CN110339706A - A kind of device and method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas - Google Patents
A kind of device and method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas Download PDFInfo
- Publication number
- CN110339706A CN110339706A CN201910530394.4A CN201910530394A CN110339706A CN 110339706 A CN110339706 A CN 110339706A CN 201910530394 A CN201910530394 A CN 201910530394A CN 110339706 A CN110339706 A CN 110339706A
- Authority
- CN
- China
- Prior art keywords
- symmetrical
- waste gas
- industrial waste
- cover board
- vacuum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007789 gas Substances 0.000 title claims abstract description 54
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 37
- 239000002440 industrial waste Substances 0.000 title claims abstract description 35
- 238000012545 processing Methods 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052751 metal Inorganic materials 0.000 claims abstract description 54
- 239000002184 metal Substances 0.000 claims abstract description 54
- 239000000463 material Substances 0.000 claims abstract description 23
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 21
- 238000007146 photocatalysis Methods 0.000 claims abstract description 8
- 230000001699 photocatalysis Effects 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 210000002268 wool Anatomy 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 8
- 230000009977 dual effect Effects 0.000 claims description 7
- 239000003344 environmental pollutant Substances 0.000 abstract description 22
- 231100000719 pollutant Toxicity 0.000 abstract description 22
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 7
- 238000000746 purification Methods 0.000 abstract description 7
- 238000006385 ozonation reaction Methods 0.000 abstract description 5
- 238000013461 design Methods 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 11
- 230000003647 oxidation Effects 0.000 description 10
- 239000000356 contaminant Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 230000001590 oxidative effect Effects 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 7
- 230000008569 process Effects 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000012855 volatile organic compound Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 229920006351 engineering plastic Polymers 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000004088 simulation Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000010504 bond cleavage reaction Methods 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 230000001131 transforming effect Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229910009973 Ti2O3 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical class CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- GEYXPJBPASPPLI-UHFFFAOYSA-N manganese(III) oxide Inorganic materials O=[Mn]O[Mn]=O GEYXPJBPASPPLI-UHFFFAOYSA-N 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/007—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/76—Gas phase processes, e.g. by using aerosols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/88—Handling or mounting catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/80—Type of catalytic reaction
- B01D2255/802—Photocatalytic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/804—UV light
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The invention discloses a kind of device and methods of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, which includes: opaque shell；The metal cover board of the opaque case top is set；It is arranged in opaque shell and is fixed on the quartz glass tube on metal cover board；Catalysis material in quartz glass tube is set；And two vacuum UV lamps on metal cover board towards opaque enclosure interior are set.Method of the invention, using the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, the present invention realizes vacuum ultraviolet photodestruciton, photocatalysis, catalytic ozonation synergistic purification remove the integrated design methods of a variety of industrial gaseous pollutants.The vacuum-ultraviolet light of symmetrical ditrysian type structure realizes the making full use of of ultraviolet light, react in the advantages that the making full use of and remove of ozone that generates, while also having the characteristics that easy to install replace, easy to use safeguard.
Description
Technical field
The present invention relates to the purification device fields of industrial gasses pollutant, and in particular to a kind of symmetrical ditrysian type ultraviolet light is urged
Change the device and method of processing industrial waste gas.
Background technique
The gaseous pollutant of industrial discharge is one of important root of atmosphere pollution, and especially Fine Chemical discharges
The pollution problem of toxic, stench class gaseous pollutant has been got worse, and is the current most typical pollution sources of China's atmospheric environment
One of.Ultraviolet catalytic technology is that current photochemical method is applied to most active field in many researchs of ring contamination control,
Especially gas purification, deodorizing sterilizing and in terms of application it is more and more extensive.Due to operational reliability
Height, occupied area is small, can handle the advantages that multiple pollutant simultaneously, has started to be applied to environmental improvement neck in the eighties in last century
Domain, be it is existing be used to handle VOCs (volatile organic compounds, volatile organic matter), the advanced subject of research
One of, just increasingly attract people's attention.
