technical field: what the present invention relates to is the method for heavy hydrocarbon in a kind of natural the qi exhaustion heavy hydrocarbon technology, particularly heavy hydrocarbon absorbing and removing Sweet natural gas.
Two, background technology: Sweet natural gas is before liquefaction, and wherein contained heavy hydrocarbon must be removed, in order to avoid heavy hydrocarbon freezes and occluding device and pipeline at low temperatures.Existing natural qi exhaustion heavy hydrocarbon method has absorption method and rectification method etc. both at home and abroad.When adopting absorption method to take off heavy hydrocarbon, sorbent material commonly used is molecular sieve, silica gel and activated alumina etc., the degree that heavy hydrocarbon removes depends on the load of sorbent material and regenerated form etc., and this method and technology maturation can be reduced to the requirement of natural gas liquefaction with purifying heavy hydrocarbons content in the Sweet natural gas of back.But this method needs 2 adsorption tower blocked operations, and needs increase regeneration to use process furnace, and energy consumption is big.Rectification method takes off the principle that heavy hydrocarbon utilizes rectifying, and in rectifying tower, different according to heavy hydrocarbon and Sweet natural gas boiling point are separated heavy hydrocarbon contained in the Sweet natural gas.This method and technology maturation can be reduced to the requirement of natural gas liquefaction with purifying heavy hydrocarbons content in the Sweet natural gas of back.But adopt this method, need the thermal source heating at the bottom of the tower of rectifying tower, and cat head needs the low-temperature receiver cooling, thereby need set up heating system and cat head cooling system at the bottom of the rectifying tower, energy consumption is big.The shortcoming of above-mentioned two kinds of natural qi exhaustion heavy hydrocarbon methods is the technical process complexity, and energy consumption is big, and investment is high, is unfavorable for liquefied natural gas (LNG) plant saving investment, cuts down the consumption of energy.
Three, summary of the invention: the objective of the invention is to overcome the prior art above shortcomings, the method for heavy hydrocarbon in a kind of heavy hydrocarbon absorbing and removing Sweet natural gas is provided.The object of the present invention is achieved like this, in the method for the invention, the Sweet natural gas that contains heavy hydrocarbon enters the bottom of taking off the heavy hydrocarbon tower, after in taking off the heavy hydrocarbon tower, removing most of heavy hydrocarbon wherein, discharge and be cooled to gas-liquid two-phase from the top of taking off the heavy hydrocarbon tower, gas phase enters subsequent processing, liquid phase is admitted to the top of taking off the heavy hydrocarbon tower and makes heavy hydrocarbon and Sweet natural gas counter current contact after the supercharging of heavy hydrocarbon pump, thereby the most of heavy hydrocarbon in the Sweet natural gas is washed, may further comprise the steps: the first step will contain the heavy hydrocarbon Sweet natural gas and be divided into two bursts of logistics, one logistics and the gas phase heat exchange in gas-gas heat exchanger that comes autospasy heavy hydrocarbon cat head, another burst logistics and the liquid phase heat exchange in gas-liquid heat-exchange that comes at the bottom of the autospasy heavy hydrocarbon tower; Second step will be after gas-gas heat exchanger, gas-liquid heat-exchange heat exchange two strands contains the heavy hydrocarbon Sweet natural gas and mixes, and sends into the bottom of taking off the heavy hydrocarbon tower, with the heavy hydrocarbon counter current contact from cat head, after the most of heavy hydrocarbon in the Sweet natural gas is washed down, comes out from cat head; The 3rd step will be from taking off the natural gas via gas-gas heat exchanger heating that the heavy hydrocarbon cat head comes out; The 4th step will cool off from the heavy hydrocarbon cat head natural gas via refrigerant cooler of taking off of gas-gas heat exchanger, and wherein contained heavy hydrocarbon component is condensed; The 5th step was sent cooled Sweet natural gas into heavy hydrocarbon and divides flow container to carry out gas-liquid separation, and gas phase wherein is admitted to subsequent processing and handles, and liquid phase is boosted through the heavy hydrocarbon pump; Heavy hydrocarbon after the 6th step will boost is sent into the top of taking off the heavy hydrocarbon tower, and with the heavy hydrocarbon in the washing Sweet natural gas, liquid is collected into the bottom of taking off the heavy hydrocarbon tower; The liquid that the 7th step will take off at the bottom of the heavy hydrocarbon tower is extracted out, sends into the gas-liquid heat-exchange heating; The 8th step will be sent into the heavy hydrocarbon heater heats from the liquid of gas-liquid heat-exchange, and the promoting the circulation of qi liquid of going forward side by side separates, and gas phase wherein is admitted to factory's fuel gas system, and liquid phase is admitted to subsequent processing and handles.
