CN110358478A - A kind of universal type industrial glue and preparation method thereof - Google Patents
A kind of universal type industrial glue and preparation method thereof Download PDFInfo
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- CN110358478A CN110358478A CN201910603085.5A CN201910603085A CN110358478A CN 110358478 A CN110358478 A CN 110358478A CN 201910603085 A CN201910603085 A CN 201910603085A CN 110358478 A CN110358478 A CN 110358478A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F118/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F118/02—Esters of monocarboxylic acids
- C08F118/04—Vinyl esters
- C08F118/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
Abstract
The invention discloses a kind of universal type industrial glue and, the raw material including following parts by weight: 40-50 parts of polyvinyl alcohol, 3-5 parts of formaldehyde, 2-5 parts of hydrochloric acid, 6-9 parts of sodium hydroxide, 2 parts of whole chain agent, 400-600 parts of water, 300-420 parts of vinylacetate, 4-6 parts of OP-10,36-39 parts of dibutyl phthalate, 0.2-0.8 parts of potassium peroxydisulfate.By adopting the above technical scheme, the technique is stable in process of production, and anti-freezing property is be not in freeze for subzero 3-5 degrees Celsius the phenomenon that；And relative to the industrial glue of 1788 type polyvinyl alcohol production, production cost is lower.
Description
Technical field
The present invention relates to industrial glue technical field, a kind of universal type industrial glue and preparation method thereof is referred specifically to.
Background technique
Industrial glue is industrially used for the technology that homogeneous or heterogeneous surface is linked together with adhesive, adhesive
It is continuous with stress distribution, it is light-weight, or the features such as sealing.Polyvinyl acetate emulsion is commonly called as white glue, is one of the most common type
Industrial adhesive.However, there is seasonal problems for the production of the glue, produced in winter using polyvinyl alcohol (1799 type)
White glue, there is will freeze and be not available when being lower than 5 degrees Celsius.Some producers use the polyethylene of import in winter
Alcohol (1788 types or 217 types) produces white glue, although the problem of can solve resistance to jelly, 1788 types or 217 types are relative to 1799 types
For price it is much higher.
Summary of the invention
The present invention is insufficient according to prior art, proposes a kind of universal type industrial glue and preparation method thereof, cost of manufacture
It is cheap, and will not freeze at low ambient temperatures, use scope is wider.
In order to solve the above-mentioned technical problem, the technical solution of the present invention is as follows:
A kind of universal type industrial glue, the raw material including following parts by weight: 40-50 parts of polyvinyl alcohol, 3-5 parts of formaldehyde,
2-5 parts of hydrochloric acid, 6-9 parts of sodium hydroxide, 2 parts of whole chain agent, 400-600 parts of water, 300-420 parts of vinylacetate, OP-104-6 parts,
36-39 parts of dibutyl phthalate, 0.2-0.8 parts of potassium peroxydisulfate.
Preferably, the polyvinyl alcohol is 1799 types.
Preferably, the OP-10 is nonionic surfactant alkyl phenol polyoxyethylene ether.
A kind of preparation method of universal type industrial glue, successively the following steps are included: including prepared by raw material preparation and finished product,
Wherein material preparation step includes,
Step 1: by load weighted polyvinyl alcohol and 95% load weighted water is taken successively to be added in a reaction kettle, stirring is risen
Temperature keeps the temperature 3 hours to 90-98 degrees Celsius；
Step 2: it is cooling after heat preservation, it is cooled to room temperature and hydrochloric acid, adjusting pH value to 1 is added dropwise, and stir 10 minutes；
Step 3: formaldehyde is added dropwise；
Step 4: carrying out condensation reaction after formaldehyde completion of dropwise addition；
Step 5: condensation terminal, i.e. addition sodium hydroxide solution is neutralized to PH7-7.5, stirs 10 minutes；
Step 6: whole chain agent is added in 45 degrees Celsius of heat preservation half an hour；
Step 7: being cooled to room temperature and vacuumizing half an hour to get freeze proof protecting colloid.
Preferably, wherein finished product preparation step includes:
Step 8: squeezing into protecting colloid described in step 7 into a polymeric kettle, while OP-10 and 70% is added
Load weighted potassium peroxydisulfate simultaneously covers, and 20% load weighted vinylacetate is added；
Step 9: stirring 10 minutes, after being warming up to 60 degrees Celsius, stop heating, it is allowed to flow back；
Step 10: remaining vinyl acetate is added dropwise and potassium peroxydisulfate carries out polymerization reaction after reflux；
Step 11: allowing it to be warming up to 85 degrees Celsius after vinyl acetate completion of dropwise addition and keeping the temperature 1 hour；
Step 12: being cooled to 70-75 degrees Celsius after heat preservation, o-2 potassium acid dibutyl ester is added；
Step 13: temperature is down to 60 degrees Celsius, 10% solution of sodium bicarbonate is added；
Step 14: stirring 15 minutes, discharge finished product.
