CN110350270A - The cooling heat-transfer device of plate type heating and the controllable temperature lithium battery group using the device - Google Patents

The cooling heat-transfer device of plate type heating and the controllable temperature lithium battery group using the device Download PDF

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Publication number
CN110350270A
CN110350270A CN201910745766.5A CN201910745766A CN110350270A CN 110350270 A CN110350270 A CN 110350270A CN 201910745766 A CN201910745766 A CN 201910745766A CN 110350270 A CN110350270 A CN 110350270A
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China
Prior art keywords
heat
cooling heat
heating
lithium battery
plate type
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CN201910745766.5A
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Chinese (zh)
Inventor
邓昌沪
邓梁
孙勇军
杨志明
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Shenzhen Weite Xinda Technology Co Ltd
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Shenzhen Weite Xinda Technology Co Ltd
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Priority to CN201910745766.5A priority Critical patent/CN110350270A/en
Priority to PCT/CN2019/104565 priority patent/WO2021026979A1/en
Publication of CN110350270A publication Critical patent/CN110350270A/en
Withdrawn legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0585Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/613Cooling or keeping cold
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/615Heating or keeping warm
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/62Heating or cooling; Temperature control specially adapted for specific applications
    • H01M10/625Vehicles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/64Heating or cooling; Temperature control characterised by the shape of the cells
    • H01M10/647Prismatic or flat cells, e.g. pouch cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/653Means for temperature control structurally associated with the cells characterised by electrically insulating or thermally conductive materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6551Surfaces specially adapted for heat dissipation or radiation, e.g. fins or coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6554Rods or plates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6556Solid parts with flow channel passages or pipes for heat exchange
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/656Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
    • H01M10/6567Liquids
    • H01M10/6568Liquids characterised by flow circuits, e.g. loops, located externally to the cells or cell casings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/657Means for temperature control structurally associated with the cells by electric or electromagnetic means
    • H01M10/6571Resistive heaters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The present invention provides a kind of cooling heat-transfer devices of plate type heating, including heating cooling heat-conducting piece, the cooling heat-conducting piece that heats is made of heat exchanger plate and the infrared heating film being attached on the heat exchanger plate one side, and the heat exchanger plate is equipped with the first water conservancy diversion cavity for loading graphene fluid media (medium).At low ambient temperatures, infrared heating film heating power heats the object being in contact with it.Under high temperature environment, infrared heating film stops being powered, and the heat that object itself generates is transferred on graphene fluid media (medium) by way of heat transfer.The purpose that heat is reached for object cooling is taken away in the flowing of graphene fluid media (medium).The purpose that object controllable temperature is realized by way of heat temperature raising, heat transfer cooling, guarantees that object is not influenced and played the function of itself script by environmental change.

Description

The cooling heat-transfer device of plate type heating and the controllable temperature lithium battery group using the device
Technical field
The present invention relates to temperature control device technical field, refers in particular to a kind of cooling heat-transfer device of plate type heating and use the dress The controllable temperature lithium battery group set.
Background technique
In new-energy automobile accessory, lithium battery is widely used as power source source.Lithium battery operating temperature limit In a certain range, at low ambient temperatures, since electrolysis fluid viscosity increases, hinder to lead to shadow between the round-trip anode of lithium ion, cathode Flash-over characteristic is rung, is lower than in the case of -40 DEG C, ice crystal is caused capacity to reduce to no current and exported by electrolyte.Document is recorded :- 20 DEG C of 25 degree of ratios, capacity reduce 50%.Power attenuation becomes apparent, and -20 DEG C, 0.2C discharge voltage plateau 3.3V;- 20 DEG C, 0.5C electric discharge, voltage platform < 3V;- 20 DEG C, almost place's no current exports [Chen Jitao, Zhou Henghui, Ni Jiangfeng, Chang Wen for 1C electric discharge Protect, Ci Yunxiang, C/LiCoO2 system lithium cell low temperature charge-discharge performance [J] battery 2004, volume 34, the 2nd phase], electricity will be caused Electrical automobile can not start.
