CN110329008A - A kind of cord of full-steel radial ply tyres for passenger cars carcass - Google Patents
A kind of cord of full-steel radial ply tyres for passenger cars carcass Download PDFInfo
- Publication number
- CN110329008A CN110329008A CN201910562443.2A CN201910562443A CN110329008A CN 110329008 A CN110329008 A CN 110329008A CN 201910562443 A CN201910562443 A CN 201910562443A CN 110329008 A CN110329008 A CN 110329008A
- Authority
- CN
- China
- Prior art keywords
- cord
- steel
- parts
- full
- passenger cars
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 136
- 239000010959 steel Substances 0.000 title claims abstract description 136
- 239000003292 glue Substances 0.000 claims abstract description 54
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 32
- 229920001971 elastomer Polymers 0.000 claims abstract description 26
- 239000005060 rubber Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 21
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 18
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011230 binding agent Substances 0.000 claims abstract description 17
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 17
- 239000011593 sulfur Substances 0.000 claims abstract description 17
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims abstract description 15
- 150000001868 cobalt Chemical class 0.000 claims abstract description 14
- 239000012190 activator Substances 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 32
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 239000006229 carbon black Substances 0.000 claims description 20
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 238000003490 calendering Methods 0.000 claims description 12
- 244000043261 Hevea brasiliensis Species 0.000 claims description 11
- 229920003052 natural elastomer Polymers 0.000 claims description 11
- 229920001194 natural rubber Polymers 0.000 claims description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- 238000012550 audit Methods 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 230000035935 pregnancy Effects 0.000 claims description 10
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical group OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 claims description 9
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical group NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- CTIHZTFULZJBGQ-UHFFFAOYSA-L cobalt(2+);decanoate Chemical compound [Co+2].CCCCCCCCCC([O-])=O.CCCCCCCCCC([O-])=O CTIHZTFULZJBGQ-UHFFFAOYSA-L 0.000 claims description 6
- 230000006835 compression Effects 0.000 claims description 6
- 238000007906 compression Methods 0.000 claims description 6
- 239000006071 cream Substances 0.000 claims description 6
- UEZWYKZHXASYJN-UHFFFAOYSA-N cyclohexylthiophthalimide Chemical group O=C1C2=CC=CC=C2C(=O)N1SC1CCCCC1 UEZWYKZHXASYJN-UHFFFAOYSA-N 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical group [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 claims description 6
- 238000004073 vulcanization Methods 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- LQLQDKBJAIILIQ-UHFFFAOYSA-N Dibutyl terephthalate Chemical compound CCCCOC(=O)C1=CC=C(C(=O)OCCCC)C=C1 LQLQDKBJAIILIQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 238000007747 plating Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 238000001179 sorption measurement Methods 0.000 claims description 5
- 101100149706 Arabidopsis thaliana SMR10 gene Proteins 0.000 claims description 4
- KVBYPTUGEKVEIJ-UHFFFAOYSA-N benzene-1,3-diol;formaldehyde Chemical compound O=C.OC1=CC=CC(O)=C1 KVBYPTUGEKVEIJ-UHFFFAOYSA-N 0.000 claims description 4
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000011159 matrix material Substances 0.000 claims 1
- 238000005096 rolling process Methods 0.000 abstract description 5
- 239000000446 fuel Substances 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 5
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 238000004513 sizing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 2
- 229920001021 polysulfide Polymers 0.000 description 2
- 239000005077 polysulfide Substances 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- AQMRBJNRFUQADD-UHFFFAOYSA-N copper(I) sulfide Chemical compound [S-2].[Cu+].[Cu+] AQMRBJNRFUQADD-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- CMAUJSNXENPPOF-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-cyclohexylcyclohexanamine Chemical compound C1CCCCC1N(C1CCCCC1)SC1=NC2=CC=CC=C2S1 CMAUJSNXENPPOF-UHFFFAOYSA-N 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0041—Compositions of the carcass layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/0007—Reinforcements made of metallic elements, e.g. cords, yarns, filaments or fibres made from metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/02—Carcasses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/062—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