In the methods of the invention, taking off the heavy hydrocarbon tower is packing tower, and the heavy hydrocarbon pump is an impeller pump, and refrigerant cooler can be a water cooler, also can be the part of ice chest, and the heavy hydrocarbon well heater had both played the effect with the thermal source heat exchange, played the effect of gas-liquid separation again.
Adopt the inventive method, natural qi exhaustion heavy hydrocarbon stream journey obtains simplifying, and plant energy consumption reduces greatly, and it is effective to take off heavy hydrocarbon, purifies back Sweet natural gas heavy hydrocarbon molar content and can reduce to below the 10ppm, can satisfy the needs of natural gas liquefaction.
Four, description of drawings: Fig. 1 is the method flow diagram of heavy hydrocarbon in the heavy hydrocarbon absorbing and removing Sweet natural gas, among the figure: 1, pipeline 2, pipeline 3, pipeline 4, pipeline 5, pipeline 6, pipeline 7, take off heavy hydrocarbon tower 8, pipeline 9, gas-gas heat exchanger 10, pipeline 11, refrigerant cooler 12, pipeline 13, pipeline 14, heavy hydrocarbon divides flow container 15, pipeline 16, heavy hydrocarbon pump 17, pipeline 18, pipeline 19, gas-liquid heat-exchange 20, pipeline 21, heavy hydrocarbon well heater 22, pipeline 23, pipeline 24, pipeline 25, pipeline 26, pipeline 27, pipeline.
Fig. 2 is the method main streams parameter list of heavy hydrocarbon in the heavy hydrocarbon absorbing and removing Sweet natural gas.
Five, embodiment: the present invention realizes by following examples, in the method for the invention, the Sweet natural gas that contains heavy hydrocarbon enters the bottom of taking off heavy hydrocarbon tower 7, after in taking off heavy hydrocarbon tower 7, removing most of heavy hydrocarbon wherein, discharge and be cooled to gas-liquid two-phase from the top of taking off heavy hydrocarbon tower 7, gas phase enters subsequent processing, liquid phase is admitted to the top of taking off heavy hydrocarbon tower 7 and makes heavy hydrocarbon and Sweet natural gas counter current contact after 16 superchargings of heavy hydrocarbon pump, thereby the most of heavy hydrocarbon in the Sweet natural gas is washed, may further comprise the steps: the first step will be divided into two bursts of logistics from the heavy hydrocarbon Sweet natural gas that contains of pipeline 1, one logistics enters in the gas-gas heat exchanger 9 by pipeline 2, with the gas phase heat exchange that comes autospasy heavy hydrocarbon tower 7, temperature reduces, come out by pipeline 4, another burst logistics enters in the gas-liquid heat-exchange 19 by pipeline 3, with the liquid phase heat exchange that comes autospasy heavy hydrocarbon tower 7, temperature reduces, and comes out by pipeline 5; Second step will contain the heavy hydrocarbon Sweet natural gas from pipeline 4, pipeline 5 two strands and mix, and send into the bottom of taking off heavy hydrocarbon tower 7 by pipeline 6, with the heavy hydrocarbon counter current contact from cat head, after the most of heavy hydrocarbon in the Sweet natural gas is washed down, discharge from cat head; The 3rd step will be sent into gas-gas heat exchanger 9 heat exchange by pipeline 8 from taking off the Sweet natural gas that comes out at heavy hydrocarbon tower 7 tops, and temperature raises; The 4th step will be sent in the refrigerant cooler 11 by pipeline 10 from the heavy hydrocarbon cat head Sweet natural gas that takes off of gas-gas heat exchanger 9, with the refrigeration agent heat exchange, temperature reduces, wherein contained heavy hydrocarbon component is condensed, come out by pipeline 12, in refrigerant cooler 11, refrigeration agent enters by pipeline 24, comes out by pipeline 25; The 5th step Sweet natural gas that will come out in the refrigerant cooler 11 is sent into heavy hydrocarbon and is divided and carry out gas-liquid separation in the flow container 14, and gas phase is wherein come out by pipeline 13, is admitted to subsequent processing and handles, and liquid phase is come out by pipeline 15, through 16 superchargings of heavy hydrocarbon pump; The 6th step will be sent into the top of taking off heavy hydrocarbon tower 7 by pipeline 17 through the heavy hydrocarbon of heavy hydrocarbon pump 16 superchargings, and with the heavy hydrocarbon in the washing Sweet natural gas, liquid is collected into the bottom