CN1103619C

CN1103619C - Scale preventing method for the concentration process of solution or liquid mixture

Info

Publication number: CN1103619C
Application number: CN98117306A
Authority: CN
Inventors: 陈源
Original assignee: Individual
Current assignee: Individual
Priority date: 1998-08-11
Filing date: 1998-08-11
Publication date: 2003-03-26
Anticipated expiration: 2018-08-11
Also published as: CN1244438A

Abstract

The present invention relates to a scale prevention method in a concentration process of a solution or a mixing liquid. The present invention is characterized in that the superheated vapor of a liquid directly mixes with and contacts the liquid in a container when the liquid is concentrated, and the liquid is evaporated by the superheat degree of the superheated vapor and saturated vapor under the same pressure. In the method of the present invention, the container filled with the evaporated liquid or the outer wall of a pipeline does not need heating. Consequently, the present invention avoids the problem that the solid substance contained by the evaporated liquid scales on the wall of the container when indirect heating is carried out. The present invention largely reduces the influence of the scale on the production.

Description

A kind of method that in solution or mixed liquor concentration process, prevents fouling

The present invention relates to a kind of method of liquid concentration, said liquid is solution or mixed liquor, belongs to the evaporation technique field.

In industrial production such as medicine, chemical industry, papermaking, metallurgy, usually need the concentration of solution to be increased some solution evaporation, also usually need the mixed liquor of some liquid-solid two-phase is evaporated so that its solid content is separated out.In these courses of reaction, conventional method is that solution or mixing material are placed container, implement heating from the outside, reach boiling point of liquid and evaporate, because in this container, its thermograde be with the heater span from increase and successively decrease gradually, the heating wall surface temperature the highest, be easy to fouling most.Adopt such technology regular meeting to make some DDGS and impurity in the solution be heated fouling on the wall of container, the formation of fouling reduces heat transfer coefficient, increases energy consumption, and production capacity descends.For scale removal, also to adopt method and increase equipment machinery or chemistry, this has not only strengthened production cost, also can cause to produce to interrupt.Such as, black liquor is handled and is just had such problem in paper industry.The processing of black liquid is great the topic that concerns environmental pollution, the situation that just exists the serious fouling of evaporator wall, influence to produce in the critical process black liquor vaporizing of handling black liquor in order to remove fouling, not only drops into increase, also want breaks in production, serious environment pollution.

Superheated vapor is a high-temperature vapour, it is existing multiple utilization in industrial production, the superheated-steam cracking, to cross thermal distillation all be that to utilize the heat energy of superheated vapor to carry out industrial, yet, but not to prevent that the container for evaporation fouling from being that purpose uses superheated vapor to remove concentrated liquid.

The purpose of this invention is to provide a kind of method of liquid being evaporated with superheated vapor, it can avoid fouling on container inner wall in evaporation process.

The object of the present invention is achieved like this:

A kind of method that in solution or mixed liquor concentration process, prevents fouling, its characteristics are, when making a kind of solution or contain the mixed liquor evaporation and concentration of solid content, constantly direct the mixing in container for evaporation with this liquid of the superheated vapor of this liquid contacted, and superheated vapor impels this liquid constantly to be evaporated from container after discharging heat.

The above-mentioned method that prevents fouling, described liquid are a kind of solution or mixed liquor, and the superheated vapor of described feeding is the liquid superheat steam identical with its liquid phase part, and the vapor volume that evaporates is the steam of feeding and the steam sum that the liquid liquid phase part is evaporated.

The above-mentioned method that prevents fouling, described liquid is black liquid, the superheated vapor of described feeding is an overheated steam.

The above-mentioned method that prevents fouling, the described partially liq steam that is evaporated makes it return to former temperature, and recycles once more through a closed circuit steam circulating heater.