- D07B1/0626—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration the reinforcing cords consisting of three core wires or filaments and at least one layer of outer wires or filaments, i.e. a 3+N configuration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/0007—Reinforcements made of metallic elements, e.g. cords, yarns, filaments or fibres made from metal
- B60C2009/0021—Coating rubbers for steel cords
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2023—Strands with core
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2024—Strands twisted
- D07B2201/2025—Strands twisted characterised by a value or range of the pitch parameter given
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2024—Strands twisted
- D07B2201/2027—Compact winding
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/30—Inorganic materials
- D07B2205/3021—Metals
- D07B2205/3067—Copper (Cu)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Abstract
The invention belongs to automobile tire technical field more particularly to a kind of cords of full-steel radial ply tyres for passenger cars carcass.Handling poor, the resistance to load property of car tyre solved currently on the market is strong, and rolling resistance is big, is badly in need of a kind of carcass ply with higher fatigue durability and intensity to meet the technical problem of the needs of full-steel radial ply tyres for passenger cars.Glue composition is covered by cord to be made with steel cord;It includes base rubber, reinforcing agent, vulcanizing activator, anti-aging agent, promotor, insoluble sulfur, binder resin, methylene donor, cobalt salt, antiscorching agent that cord, which covers glue composition,;The steel cord is twisted by 9 outermost cover wires around 3 twisting steel wire of internal layer volumes.Tire safety intensity made of the carcass ply of full-steel radial ply tyres for passenger cars produced by the present invention is obviously improved, the low manufacture cost of manufactured tire, and tire drag reduces, fuel consumption per hundred kilometers reduces 2%-4%, conducive to low-carbon environment-friendly, comfort is promoted, and braking distance is improved.
Description
Technical field
The invention belongs to automobile tire technical field more particularly to a kind of cords of full-steel radial ply tyres for passenger cars carcass.
Background technique
Automobile industry is worldwide grown rapidly, and automobile tire is the important component of vehicle, quality and
The quality of performance directly influences vehicle performance.The body piles that meridian tyre body curtain cloth layer is formed by covering glue cord fabric,
It is the stress frame layer of tire.Radial divides according to carcass ply, and carcass is the referred to as All-steel tire of steel wire,
It is generally used for business load-carrying tire;Carcass is that fiber is half steel tire, is generally used for riding tire.
Car tyre operability is poor currently on the market, and resistance to load property is poor, and rolling resistance is big, is badly in need of a kind of with higher resistance to tired
The carcass ply of labor and intensity meets the needs of full-steel radial ply tyres for passenger cars.
Summary of the invention
The present invention provides a kind of cord of full-steel radial ply tyres for passenger cars carcass, solve currently on the market riding
Handling poor, the resistance to load property of tire is strong, and rolling resistance is big, and it is next to be badly in need of a kind of carcass ply with higher fatigue durability and intensity
Meets the technical problem of the needs of full-steel radial ply tyres for passenger cars.
In order to achieve the above object, the present invention provides the following technical scheme that
A kind of cord of full-steel radial ply tyres for passenger cars carcass, it is characterised in that: the carcass ply covers glue by cord
Composition is made with steel cord;
It includes parts by weight that the cord, which covers glue composition: 100 parts of base rubber, 45-60 parts of reinforcing agent, vulcanization are lived
8-10 parts of agent of property, 1-3 parts of anti-aging agent, 1-1.5 parts of promotor, 4-6 parts of insoluble sulfur, 1-2 parts of binder resin, methylene are given
Give 4-6 parts of body, 0.4-1.2 parts of cobalt salt, 0.1-0.4 parts of antiscorching agent;
The steel cord is twisted by 9 outermost cover wires around 3 twisting steel wire of internal layer volumes.
Further, 70-100 parts of natural rubber, 0-30 parts of butadiene-styrene rubber in the base rubber;Described is natural
Rubber is SMR10/20 or STR10/20;The butadiene-styrene rubber is the SBR1502 of low temperature cream polymerizing technology production.
