CN110330915A - Haloflex lamination fire retarding conveying band rubberizing and preparation method thereof - Google Patents

Haloflex lamination fire retarding conveying band rubberizing and preparation method thereof Download PDF

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Publication number
CN110330915A
CN110330915A CN201910641307.2A CN201910641307A CN110330915A CN 110330915 A CN110330915 A CN 110330915A CN 201910641307 A CN201910641307 A CN 201910641307A CN 110330915 A CN110330915 A CN 110330915A
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China
Prior art keywords
weight
parts
agent
haloflex
conveying band
Prior art date
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Pending
Application number
CN201910641307.2A
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Chinese (zh)
Inventor
苏鲲鹏
曲成东
范旭梦
孟阳
孙业斌
杨可
徐振龙
顾欣坚
陈希
陈旭芳
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Wuxi Boton Technology Co Ltd
Wuxi Centennial Industrial Transport Co Ltd
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Wuxi Boton Technology Co Ltd
Wuxi Centennial Industrial Transport Co Ltd
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Application filed by Wuxi Boton Technology Co Ltd, Wuxi Centennial Industrial Transport Co Ltd filed Critical Wuxi Boton Technology Co Ltd
Priority to CN201910641307.2A priority Critical patent/CN110330915A/en
Publication of CN110330915A publication Critical patent/CN110330915A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J107/00Adhesives based on natural rubber
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/26Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment
    • C09J123/28Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C09J123/286Chlorinated polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The present invention relates to a kind of haloflex lamination fire retarding conveying band rubberizings and preparation method thereof, rubber-type chlorinated polyethylene and natural rubber are put into mixer, mixing 1-2min;Then reinforcing agent, stearic acid, fire retardant, softening plasticizer, anti-aging agent and activated magnesia, mixing 3-5min is added in lift floating weight;Vulcanizing agent, promotor and nano zine oxide are put into mixer again, are kneaded 3-4min, dump temperature is controlled at 100-140 DEG C, the 5-10min that turned refining, is cooled to room temperature by thickness 8-12mm slice, blower to get product lamination fire retarding conveying band rubberizing.The present invention, which uses, can effectively solve the problems, such as not breaking using the lamination inhibiting tape roll friction that rubber is matrix completely based on haloflex, can greatly improve flame retardant property.The present invention does not add any adhesive, can greatly reduce cost.