of taking off heavy hydrocarbon tower 7; The 7th step will be taken off the liquid of heavy hydrocarbon tower 7 bottoms and be sent into gas-liquid heat-exchange 19 heating by pipeline 18; The 8th step will be sent into 21 heating of heavy hydrocarbon well heater by pipeline 20 from the heavy hydrocarbon of gas-liquid heat-exchange 19, the promoting the circulation of qi liquid of going forward side by side separates, gas phase wherein is admitted to factory's fuel gas system by pipeline 22, liquid phase is admitted to subsequent processing by pipeline 23 and handles, in heavy hydrocarbon well heater 21, thermal source enters by pipeline 26, comes out by pipeline 27.
In the methods of the invention, take off heavy hydrocarbon tower 7 and be packing tower, heavy hydrocarbon pump 16 is an impeller pump, and heavy hydrocarbon well heater 21 had both played the effect with the thermal source heat exchange, played the effect of gas-liquid separation again.
The parameter of present embodiment main streams is seen Fig. 2.Data setting raw natural gas flow among Fig. 2 is that 498.6kmol/h, temperature are that 39.9 ℃, pressure are that 5.681MPa, heavy hydrocarbon molar content are 1.147%.Data among the figure obtain with engineering software HYSIS simulation process process, and have passed through the check of engineering practice, and power only is 7.5kw, purify back Sweet natural gas heavy hydrocarbon molar content and are lower than 10ppm.
Claims (3)
1. the method for heavy hydrocarbon in the heavy hydrocarbon absorbing and removing Sweet natural gas, it is characterized in that: in the method for the invention, the Sweet natural gas that contains heavy hydrocarbon enters the bottom of taking off heavy hydrocarbon tower (7), after in taking off heavy hydrocarbon tower (7), removing most of heavy hydrocarbon wherein, discharge and be cooled to gas-liquid two-phase from the top of taking off heavy hydrocarbon tower (7), gas phase enters subsequent processing, liquid phase is admitted to the top of taking off heavy hydrocarbon tower (7) and makes heavy hydrocarbon and Sweet natural gas counter current contact after heavy hydrocarbon pump (16) supercharging, thereby the most of heavy hydrocarbon in the Sweet natural gas is washed, may further comprise the steps: the first step will contain the heavy hydrocarbon Sweet natural gas and be divided into two bursts of logistics, one logistics and the gas phase heat exchange in gas-gas heat exchanger (9) that comes autospasy heavy hydrocarbon tower (7) top, another burst logistics and the liquid phase heat exchange in gas-liquid heat-exchange (19) that comes autospasy heavy hydrocarbon tower (7) end; Second step will be after gas-gas heat exchanger (9), gas-liquid heat-exchange (19) heat exchange two strands contains the heavy hydrocarbon Sweet natural gas and mixes, send into the bottom of taking off heavy hydrocarbon tower (7), with heavy hydrocarbon counter current contact, after the most of heavy hydrocarbon in the Sweet natural gas is washed down, come out from cat head from cat head; The 3rd step will eject next natural gas via gas-gas heat exchanger (9) heating from taking off heavy hydrocarbon tower (7); The 4th step will cool off from heavy hydrocarbon tower (7) the top natural gas via refrigerant cooler (11) of taking off of gas-gas heat exchanger (9), and wherein contained heavy hydrocarbon component is condensed; The 5th step was sent cooled Sweet natural gas into heavy hydrocarbon and divides flow container (14) to carry out gas-liquid separation, and gas phase wherein is admitted to subsequent processing and handles, and liquid phase is boosted through heavy hydrocarbon pump (1 6); Heavy hydrocarbon after the 6th step will boost is sent into the top of taking off heavy hydrocarbon tower (7), and with the heavy hydrocarbon in the washing Sweet natural gas, liquid is collected into the bottom of taking off heavy hydrocarbon tower (7); The 7th step will be taken off the liquid extraction at heavy hydrocarbon tower (7) end, send into gas-liquid heat-exchange (19) heating; The 8th step will be sent into heavy hydrocarbon well heater (21) heating from the liquid of gas-liquid heat-exchange (19), and the promoting the circulation of qi liquid of going forward side by side separates, and gas phase wherein is admitted to factory's fuel gas system, and liquid phase is admitted to subsequent processing and handles.