Further, the dosage of the butadiene-styrene rubber is 10-30 parts by weight;
The dosage of the reinforcing agent is 48-54 parts by weight, and the reinforcing agent is Audit For Process technique N326 carbon black, institute
The nitrogen adsorption surface area for the Audit For Process technique N326 carbon black stated is 72-84 ㎡/g, and dibutyl terephthalate absorbs after compression
Value is 62-74ml/g.
Further, the vulcanizing activator is the zinc oxide produced using zinc ingot metal as raw material indirect method, and specific surface area is
4-8㎡/g;
The dosage of the anti-aging agent is 2-3 parts by weight, and the anti-aging agent is p phenylenediamine type antioxidant 6PPD;
The promotor is sulfenamide type accelerators DZ;
The insoluble sulfur is HD OT-20.
Further, the dosage of the binder resin is 1.2-1.8 parts, and the binder resin is resorcinol first
Urea formaldehyde;
The methylene donor is hexamethylolmelamine pregnancy ether, in hexamethylolmelamine pregnancy ether
HMMM content 65%, white carbon black content 35%;
The cobalt salt is the cobalt decanoate that effective content is 20-21%;
The antiscorching agent is N- cyclohexylthiophthalimide.
Further, all steel wire diameters are identical, are 0.693-0.763mm;
It is 10.0mm that the cover wire of the steel cord, which compiles the lay pitch twisted,;The steel wire of internal layer of the steel cord, which is compiled, to be twisted
The lay pitch be 5.00mm.
Further, the cover wire and steel wire of internal layer of the steel cord are twisted using S in the same direction to volume, one-pass molding.
Further, Fracture Force >=755N of the steel cord;The steel cord covers the viscous of glue composition with described
With joint efforts >=700N;
The plating weight of copper of the steel cord is 3.5-6.3g/kg, and the copper content of coating is 61.0%-66.0%;It is described
Steel cord line density be 2.20-2.44g/m.
Further, the steel cord is suitable for NT, HT, ST, UT or MT grade steel wire.
Further, carcass ply calendering covers glue composition with a thickness of 1.2mm-2.5mm, covers glue composition thickness
Spend tolerance+0.05mm;The calendering density of the carcass ply is 50-110 root/dm.
Compared with prior art, the invention has the following advantages:
1, tire safety intensity made of the carcass ply of full-steel radial ply tyres for passenger cars produced by the present invention significantly mentions
It rises, the risk damaged after tire collides under steam can be further reduced.
2, compared to tire made of more other fibrous materials, the carcass of full-steel radial ply tyres for passenger cars produced by the present invention
The low manufacture cost of tire made of cord, tire drag reduce, and fuel consumption per hundred kilometers reduces 2%-4%, are conducive to low-carbon ring
It protects.
3, tire made of the carcass ply of full-steel radial ply tyres for passenger cars produced by the present invention in the process of moving relax
Adaptive, handling are promoted, and braking distance and noise level are improved.
Detailed description of the invention
Fig. 1 is steel cord structural schematic diagram provided in an embodiment of the present invention;
1- steel wire of internal layer, 2- cover wire.
Specific embodiment
In the following, the present invention is specifically described by illustrative embodiment.It should be appreciated, however, that not into
In the case that one step describes, element, structure and features in an embodiment can also be advantageously incorporated into other embodiment party
In formula.
In the description of the present invention, it is to be understood that, the orientation of the instructions such as term " on ", "lower", "bottom", "inner" or
Positional relationship be based on attached orientation or positional relationship shown in FIG. 1, be merely for convenience of description of the present invention and simplification of the description, and
It is not that the device of indication or suggestion meaning or element must have a particular orientation, be constructed and operated in a specific orientation, therefore
It is not considered as limiting the invention.
Term " first ", " second " be used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance or
Implicitly indicate the quantity of indicated technical characteristic." first " is defined as a result, the feature of " second " can be expressed or hidden
It include one or more of the features containing ground.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " connected ",
" connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can be with
It is to be connected directly, the connection inside two elements can also be can be indirectly connected through an intermediary.For this field
For those of ordinary skill, the concrete meaning of above-mentioned term in the present invention can be understood with concrete condition.