Description

Haloflex lamination fire retarding conveying band rubberizing and preparation method thereof
Technical field
The present invention relates to a kind of haloflex lamination fire retarding conveying band rubberizings and preparation method thereof, and the invention belongs to convey Band rubberizing production technical field.
Background technique
Lamination fire retarding conveying band is due to using fabric core for skeleton, light in weight, and energy consumption is small in use process, so by visitor The favor at family.But the requirement of the standard according to MT830, in order to guarantee to be perfectly safe, lamination fire retarding conveying band roll friction must It must rub.If the use of rubber being completely matrix, during roll friction, rubber can coking formation lubricant layer, can not make defeated Band is sent to disconnect;Or coking lubrication damage layer, temperature, which is above standard, requires 325 DEG C.
Summary of the invention
An object of the present invention is to overcome the deficiencies in the prior art, is provided a kind of with excellent adhesiveness The haloflex lamination fire retarding conveying band rubberizing of energy, flame retardant property and hot mastication rheological property.
It is a further object of the present invention to provide a kind of preparation methods of haloflex lamination fire retarding conveying band rubberizing.
According to technical solution provided by the invention, the haloflex lamination fire retarding conveying band rubberizing includes following each group Point:
Rubber-type chlorinated polyethylene 50-100 parts by weight, fire retardant 67-83 parts by weight, are mended at natural rubber 0-50 parts by weight Strong agent 50-75 parts by weight, it is activated magnesia 5-15 parts by weight, nano zine oxide 0.5-3 parts by weight, stearic acid 1-2 parts by weight, soft Change plasticizer 45-75 parts by weight, anti-aging agent 3.5-6.5 parts by weight, vulcanizing agent 1-2 parts by weight and promotor 2-5 parts by weight;
After rubber-type chlorinated polyethylene and natural rubber is added in mixer, sequentially add activated magnesia, stearic acid, Anti-aging agent, fire retardant, reinforcing agent, softening agent are eventually adding vulcanizing agent, promotor and nano zine oxide and are kneaded;It carries out again Vulcanize to get the fire retarding conveying band rubberizing of haloflex lamination is arrived.
The vulcanizing agent is one of vulcanizing agent PT-75, vulcanizing agent TDD, vulcanizing agent ECHO, DCP, vulcanizing agent or several Kind.
The promotor be one of captax, altax, Vulcanization accelerator TMTD, promotor 903, accelerant B F or It is several.
The softening plasticizer is one or more of coumarone indene resin, DOP, DEHP, DOS.
The reinforcing agent is one or more of carbon black N220, N330, N234, white carbon black.
The anti-aging agent is one of anti-aging agent RD, antioxidant 4020, antioxidant BLE, protection wax, microwax or several Kind.
The fire retardant is one or more of chlorinated paraffin, antimony oxide, magnesium hydroxide, zinc borate.
A kind of preparation method of haloflex lamination fire retarding conveying band rubberizing the following steps are included:
A, take 0~50 parts by weight of natural rubber in plasticating on open mill, roll spacing setting in 2~4mm, roller temperature setting 35~ 45 DEG C, the 10min that plasticates obtains broken-down rubber;
B, rubber-type chlorinated polyethylene 50-100 parts by weight and natural rubber 0-50 parts by weight are put into mixer, mixing 1-2min;
C, lift floating weight is added reinforcing agent 50-70 parts by weight, stearic acid 1-2 parts by weight, fire retardant 67-83 parts by weight, soft Change plasticizer 45-75 parts by weight, anti-aging agent 3.5-6.5 parts by weight, activated magnesia 5-15 parts by weight, mixing 3-5min;
D, vulcanizing agent 1-2 parts by weight, promotor 2-5 parts by weight, nano zine oxide 0.5-3 parts by weight are put into mixer In, dumping is carried out after being kneaded 3-4min;
E, turn refining 5-10min after dumping, by thickness 8-12mm slice and is cooled to room temperature fire-retardant defeated to get lamination after turning refining Send band rubberizing.
The present invention uses the lamination inhibiting tape that can be effectively solved based on haloflex completely using rubber for matrix The problem of roll friction does not break can greatly improve flame retardant property.The present invention does not add any adhesive, can be greatly Reduce cost.
Specific embodiment
The present invention is further explained in the light of specific embodiments.
Rubber-type chlorinated polyethylene in following embodiment is purchased from Hangzhou Keli Chemical Co., Ltd., and name of product is Chlorinated polyethylene rubber (sheet), product type CH-800.
Embodiment 1
A, take 50 parts by weight of natural rubber in plasticating on open mill, roll spacing 3mm, 40 DEG C of roller temperature, the 10min that plasticates is plasticated Glue;
B, by resulting 50 parts by weight of the natural rubber investment mixing of plasticating of 50 parts by weight of rubber-type chlorinated polyethylene and step a In machine, mixing 1min;
C, 5 parts by weight of activated magnesia, 2 parts by weight of stearic acid, 40 parts by weight of chlorinated paraffin, three oxidations are then sequentially added Two antimony, 7 parts by weight, 10 parts by weight of magnesium hydroxide, 10 parts by weight of zinc borate, antioxidant 4020 are 2 parts by weight, anti-aging agent RD 1.5 Parts by weight, mixing 3min;