Ultraviolet catalytic technology has chemical oxidation ability, and (high-energy photoelectron, living radical, ozone etc. directly participate in by force
The excitation of target contaminant, oxidation), the advantages that reactor design is small in size, initial investment expense is low, easily operated.Currently, purple
The technique that outer photocatalysis technology also develops different characteristics in terms of the purification removal of volatile organic matter (VOCs).Ultraviolet light is urged
Change Technical comparing and meets that low concentration, operation and maintenance are simple, the lower requirement of initial stage input cost；It is ultraviolet and in running well
Catalysis technique only relies on work about electric power, does not generate high temperature, and safety guarantee is high, without additional addition auxiliary fuel, does not generate two
Secondary pollution is generated without secondary waste object, is situated between without filling and replacement.Under the excitation of ultraviolet light, the atom of pollutant
Structure changes, and low molecule intermediate product is gradually oxidized under the action of oxidant, and organic pollutant ultimately generates CO2
And H2O.It, can be with since short wavelength ultraviolet photon energy is higher than the bond energy of most of polluter intramolecule chemical bonds
Its fracture is directly made to the effect of molecular chemical bond by UV photons, to achieve the purpose that decomposition.Currently, ultraviolet light is urged
The removal effect that change technology is used to aoxidize toxic VOCs is still not ideal enough, under lower input energy and reaction time, mesh
Mark pollutant the problems such as there are incomplete mineralisings.
Dual wavelength vacuum ultraviolet photocatalysis treatment industrial waste gas based on symmetrical ditrysian type structure according to the present invention
Method.Compared to common ultraviolet catalytic technology, having used vacuum ultraviolet i.e. wavelength is the ultraviolet light of 185nm, vacuum ultraviolet
Other than the performance with common ultraviolet, can also by air oxygen and steam transforming at a large amount of strong oxidizing properties activity
Group (HO2, O, OH isoreactivity free radical), while the ozone with strong oxidizing property is generated, promote target contaminant point
Sub-key aoxidizes scission of link by high concentration active group under the conditions of lower energy input, and the small molecule that formation is easier to oxidation removal is organic
Object, and target contaminant is mineralized thoroughly using the active catalyst component (titanium, manganese) of vacuum ultraviolet irradiation area.This method tool
There are specific innovative, practicability and economy.
Summary of the invention
In order to overcome the shortcomings of the prior art, have for industrial gaseous pollutant, especially atm number, low concentration
Machine exhaust gas (benzene homologues, esters) and odorant (H2S、NH3, thioether, mercaptan and organic amine) efficient removal, the present invention mentions
A kind of device and method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas is supplied.
The present invention realizes vacuum ultraviolet photodestruciton, photocatalysis, a variety of industrial gas of catalytic ozonation synergistic purification removal
The integrated design method of state pollutant.Wherein, the vacuum-ultraviolet light of symmetrical ditrysian type structure realizes the abundant benefit of ultraviolet light
With the advantages that the making full use of and remove of ozone that generates in, reaction, while also there is replacement easy to install, be easy to use and safeguard etc.
Feature.The processing of atmosphere capacity industrial waste gas can be realized at normal temperatures and pressures, and investment operating cost is low, operational safety is high, reaches
The requirement for having arrived industrial functionization, has a extensive future.
A kind of device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, comprising:
Opaque shell；
The metal cover board of the opaque case top is set；
The quartz glass tube in the opaque shell and being fixed on the metal cover board is set；
Catalysis material in the quartz glass tube is set；
And two vacuum UV lamps on the metal cover board towards the opaque enclosure interior are set.
In the present invention, device includes vacuum UV lamp, metal cover board, opaque shell, metal sheeting and quartz glass
Pipe, catalysis material.Gaseous pollutant enters the conversion zone in opaque shell at quartz glass tube through air inlet in industrial source,
Under the excitation of the vacuum-ultraviolet light of vacuum UV lamp, the atomic structure of pollutant changes, under the action of oxidant by
Step be oxidized to low molecule intermediate product, by air oxygen and steam transforming at a large amount of strong oxidizing property active groups
(HO2, O, OH isoreactivity free radical), while the ozone with strong oxidizing property is generated, promote target contaminant molecular link
Scission of link is aoxidized by high concentration active group under the conditions of lower energy input, forms the small organic molecule for being easier to oxidation removal,
And target contaminant is set thoroughly to be mineralized into CO using the active catalyst component (titanium, manganese) of vacuum ultraviolet irradiation area2、H2O；Most
Eventually, it is discharged by the gas of advanced treating through gas outlet.