A kind of cord of full-steel radial ply tyres for passenger cars carcass provided in an embodiment of the present invention, the carcass ply by
Cord covers glue composition and is made with steel cord;
The method (generally using rolling process) covered glue composition and steel cord while pass through calendering or extrusion is made and covers glue
Cord.It is required that steel cord density array straight uniform, covers glue and steel cord bonds, be crowded between line gap and cover glue, steel cord structure
In penetrate into part and cover glue, it is uniform that cord upper and lower surface covers glue film stock thickness, covers rubberized cord surfacing.
It includes parts by weight that the cord, which covers glue composition: 100 parts of base rubber, 45-60 parts of reinforcing agent, vulcanization are lived
8-10 parts of agent of property, 1-3 parts of anti-aging agent, 1-1.5 parts of promotor, 4-6 parts of insoluble sulfur, 1-2 parts of binder resin, methylene are given
Give 4-6 parts of body, 0.4-1.2 parts of cobalt salt, 0.1-0.4 parts of antiscorching agent;
The steel cord is twisted by 9 outermost cover wires around 3 twisting steel wire of internal layer volumes.
In an alternative embodiment, natural rubber 70-100 parts in the base rubber, 0-30 parts of butadiene-styrene rubber;Institute
The natural rubber stated is SMR10/20 or STR10/20;The butadiene-styrene rubber is the SBR1502 of low temperature cream polymerizing technology production.
Weight proportion is used in the embodiment of the present invention, in terms of 100 parts of base rubbers, natural rubber contains in base rubber
Preferably 70 parts or more of amount.When natural gum content is less than 70 parts, the decline of glue tensile strength is covered, curingprocess rate slows down.The present invention is implemented
The cord for the full-steel radial ply tyres for passenger cars carcass that example provides covers glue, wherein the preferred low temperature cream polymerizing technology production of butadiene-styrene rubber content
SBR1502, styrene-content 23.5%, butadiene content 76.5%, Mooney viscosity 52 ± 5.The embodiment of the present invention
In, preferably 10 parts or more of butadiene-styrene rubber content, it is ensured that sizing material has preferable reversion resistance, heat-resisting quantity and higher anti-impact
Hit energy absorption capacity.
The dosage of reinforcing agent described in the embodiment of the present invention is 48-54 parts by weight, and the reinforcing agent is Audit For Process work
The nitrogen adsorption surface area of skill N326 carbon black, the Audit For Process technique N326 carbon black is 72-84 ㎡/g, to benzene two after compression
Formic acid dibutyl ester absorption value is 62-74ml/g.
Reinforcing agent is N326 carbon black in the embodiment of the present invention, can be promoted and cover glue mechanical strength and ensure to roll dimensionally stable
Property, optimal dosage is 48-54 parts, and carbon black loading is too low to will cause the decline of rubber manufacturing machinery intensity, and dosage is excessively high to will cause rubber life
Heat flexible resistance that is excessively high and influencing rubber.It is preferable to use Audit For Process technique N326 carbon black in the embodiment of the present invention, nitrogen is inhaled
Surface area is 72-84 ㎡/g, and dibutyl terephthalate absorption value is 62-74ml/g after compression, and the carbon black structure degree is low,
Produced rubber mobility is good, and sizing material easily penetrates into steel wire gap in calender line, promotes steel wire bonding force, and have higher
Tensile strength and elongation, it is ensured that have higher resistance to load property and impact resistance using the tire for covering glue production.
In an alternative embodiment, the vulcanizing activator is the zinc oxide produced using zinc ingot metal as raw material indirect method, than
Surface area is 4-8 ㎡/g;Zinc oxide content is high in the embodiment of the present invention, not will cause steel wire " losing zinc ", does not influence rubber and steel
The bonding force of silk cord.
The dosage of the anti-aging agent is 2-3 parts by weight, and the anti-aging agent is p phenylenediamine type antioxidant 6PPD;This
The preferred 2-3 parts of p phenylenediamine type antioxidant 6PPD of anti-aging agent (N- (1,3- dimethyl) butyl-N'- phenyl in inventive embodiments
P-phenylenediamine), with heat resistanceheat resistant oxygen, ozone-resistant, anti-fatigue performance is balanced, and dosage is promoted, and ozone resistants, fatigue resistance are promoted,
Dosage reduces, and thermo oxidative aging performance is promoted.