D, DOP is then added is 40 parts by weight, 5 parts by weight of 1# coumarone indene resin, 50 parts by weight of N330 carbon black;It again will vulcanization 2 parts by weight of agent, 2 parts by weight of promotor, 1 parts by weight of nano zine oxide are put into mixer, are kneaded 3min,
E, dumping, the 8min that turned refining, be cooled to room temperature by thickness 8mm slice, blower it is fire-retardant to get haloflex lamination Conveyer belt rubberizing.
By haloflex lamination fire retarding conveying band rubberizing that embodiment 1 obtains in vulcanizing on vulcanizing press, sulphur Changing temperature is 155 DEG C, sulfide stress 10MPa, vulcanization time 40min.Haloflex lamination fire retarding conveying band after vulcanization The physical mechanical property of rubberizing is shown in Table 1.
Embodiment 2
A, take 20 parts by weight of natural rubber in plasticating on open mill, roll spacing 3mm, 40 DEG C of roller temperature, the 10min that plasticates is plasticated Glue;
B, resulting 20 parts by weight of natural rubber of plasticating of 80 parts by weight of haloflex and step a are put into mixer, Mixing 1min;
C, 12 parts by weight of activated magnesia, 2 parts by weight of stearic acid, 50 parts by weight of chlorinated paraffin, three oxygen are then sequentially added Change that two antimony, 8 parts by weight, 15 parts by weight of magnesium hydroxide, 10 parts by weight of zinc borate, antioxidant 4020 are 2 parts by weight, anti-aging agent RD is 1.5 parts by weight, antioxidant MB are 1.5 parts by weight, mixing 3-5min;
D, DOS is then added is 40 parts by weight, 8 parts by weight of 1# coumarone indene resin, 50 parts by weight of N220 carbon black, white carbon black 20 Parts by weight;It is again 2 parts by weight, 2 parts by weight of nano zine oxide by 2 parts by weight of vulcanizing agent, 1 parts by weight of promotor, Vulcanization accelerator TMTD It puts into mixer, is kneaded 4min dumping;
E, turned refining 6min, be cooled to room temperature to get the fire-retardant conveying of haloflex lamination by thickness 8mm slice, blower Band rubberizing.
By haloflex lamination fire retarding conveying band rubberizing that embodiment 2 obtains in vulcanizing on vulcanizing press, sulphur Changing temperature is 155 DEG C, sulfide stress 10MPa, vulcanization time 40min.Haloflex lamination fire retarding conveying band after vulcanization The physical mechanical property of rubberizing is shown in Table 1.
Embodiment 3
B, 100 parts by weight of haloflex are put into mixer, mixing 1min;
C, 15 parts by weight of activated magnesia, 1 parts by weight of stearic acid, 40 parts by weight of chlorinated paraffin, three oxygen are then sequentially added Change that two antimony, 6 parts by weight, 20 parts by weight of magnesium hydroxide, 10 parts by weight of zinc borate, antioxidant 4020 are 2 parts by weight, anti-aging agent RD is 1.5 parts by weight, antioxidant MB are 3 parts by weight, mixing 4min;
D, DOP is then added is 60 parts by weight, 10 parts by weight of 1# coumarone indene resin, 45 parts by weight of N220 carbon black, white carbon black 30 parts by weight;Again by 1.5 parts by weight of vulcanizing agent, 1.5 parts by weight of promotor, 2 parts by weight of nano zine oxide investment mixer, mix Refining 4min, dumping,
E, turned refining 9min, by thickness 10mm slice, room temperature blower cooling it is fire-retardant defeated to get product haloflex lamination Send band rubberizing.
By haloflex lamination fire retarding conveying band rubberizing that embodiment 3 obtains in vulcanizing on vulcanizing press, sulphur Changing temperature is 155 DEG C, sulfide stress 10MPa, vulcanization time 40min.Haloflex lamination fire retarding conveying band after vulcanization The physical mechanical property of rubberizing is shown in Table 1.
Comparative example 1
It is kneaded: 40 parts by weight of neoprene and 60 parts by weight of natural rubber being put into mixer, mixing 1min;Then according to Secondary 1 parts by weight of addition stearic acid, 2 parts by weight of nano zine oxide, 40 parts by weight of chlorinated paraffin, 10 parts by weight of antimony oxide, hydrogen 30 parts by weight of aluminium oxide, 10 parts by weight of zinc borate, 10 parts by weight of ammonium polyphosphate, antioxidant 4020 are 2 parts by weight, anti-aging agent RD is 1.5 parts by weight, adhesive RS are 2.5 parts by weight mixing 4min;Then 3 parts by weight of 1# coumarone indene resin, N330 carbon black 30 are added Parts by weight, 20 parts by weight of white carbon black;It is again 4.5 parts by weight investment by 4 parts by weight of vulcanizing agent, 3 parts by weight of promotor, adhesive RS In mixer, be kneaded 5min, dumping, the 8min that turned refining, be cooled to room temperature by thickness 7mm slice, blower it is fire-retardant defeated to get lamination Send band rubberizing.
By haloflex lamination fire retarding conveying band rubberizing that comparative example 1 obtains in vulcanizing on vulcanizing press, sulphur Changing temperature is 155 DEG C, sulfide stress 10MPa, vulcanization time 40min.Haloflex lamination fire retarding conveying band after vulcanization The physical mechanical property of rubberizing is shown in Table 1.
Table 1
Note: canvas used is EP150 type RFL dipped canvas.