When charging and discharging lithium battery, inside battery heat production includes: ohm heat, the electrochemical reaction of the internal resistance in battery system Heat, side reaction heat and polarization heat;Wherein side reaction heat is generated due to decomposition of electrolyte etc. in battery use process, Polarization heat is generated since the electromotive force of electrode deviates balance electric gesture, and lithium battery is in lasting charge or discharge process, such as Fruit fails timely by inside battery heat production by effectively radiating, and it is excessively high and formed to may cause battery temperature under high temperature environment Thermal runaway even can make battery that explosion on fire occur when serious.
To sum up, to guarantee the normal output power of battery, extending battery cycle life, it is necessary to carry out heat pipe to battery Reason --- the normal working temperature of battery is maintained, the overall performance of electric car under low temperature environment is improved, cold season should be met The heating and heat preservation of section, it is necessary to guarantee the dynamic lithium battery cooling and heat dissipation of the electric car under hot environment.
Summary of the invention
The technical problems to be solved by the present invention are: design one is used for the dress of heating and thermal insulation when heat dissipation, low temperature when high temperature It sets.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention are as follows: a kind of cooling heat-transfer device of plate type heating, Including heating cooling heat-conducting piece, the cooling heat-conducting piece of the heating is by heat exchanger plate and is attached to red on the heat exchanger plate one side Additional hotting mask is constituted, and the heat exchanger plate is equipped with the first water conservancy diversion cavity for loading graphene fluid media (medium).
It further, further include radiator, the radiator is equipped with the second water conservancy diversion for loading graphene fluid media (medium) Cavity;The first water conservancy diversion cavity is equipped with the first inlet and the first liquid outlet, and the second water conservancy diversion cavity is equipped with the second feed liquor Mouth and the second liquid outlet;First liquid outlet is connect with second inlet, second liquid outlet with described first into The connection of liquid mouth.
Further, circulating pump is also connected between second liquid outlet and first inlet.
Further, circulation conducting valve is additionally provided between the circulating pump and first inlet.
Further, fluid reservoir is additionally provided between the circulating pump and the circulation conducting valve.
Further, there are two the cooling heat-conducting pieces of the heating;Two first liquid outlets pass through the first tee pipe fitting It is connect with second inlet;Two first inlets are connect by the second tee pipe fitting with the circulation conducting valve.
Further, the infrared heating film, the heat exchanger plate and the first water conservancy diversion cavity are in rectangle, and described The baffle group of the restricted graphene fluid media (medium) flowing in wave shape of setting in one diversion cavity body;The radiator is fin heat dissipation Device.
Further, by infra-red radiation layer occurs for the infrared heating film and the insulation of layer occurs for the package infra-red radiation Layer is constituted;Layer occurs for the infra-red radiation by carbon black or micro-nano graphite composite powder or carbon nano-fiber or carbon nanotube or graphene Material is made;The heat exchanger plate is made of aluminium;The graphene fluid media (medium) is made of graphene and dimethicone, institute The mass ratio for stating graphene and the dimethicone is 5-10:90-95.
A kind of controllable temperature lithium battery group, including lithium battery group and plate type heating cool down heat-transfer device, and the plate type heating is cold But heat-transfer device is connect by the cooling heat-conducting piece of the heating with the lithium battery group.
Further, the lithium battery electric core of the lithium battery group is made of at least two laminates, the side of every layer of lamination Edge connects with the infrared heating film for heating cooling heat-conducting piece;The lithium battery group is located at the cooling heat-conducting piece of two heating Between.
The beneficial effects of the present invention are: at low ambient temperatures, the object that infrared heating film heating power will be in contact with it It is heated.Under high temperature environment, infrared heating film stops being powered, and the heat that object itself generates is turned by way of heat transfer It moves on on graphene fluid media (medium).The purpose that heat is reached for object cooling is taken away in the flowing of graphene fluid media (medium).Pass through heating The mode that heating, heat transfer cool down realizes the purpose of object controllable temperature, guarantees that object is not influenced by environmental change and plays itself The function of script.