Preferably, formaldehyde is added dropwise in the step 3, rate of addition control was dripped off at 40 minutes.
Preferably, the step 4 kind condensation reaction is specifically that occur half milky white for heat preservation to solution after formaldehyde completion of dropwise addition
Color, as condensation terminal.
Preferably, the step 10 is specifically that remaining vinyl acetate is added dropwise, remaining persulfuric acid is added after being added dropwise 2 hours
Potassium, and a potassium peroxydisulfate is added at interval of half an hour, entire polymeric reaction temperature control is at 80-85 degrees Celsius.
Preferably, the step 11 vinyl acetate was completed to be added dropwise within 7 hours.
The present invention have the characteristics that it is following and the utility model has the advantages that
By adopting the above technical scheme, the technique is stable in process of production, and anti-freezing property will not go out at subzero 3-5 degrees Celsius
The phenomenon that now freezing；And relative to the industrial glue of 1788 type polyvinyl alcohol production, production cost is lower.
Specific embodiment
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can phase
Mutually combination.
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", "upper", "lower",
The orientation or positional relationship of the instructions such as "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside",
Be merely for convenience of description of the present invention and simplification of the description, rather than the device or element of indication or suggestion meaning must have it is specific
Orientation, be constructed and operated in a specific orientation, therefore be not considered as limiting the invention.In addition, term " first ",
" second " etc. is used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance or implicitly indicates indicated skill
The quantity of art feature.The feature for defining " first ", " second " etc. as a result, can explicitly or implicitly include one or more
Multiple this feature.In the description of the present invention, unless otherwise indicated, the meaning of " plurality " is two or more.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " phase
Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected；It can
To be mechanical connection, it is also possible to be electrically connected；It can be directly connected, can also can be indirectly connected through an intermediary
Connection inside two elements.For the ordinary skill in the art, above-mentioned term can be understood by concrete condition
Concrete meaning in the present invention.
Embodiment 1
A kind of universal type industrial glue is present embodiments provided, the raw material including following parts by weight: 40 parts of polyvinyl alcohol,
3 parts of formaldehyde, 2 parts of hydrochloric acid, 6 parts of sodium hydroxide, 2 parts of whole chain agent, 400 parts of water, 3000 parts of vinylacetate, OP-104 parts, adjacent benzene
36 parts of dibutyl carboxylic acid, 0.2 part of potassium peroxydisulfate.
Preferably, the polyvinyl alcohol is 1799 types.
Preferably, the OP-10 is nonionic surfactant alkyl phenol polyoxyethylene ether.
Embodiment 2
The present embodiment the difference from embodiment 1 is that, the raw material including following parts by weight: 45 parts of polyvinyl alcohol, formaldehyde
4 parts, 3.5 parts of hydrochloric acid, 7 parts of sodium hydroxide, 2 parts of whole chain agent, 500 parts of water, 360 parts of vinylacetate, OP-105 parts, O-phthalic
37.5 parts of dibutyl phthalate, 0.6 part of potassium peroxydisulfate.
Embodiment 3
The present embodiment the difference from embodiment 1 is that, the raw material including following parts by weight: 40-50 parts of polyvinyl alcohol,
5 parts of formaldehyde, 5 parts of hydrochloric acid, 9 parts of sodium hydroxide, 2 parts of whole chain agent, 600 parts of water, 420 parts of vinylacetate, OP-106 parts, adjacent benzene two
39 parts of formic acid dibutyl ester, 0.8 part of potassium peroxydisulfate.
According to above-described embodiment compared with traditional glue carries out experiment, specific relatively data such as table 1:
Table 1
Embodiment 4
The present invention also provides a kind of preparation methods of universal type industrial glue, successively the following steps are included: including raw material
Preparation and finished product preparation,
Wherein material preparation step includes,
Step 1: by load weighted polyvinyl alcohol and 95% load weighted water is taken successively to be added in a reaction kettle, stirring is risen
Temperature keeps the temperature 3 hours to 90-98 degrees Celsius；
Step 2: it is cooling after heat preservation, it is cooled to room temperature and hydrochloric acid, adjusting pH value to 1 is added dropwise, and stir 10 minutes；
Step 3: formaldehyde is added dropwise；
Step 4: carrying out condensation reaction after formaldehyde completion of dropwise addition；
Step 5: condensation terminal, i.e. addition sodium hydroxide solution is neutralized to PH7-7.5, stirs 10 minutes；
Step 6: whole chain agent is added in 45 degrees Celsius of heat preservation half an hour；
Step 7: being cooled to room temperature and vacuumizing half an hour to get freeze proof protecting colloid.