The promotor is sulfenamide type accelerators DZ;Preferred 1-1.5 parts of slow acting type time in the embodiment of the present invention
Sulfonamides accelerator DZ (N, N-2 dicyclohexyl -2,2- bisbenzothiazole sulfenamide), which has preferable processing
Safety, time of scorch is long, and making sizing material in process has preferable mobility, good penetrability of the rubber to steel wire, bonding
Power is high.
The insoluble sulfur is HD OT-20.The preferred 4-6 of insoluble sulfur HD OT-20 in the embodiment of the present invention
Part, the insoluble vulcanization thermostabilization of the model is high, is not easy to spray, and can be effectively ensured and cover sticky in glue process, sulfur consumption mistake
It is low, the cuprous sulfide amount deficiency for covering glue and steel wire surface is formed can be made, influence steel wire bonding force, sulfur consumption is excessively high, will cause
Adhesive-coating vulcanization post-crosslinking density is excessively high, and forms more polysulfide bond, and crosslink density is excessively high to will affect that cover resisting for glue flexibility,
Polysulfide bond is easy to generate more serious recovery in tire vulcanization process, influences tyre performance.
In an alternative embodiment, the dosage of the binder resin is 1.2-1.8 parts, between the binder resin is
Resorcinol formaldehyde resin;
Methylene donor described in the embodiment of the present invention is hexamethylolmelamine pregnancy ether, hexamethylol three
HMMM content 65% in poly cyanamid pregnancy ether, white carbon black content 35%;The preferred 1.2-1.8 parts of resorcinol first of binder resin
Urea formaldehyde cooperates 2.5-5 parts of RA65 of methylene donor (HMMM content 65%, white carbon black content 35%), and the two forms m- first
Binding system promotes the bonding force of rubber and steel wire, and the excessively high creep resistance that will affect sizing material of dosage, dosage is too low to be will lead to
Rubber and steel wire bonding force decline.
Cobalt salt described in the embodiment of the present invention is the cobalt decanoate that effective content is 20-21%;Cobalt decanoate can promote to vulcanize
Cuprous growth, dosage is too low, and glue and steel wire bonding force are covered in reduction, and dosage is excessively high, and steel wire can be accelerated to cover glue aging, influences to take turns
The tire service life.
Antiscorching agent described in the embodiment of the present invention is N- cyclohexylthiophthalimide.Antiscorching agent is preferred
0.1-0.4 parts of CTP (N- cyclohexylthiophthalimide), dosage is excessively high, can delay rubber vulcanization speed, reduces glue
Expect physical mechanical property, dosage is too low, will affect the process safety for covering glue.
In an alternative embodiment, all steel wire diameters are identical, are 0.693-0.763mm;
It is 10.0mm that the cover wire of the steel cord, which compiles the lay pitch twisted,;The steel wire of internal layer of the steel cord, which is compiled, to be twisted
The lay pitch be 5.00mm.
In an alternative embodiment, the cover wire and steel wire of internal layer of the steel cord are twisted using S in the same direction to volume, and one
Secondary molding.
In an alternative embodiment, Fracture Force >=755N of the steel cord;The steel cord covers glue group with described
Close bonding force >=700N of object;
The plating weight of copper of the steel cord is 3.5-6.3g/kg, and the copper content of coating is 61.0%-66.0%;It is described
Steel cord line density be 2.20-2.44g/m.
In an alternative embodiment, the steel cord is suitable for NT, HT, ST, UT or MT grade steel wire.
In an alternative embodiment, the carcass ply calendering covers glue composition with a thickness of 1.2mm-2.5mm, covers glue
Composition thickness tolerance+0.05mm;The calendering density of the carcass ply is 50-110 root/dm.