Detailed description of the invention
Specific structure of the invention is described in detail with reference to the accompanying drawing
Fig. 1 is the structure connection signal of the controllable temperature lithium battery group of the invention using the cooling heat-transfer device of plate type heating Figure;
Fig. 2 is cross-sectional detail structure chart and the flowing signal of graphene fluid media (medium) of the cooling heat-conducting piece of heating of the invention Figure;
Fig. 3 is the side detail structure chart of the cooling heat-conducting piece of heating of the invention;
Fig. 4 is lithium battery structure detail view of the invention;
Wherein, the cooling heat-conducting piece of 1- heating, the first inlet of 101-, the first liquid outlet of 102-, 103- the first water conservancy diversion cavity, 104- baffle group, 105- heat exchanger plate, 106- infrared heating film;2- radiator, the second inlet of 201-, 202- second go out liquid Mouthful;3- circulating pump;4- recycles conducting valve;5- fluid reservoir;6- lithium battery, 601- lamination, 602- battery case;The first tee tube of 7- Part;The second tee pipe fitting of 8-;9- third tee pipe fitting;10- enters pot valve;11- tightens hoop.
Specific embodiment
The most critical design of the present invention is: setting infrared heating film is evenly heated heating, heat exchanger plate fast speed belt is set Walk waste heat.
For the feasibility for being discussed further inventive concept, in conjunction with technology contents of the invention, construction feature, realized purpose And effect specific embodiment and cooperate attached drawing to be explained in detail.
Fig. 1, Fig. 2 and Fig. 3, a kind of cooling heat-transfer device of plate type heating are please referred to, including heats cooling heat-conducting piece 1, institute It states and heats cooling heat-conducting piece 1 by heat exchanger plate 105 and 106 structure of infrared heating film being attached on 105 one side of heat exchanger plate At the heat exchanger plate 105 is equipped with the first water conservancy diversion cavity 103 for loading graphene fluid media (medium).At low ambient temperatures, red Additional 106 heating power of hotting mask heats the object being in contact with it.The infra-red radiation that infrared heating film 106 generates is with thin The homogeneous radiation of film surface forms planar heat source, is uniformly heated by planar radiation coverage, these are radiated by planar and cover The material absorbing infra-red radiation of range generates temperature and increases effect.Under high temperature environment, infrared heating film 106 stops being powered, The heat that object itself generates is transferred on graphene fluid media (medium) by way of heat transfer.Graphene fluid media (medium) flows band Walk the purpose that heat is reached for object cooling.The purpose of object controllable temperature is realized by way of heat temperature raising, heat transfer cooling, Guarantee that object is not influenced and played the function of itself script by environmental change.
It further, further include radiator 2, the radiator 2 is equipped with and leads for loading the second of graphene fluid media (medium) Flow cavity;The first water conservancy diversion cavity 103 is equipped with the first inlet 101 and the first liquid outlet 102, and the second water conservancy diversion cavity is set There are the second inlet 201 and the second liquid outlet 202;First liquid outlet 102 is connect with second inlet 201, described Second liquid outlet 202 is connect with first inlet 101.First water conservancy diversion cavity 103, the first liquid outlet 102, the second inlet 201, the second water conservancy diversion cavity, the second liquid outlet 202, the first inlet 101, the first water conservancy diversion cavity 103 are sequentially connected, and make graphene Fluid media (medium) circulates between the first water conservancy diversion cavity 103 and the second water conservancy diversion cavity, i.e., graphene fluid media (medium) is led first The stream systemic heat of cavity 103 is flowed into the second diversion cavity body with graphene fluid media (medium) and is transferred on radiator 2.It dissipates Hot device 2 radiates, and the graphene fluid media (medium) after cooling down is re-circulated in the first water conservancy diversion cavity 103 and takes away more heat Amount, and then realize to object continued down.
Further, circulating pump 3 is also connected between second liquid outlet 202 and first inlet 101.Circulation 3 driving graphene fluid media (medium) of pump accelerates flowing, accelerates radiating rate.
Further, circulation conducting valve 4 is additionally provided between the circulating pump 3 and first inlet 101.In high temperature ring Under border, circulation conducting valve 4 is opened, graphene fluid media (medium) recycle stream between the first water conservancy diversion cavity 103 and the second water conservancy diversion cavity It is dynamic.At low ambient temperatures, circulation conducting valve 4 is closed, and the graphene fluid media (medium) of no relative low temperature is again introduced into the first diversion cavity The heat that more object self heats or the generation of infrared heating film 106 are taken away in body 103, reduces thermal loss.
