CN110357581A - A method of lightweight wall plate is prepared using ceramic solid waste - Google Patents

A method of lightweight wall plate is prepared using ceramic solid waste Download PDF

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Publication number
CN110357581A
CN110357581A CN201910686109.8A CN201910686109A CN110357581A CN 110357581 A CN110357581 A CN 110357581A CN 201910686109 A CN201910686109 A CN 201910686109A CN 110357581 A CN110357581 A CN 110357581A
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solid waste
wall plate
vertical
lightweight wall
hole
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叶活耀
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1352Fuel ashes, e.g. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
    • E04C2/06Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres reinforced
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/44Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the purpose
    • E04C2/46Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the purpose specially adapted for making walls
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2002/005Appearance of panels
    • E04C2002/007Panels with the appearance of a brick wall
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Architecture (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to a kind of methods for preparing lightweight wall plate using ceramic solid waste, include material and proportion and manufacturing process flow, material mixture ratio are as follows: ceramic solid waste 70~85%, flyash 5~10%, discarded dregs 5~10%, sludge 5~10%, foaming agent are the 0.2~0.8% of total material;Process flow are as follows: 1) will be sieved after broken ceramic solid waste, flyash drying;2) ball milling is carried out respectively;3) it is measured according to the ratio;4) material does stirring 2 minutes in blender;5) assembly mold is laid with incombustible paper, is packed into powder and is sent into sintering oven sintering;6) 40 DEG C of kiln discharges successively are cooled to by preheating, sintering, cooling three operation stages;7) lightweight wall plate green body takes out, and is cut into predetermined size and shape by drawing;8) it crosses, process vertical through holes, cross through hole, vertical threading via hole, lateral threading via hole;9) vertical reinforcement is put in vertical through holes, puts transverse steel in cross through hole;10) glues pouring machine is poured into vertical through holes and cross through hole.