Steel cord used in the cord of full-steel radial ply tyres for passenger cars carcass in the embodiment of the present invention, is a kind of endurance
It is had excellent performance and can improve the body cord of strike-through performance, using lesser monofilament and cord diameter, it is ensured that identical
Under the premise of attached glue thickness, keep cord calendering thinner, rubber material using quantity more saves, and meets tire lightweight requirements, and can be with
Rolling resistance is reduced, and lesser monofilament and cord diameter can get higher tire fatigue behaviour;Steel wire model 3+9 ×
0.175NT。
In order to become apparent from the carcass for introducing full-steel radial ply tyres for passenger cars provided by the embodiment of the present invention in detail
Cloth is described below in conjunction with specific embodiment.
Embodiment 1
A kind of cord of full-steel radial ply tyres for passenger cars carcass, the carcass ply cover glue composition and steel by cord
Cord is made;
It includes parts by weight that the cord, which covers glue composition: 100 parts of base rubber, 45 parts of reinforcing agent, vulcanizing activator
8 parts, 1 part of anti-aging agent, 1 part of promotor, 4 parts of insoluble sulfur, 1 part of binder resin, 4 parts of methylene donor, 0.4 part of cobalt salt,
0.1 part of antiscorching agent;
The steel cord is twisted by 9 outermost cover wires around 3 twisting steel wire of internal layer volumes.
70 parts of natural rubber, 30 parts of butadiene-styrene rubber in the base rubber;The natural rubber is SMR10/20;
The butadiene-styrene rubber is the SBR1502 of low temperature cream polymerizing technology production.
The reinforcing agent is Audit For Process technique N326 carbon black, the nitrogen adsorption of the Audit For Process technique N326 carbon black
Surface area is 72-84 ㎡/g, and dibutyl terephthalate absorption value is 62-74ml/g after compression.
The vulcanizing activator is the zinc oxide produced using zinc ingot metal as raw material indirect method, and specific surface area is 4-8 ㎡/g;
The anti-aging agent is p phenylenediamine type antioxidant 6PPD;
The promotor is sulfenamide type accelerators DZ;
The insoluble sulfur is HD OT-20.
The binder resin is resorcinol formaldehyde resin;
The methylene donor is hexamethylolmelamine pregnancy ether, in hexamethylolmelamine pregnancy ether
HMMM content 65%, white carbon black content 35%;
The cobalt salt is the cobalt decanoate that effective content is 20-21%;
The antiscorching agent is N- cyclohexylthiophthalimide.
All steel wire diameters are identical, are 0.693-0.763mm;
It is 10.0mm that the cover wire of the steel cord, which compiles the lay pitch twisted,;The steel wire of internal layer of the steel cord, which is compiled, to be twisted
The lay pitch be 5.00mm.
The cover wire and steel wire of internal layer of the steel cord are twisted using S in the same direction to volume, one-pass molding.
Fracture Force >=755N of the steel cord;The steel cord and the bonding force for covering glue composition >=
700N;
The plating weight of copper of the steel cord is 3.5-6.3g/kg, and the copper content of coating is 61.0%-66.0%;It is described
Steel cord line density be 2.20-2.44g/m.
The steel cord is suitable for NT, HT, ST, UT or MT grade steel wire.
The described carcass ply calendering covers glue composition with a thickness of 1.2mm-2.5mm, cover glue composition thickness deviation ±
0.05mm;The calendering density of the carcass ply is 50-110 root/dm.
Embodiment 2
A kind of cord of full-steel radial ply tyres for passenger cars carcass, the carcass ply cover glue composition and steel by cord
Cord is made;
It includes parts by weight that the cord, which covers glue composition: 100 parts of base rubber, 60 parts of reinforcing agent, vulcanizing activator
10 parts, 3 parts of anti-aging agent, 1.5 parts of promotor, 6 parts of insoluble sulfur, 2 parts of binder resin, 6 parts of methylene donor, cobalt salt 1.2
Part, 0.4 part of antiscorching agent;
The steel cord is twisted by 9 outermost cover wires around 3 twisting steel wire of internal layer volumes.
80 parts of natural rubber, 20 parts of butadiene-styrene rubber in the base rubber;The natural rubber is STR10/20;
The butadiene-styrene rubber is the SBR1502 of low temperature cream polymerizing technology production.