Further, fluid reservoir 5 is additionally provided between the circulating pump 3 and the circulation conducting valve 4.Circulating pump 3 and circulation Conducting valve 4 is connect by third tee pipe fitting 9 with fluid reservoir 5.It is additionally provided between third tee pipe fitting 9 and fluid reservoir 5 into tank Valve 10.Entering pot valve 10 and circulation conducting valve 4 is solenoid valve.The fluid inlet and outlet of fluid reservoir 5 is arranged in tank base, and tank body Position be higher than circulation line position.Under low temperature environment, when needing to object heat temperature raising, circulation conducting valve 4 is closed, is opened Enter pot valve 10, the graphene fluid media (medium) on circulation line is delivered into fluid reservoir 5 by circulating pump 3.After the completion of conveying, close into Pot valve 10,106 electrified regulation of infrared heating film.At this point, the first water conservancy diversion cavity 103 and the second water conservancy diversion cavity are cavity, and chamber Interior air relative static conditions.In the opposing stationary cavity of air, the thermal coefficient of air themperature " zero " DEG C is 0.024W/ M DEG C, the thermal coefficient of air themperature " 100 " DEG C is 0.031W/m DEG C.When i.e. infrared heating film 106 heats, pass through heating The dissipation heat of cooling 1 pair of outside of heat-conducting piece can be ignored.When temperature is excessively high to be needed to cool down to object, enter pot valve 10 open, and the graphene fluid media (medium) of fluid reservoir 5 again flows into circulation line using the effect of liquid level difference and self gravity On.After entering the closing of pot valve 10, circulation conducting valve 4 is opened, and then circulating pump 3 is opened, into cooling state.
Further, there are two the cooling heat-conducting pieces 1 of the heating;Two first liquid outlets 102 pass through the first threeway Pipe fitting 7 is connect with second inlet 201;Two first inlets 101 pass through the second tee pipe fitting 8 and the circulation Conducting valve 4 connects.The cooling heat-conducting pieces 1 of two heating are set, heating and cooling area are increased, realize quickly to stereo object into Row cooling and heating.Two are heated the connection that cooling heat-conducting piece 1 passes through the first tee pipe fitting 7 and the second tee pipe fitting 8, are made jointly With radiator 2, circulating pump 3, fluid reservoir 5 and circulation conducting valve 4.More preferably heat dissipation, heating effect are realized using a small amount of component.
Further, the infrared heating film 106, the heat exchanger plate 105 and the first water conservancy diversion cavity 103 are in square Shape, the baffle group 104 of the interior restricted graphene fluid media (medium) flowing in wave shape of setting of the first water conservancy diversion cavity 103;It is described to dissipate Hot device 2 is fin radiator.The infrared heating film 106, the heat exchanger plate 105 and the first water conservancy diversion cavity 103 are in Rectangle, that is, heating cooling heat-conducting piece 1 is in rectangle, is conveniently tightly attached in the plane of regular article and radiates or heat.It is cold due to heating But 1 plane of heat-conducting piece is big, and circulation line is small, to guarantee graphene fluid media (medium) Uniform Flow in the first water conservancy diversion cavity 103, Heat dissipation effective area is improved, setting baffle group 104 makes the flowing in wave shape of graphene fluid media (medium).As schematically in Fig. 2 arrow. Fin radiator heat dissipation area is big, is conducive to quickly be dissipated the heat of the intracorporal graphene fluid media (medium) of the second diversion cavity Hair.Fin radiator is manufactured using aluminium foil, and the thermal coefficient of aluminium is 230W/m DEG C, and density is small, and machining property is superior.
Further, by infra-red radiation layer occurs for the infrared heating film 106 and layer occurs for the package infra-red radiation Insulating layer is constituted;Layer occurs for the infra-red radiation by carbon black or micro-nano graphite composite powder or carbon nano-fiber or carbon nanotube or stone Black alkene material is made;The heat exchanger plate 105 is made of aluminium;The graphene fluid media (medium) is by graphene and dimethicone Composition, the graphene and the dimethicone mass ratio are 5-10:90-95.Insulating layer wraps up infra-red radiation and layer occurs, and keeps away Exempt from that leaky occurs.Optional 80 μm or 100 μm or 120 μm of thickness of layer occur for infra-red radiation.Preferably, the graphene with Mass ratio between the dimethicone are as follows: graphene: dimethicone=5:95.It is made of graphene and dimethicone Graphene fluid media (medium) thermal coefficient it is big, i.e., heating conduction is splendid, but has heat resistance, cold resistance, waterproofness, and surface Power is small, viscosity varies with temperature small, chemical property stabilization, harmless.Graphene fluid media (medium) can be at -50 DEG C~200 DEG C It is used for a long time under environment.Graphite olefinic bidimensional nano material, resistivity about 10-6 Ω cm, than copper or silver-colored lower, thermal conductivity 5300W/m DEG C, more than 14 times of 377W/m DEG C of thermal coefficient of copper.2630 ㎡ of theoretical specific surface area/g of graphene.When It is dispersed in dimethicone, can form preferable heat conduction network.Therefore at low ambient temperatures, infrared heating film 106 heats When, the graphene fluid media (medium) in the first water conservancy diversion cavity 103 is transferred to fluid reservoir 5 and is stored, shape in the first water conservancy diversion cavity 103 is made At cavity, avoid heat another from not contacting with infrared heating film 106 for cooling heat-conducting piece 1 is heated by graphene fluid media (medium) It distributes on one side.