Adopt this method that prevents fouling, the superheated vapor that is concentrated evaporated liquid is directly mixed in container with this liquid to be contacted, utilize superheated vapor and make this liquid evaporation with the degree of superheat of saturated vapour under the pressure, owing to need not to heat to filling the container that is evaporated liquid or the outer wall of pipeline, the wall temperature can not be higher than liquid, thereby has avoided being evaporated the problem that the contained solute of liquid or solid content matter are easy to fouling on wall.Because the superheated vapor component that adopts is identical with the liquid phase part that is evaporated liquid, so can change the character of primary liquid or produce other chemical reaction.

Below in conjunction with drawings and Examples the present invention is described in detail:

Fig. 1 is the principle schematic that the present invention uses in the black liquid concentration and evaporation.

Fig. 2 is the principle schematic after the present invention sets up closed circuit steam circulating heater;

Can see that in Fig. 1 the capital equipment that prevents the fouling method is container for evaporation or is referred to as evaporator 2 that the heat transfer medium that uses is superheated vapor.Fill the liquid that needs evaporation and concentration in the evaporator 2, the rare black liquor in the paper mill for example, rare black liquor is fed by evaporator inlet 4, overheated steam feeds from the below inlet 6 of evaporator, and overheated steam mixes with black liquor, emits heat, with the water evaporates in the black liquor, become saturated vapour, discharge from the top outlet 7 of evaporator, concentrated black liquid is discharged from evaporator below outlet 5.

In actual production, overheated steam can adopt the tail gas of power plant or private station, and is very economical.The saturated vapour that also can take to discharge heats the back cyclic utilization method again, can realize like this from balancing.In process of production, the temperature of supposing the overheated steam of employing is 400 degree, pressure is P=3.0 atmospheric pressure, the overheated steam heat content is 782.4 kilocalories/kilogram, with pressure saturated vapour heat content is 650.7 kilocalories/kilogram, heat of gasification is 517.3 kilocalories/kilogram, but then the per kilogram overheated steam becomes saturated vapour to release the heat transpiring moisture that sends be (782.4-650.77)/517.3=0.255 kilogram.That is to say, under the situation of above-mentioned sufficient condition heat exchange.Per 4 kilograms of overheated steams approximately can evaporate 1 kilogram of moisture, generate about 6 kilograms of saturated vapours.

Superheated vapor generating means 1 among Fig. 1 is power plant's tail gas or steam circulating heater.In order to guarantee to discharge the quality of filling gas of evaporator and avoid the black liquor loss, add a moisture trap 3 in the exit.

In device shown in Figure 2, the superheated vapor of use is that the steam of self output uses through heat cycles, and need not power plant or private station provides tail gas, can realize heating so be called closed circuit steam circulation from balancing.The high temperature oil that the outer thermal source 9 of heating superheated vapor adopts the coal burning heat-conducting oil stove to send here, or adopt electrical heating, certainly, also can adopt other thermal source.

Can set up Venturi tube 10 and circulating pump 12 in the closed circuit steam circulating heater, the collapsible tube one termination circulating pump of Venturi tube, anemostat one termination evaporator, the closed circuit steam circulating line 8 of trunnion one termination.The negative pressure of utilizing Venturi tube 10 to produce, but heating steam automatic stream evaporator 2 forms automatic closed cycle.The concentrated black liquid major part that circulating pump 12 is discharged evaporator enters next procedure, and only some enters Venturi tube to produce negative pressure.

Claims

1. method that in solution or mixed liquor concentration process, prevents fouling, it is characterized in that: when making a kind of liquid evaporation and concentration, constantly direct the mixing in container for evaporation with this liquid of overheated steam contacted, superheated vapor impels this liquid constantly to be evaporated from container after discharging heat, described liquid is black liquid, the described part steam that is evaporated is through a closed circuit steam circulating heater, outer thermal source makes it return to former temperature, and reuse, circulation then utilizes a Venturi tube and circulating pump to form an automatic closed circuit circulatory system and finishes.