It is used as the preferred technical solution of the present invention below:
Preferably, the opaque shell by thick 2mm~4mm engineering plastics by surface cutting, fluting or directly
The processes such as pressing mold, sintering are made；The opaque shell is 110~150mm of outer annular diameter, 90~130mm of annular diameters, depth
The bottom cylinder of 120~160mm is spent, most preferably, the opaque shell is outer annular diameter 132mm, annular diameters 110mm, depth
The bottom cylinder for spending 140mm has 8 interfaces fixed for flange in outer ring and interior interannular；The shell of choosing meets opaque with protection
Personnel endanger from the irradiation of ultraviolet light, while being increased as much as possible in shell internal reflection ultraviolet light with making full use of ultraviolet light
Big UV-illuminated region.
Preferably, the metal cover board is the cylindrical structure of 110~150mm of diameter, 6~18mm of thickness, most preferably
, the metal cover board is the cylindrical structure of diameter 132mm, thickness 12mm, the predominantly gold such as thickness 2mm~4mm stainless steel, aluminium
Belong to a kind of welding fabrication of material；The circle for placing vacuum UV lamp for having 2 symmetrical diameters to be 18.9mm thereon is recessed
Slot aperture, 1 diameter positioned at circular cover the center point for placing quartz glass tube are the circular opening of 10mm, 9 use
In the threaded openings of 3M screw, 1 diameter for air inlet is the circular opening of 6mm, and edge has 8 to be used for what flange was fixed
Interface.
Preferably, the metal cover board is connected and fixed by flange-interface and the opaque shell, and it is equipped with close
Gasket；When carrying out vacuum ultraviolet catalytic oxidation, whole device system keeps sealing.
Preferably, the internal diameter of the quartz glass tube be 4~8mm, 8~12mm of outer diameter, 130~170mm of length, most
Preferably, the internal diameter of the quartz glass tube is 6mm, and outer diameter 10mm, length 150mm are connected and fixed on by metal sheeting
Metal cover board the center point, and it is equipped with gasket seal；Mass space velocity maintains 150000cm when reaction carries out3g h-1, and guarantee stone
Catalyst placement location is reasonable in English glass tube, obtains efficient, stable ultraviolet light region.
The quartz glass tube is connected and fixed on the center of the metal cover board by metal sheeting, and is equipped with gasket
Piece.
Two vacuum UV lamps on the metal cover board towards the opaque enclosure interior are set, symmetric double is formed
Cellular type structure, forms 2 vacuum ultraviolet irradiation areas, the high 80mm~100mm of single irradiation area, length and width be 11mm~
The main members such as 90mm, including 1 vacuum UV lamp, 1 piece of metal sheeting.
The diameter of the vacuum UV lamp is 15~24mm, and most preferably, the diameter of the vacuum UV lamp is
18.7mm, when work, can launch the ultraviolet light of 185nm and 254nm dual wavelength simultaneously, be connected and fixed on gold by metal sheeting
Belong on cover board, and is equipped with gasket seal.The vacuum UV lamp power is 3~8W, most preferably, single vacuum UV lamp function
Only 5W, service life theory are more than 16000h to rate, and operation easy to install uses, low energy consumption.
Two vacuum UV lamps are connected and fixed on metal cover board by metal sheeting, and are equipped with gasket seal.Institute
Two vacuum UV lamps stated are with the center symmetric setting of the metal cover board.
Preferably, the metal sheeting has 3 to be used for 3M thereon for fixing vacuum UV lamp and quartz glass tube
The opening of screw；Whole device system keeps sealing when reaction carries out, and passes through stringent aerodynamic simulations and test, with
Ensure that air resistance and oxidation processes effect reach optimal balance in device operational process.
Preferably, being compacted to form fixed bed with silica wool, with fixed bed to addition silica wool in the middle part of quartz glass tube
Form supported catalyst material；A certain amount of catalysis material is added in the middle part of quartz glass tube, and is compacted to form fixation with silica wool
Bed, required catalyst quality is only 0.2g；Realize removal of the vacuum ultraviolet catalysis oxidation to pollutant, while catalyst can urge
Change the ozone O that vacuum ultraviolet generates3The oxidation reaction of pollutant, also can effectively avoid O3Secondary pollution problem.
A kind of method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, at symmetrical ditrysian type ultraviolet catalytic
The device for managing industrial waste gas, includes the following steps:
(1) it by the middle part addition silica wool into quartz glass tube, is compacted to form fixed bed with silica wool, with the shape of fixed bed
Formula supported catalyst material；
(2) two vacuum UV lamps are opened, when work can launch the ultraviolet light of 185nm and 254nm dual wavelength simultaneously, will
Industrial waste gas is from the device that air inlet is passed through symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, and the gas after reaction is through stone
Gas outlet discharge at the top of English glass tube.