Claims (8)

1. a kind of haloflex lamination fire retarding conveying band rubberizing, it is characterized in that: the conveyer belt rubberizing includes following each component:
Rubber-type chlorinated polyethylene 50-100 parts by weight, natural rubber 0-50 parts by weight, fire retardant 67-83 parts by weight, reinforcing agent 50-75 parts by weight, activated magnesia 5-15 parts by weight, nano zine oxide 0.5-3 parts by weight, stearic acid 1-2 parts by weight, softening increase Mould agent 45-75 parts by weight, anti-aging agent 3.5-6.5 parts by weight, vulcanizing agent 1-2 parts by weight and promotor 2-5 parts by weight;
After rubber-type chlorinated polyethylene and natural rubber is added in mixer, sequentially adds activated magnesia, stearic acid, prevents always Agent, fire retardant, reinforcing agent, softening agent are eventually adding vulcanizing agent, promotor and nano zine oxide and are kneaded;Vulcanized again, Obtain haloflex lamination fire retarding conveying band rubberizing.
2. haloflex lamination fire retarding conveying band rubberizing as described in claim 1, it is characterized in that: the vulcanizing agent is vulcanization One or more of agent PT-75, vulcanizing agent TDD, vulcanizing agent ECHO, DCP, vulcanizing agent.
3. lamination fire retarding conveying band rubberizing as described in claim 1, it is characterized in that: the promotor is captax, promotor One or more of DM, Vulcanization accelerator TMTD, promotor 903, accelerant B F.
4. haloflex lamination fire retarding conveying band rubberizing as described in claim 1, it is characterized in that: the softening plasticizer is One or more of coumarone indene resin, DOP, DEHP, DOS.
5. haloflex lamination fire retarding conveying band rubberizing as described in claim 1, it is characterized in that: the reinforcing agent is carbon black One or more of N220, N330, N234, white carbon black.
6. haloflex lamination fire retarding conveying band rubberizing as described in claim 1, it is characterized in that: the anti-aging agent is anti-old One or more of agent RD, antioxidant 4020, antioxidant BLE, protection wax, microwax.
7. haloflex lamination fire retarding conveying band rubberizing as described in claim 1, it is characterized in that: the fire retardant is chlorination One or more of paraffin, antimony oxide, magnesium hydroxide, zinc borate.
8. the preparation method of haloflex lamination fire retarding conveying band rubberizing described in claim 1, it is characterized in that this method includes Following steps:
A, take 0 ~ 50 parts by weight of natural rubber in plasticating on open mill, in 2 ~ 4mm, the modeling at 35 ~ 45 DEG C is arranged in roller temperature for roll spacing setting Refining 10min obtains broken-down rubber;
B, rubber-type chlorinated polyethylene 50-100 parts by weight and natural rubber 0-50 parts by weight are put into mixer, mixing 1- 2min;
C, reinforcing agent 50-70 parts by weight are added in lift floating weight, and stearic acid 1-2 parts by weight, fire retardant 67-83 parts by weight, softening increase Mould agent 45-75 parts by weight, anti-aging agent 3.5-6.5 parts by weight, activated magnesia 5-15 parts by weight, mixing 3-5min;
D, it by vulcanizing agent 1-2 parts by weight, promotor 2-5 parts by weight, nano zine oxide 0.5-3 parts by weight investment mixer, mixes Dumping is carried out after refining 3-4min;
E, turn refining 5-10min after dumping, by thickness 8-12mm slice and is cooled to room temperature after turning refining to get lamination fire retarding conveying band Rubberizing.
CN201910641307.2A 2019-07-16 2019-07-16 Haloflex lamination fire retarding conveying band rubberizing and preparation method thereof Pending CN110330915A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112011297A (en) * 2020-07-23 2020-12-01 泉州市福采转印科技有限公司 Solid glue for EVA slipper transfer printing and preparation method thereof
CN113322026A (en) * 2021-05-31 2021-08-31 深圳市沃尔核材股份有限公司 Self-adhesive arc-resistant fire-resistant flame-retardant adhesive tape and preparation method thereof
CN113354878A (en) * 2021-05-25 2021-09-07 无锡百年通工业输送有限公司 Flame-retardant ozone-resistant tubular conveyor belt covering rubber and preparation method thereof

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CN108285760A (en) * 2018-02-23 2018-07-17 无锡宝通科技股份有限公司 A kind of Flame-Retardant and Oil-Resistant conveyer belt rubberizing and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112011297A (en) * 2020-07-23 2020-12-01 泉州市福采转印科技有限公司 Solid glue for EVA slipper transfer printing and preparation method thereof
CN113354878A (en) * 2021-05-25 2021-09-07 无锡百年通工业输送有限公司 Flame-retardant ozone-resistant tubular conveyor belt covering rubber and preparation method thereof
CN113322026A (en) * 2021-05-31 2021-08-31 深圳市沃尔核材股份有限公司 Self-adhesive arc-resistant fire-resistant flame-retardant adhesive tape and preparation method thereof

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