2. according to the method for heavy hydrocarbon in the described heavy hydrocarbon absorbing and removing of claim 1 Sweet natural gas, it is characterized in that: taking off heavy hydrocarbon tower (7) is packing tower, and heavy hydrocarbon pump (16) is an impeller pump.
3. the method for heavy hydrocarbon in the heavy hydrocarbon absorbing and removing Sweet natural gas according to claim 1 is characterized in that: the used medium of heavy hydrocarbon is a heavy hydrocarbon in the washing Sweet natural gas in taking off heavy hydrocarbon tower (7).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100180344A CN100365101C (en) | 2005-09-23 | 2005-09-23 | Method for removing heavy hydrocarbon in natural gas by heavy hydrocarbon absorption |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100180344A CN100365101C (en) | 2005-09-23 | 2005-09-23 | Method for removing heavy hydrocarbon in natural gas by heavy hydrocarbon absorption |
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| CN1743418A CN1743418A (en) | 2006-03-08 |
| CN100365101C true CN100365101C (en) | 2008-01-30 |
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| CNB2005100180344A Expired - Fee Related CN100365101C (en) | 2005-09-23 | 2005-09-23 | Method for removing heavy hydrocarbon in natural gas by heavy hydrocarbon absorption |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8578734B2 (en) * | 2006-05-15 | 2013-11-12 | Shell Oil Company | Method and apparatus for liquefying a hydrocarbon stream |
| CN101508923B (en) * | 2009-03-12 | 2012-10-10 | 西安长庆科技工程有限责任公司 | Dehydration and de-heavy hydrocarbon apparatus and process for natural gas |
| CN101787314B (en) * | 2010-04-01 | 2013-04-17 | 中国石油大学(华东) | Process for compact natural gas liquefying and floating production |
| CN103865601B (en) * | 2014-03-13 | 2015-07-08 | 中国石油大学(华东) | Heavy hydrocarbon recovery method of propane precooling and deethanizer top reflux |
| CN112300844B (en) * | 2020-11-13 | 2022-02-18 | 大庆市中瑞燃气有限公司 | LNG liquefied heavy hydrocarbon removal method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2104753C1 (en) * | 1996-05-28 | 1998-02-20 | Товарищество с ограниченной ответственностью "ВолгоУралТехнология" | Method of producing commercial natural gas |
| CN1414067A (en) * | 2002-09-17 | 2003-04-30 | 大庆油田有限责任公司 | Recovery method of light hydrocarbon in natural gas |
| CN1490386A (en) * | 2003-08-17 | 2004-04-21 | 河南中原绿能高科有限责任公司 | Method for removing benzene in natural gas by isopentane |
-
2005
- 2005-09-23 CN CNB2005100180344A patent/CN100365101C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2104753C1 (en) * | 1996-05-28 | 1998-02-20 | Товарищество с ограниченной ответственностью "ВолгоУралТехнология" | Method of producing commercial natural gas |
| CN1414067A (en) * | 2002-09-17 | 2003-04-30 | 大庆油田有限责任公司 | Recovery method of light hydrocarbon in natural gas |
| CN1490386A (en) * | 2003-08-17 | 2004-04-21 | 河南中原绿能高科有限责任公司 | Method for removing benzene in natural gas by isopentane |
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