In step (1), the catalysis material consists of the following mass percentage components:
Most preferably, the catalysis material consists of the following mass percentage components:
Atm number industrial gaseous pollutant enters symmetrical ditrysian type structure dual wavelength vacuum through tubaeform or taper air inlet
Oxidation reaction occurs for the integrated apparatus of ultraviolet catalytic oxidation；Wherein, the symmetrical ditrysian type structure is by 2 vacuum ultraviolet
Irradiation area composition；The quartz glass tube is connected and fixed on metal cover board the center point by metal sheeting；To quartz glass
Silica wool is added in the middle part of pipe, is compacted to form fixed bed with silica wool, as a fixed bed supported catalyst material；The metal
Cover board is mainly a kind of welding fabrication of the metal materials such as stainless steel, aluminium；The opaque shell is that engineering plastics pass through table
Face cutting, fluting or the processes such as direct die press, sintering are made, and are connected and fixed by flange and metal cover board；Gas after reaction
Integrated treatment unit is discharged through gas outlet in body.
Compared with prior art, the present invention has the advantage that
(1) the deep purifying target contaminant in the same opaque shell can configure vacuum purple according to actual needs
The type of the installation number of outer lamp, the installation number of quartz glass tube and catalyst, it is easy to operate, occupied area is small；
(2) using number of fitting parts is few, structure is simple, processing cost is low needed for the vacuum ultraviolet of symmetrical ditrysian type structure,
In addition, the plug-in type assembling form of air inlet, the flange connection of gas outlet and equipment body structure and each component, it can
Maintenance cost is effectively reduced, improves operational safety；
(3) present invention realizes vacuum ultraviolet photodestruciton, photocatalysis, a variety of industry of catalytic ozonation synergistic purification removal
The integrated design method of gaseous pollutant.Wherein, the vacuum-ultraviolet light of symmetrical ditrysian type structure realizes the abundant of ultraviolet light
Using the advantages that the making full use of and remove of ozone that generates in, reaction, while also there is replacement easy to install, be easy to use and safeguard
The features such as.The processing of atmosphere capacity industrial waste gas can be realized at normal temperatures and pressures, and investment operating cost is low, operational safety is high,
The requirement for having reached industrial functionization, has a extensive future.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for the device that the symmetrical ditrysian type ultraviolet catalytic of the present invention handles industrial waste gas；
Fig. 2 is that the symmetrical ditrysian type ultraviolet catalytic of the present invention handles the device of industrial waste gas showing to the removal efficiency of toluene
It is intended to.
Specific embodiment
The present invention is further explained in the light of specific embodiments, but the scope of protection of the present invention is not limited thereto.
Embodiment 1:
As shown in Figure 1, a kind of device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, including it is air inlet 1, impermeable
Bare hull body 2, vacuum UV lamp 3, vacuum ultraviolet irradiation area 4 and quartz glass tube 5, catalysis material 6 etc..The symmetrical ditrysian type
The device of ultraviolet catalytic processing industrial waste gas, comprising: opaque shell 2；The metal cover board at opaque 2 top of shell is set
7；It is arranged in opaque shell 2 and is fixed on the quartz glass tube 5 at 7 center of metal cover board；It is arranged in quartz glass tube 5
Catalysis material 6；And be fixed on metal cover board 7 towards two vacuum UV lamps inside opaque shell 2, two are true
Empty ultraviolet lamp is fixed on metal cover board 7 with the central symmetry of metal cover board 7.
Opaque shell 2 passes through the processes such as surface cutting, fluting or direct die press, sintering by thick 2mm~4mm engineering plastics
It is made；Opaque shell 2 be outer annular diameter 132mm, annular diameters 110mm, depth 140mm bottom cylinder, in outer ring and interior interannular
There are 8 interfaces fixed for flange；The shell of choosing meets the opaque irradiation harm to protect personnel from ultraviolet light, simultaneously
Increase UV-illuminated region as much as possible in shell internal reflection ultraviolet light to make full use of ultraviolet light.