It please refers to Fig. 1, Fig. 2 and Fig. 3, a kind of controllable temperature lithium battery group, including lithium battery group and plate type heating cooling is led Thermal, the cooling heat-transfer device of the plate type heating are connect by the cooling heat-conducting piece 1 of the heating with the lithium battery group.By structure Put at the neat rule of the lithium battery of lithium battery group, five smooth planes can be formed --- the side wall of lithium battery group.It heats cold But heat-conducting piece 1 is located on the side wall of lithium battery group, and the infrared heating film 106 of the cooling heat-transfer device of plate type heating mentions for lithium battery group For heat temperature raising, enable lithium battery group normal use during the cold season.The stone recycled in first water conservancy diversion cavity 103 of heat exchanger plate The heat that black alkene fluid media (medium) generates when lithium battery group charging, discharging is transferred to radiator 2 and distributes.Plate type heating cooling is thermally conductive Device not only ensure that the safety of lithium battery group at high temperature, at the same during the cold season when lithium battery group is heated, keep lithium electric Chi Zuneng can be worked normally under the temperature environment of various complicated variations.
When 6 charge and discharge of lithium battery, the cooling mechanism of battery heat production includes: heat transfer, thermal convection, heat radiation.Heat transfer, lithium There are temperature differences for the object of battery 6 and external contact, heat are transmitted to cryogenic object macroscopically, being high temp objects, microcosmic On, unordered warm-up movement is carried out for the microcosmic particle in substance.Thermal convection, thermal convection happen in fluid and another fluid or Between person's solid, the heat that surrounding is taken away while relative motion occurs for fluid.Heat transfer is also occurred that while thermal convection, Thermal convection single cannot exist, and own temperature increases when 6 charge and discharge of lithium battery, and the raised lithium battery 6 of temperature is contacted with surrounding Heat exchange behavior occurs for air.Heat radiation, thermodynamic argument think, the electromagnetic radiation of the disordered motion of microcosmic particle to object The fuel factor generated after surface is referred to as heat radiation.It, will be to outside it as long as the temperature of object is higher than absolute " zero " DEG C Radiation is generated, and temperature is higher, radiated stronger.Heat radiation does not need transfer medium, does not need directly to contact, object is not yet The disconnected radiation energy for absorbing foreign body and to external emission radiation energy, difference is exactly heat caused by radiation heat transfer.? It is matched by the integrated lithium battery group constituted of multiple lithium batteries 6 on electric car, it is arranged in narrow car body, integrated level Height, compact-sized, cross-ventilation narrow space, it is difficult to the exterior space for providing enough lithium battery groups is used for the heat exchange of thermal convection, The heat exchange radiating mode of thermal convection is difficult to directly realize in the structure of lithium battery group.The use mounting ring of opposite dynamic lithium battery Border is in closed battery case, and usual lithium battery and battery case are void-free fastening structure, between lithium battery and battery case Temperature difference very little, the heat of radiation heat transfer, which plays, is not obvious dynamic lithium battery cooling.Therefore it is cold with plate type heating by lithium battery group But heat-transfer device combines and forms controllable temperature lithium battery group, i.e., the controllable temperature lithium battery formed in such a way that heat transfer is radiated Group is more suitable for electric car use.