The further setting of the present embodiment, wherein finished product preparation step include:
Step 8: squeezing into protecting colloid described in step 7 into a polymeric kettle, while OP-10 and 70% is added
Load weighted potassium peroxydisulfate simultaneously covers, and 20% load weighted vinylacetate is added；
Step 9: stirring 10 minutes, after being warming up to 60 degrees Celsius, stop heating, it is allowed to flow back；
Step 10: remaining vinyl acetate is added dropwise and potassium peroxydisulfate carries out polymerization reaction after reflux；
Step 11: allowing it to be warming up to 85 degrees Celsius after vinyl acetate completion of dropwise addition and keeping the temperature 1 hour；
Step 12: being cooled to 70-75 degrees Celsius after heat preservation, o-2 potassium acid dibutyl ester is added；
Step 13: temperature is down to 60 degrees Celsius, sodium bicarbonate is added, sodium bicarbonate is that the sodium bicarbonate that concentration is 10% is molten
Liquid；
Step 14: stirring 15 minutes, discharge finished product.
Specifically, formaldehyde is added dropwise in the step 3, rate of addition control was dripped off at 40 minutes.
Specifically, the step 4 kind condensation reaction is specifically that occur half milky white for heat preservation to solution after formaldehyde completion of dropwise addition
Color, as condensation terminal.
Specifically, the step 10 is specifically that remaining vinyl acetate is added dropwise, remaining persulfuric acid is added after being added dropwise 2 hours
Potassium, and a potassium peroxydisulfate is added at interval of half an hour, entire polymeric reaction temperature control is at 80-85 degrees Celsius.
Specifically, the step 11 vinyl acetate was completed to be added dropwise within 7 hours.
It in above-mentioned technical proposal, is learnt according to research, hydrogen bond is the root that glue freezes, therefore to solve the problems, such as to freeze
It just needs to reduce the active force of hydrogen bond, that is, reduces the quantity of hydroxyl, therefore use polyvinyl alcohol contracting first under the conditions of certain temperature
The quantity of the method reduction-OH of aldehyde, while it being allowed to form Liu Yuanhuan to greatest extent, increase steric hindrance, while whole chain agent is added and subtracts
Few branch degree.
Specifically, hydrochloric acid is added in step 2 as catalyst, in the condensation reaction, catalyst, which is added, can greatly speed up contracting
The speed of reaction is closed, and hydrochloric acid when concentration is 1, obtains best catalytic effect as catalyst.
Specifically, formaldehyde is added dropwise in step 3, formaldehyde is that reactant plays very big influence to condensation reaction naturally, and concentration is big
Reaction rate is fast, but for the protecting colloid for preparing freeze proof glue after condensation product forms a certain number of hexatomic rings, just
It is unnecessary to prevent going on smoothly for polymerization reaction because of the presence of formaldehyde with the presence of formaldehyde.Also therefore, in aldolisation knot
Shu Hou, it is necessary to dispose formaldehyde, therefore oxidant need to be added in step 6, with oxidation of formaldehyde at carbon dioxide and water.
Specifically, even if controlling temperature well, but also inevitably having many branches due to the complexity of condensation reaction
Structure generates, and branched structure is unfavorable to production glue and frost resistance, therefore uses the whole chain agent of addition and he is organized into straight chain
Or the molecular state that branch is less.
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right
It include portion to these embodiments in the case where not departing from the principle of the invention and spirit for those skilled in the art
Part carries out a variety of change, modification, replacement and modification, still falls in protection scope of the present invention.
Claims (7)
1. a kind of universal type industrial glue, which is characterized in that the raw material including following parts by weight: 40-50 parts of polyvinyl alcohol, first
3-5 parts of aldehyde, 2-5 parts of hydrochloric acid, 6-9 parts of sodium hydroxide, 2 parts of whole chain agent, 400-600 parts of water, 300-420 parts of vinylacetate, OP-
10 4-6 parts, 36-39 parts of dibutyl phthalate, 0.2-0.8 parts of potassium peroxydisulfate.