Description

A method of lightweight wall plate is prepared using ceramic solid waste
Technical field
The present invention relates to a kind of method for preparing lightweight wall plate using ceramic solid waste, belong to industrial solid castoff utilize with Building energy conservation materials for wall field, and in particular to a kind of to utilize the solid wastes such as ceramic solid waste, flyash, discarded dregs, sludge Object, again by being machined into a kind of lightweight wall plate with heat preservation, fire-proof function after high temperature sintering.
Background technique
Ceramic can generate a large amount of solid waste in production process, wherein most be cracking or deformation ceramic product, Waste material and ceramic defect ware that work in-process generates etc..With increasing rapidly for ceramic yield, the solid waste of generation is increasingly Increase.Currently, China's ceramic industry treatment of wastes produced is relatively low with utilization rate, a large amount of waste residues is caused to tie up arable land, pollution environment, Limit the development of ceramic industry.Ceramic industry solid waste becomes the problem of society and business circles are paid close attention to jointly using oneself;
The flyash of coal power plant discharge, also belongs to solid waste, also has pollution to environment and water source;
Urbanization, the speed-raising of urbanization, the reconstruction of the old city town in shanty town constantly expand, and produce largely discarded dregs, There is biggish pollution to environment and underground water source;
Sand(-)washing plant will generate a large amount of washed-out sand sludge in the process of sand, the sewage of industrial enterprise is produced by precipitating The domestic sludge of raw industrial sludge, city domestic sewage treatment plant settlement of sewage generation, it is harmful to environment, it is necessary to carry out Harmless treatment;
On the other hand, China uses most important thermal insulating material of the B2 grades of combustible material polyphenylene heat insulation slabs as building energy conservation Material, it is cheap although its thermal insulation property is superior, it is easy for construction;But it is easy to that serious fire occurs: as Beijing is entreated Depending on the wildfire occurred during the construction of exterior insulation system of new address 2009-02-03;The prosperous 2011-02-03 in Shenyang ten thousand is drawn due to fireworks The wildfire built up and occurred using the skyscraper outer heat preservation system of many years risen;Shanghai Jiangzhou road 2010-11-15 Building exterior wall heat preserving decoration renovation during the wildfire etc. that occurs, be all caused by polyphenylene heat insulation slab.For these Wildfire, relevant departments use series of improving measures, from heat preservation, fire proofing material to building heat preservation and architecture-integral. Although country pays much attention to the fire safety problem of architectural design, new to have formulated " Code for fire protection design of buildings " GB 50016-2014;But It is that by practice in recent years, or based on polyphenylene heat insulation slab, inorganic heat insulation material only accounts for few a part, few at this In the inorganic heat insulation material of part, the mainly foam glass of rock wool, air-entrained concrete building block, foam concrete block and fritter Deng, the lightweight wall plate of bulk cannot be formed, wall, but also substitution insulating layer have not only been substituted, and can be prevented fires, it is also durable.
How the solid waste such as ceramic solid waste, flyash, discarded dregs, sludge are fabricated to one kind has heat preservation, prevents Fiery, durable lightweight wall plate, had both solved the problem of environmental pollution of above-mentioned solid waste, and it is energy-efficient also to solve energy saving building Heat preservation, heat-insulated, the integrated wall problem of fire prevention, are the projects urgently studied.
The present invention attempts to carry out existing energy saving building insulating wall material technology innovation, substitution, designs a kind of utilization Method of the solid waste such as the ceramic solid waste preparation with heat preservation, the lightweight wall plate of fire-proof function, had both solved ceramic solid waste, powder The problem of environmental pollution of the solid waste such as coal ash, discarded dregs, sludge also solves the heat preservation, heat-insulated, anti-of energy saving building The deficient problem of fiery integrated wall material, improves the thermal insulation property of wall, fire protecting performance, and endurance quality has accomplished thermal insulating material Material and building same service life.
Summary of the invention
The technical scheme of the present invention is realized as follows: a kind of method for preparing lightweight wall plate using ceramic solid waste, special Sign is: including material and proportion and manufacturing process flow, material mixture ratio are as follows: ceramic solid waste 70~85%, flyash 5~ 10%, dregs 5~10%, sludge 5~10% are discarded, foaming agent is the 0.2~0.8% of total material;Process flow are as follows:
1) it will be sieved after broken ceramic solid waste, flyash, discarded dregs, sludge drying, remove metal impurities;
2) ceramic solid waste, flyash, discarded dregs, sludge carry out ball milling respectively after will be broken, and the fineness of dry powder is 200 Mesh, and send the storage of dry powder pan feeding standby, stand-by;
3) ceramic solid waste, flyash, discarded dregs, sludge, foaming agent are measured respectively according to the ratio;
4) material measured is launched in blender, does stirring 2 minutes;
5) sintering mold is assembled, incombustible paper is laid on die bottom plate, dry mash is loaded on incombustible paper, it will be equipped with dry The mold of powder is sent into continuous sintering tunnel oven and is sintered;
6) dry mash will be equipped with dry successively by heating preheating, three Isothermal sinter, cooling down operation stages in kiln Powder is sintered in continous way fired tunnel kiln, in heating warm-up phase, 9~25 DEG C/min of rate of heating, when temperature reaches When to 1130 DEG C, into the Isothermal sinter stage;The temperature range in Isothermal sinter stage fluctuates between 1130 DEG C~1280 DEG C, permanent Warm sintering time 0.5h~1.2h, the SiO of different wastes2、Al2O3、CaO+MgO、K2The content of O+NaO is different, takes difference Isothermal sinter temperature;In the cooling down stage, rate of temperature fall is 2~11 DEG C/min, belongs to slow cooling, prevents sintering wallboard Stress cracking is generated, until being cooled to 40 DEG C in kiln;
7) lightweight wall plate sintered is taken out out of mold;
8) lightweight wall plate is cut into defined size and shape by drawing;
9) it crosses to the baked light-weight wallboard 1 of well cutting, processes elongated recessed of elongated boss 2, one Slot 3, several vertical through holes 4, several cross through hole 5 and vertical threading via hole 9, lateral threading via hole 10;
10) vertical reinforcement 6 and fixation are placed in several vertical through holes 4, put lateral steel in several cross through hole 5 Muscle 7 and fixation;
11) metal connecting piece 11 for being located at 5 both ends of cross through hole is weldingly connected with transverse steel 7;
12) it after placing vertical reinforcement 6 and transverse steel 7, is poured into several vertical through holes 4 and several cross through hole 5 Self-leveling glues pouring machine 8;
13) it will be poured the lightweight wall plate after Self-leveling glues pouring machine 8, and was sent into curing kilns and carries out steam curing or nature Maintenance;