The reinforcing agent is Audit For Process technique N326 carbon black, the nitrogen adsorption of the Audit For Process technique N326 carbon black
Surface area is 72-84 ㎡/g, and dibutyl terephthalate absorption value is 62-74ml/g after compression.
The vulcanizing activator is the zinc oxide produced using zinc ingot metal as raw material indirect method, and specific surface area is 4-8 ㎡/g;
The anti-aging agent is p phenylenediamine type antioxidant 6PPD;
The promotor is sulfenamide type accelerators DZ;
The insoluble sulfur is HD OT-20.
The binder resin is resorcinol formaldehyde resin;
The methylene donor is hexamethylolmelamine pregnancy ether, in hexamethylolmelamine pregnancy ether
HMMM content 65%, white carbon black content 35%;
The cobalt salt is the cobalt decanoate that effective content is 20-21%;
The antiscorching agent is N- cyclohexylthiophthalimide.
All steel wire diameters are identical, are 0.693-0.763mm;
It is 10.0mm that the cover wire of the steel cord, which compiles the lay pitch twisted,;The steel wire of internal layer of the steel cord, which is compiled, to be twisted
The lay pitch be 5.00mm.
The cover wire and steel wire of internal layer of the steel cord are twisted using S in the same direction to volume, one-pass molding.
Fracture Force >=755N of the steel cord;The steel cord and the bonding force for covering glue composition >=
700N;
The plating weight of copper of the steel cord is 3.5-6.3g/kg, and the copper content of coating is 61.0%-66.0%;It is described
Steel cord line density be 2.20-2.44g/m.
The steel cord is suitable for NT, HT, ST, UT or MT grade steel wire.
The described carcass ply calendering covers glue composition with a thickness of 1.2mm-2.5mm, cover glue composition thickness deviation ±
0.05mm;The calendering density of the carcass ply is 50-110 root/dm.
Embodiment 3
The difference from embodiment 1 is that: the carcass ply covers glue composition by cord and is made with steel cord;
It includes parts by weight that the cord, which covers glue composition: 100 parts of base rubber, 50 parts of reinforcing agent, vulcanizing activator
9 parts, 2 parts of anti-aging agent, 1.2 parts of promotor, 5 parts of insoluble sulfur, 1.5 parts of binder resin, 5 parts of methylene donor, cobalt salt
0.8 part, 0.3 part of antiscorching agent.
Comparative example 1
The difference from embodiment 1 is that: the carcass ply covers glue composition by cord and is made with steel cord;
It includes parts by weight that the cord, which covers glue composition: 100 parts of base rubber, 40 parts of reinforcing agent, vulcanizing activator
6 parts, 0.5 part of anti-aging agent, 0.5 part of promotor, 2 parts of insoluble sulfur, 0.5 part of binder resin, 3 parts of methylene donor, cobalt salt
0.2 part, 0.05 part of antiscorching agent.
Comparative example 2
The difference from embodiment 1 is that: the carcass ply covers glue composition by cord and is made with steel cord;
It includes parts by weight that the cord, which covers glue composition: 100 parts of base rubber, 70 parts of reinforcing agent, vulcanizing activator
12 parts, 5 parts of anti-aging agent, 2 parts of promotor, 8 parts of insoluble sulfur, 3 parts of binder resin, 8 parts of methylene donor, cobalt salt 1.5
Part, 0.6 part of antiscorching agent;
Tire safety intensity made of the carcass ply of full-steel radial ply tyres for passenger cars made from 1-3 of the embodiment of the present invention
It is obviously improved, is further reduced the risk damaged after tire collides under steam.Compared to made of more other fibrous materials
Tire, the cost of manufacture of tire made of the carcass ply of full-steel radial ply tyres for passenger cars made from 1-3 of the embodiment of the present invention
Low, tire drag reduces, and fuel consumption per hundred kilometers reduces 2%-4%, is conducive to low-carbon environment-friendly.1-3 of the embodiment of the present invention is made
Full-steel radial ply tyres for passenger cars carcass ply made of tire comfort in the process of moving, handling promoted, system
Dynamic distance and noise level are improved.