Further, referring to Fig. 4,6 battery core of lithium battery of the lithium battery group is made of at least two laminates 601, often The edge of the layer lamination 601 connects with the infrared heating film 106 for heating cooling heat-conducting piece 1;The lithium battery group position Between the cooling heat-conducting piece 1 of two heating.The cell lamination 601 of each layer of lithium battery 6, successively by anode pole piece, diaphragm Material and cathode pole piece stacking are constituted.Anode pole piece includes positive electrode coating and aluminum foil current collector, and cathode pole piece includes cathode Material coating and copper foil current collector.Positive electrode coating and negative electrode material coating are all the mixtures of powder Yu adhesive colloid, That is the thermal resistivity of diaphragm and positive electrode coating and negative electrode material coating is bigger.Therefore lithium is formed by multi-layer stacks 601 Battery battery core, in 601 plane of lamination to external transmission of heat by contact, there are biggish thermal resistances, if heat cooling heat-conducting piece 1 with it is folded 601 plane contact of piece, heating and heat dissipation effect are poor.And lamination edge is the cutting of aluminum foil current collector and copper foil current collector Face, 106 need of infrared heating film for heating cooling heat-conducting piece 1 pass through 16 μm of diaphragm, battery case 602 is and 601 side of lamination Edge connects, and junction without coating, i.e. junction thermal resistance is smaller.Therefore external heat source is contacted (i.e. by battery case 602 Infrared heating film 106) or cold source (i.e. heat exchanger plate 105), it can achieve the effect of preferably heat transfer heating or cooling heat dissipation.Folded The opposite both sides edge of piece 601 is respectively provided with the cooling heat-conducting piece 1 of heating, promotes the whole temperature control effect of controllable temperature lithium battery group.This Outside, it is to guarantee heating cooling effect, is fixed together using tightening hoop 11 and will heat cooling heat-conducting piece 1 with lithium battery group.Work as lithium When battery pack is scrapped, release tighten hoop 11 can more lithium change battery pack, and the cooling heat-transfer device of plate type heating then continues to use simultaneously New controllable temperature battery pack is formed with lithium battery group, reduces the automobile parts replacement cost of client.
In conclusion the cooling heat-transfer device of plate type heating provided by the invention and the controllable temperature lithium battery using the device Group, heats that cooling heat-conducting piece, radiator, circulating pump, circulation conducting valve is sequentially connected makes the first water conservancy diversion cavity and the second diversion cavity The circulation line for the flowing of graphene fluid media (medium) is formed between body.Under high temperature environment, heating cooling heat-conducting piece will be with it The heat of the lithium battery group of contact is transferred on graphene fluid media (medium), and heat moves to heat dissipation with graphene flow of fluid medium turn It is distributed on device.Fluid reservoir is connected to by third tee pipe fitting between circulating pump and circulation conducting valve.At low ambient temperatures, pump is followed Graphene fluid media (medium) on circulation line is transferred to fluid reservoir by pump, and the first diversion cavity body is made to form cavity, reduces heat transfer Rate, while the heating of infrared heating film makes lithium battery group and its periphery border heat up.Pass through the cooling heat-transfer device of plate type heating, lithium Battery pack temperature is controllable, can under various natural temperature environment normal use, and be suitable as automobile parts use.
Herein first, second ... only represents the differentiation of its title, not representing their significance level and position has what It is different.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification and accompanying drawing content is applied directly or indirectly in other relevant skills Art field, is included within the scope of the present invention.

Claims (10)

1. a kind of cooling heat-transfer device of plate type heating, which is characterized in that including heating cooling heat-conducting piece, the heating cooling is thermally conductive Part is made of heat exchanger plate and the infrared heating film being attached on the heat exchanger plate one side, and the heat exchanger plate is equipped with for filling Carry the first water conservancy diversion cavity of graphene fluid media (medium).
2. the cooling heat-transfer device of plate type heating as described in claim 1, which is characterized in that it further include radiator, the radiator Equipped with the second water conservancy diversion cavity for loading graphene fluid media (medium);The first water conservancy diversion cavity is equipped with the first inlet and first Liquid outlet, the second water conservancy diversion cavity are equipped with the second inlet and the second liquid outlet;First liquid outlet with described second into The connection of liquid mouth, second liquid outlet are connect with first inlet.
3. the cooling heat-transfer device of plate type heating as claimed in claim 2, which is characterized in that second liquid outlet and described first Circulating pump is also connected between inlet.