14) lightweight wall plate conserved carries out presentation quality, dimensional discrepancy, mechanical property, thermal property, fire protecting performance etc. It tests;
15) to qualified product packaging;
16) product warehousing.
Using the method produce lightweight wall plate be by baked light-weight wallboard 1, boss 2, groove 3, several vertical through holes 4, Several cross through hole 5, several vertical reinforcements 6, several transverse steels 7, glues pouring machine 8, vertical threading via hole 9, laterally threading Through-hole 10, several metal connecting pieces 11 are constituted.
The foaming agent is silicon carbide, and the incombustible paper is aluminum silicate fiber paper.
Detailed description of the invention:
Fig. 1 is a kind of process flow chart for the method that lightweight wall plate is prepared using ceramic solid waste of the present invention;
Fig. 2 is to be shown using a kind of lightweight wall plate solid for the method production for preparing lightweight wall plate using ceramic solid waste of the present invention It is intended to;
Fig. 3 is to be shown using a kind of lightweight wall plate left view for the method production for preparing lightweight wall plate using ceramic solid waste of the present invention It is intended to;
Fig. 4 is to be shown using a kind of lightweight wall plate vertical view for the method production for preparing lightweight wall plate using ceramic solid waste of the present invention It is intended to;
Fig. 5 is to be cutd open using a kind of lightweight wall plate A-A for the method production for preparing lightweight wall plate using ceramic solid waste of the present invention Face schematic diagram;
Fig. 6 is to be cutd open using a kind of lightweight wall plate B-B for the method production for preparing lightweight wall plate using ceramic solid waste of the present invention Face schematic diagram;
Fig. 7 is using a kind of connection of the lightweight wall plate for the method production for preparing lightweight wall plate using ceramic solid waste of the present invention The C-C diagrammatic cross-section of part 11;
Fig. 8 is using a kind of connection of the lightweight wall plate for the method production for preparing lightweight wall plate using ceramic solid waste of the present invention The schematic front view of part 11.
In figure: 1 is baked light-weight wallboard
2 be boss
3 be groove
4 be vertical through holes
5 be cross through hole
6 be vertical reinforcement
7 be transverse steel
8 be glues pouring machine
9 be vertical threading via hole
10 be lateral threading via hole
11 be metal connecting piece
12 be connecting hole
Specific embodiment
The invention is realized in this way 1~Fig. 8 is described further with reference to the accompanying drawing: a kind of to utilize ceramic solid waste system The method of standby lightweight wall plate, includes material and proportion and manufacturing process flow, material mixture ratio are as follows: ceramic solid waste 70~85%, Flyash 5~10%, discards dregs 5~10%, sludge 5~10%, and foaming agent is the 0.2~0.8% of total material;Process flow Are as follows:
1) it will be sieved after broken ceramic solid waste, flyash, discarded dregs, sludge drying, remove metal impurities;
2) ceramic solid waste, flyash, discarded dregs, sludge are subjected to ball milling respectively, the fineness of dry powder is 200 mesh, and is sent The storage of dry powder pan feeding is standby, stand-by;
3) ceramic solid waste, flyash, discarded dregs, sludge, foaming agent are measured respectively according to the ratio;
4) material measured is launched in blender, does stirring 2 minutes;
5) sintering mold is assembled, incombustible paper is laid on die bottom plate, dry mash is loaded on incombustible paper, dry powder will be housed The mold of material is sent into continuous sintering tunnel oven and is sintered;
6) dry mash is in kiln successively by heating preheating, three Isothermal sinter, cooling down operation stages: pre- in heating Hot stage, 9~25 DEG C/min of rate of heating, when temperature reaches 1130 DEG C, into the Isothermal sinter stage;The Isothermal sinter stage Temperature range fluctuated between 1130 DEG C~1280 DEG C, Isothermal sinter time 0.5h~1.2h, different trade wastes SiO2、Al2O3、CaO+MgO、K2The content of O+NaO is different, takes different Isothermal sinter temperature;In the cooling down stage, drop Warm rate is 2~11 DEG C/min, belongs to slow cooling, prevents sintering wallboard from generating stress cracking, until being cooled to 40 DEG C in kiln;
7) lightweight wall plate sintered is taken out out of mold;
8) lightweight wall plate is cut into defined size and shape by drawing;
9) it crosses to the baked light-weight wallboard 1 of well cutting, processes elongated recessed of elongated boss 2, one Slot 3, several vertical through holes 4, several cross through hole 5 and vertical threading via hole 9, lateral threading via hole 10;
10) vertical reinforcement 6 and fixation are placed in several vertical through holes 4, put lateral steel in several cross through hole 5 Muscle 7 is simultaneously fixed;
11) metal connecting piece 11 for being located at 5 both ends of cross through hole is weldingly connected with transverse steel 7;
12) it after placing vertical reinforcement 6 and transverse steel 7, is poured into several vertical through holes 4 and several cross through hole 5 Self-leveling glues pouring machine 8;
13) it will be poured the lightweight wall plate after Self-leveling glues pouring machine 8, and was sent into curing kilns and carries out steam curing or nature Maintenance;
14) lightweight wall plate conserved carries out presentation quality, dimensional discrepancy, mechanical property, thermal property, fire protecting performance etc. It tests;
15) to qualified product packaging;
16) product warehousing.
Using lightweight wall plate produced by the invention be by baked light-weight wallboard 1, boss 2, groove 3, several vertical through holes 4, Several cross through hole 5, several vertical reinforcements 6, several transverse steels 7, glues pouring machine 8, vertical threading via hole 9, laterally threading Through-hole 10, several metal connecting pieces 11 are constituted.
The foaming agent is silicon carbide;The incombustible paper is aluminum silicate fiber paper.
The beneficial effect comprise that:
1) using a kind of method for preparing lightweight wall plate using ceramic solid waste of the invention produce have heat preservation, every Heat is prevented fires, the lightweight wall plate of durable function, is the technology innovation to existing energy saving building heat-preserving wall, substitution.This lightweight Wallboard solves the serious quality problems such as the fire prevention of working procedure and exterior-wall heat insulation of exterior insulation, is carrying out energy saving building Work progress in, greatly improve speed of application, considerably reduce building cost, meanwhile, improve wall heat preservation, every Heat, sound insulation value, fire protecting performance have accomplished thermal insulation material and building same service life.Such baked light-weight wallboard has intensity High, the advantages that water absorption rate is low, thermal inertia is good, thermal insulation property is high, fire protecting performance belongs to incombustible material, durability is good, frost resistance is good, Meet the requirement of new edition " Code for fire protection design of buildings " GB 50016-2014 (version in 2018).
2) using a kind of method for preparing lightweight wall plate using ceramic solid waste of the invention, using ceramic solid waste, flyash, A large amount of solid waste such as discarded dregs, sludge, fired through feedstock processing, reasonably combined, high temperature, it is machined again form, It greatly solves environmental protection problem, turns waste into wealth, the benign cycle for reaching resource utilizes.