Metal cover board 7 is the cylindrical structure of diameter 132mm, thickness 12mm, the predominantly gold such as thickness 2mm~4mm stainless steel, aluminium
Belong to a kind of welding fabrication of material；The circle for placing vacuum UV lamp 3 for having 2 symmetrical diameters to be 18.9mm thereon is recessed
Slot aperture, the circular opening that 1 diameter positioned at 7 the center point of metal cover board for being used to place quartz glass tube 5 is 10mm, 9
For the threaded openings of 3M screw, 1 diameter for air inlet is the circular opening (i.e. air inlet 1) of 6mm, and edge has 8
The interface fixed for flange.
Metal cover board 7 is connected and fixed by flange-interface with opaque shell 2, and is equipped with gasket seal；Make vacuum ultraviolet
When catalytic oxidation carries out, whole device system keeps sealing.
The internal diameter of quartz glass tube 5 is 6mm, outer diameter 10mm, length 150mm, is connected and fixed on metal by metal sheeting 8
7 the center point of cover board, and it is equipped with gasket seal；Mass space velocity maintains 150000cm when reaction carries out3g h-1, and guarantee quartzy glass
6 placement location of catalysis material is reasonable in glass pipe 5, obtains efficient, stable ultraviolet light region.Quartz glass tube 5 passes through gold
Belong to tabletting 8 and be connected and fixed on metal cover board 7, and is equipped with gasket seal.
It is arranged on metal cover board 7 towards two vacuum UV lamps 3 inside opaque shell 2, forms symmetrical ditrysian type
Structure, forms 2 vacuum ultraviolet irradiation areas, and the high 80mm~100mm of single irradiation area, length and width are 11mm~90mm, packet
Include the main members such as 1 vacuum UV lamp, 1 piece of metal sheeting 8.
The diameter of vacuum UV lamp 3 is 18.7mm, and when work can launch the ultraviolet of 185nm and 254nm dual wavelength simultaneously
Light is connected and fixed on metal cover board 7 by metal sheeting 8, and is equipped with gasket seal.Single 3 power of vacuum UV lamp only 5W,
Service life theory is more than 16000h, and operation easy to install uses, low energy consumption.Vacuum UV lamp 3 is connected by metal sheeting 8
It is fixed on metal cover board 7, and is equipped with gasket seal.
Metal sheeting 8 has 3 openings for 3M screw for fixing vacuum UV lamp 3 and quartz glass tube 5 thereon；
Whole device system keeps sealing when reaction carries out, and passes through stringent aerodynamic simulations and test, to ensure that device is transported
Air resistance and oxidation processes effect reach optimal balance during row.
Gaseous pollutant is flowed out from air inlet 1 into opaque shell 2 by quartz glass tube 5；In vacuum UV lamp 3
In the vacuum ultraviolet irradiation area 4 of formation, oxygen and vapor in air can be converted to a large amount of strong oxidizing property active groups
(HO2, O, OH isoreactivity free radical), while generating the ozone with strong oxidizing property；Gas pollutant is in vacuum ultraviolet
It can be reacted by the photodestruciton that ultraviolet light occurs in irradiation area 4, while under the action of catalysis material 6, light-catalyzed reaction occurs
And catalytic ozonation reaction, realize vacuum ultraviolet photodestruciton, photocatalysis, catalytic ozonation synergistic purification removal it is a variety of
Industrial gaseous pollutant, makes target contaminant thoroughly be mineralized into CO2、H2O；Finally, by the gas of advanced treating from quartzy glass
The discharge of 5 upper end gas outlet of glass pipe.
According to the type of target contaminant, concentration, installation number, the peace of quartz glass tube of Proper Match vacuum UV lamp
Quantity is filled, energy utilization efficiency is optimized, optimal discharge and VOCs removal effect is obtained, realizes gas in the industrial waste gas of different tolerance
The processing of state pollutant optimizes energy consumption, reduces investment operating cost.Application examples 1:
A kind of method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, it is purple using the symmetrical ditrysian type of embodiment 1
The device of outer photocatalysis treatment industrial waste gas, includes the following steps:
(1) silica wool will be added into quartz glass tube, be compacted to form fixed bed with silica wool, be born as a fixed bed
Catalysis material is carried, the quality of catalysis material is 0.2g；Catalysis material is using load by mass percent 4.4%MnO, 5.4%
Mn2O3, 7.2%MnO2And 45.3%TiO2, 37.7%Ti2O3The catalyst of active component composition realizes that vacuum ultraviolet is catalyzed oxygen
Change the removal to pollutant, while catalyst can be catalyzed the ozone O of vacuum ultraviolet generation3The oxidation reaction of pollutant, can also
Effectively avoid O3Secondary pollution problem
(2) open two vacuum UV lamps (5W), issue 185nm and 254nm dual wavelength ultraviolet light, by industrial waste gas from
Air inlet is passed through in the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, and the gas after reaction is through on quartz glass tube
Bring out port discharge.