And tire safety intensity made of the carcass ply of full-steel radial ply tyres for passenger cars made from comparative example 1-2 does not have
It is significantly improved, the risk that tire damages after colliding under steam is higher.Not only tire drag is big, Er Qiebai
Gas mileage, which must not obtain, to be reduced, and comfort is poor, handling is low, and braking distance and noise level are poor.
Claims (10)
1. a kind of cord of full-steel radial ply tyres for passenger cars carcass, it is characterised in that: the carcass ply covers glue group by cord
Object is closed to be made with steel cord;
It includes parts by weight that the cord, which covers glue composition: 100 parts of base rubber, 45-60 parts of reinforcing agent, vulcanizing activator 8-
10 parts, 1-3 parts of anti-aging agent, 1-1.5 parts of promotor, 4-6 parts of insoluble sulfur, 1-2 parts of binder resin, methylene donor 4-6
Part, 0.4-1.2 parts of cobalt salt, 0.1-0.4 parts of antiscorching agent;
The steel cord is twisted by 9 outermost cover wires around 3 twisting steel wire of internal layer volumes.
2. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 1, it is characterised in that: the matrix rubber
Natural rubber 70-100 parts in glue, 0-30 parts of butadiene-styrene rubber;The natural rubber is SMR10/20 or STR10/20;Described
Butadiene-styrene rubber is the SBR1502 of low temperature cream polymerizing technology production.
3. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 2, it is characterised in that: the butylbenzene rubber
The dosage of glue is 10-30 parts by weight;
The dosage of the reinforcing agent is 48-54 parts by weight, and the reinforcing agent is Audit For Process technique N326 carbon black, the oil
The nitrogen adsorption surface area of furnace process N326 carbon black is 72-84 ㎡/g, and dibutyl terephthalate absorption value is 62- after compression
74ml/g。
4. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 1, it is characterised in that: the vulcanization is living
Property agent be the zinc oxide produced using zinc ingot metal as raw material indirect method, specific surface area be 4-8 ㎡/g;
The dosage of the anti-aging agent is 2-3 parts by weight, and the anti-aging agent is p phenylenediamine type antioxidant 6PPD;
The promotor is sulfenamide type accelerators DZ;
The insoluble sulfur is HD OT-20.
5. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 1, it is characterised in that: the bonding tree
The dosage of rouge is 1.2-1.8 parts, and the binder resin is resorcinol formaldehyde resin;
The methylene donor is hexamethylolmelamine pregnancy ether, the HMMM in hexamethylolmelamine pregnancy ether
Content 65%, white carbon black content 35%;
The cobalt salt is the cobalt decanoate that effective content is 20-21%;
The antiscorching agent is N- cyclohexylthiophthalimide.
6. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 1, it is characterised in that: all steel wires are straight
Diameter is identical, is 0.693-0.763mm;
It is 10.0mm that the cover wire of the steel cord, which compiles the lay pitch twisted,;The steel wire of internal layer of the steel cord compiles the lay pitch twisted
For 5.00mm.
7. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 1, it is characterised in that: the steel cord
Cover wire and steel wire of internal layer are twisted using S in the same direction to volume, one-pass molding.
8. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 1, it is characterised in that: the steel cord
Fracture Force >=755N;The steel cord and the bonding force >=700N for covering glue composition;
The plating weight of copper of the steel cord is 3.5-6.3g/kg, and the copper content of coating is 61.0%-66.0%;The steel
The line density of cord is 2.20-2.44g/m.
9. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 1, it is characterised in that: the steel cord
Suitable for NT, HT, ST, UT or MT grade steel wire.
10. the cord of full-steel radial ply tyres for passenger cars carcass according to claim 1, it is characterised in that: the carcass
Cord calendering covers glue composition with a thickness of 1.2mm-2.5mm, covers glue composition thickness deviation ± 0.05mm;The carcass ply
Calendering density be 50-110 root/dm.
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CN113087975A (en) * | 2021-03-26 | 2021-07-09 | 中策橡胶集团有限公司 | Low rolling resistance lightweight semisteel radial tire |
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