Claims (2)

1. a kind of method for preparing lightweight wall plate using ceramic solid waste, it is characterised in that: include material and proportion and manufacture work Skill process, material mixture ratio are as follows: ceramic solid waste 70~85%, flyash 5~10%, discarded dregs 5~10%, sludge 5~10%, Foaming agent is the 0.2~0.8% of total material;Process flow are as follows:
1) it will be sieved after broken ceramic solid waste, flyash, discarded dregs, sludge drying, remove metal impurities;
2) ceramic solid waste, flyash, discarded dregs, sludge are subjected to ball milling respectively, the fineness of dry powder is 200 mesh, and send dry powder Pan feeding storage is standby, stand-by;
3) ceramic solid waste, flyash, discarded dregs, sludge, foaming agent are measured respectively according to the ratio;
4) material measured is launched in blender, does stirring 2 minutes;
5) sintering mold is assembled, incombustible paper is laid on die bottom plate, dry mash is loaded on incombustible paper, dry mash will be housed Mold is sent into continuous sintering tunnel oven and is sintered;
6) dry mash is in kiln successively by heating preheating, three Isothermal sinter, cooling down operation stages: preheating rank in heating Section, 9~25 DEG C/min of rate of heating, when temperature reaches 1130 DEG C, into the Isothermal sinter stage;The temperature in Isothermal sinter stage Degree range fluctuates between 1130 DEG C~1280 DEG C, Isothermal sinter time 0.5h~1.2h, the SiO of different trade wastes2、 Al2O3、CaO+MgO、K2The content of O+NaO is different, takes different Isothermal sinter temperature;In the cooling down stage, rate of temperature fall For 2~11 DEG C/min, belong to slow cooling, prevents sintering wallboard from generating stress cracking, until being cooled to 40 DEG C in kiln;
7) lightweight wall plate sintered is taken out out of mold;
8) lightweight wall plate is cut into defined size and shape by drawing;
9) cross to the baked light-weight wallboard (1) of well cutting, process an elongated boss (2), one it is elongated recessed Slot (3), several vertical through holes (4), several cross through hole (5) and vertical threading via hole (9), lateral threading via hole (10);
10) vertical reinforcement (6) and fixation are placed in several vertical through holes (4), put transverse direction in several cross through hole (5) Reinforcing bar (7) and fixation;
11) metal connecting piece (11) for being located at cross through hole (5) both ends is weldingly connected with transverse steel (7);
12) after placing vertical reinforcement (6) and transverse steel (7), into several vertical through holes (4) and several cross through hole (5) It is poured Self-leveling glues pouring machine (8);
13) it will be poured the lightweight wall plate after Self-leveling glues pouring machine (8), and was sent into curing kilns and carries out steam curing or naturally feeding Shield;
14) lightweight wall plate conserved carries out presentation quality, dimensional discrepancy, mechanical property, thermal property, fire protecting performance etc. and carries out It examines;
15) to qualified product packaging;
16) product warehousing.
2. a kind of method for preparing lightweight wall plate using ceramic solid waste according to claim 1, it is characterised in that: use this The lightweight wall plate of method production is by baked light-weight wallboard (1), boss (2), groove (3), several vertical through holes (4), several cross To through-hole (5), several vertical reinforcements (6), several transverse steels (7), glues pouring machine (8), vertical threading via hole (9), transverse direction Threading via hole (10), several metal connecting pieces (11) are constituted.
CN201910686109.8A 2019-07-29 2019-07-29 A method of lightweight wall plate is prepared using ceramic solid waste Pending CN110357581A (en)

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