Preferable treatment effect can be reached in order to illustrate integrated apparatus of the present invention, use the implementation of embodiment 1
The laboratory simulation that the device of the symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas of example 1 has carried out 500ml/min tolerance is useless
Gas carries out lab scale, main component 200mg/m3Toluene.
As shown in Fig. 2, working as catalysis material additive amount 0.2g, mass space velocity 150000cm3g h-1When, the removal effect of toluene
Rate increases increase with time, reaches highest point 100% in reaction progress to 150min or so, and tie up always in 300min
It holds；Pollutant emission meets the newest discharge standard requirement of country.
Claims (10)
1. a kind of device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas characterized by comprising
Opaque shell；
The metal cover board of the opaque case top is set；
The quartz glass tube in the opaque shell and being fixed on the metal cover board is set；
Catalysis material in the quartz glass tube is set；
And two vacuum UV lamps on the metal cover board towards the opaque enclosure interior are set.
2. the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas according to claim 1, which is characterized in that institute
The opaque shell stated be 110~150mm of outer annular diameter, 90~130mm of annular diameters, 120~160mm of depth bottom cylinder.
3. the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas according to claim 1, which is characterized in that institute
The metal cover board stated is the cylindrical structure of 110~150mm of diameter, 6~18mm of thickness.
4. the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas according to claim 1, which is characterized in that institute
The metal cover board stated is connected and fixed by flange-interface and the opaque shell, and is equipped with gasket seal.
5. the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas according to claim 1, which is characterized in that institute
The internal diameter for the quartz glass tube stated is 4~8mm, 8~12mm of outer diameter, 130~170mm of length.
6. the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas according to claim 1, which is characterized in that institute
The quartz glass tube stated is connected and fixed on the center of the metal cover board by metal sheeting, and is equipped with gasket seal.
7. the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas according to claim 1, which is characterized in that institute
The diameter for the vacuum UV lamp stated is 15~24mm, and the vacuum UV lamp power is 3~8W.
8. the device of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas according to claim 1, which is characterized in that institute
Two vacuum UV lamps stated are connected and fixed on metal cover board by metal sheeting, and are equipped with gasket seal, and described two true
Empty ultraviolet lamp is with the center symmetric setting of the metal cover board.
9. a kind of method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, which is characterized in that purple using symmetrical ditrysian type
The device of outer photocatalysis treatment industrial waste gas, includes the following steps:
(1) it by the middle part addition silica wool into quartz glass tube, is compacted to form fixed bed with silica wool, be born as a fixed bed
Carry catalysis material；
The catalysis material consists of the following mass percentage components:
(2) two vacuum UV lamps are opened, when work can launch the ultraviolet light of 185nm and 254nm dual wavelength simultaneously, will be industrial
Exhaust gas is from the device that air inlet is passed through symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas, and the gas after reaction is through quartzy glass
The discharge of glass tube top portion gas outlet.