2. universal type industrial glue according to claim 1, which is characterized in that the polyvinyl alcohol is 1799 types.
3. universal type industrial glue according to claim 1, which is characterized in that the OP-10 is non-ionic surface active
Agent alkyl phenol polyoxyethylene ether.
4. the method for preparing universal type industrial glue described in any one of claims 1 to 3, which is characterized in that successively include
Following steps: preparing including raw material preparation and finished product,
Wherein material preparation step includes,
Step 1: by load weighted polyvinyl alcohol and 95% load weighted water is taken successively to be added in a reaction kettle, stirring is warming up to
90-98 degrees Celsius, and keep the temperature 3 hours；
Step 2: it is cooling after heat preservation, it is cooled to room temperature and hydrochloric acid, adjusting pH value to 1 is added dropwise, and stir 10 minutes；
Step 3: formaldehyde is added dropwise；
Step 4: carrying out condensation reaction after formaldehyde completion of dropwise addition；
Step 5: condensation terminal, i.e. addition sodium hydroxide solution is neutralized to PH7-7.5, stirs 10 minutes；
Step 6: whole chain agent is added in 45 degrees Celsius of heat preservation half an hour；
Step 7: being cooled to room temperature and vacuumizing half an hour to get freeze proof protecting colloid.
5. the preparation method of universal type industrial glue according to claim 4, which is characterized in that
Wherein finished product preparation step includes:
Step 8: squeezing into protecting colloid described in step 7 into a polymeric kettle, while OP-10 and 70% is added and weighs
Potassium peroxydisulfate and capping, be added 20% load weighted vinylacetate；
Step 9: stirring 10 minutes, after being warming up to 60 degrees Celsius, stop heating, it is allowed to flow back；
Step 10: remaining vinyl acetate is added dropwise and potassium peroxydisulfate carries out polymerization reaction after reflux；
Step 11: allowing it to be warming up to 85 degrees Celsius after vinyl acetate completion of dropwise addition and keeping the temperature 1 hour；
Step 12: being cooled to 70-75 degrees Celsius after heat preservation, o-2 potassium acid dibutyl ester is added；
Step 13: temperature is down to 60 degrees Celsius, 10% solution of sodium bicarbonate is added；
Step 14: stirring 15 minutes, discharge finished product.
6. the preparation method of universal type industrial glue according to claim 4, which is characterized in that be added dropwise in the step 3
Formaldehyde, rate of addition control were dripped off at 40 minutes.
7. the preparation method of universal type industrial glue according to claim 5, which is characterized in that the step 10 is specifically
Remaining vinyl acetate is added dropwise, adds remaining potassium peroxydisulfate after being added dropwise 2 hours, and add a persulfuric acid at interval of half an hour
Potassium, entire polymeric reaction temperature control is at 80-85 degrees Celsius.
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| CN201910603085.5A CN110358478A (en) | 2019-07-05 | 2019-07-05 | A kind of universal type industrial glue and preparation method thereof |
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| CN201910603085.5A CN110358478A (en) | 2019-07-05 | 2019-07-05 | A kind of universal type industrial glue and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078986A (en) * | 1992-05-21 | 1993-12-01 | 郭湘泗 | The white latex paint production technology |
| CN1089292A (en) * | 1993-01-04 | 1994-07-13 | 郭静峰 | The manufacture method of white glue with vinyl |
| CN101760157A (en) * | 2008-10-16 | 2010-06-30 | 张起明 | White latex capable of resisting low temperature |
| CN106987220A (en) * | 2017-05-03 | 2017-07-28 | 安徽忠盛新型装饰材料有限公司 | The formula and manufacturing process of a kind of white glue with vinyl |
-
2019
- 2019-07-05 CN CN201910603085.5A patent/CN110358478A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078986A (en) * | 1992-05-21 | 1993-12-01 | 郭湘泗 | The white latex paint production technology |
| CN1089292A (en) * | 1993-01-04 | 1994-07-13 | 郭静峰 | The manufacture method of white glue with vinyl |
| CN101760157A (en) * | 2008-10-16 | 2010-06-30 | 张起明 | White latex capable of resisting low temperature |
| CN106987220A (en) * | 2017-05-03 | 2017-07-28 | 安徽忠盛新型装饰材料有限公司 | The formula and manufacturing process of a kind of white glue with vinyl |
Non-Patent Citations (1)
| Title |
|---|
| 俞才林: "采用聚乙烯醇(1799型)制备抗冻白胶水", 《化学与粘合》 * |
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Application publication date: 20191022 |