4. the cooling heat-transfer device of plate type heating as claimed in claim 3, which is characterized in that the circulating pump and first feed liquor Circulation conducting valve is additionally provided between mouthful.
5. the cooling heat-transfer device of plate type heating as claimed in claim 4, which is characterized in that the circulating pump and the circulation are connected Fluid reservoir is additionally provided between valve.
6. the cooling heat-transfer device of plate type heating as claimed in claim 5, which is characterized in that the cooling heat-conducting piece of the heating has two It is a;Two first liquid outlets are connect by the first tee pipe fitting with second inlet;Two first inlets It is connect by the second tee pipe fitting with the circulation conducting valve.
7. plate type heating cools down heat-transfer device as described in claim 1 to 6 is any, which is characterized in that the infrared heating film, institute Stating heat exchanger plate and the first water conservancy diversion cavity is in rectangle, and the restricted graphene fluid of setting is situated between in the first diversion cavity body The baffle group of matter flowing in wave shape.
8. the cooling heat-transfer device of plate type heating as claimed in claim 7, which is characterized in that the infrared heating film is by infra-red radiation Layer occurs and the insulating layer composition of layer occurs for the package infra-red radiation;Layer occurs for the infra-red radiation by carbon black or micro-nano stone Ink powder body or carbon nano-fiber or carbon nanotube or grapheme material are made;The heat exchanger plate is made of aluminium;The graphite Alkene fluid media (medium) is made of graphene and dimethicone, and the mass ratio of the graphene and the dimethicone is 5-10: 90-95。
9. a kind of controllable temperature lithium battery group, including lithium battery group, which is characterized in that further include as described in claim 1 to 8 is any The cooling heat-transfer device of plate type heating, the cooling heat-transfer device of the plate type heating passes through the cooling heat-conducting piece of the heating and the lithium Battery pack connection.
10. controllable temperature lithium battery group as claimed in claim 9, which is characterized in that the lithium battery electric core of the lithium battery group is by extremely Few two laminates are constituted, and the edge of every layer of lamination connects with the infrared heating film for heating cooling heat-conducting piece;It is described Lithium battery group is located between the cooling heat-conducting piece of two heating.
CN201910745766.5A 2019-08-13 2019-08-13 The cooling heat-transfer device of plate type heating and the controllable temperature lithium battery group using the device Withdrawn CN110350270A (en)

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CN201910745766.5A CN110350270A (en) 2019-08-13 2019-08-13 The cooling heat-transfer device of plate type heating and the controllable temperature lithium battery group using the device
PCT/CN2019/104565 WO2021026979A1 (en) 2019-08-13 2019-09-05 Plate-type heating and cooling heat conduction apparatus, and temperature-controllable lithium battery pack using same

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Cited By (2)

* Cited by examiner, † Cited by third party
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CN114879770A (en) * 2022-04-29 2022-08-09 广东迅扬科技股份有限公司 Constant temperature control method based on linear regression prediction
CN115402975A (en) * 2022-02-16 2022-11-29 长兴强盛机械有限公司 Reliable durable electric pallet truck

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Publication number Priority date Publication date Assignee Title
FR3024770B1 (en) * 2014-08-11 2016-09-02 Valeo Systemes Thermiques THERMAL EXCHANGE PLATE FOR THERMAL MANAGEMENT OF BATTERY PACK
CN104479644A (en) * 2014-12-11 2015-04-01 山东大学 Graphene-type cooling medium as well as preparation method and application thereof
CN106058378B (en) * 2016-08-17 2018-08-21 江阴市辉龙电热电器有限公司 New-energy automobile power battery heats and cooling integration device
CN207781841U (en) * 2017-11-20 2018-08-28 力神动力电池系统有限公司 A kind of battery modules system having heating and refrigerating function
CN109348554A (en) * 2018-10-16 2019-02-15 浙江云墨绿能科技有限公司 A kind of electric heating film and preparation method thereof of nano ceramics graphene composite structure

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CN115402975A (en) * 2022-02-16 2022-11-29 长兴强盛机械有限公司 Reliable durable electric pallet truck
CN114879770A (en) * 2022-04-29 2022-08-09 广东迅扬科技股份有限公司 Constant temperature control method based on linear regression prediction
CN114879770B (en) * 2022-04-29 2024-02-20 广东迅扬科技股份有限公司 Constant temperature control method based on linear regression prediction

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