10. method according to claim 9, which is characterized in that the catalysis material is by following mass percent
Group is grouped as:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910530394.4A CN110339706A (en) | 2019-06-19 | 2019-06-19 | A kind of device and method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910530394.4A CN110339706A (en) | 2019-06-19 | 2019-06-19 | A kind of device and method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110339706A true CN110339706A (en) | 2019-10-18 |
Family
ID=68182332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910530394.4A Pending CN110339706A (en) | 2019-06-19 | 2019-06-19 | A kind of device and method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110339706A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101234291A (en) * | 2007-11-12 | 2008-08-06 | 青岛科技大学 | Photocatalysis fluid bed reactor device for degrading volatile organic matter |
| CN105582962A (en) * | 2015-12-22 | 2016-05-18 | 武汉理工大学 | Regeneration method of MnOx/TiO2 based low-temperature denitration catalyst |
| CN205760543U (en) * | 2016-05-30 | 2016-12-07 | 广东上典环境保护工程有限公司 | A kind of novel photoassisted oxidation tower |
| CN205897289U (en) * | 2016-08-03 | 2017-01-18 | 贾明清 | Light catalytic decomposition does not have pipe bowl and purifies body |
| CN106732572A (en) * | 2016-11-16 | 2017-05-31 | 中山大学 | A kind of scavenging material of gaseous contaminant and its preparation method and application |
| CN109603794A (en) * | 2019-01-10 | 2019-04-12 | 北京中环嘉诚环境工程有限公司 | Purify water photoactivation net and its preparation and application |
| CN210786887U (en) * | 2019-06-19 | 2020-06-19 | 浙江大学 | Device for treating industrial waste gas by symmetrical double-hole type ultraviolet light catalysis |
-
2019
- 2019-06-19 CN CN201910530394.4A patent/CN110339706A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101234291A (en) * | 2007-11-12 | 2008-08-06 | 青岛科技大学 | Photocatalysis fluid bed reactor device for degrading volatile organic matter |
| CN105582962A (en) * | 2015-12-22 | 2016-05-18 | 武汉理工大学 | Regeneration method of MnOx/TiO2 based low-temperature denitration catalyst |
| CN205760543U (en) * | 2016-05-30 | 2016-12-07 | 广东上典环境保护工程有限公司 | A kind of novel photoassisted oxidation tower |
| CN205897289U (en) * | 2016-08-03 | 2017-01-18 | 贾明清 | Light catalytic decomposition does not have pipe bowl and purifies body |
| CN106732572A (en) * | 2016-11-16 | 2017-05-31 | 中山大学 | A kind of scavenging material of gaseous contaminant and its preparation method and application |
| CN109603794A (en) * | 2019-01-10 | 2019-04-12 | 北京中环嘉诚环境工程有限公司 | Purify water photoactivation net and its preparation and application |
| CN210786887U (en) * | 2019-06-19 | 2020-06-19 | 浙江大学 | Device for treating industrial waste gas by symmetrical double-hole type ultraviolet light catalysis |
Non-Patent Citations (1)
| Title |
|---|
| 王学生等: "臭氧金属氧化物催化降解水中有机物的研究", 华东理工大学出版社, pages: 110 - 111 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108452362A (en) | Sterilize module and disinfection equipment | |
| CN104258726B (en) | A kind of device of photocatalysis treatment volatile organic matter | |
| CN205730823U (en) | A kind of reproducibility foul gas purifier | |
| CN110975560A (en) | VOCs waste gas purification treatment method and device | |
| CN107115789A (en) | The device and method of high energy UV catalyzing cooperation ozone Oxidation Treatment waste gas | |
| CN111760452A (en) | Experimental device for testing performance of photocatalytic ozone synergistic catalytic degradation of volatile organic gas and operation process thereof | |
| CN106669414A (en) | Waste gas treatment equipment | |
| CN103127811B (en) | Stinking gas treatment method | |
| CN206965478U (en) | A kind of photoelectricity ion deodorizing device | |
| CN202113707U (en) | Air purifier | |
| CN207137652U (en) | A kind of incineration tail gas denitration advanced treatment apparatus integrated with Tuo bioxin | |
| CN203741162U (en) | Ultraviolet-ozone catalytic oxidation wastewater treatment device | |
| CN112933918A (en) | Multistage gas-liquid two-phase dielectric barrier discharge waste gas treatment system and method | |
| CN110339706A (en) | A kind of device and method of symmetrical ditrysian type ultraviolet catalytic processing industrial waste gas | |
| CN209576305U (en) | Device for treating waste gas by utilizing high-energy ultraviolet photocatalysis in cooperation with ozone catalysis | |
| CN110559827B (en) | Treatment process of papermaking waste gas | |
| CN210786887U (en) | Device for treating industrial waste gas by symmetrical double-hole type ultraviolet light catalysis | |
| CN107029526A (en) | A kind of incineration tail gas denitration advanced treatment process integrated with Tuo bioxin | |
| CN208287802U (en) | A kind of UV photooxidation catalytic unit | |
| JP2006272034A (en) | Contamination gas treatment device and method using photocatalyst | |
| CN206262316U (en) | A kind of plasma apparatus for removing kitchen garbage stench | |
| CN202741004U (en) | Organic exhaust gas purifier employing photolysis catalyst | |
| CN205965504U (en) | Waste gas processing system | |
| CN202876632U (en) | Obnoxious gas treatment device | |
| CN110064291B (en) | Integrated low-concentration stink waste gas treatment device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |