CN110326876A - Antibacterial pressure resistance single tube Lipstick holder and its material preparation method - Google Patents

Antibacterial pressure resistance single tube Lipstick holder and its material preparation method Download PDF

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Publication number
CN110326876A
CN110326876A CN201910564674.7A CN201910564674A CN110326876A CN 110326876 A CN110326876 A CN 110326876A CN 201910564674 A CN201910564674 A CN 201910564674A CN 110326876 A CN110326876 A CN 110326876A
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China
Prior art keywords
pearl
diameter
pen body
forked standard
pressure resistance
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CN201910564674.7A
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Chinese (zh)
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CN110326876B (en
Inventor
黄建艺
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Zhejiang Zhengzhuang Industrial Co Ltd
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Zhejiang Zhengzhuang Industrial Co Ltd
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    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/02Casings wherein movement of the lipstick or like solid is a sliding movement
    • A45D40/04Casings wherein movement of the lipstick or like solid is a sliding movement effected by a screw
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/20Pencil-like cosmetics; Simple holders for handling stick-shaped cosmetics or shaving soap while in use
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/24Casings for two or more cosmetics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/20Pencil-like cosmetics; Simple holders for handling stick-shaped cosmetics or shaving soap while in use
    • A45D2040/201Accessories
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to a kind of antibacterial pressure resistance single tube Lipstick holder and its material preparation methods, cause rotation feel poor for the design of existing similar product structure is not good enough, stability is poor, prepares the technical issues of material is further improved and designs.The forked standard of the Lipstick holder and one end fitting of pen body constitute a chamber, and it is intracavitary that pearl is set to the pen;Its main points is that the internal diameter of the pen body is cylindrical cavity, and the pearl of forked standard is inserted in end seat bore equipped with one of thread groove, and the external screw thread of pearl one end is screwed in forked standard by thread groove, and the outer diameter of thread groove is equipped with the circle muscle of protrusion;The outer diameter of the pearl other end is equipped with the muscle position being equally spaced vertically, the corresponding pen body inner wall in muscle position is equipped with guide groove, circle diameter diameter at muscle position, which is less than at the external screw thread of pearl, encloses diameter diameter, pearl is limited in the seat mouth of forked standard in pen body by muscle position, the spacing board of the upper and lower cavity of pearl internal diameter is equipped with through-hole, pearl it is upper intracavitary equipped with the convex ribs being equally spaced, above-mentioned section components are made of antibacterial pressure-resistant material.

Description

Antibacterial pressure resistance single tube Lipstick holder and its material preparation method
Technical field
It is a kind of antibacterial pressure resistance single tube Lipstick holder and its material preparation method the present invention relates to lipstick tube.
Background technique
Lipstick tube is widely used in the color make-ups packaging field such as lipstick, lipstick, since product structure and principle need, well known mouth The part of red pipe is made of different raw material, i.e., is made of plastics, metal.Its structure generally by lid, pen body, forked standard and Pearl composition, moves up and down the pearl in pen body by the rotation between pen body and forked standard, the stretching of lipstick cream in pearl or It retracts in pen body.Application number 201720319999.5 of such lipstick as disclosed in Chinese patent literature, authorized announcement date 2017.11.24, utility model title " a kind of pearl bullet type bump structure pen shape lipstick ";But the said goods and similar product In pen body between forked standard outer diameter and pen body internal diameter between smaller, airtight pressure when mutually being rotated between pen body and forked standard, in pen body Change it is more unstable, cause using when comfort it is poor, the stability of pearl is poor, to influence whole use and longevity Life.
Summary of the invention
To overcome above-mentioned deficiency, the purpose of the present invention is provide a kind of antibacterial pressure resistance single tube Lipstick holder and its material to this field Preparation method for material, solving it, existing similar product structure design is not good enough to cause rotation feel poor, and stability is poor, dependent part Part prepares the technical issues of material is further improved.The purpose is to what is be achieved through the following technical solutions.
A kind of antibacterial pressure resistance single tube Lipstick holder, the forked standard of the Lipstick holder and one end fitting of pen body constitute a chamber, suit place Forked standard outer diameter be equipped with sealing ring, pearl is set to that the pen is intracavitary, and the other end aperture internal diameter of pen body is equipped with limited mouth, aperture The pen body of outer diameter is equipped with outer cover, and the epicoele port of pearl is limited in the limited mouth in pen body, and the limited mouth outer diameter of pen body is necking; Its structure designing points is that the internal diameter of the pen body is cylindrical cavity, and the pearl of forked standard is inserted in end seat bore and is equipped with one of thread groove, The external screw thread of pearl one end is screwed in forked standard by thread groove, and the outer diameter of thread groove is equipped with the circle muscle of protrusion;The pearl other end Outer diameter is equipped with the muscle position being equally spaced vertically, and the corresponding pen body inner wall in muscle position is equipped with guide groove, and the circle diameter diameter at muscle position is less than Diameter diameter is enclosed at the external screw thread of pearl, pearl is limited in the seat mouth of forked standard in pen body by muscle position, the upper and lower cavity of pearl internal diameter it Spacing board is equipped with through-hole, and partition is located at internal diameter at the muscle position of pearl, pearl it is upper intracavitary equipped with the convex ribs being equally spaced.To pearl Mobile by muscle position and guide groove between son and pen body, thread groove reduces the inner wall thickness of forked standard below circle muscle, pen body internal diameter Gap increases between forked standard outer diameter, cooperates the through-hole of pearl, keeps air-tightness when pearl is mobile in pen body more stable.
Upper and lower ends are respectively equipped with limit salient point at the muscle position of the pearl, and the circle muscle diameter of forked standard is less than below circle muscle Circle is imported, sealing ring is set to the ring recess for importing forked standard outer diameter at circle, and circle is imported above the ring recess of forked standard and is equipped with buckle ring, forked standard is logical The catching groove for crossing buckle ring and pen body internal diameter fastens.Above structure convenient between forked standard and pen body assembly and pearl in pen body It is further stablize movement.
The pen body is antibacterial pressure resistance pen body, and forked standard is antibacterial pressure resistance forked standard, and antibacterial pressure-resistant material includes according to weight hundred Divide the following components of meter: ABS resin 50-70%, PET resin 10-30%, graphene oxide 5-10%, emulsifier 1-5%, nanometer two Titanium oxide 1-5%, coupling agent 0.1-2%, antioxidant 0.5-2%, optothermal stabilizer 0.1-0.5%.
The mass fraction accounting of water is 52% in the reaction kettle, and the emulsifier is the alkali metal salt of fatty acid.
The coupling agent is selected from least one of phosphate coupling agent, silane coupling agent.
The antioxidant is selected from least one of phenolic antioxidant 1010, auxiliary antioxidant 168.
The optothermal stabilizer is selected from 2- hydroxyl -4- methoxy benzophenone, 2- cyano -3,3 '-diphenyl-ethyl acrylate At least one of.
The preparation step of the antimicrobial macromolecule material is as follows: 1) in above-mentioned weight ratio weigh each ratio ABS resin, PET resin, emulsifier and coupling agent are placed in blender, are stirred 3-5 hours in the reaction kettle of 80-120 degree, are uniformly mixed, It handling 1-2 hours, is vacuumized under 70-80 degree 15-20 hours in ultrasonic wave, obtained mixture is placed in freezing equipment, It is freezed 4-6 hours in a low temperature of subzero 10 degree;2) graphene oxide after measuring will be sequentially added in the mixture after freezing, is received Rice titanium dioxide, antioxidant and optothermal stabilizer, and be stirred, obtained mixture is placed in conical double ribbon screw extruder material Melting extrusion, extrusion plastic particle are carried out in bucket;3) obtained plastic grain is put into injection moulding machine, by being molded into Type.
Rationally, Assembling Production is convenient, and usage comfort is good, and stability is good, and preparation method is feasible for structure of the invention design;Its It is suitable as using with the double end lip products of lash curler and informer's head and the structure of similar product is improved and material improvement.
Detailed description of the invention
Fig. 1 is schematic cross-sectional view of the invention.
Fig. 2 is the configuration schematic diagram of Fig. 1.
Figure number and title: 1, outer cover, 2, pen body, 201, guide groove, 3, pearl, 301, muscle position, 302, through-hole, 4, close Seal, 5, forked standard, 501, thread groove, 502, circle muscle, 503, buckle ring.
Specific embodiment
Now in conjunction with attached drawing, structure of the invention is further described.As shown in Figure 1 and Figure 2, the forked standard 5 and pen of the Lipstick holder One end fitting of body 2 constitutes a chamber, and the forked standard outer diameter of suit place is equipped with sealing ring 4, and it is intracavitary that pearl 3 is set to the pen, pen body Other end aperture internal diameter be equipped with limited mouth, the pen body of aperture outer diameter is equipped with outer cover 1, and the epicoele port of pearl is limited in pen body Limited mouth, the limited mouth outer diameter of pen body is necking.Its specific structure is as follows: the internal diameter of pen body is cylindrical cavity, the pearl of forked standard End seat bore is inserted in equipped with one of thread groove 501, the external screw thread of pearl one end is screwed in forked standard by thread groove, outside thread groove Diameter is equipped with the circle muscle 502 of protrusion;The outer diameter of the pearl other end is equipped with the muscle position 301 being equally spaced vertically, the corresponding pen body in muscle position Inner wall is equipped with guide groove 201, and the circle diameter diameter at muscle position, which is less than at the external screw thread of pearl, encloses diameter diameter, and pearl is limited by muscle position In the seat mouth of forked standard in pen body, the spacing board of the upper and lower cavity of pearl internal diameter is equipped with through-hole 302, in partition is located at the muscle position of pearl Diameter, pearl it is upper intracavitary equipped with the convex ribs being equally spaced.Meanwhile upper and lower ends are respectively equipped with limit salient point at the muscle position of pearl, The circle muscle diameter of forked standard is less than the importing circle below circle muscle, and sealing ring is set to the ring recess for importing forked standard outer diameter at circle, forked standard Circle is imported above ring recess is equipped with buckle ring 50), forked standard is fastened by the catching groove of buckle ring and pen body internal diameter.Above-mentioned pen body is antibacterial pressure resistance Pen body, forked standard are antibacterial pressure resistance forked standard, and the specific preparation method of antibacterial pressure-resistant material is as follows.
ABS resin 60g, PET resin 20g, emulsifier 5g and coupling agent 1g is weighed by above-mentioned weight ratio to be placed in blender, It is stirred 1 hour in 80 degree of reaction kettle, is uniformly mixed, handles 1 hour, vacuumized under 70 degree 15 hours in ultrasonic wave;? To mixture be placed in freezing equipment, freezed 4 hours in a low temperature of subzero 10 degree;By the mixture after obtained freezing In, graphene oxide 10g, antioxidant 0.5g, optothermal stabilizer 0.5g and nano-titanium dioxide 3g after sequentially adding metering, and It is stirred;Obtained mixture is placed in conical double ribbon screw extruder hopper and carries out melting extrusion, squeezes plastic grain;It will Obtained plastic grain, which is placed in, to be squeezed out in System of Hollow Blow Shaping Machine, and tubulose embryo is squeezed out;Obtained plastic grain is put into injection molding In molding machine, pass through injection molding.
Embodiment 2
ABS resin 50g, PET resin 30g, emulsifier 5g and coupling agent 1g is claimed to be placed in blender by above-mentioned weight ratio, 100 Stirring 1.5 hours in the reaction kettle of degree, are uniformly mixed, handle 1.5 hours, vacuumize under 75 degree 15 hours in ultrasonic wave;It will Obtained mixture is placed in freezing equipment, is freezed 5 hours in a low temperature of subzero 10 degree;By the mixture after obtained freezing In, successively plus graphene oxide 10g, antioxidant 0.5g, optothermal stabilizer 0.1g and nano-titanium dioxide 3.4g, and stir mixed It closes;Obtained mixture is placed in conical double ribbon screw extruder hopper and carries out melting extrusion, extrusion plastic particle;It will obtain Plastic grain be placed in squeeze out System of Hollow Blow Shaping Machine in, squeeze out tubulose embryo;Obtained plastic grain is put into injection molding In machine, pass through injection molding.
Embodiment 3
ABS resin 70g, PET resin 15g, emulsifier 5g and coupling agent 1g is weighed by above-mentioned weight ratio to be placed in blender, Stirring 2 hours in 120 degree of reaction kettle, are uniformly mixed, handle 2 hours, vacuumize under 80 degree 20 hours in ultrasonic wave;Will To mixture be placed in freezing equipment, freezed 6 hours in a low temperature of subzero 10 degree;By the mixture after obtained freezing In, graphene oxide 5g, antioxidant 0.5g, optothermal stabilizer 0.5g and nano-titanium dioxide 3g are sequentially added, and be stirred; Obtained mixture is placed in conical double ribbon screw extruder hopper and carries out melting extrusion, extrusion plastic particle;By what is obtained Plastic grain is put into injection moulding machine, passes through injection molding.
The mass fraction accounting of water is 52% in the reaction kettle of above-described embodiment, and emulsifier is the alkali metal salt of fatty acid.

Claims (8)

1. a kind of antibacterial pressure resistance single tube Lipstick holder, the forked standard (5) of the Lipstick holder and one end fitting of pen body (2) constitute a chamber, set Forked standard outer diameter at conjunction is equipped with sealing ring (4), and pearl (3) is set to that the pen is intracavitary, and the other end aperture internal diameter of pen body is equipped with The pen body of limited mouth, aperture outer diameter is equipped with outer cover (1), and the epicoele port of pearl is limited in the limited mouth in pen body, the limit of pen body Position mouth outer diameter is necking;It is characterized in that the internal diameter of the pen body (2) is cylindrical cavity, the pearl (3) of forked standard (5) is inserted in end seat mouth Diameter is equipped with one of thread groove (501), and the external screw thread of pearl one end is screwed in forked standard by thread groove, and the outer diameter of thread groove is equipped with convex The circle muscle (502) risen;The outer diameter of the pearl other end is equipped with the muscle position (301) being equally spaced vertically, the corresponding pen body inner wall in muscle position Equipped with guide groove (201), the circle diameter diameter at muscle position, which is less than at the external screw thread of pearl, encloses diameter diameter, and pearl is limited in by muscle position The seat mouth of forked standard in pen body, the spacing board of the upper and lower cavity of pearl internal diameter are equipped with through-hole (302), in partition is located at the muscle position of pearl Diameter, pearl it is upper intracavitary equipped with the convex ribs being equally spaced.
2. antibacterial pressure resistance single tube Lipstick holder according to claim 1, it is characterised in that the muscle position (301) of the pearl (3) Place's upper and lower ends are respectively equipped with limit salient point, and the circle muscle diameter of forked standard (5) is less than the importing circle below circle muscle, and sealing ring (4) is set It is placed in the ring recess for importing forked standard outer diameter at circle, circle is imported above the ring recess of forked standard and is equipped with buckle ring (503), forked standard passes through buckle ring and pen The catching groove of body internal diameter fastens.
3. the preparation method of antibacterial pressure resistance single tube Lipstick holder according to claim 1, it is characterised in that the pen body (2) is Antibacterial pressure resistance pen body, forked standard (5) are antibacterial pressure resistance forked standard, and antibacterial pressure-resistant material includes the following components according to weight percentage: ABS resin 50-70%, PET resin 10-30%, graphene oxide 5-10%, emulsifier 1-5%, nano-titanium dioxide 1-5%, coupling Agent 0.1-2%, antioxidant 0.5-2%, optothermal stabilizer 0.1-0.5%.
4. the preparation method of antibacterial pressure resistance single tube Lipstick holder according to claim 3, it is characterised in that in the reaction kettle The mass fraction accounting of water is 52%, and the emulsifier is the alkali metal salt of fatty acid.
5. the preparation method of antibacterial pressure resistance single tube Lipstick holder according to claim 3, it is characterised in that the coupling agent choosing From at least one of phosphate coupling agent, silane coupling agent.
6. the preparation method of antibacterial pressure resistance single tube Lipstick holder according to claim 3, it is characterised in that the antioxidant choosing From at least one of phenolic antioxidant 1010, auxiliary antioxidant 168.
7. the preparation method of antibacterial pressure resistance single tube Lipstick holder according to claim 3, it is characterised in that the photo-thermal is stablized Agent is selected from least one of 2- hydroxyl -4- methoxy benzophenone, 2- cyano -3,3 '-diphenyl-ethyl acrylate.
8. the preparation method of antibacterial pressure resistance single tube Lipstick holder according to claim 3, it is characterised in that the antibacterial high score The preparation step of sub- material is as follows: 1) ABS resin, PET resin, emulsifier and the coupling agent of each ratio are weighed in above-mentioned weight ratio It is placed in blender, is stirred 3-5 hours in the reaction kettle of 80-120 degree, be uniformly mixed, handled 1-2 hours in ultrasonic wave, in It is vacuumized under 70-80 degree 15-20 hours, obtained mixture is placed in freezing equipment, freezes 4-6 in a low temperature of subzero 10 degree Hour;2) graphene oxide, nano-titanium dioxide, antioxidant and photo-thermal after measuring will be sequentially added in the mixture after freezing Stabilizer, and be stirred, obtained mixture, which is placed in conical double ribbon screw extruder hopper, carries out melting extrusion, squeezes out modeling Expect particle;3) obtained plastic grain is put into injection moulding machine, passes through injection molding.
CN201910564674.7A 2019-06-27 2019-06-27 Antibacterial pressure-resistant single-tube lipstick pen and material preparation method thereof Active CN110326876B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110789842A (en) * 2019-10-25 2020-02-14 浙江正庄实业有限公司 Antibacterial high-molecular press type small spray head and preparation method thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10192048A (en) * 1996-12-27 1998-07-28 Kao Corp Pen type lip cosmetic applying container
CN201839988U (en) * 2010-09-08 2011-05-25 浙江阿克希龙舜华铝塑业有限公司 Lipstick tube beam core with simple structure
CN205106740U (en) * 2015-09-25 2016-03-30 浙江阿克希龙舜华铝塑业有限公司 Lipstick pipe that lotion can be used up
CN107163359A (en) * 2017-07-18 2017-09-15 合肥万之景门窗有限公司 A kind of antibacterial wear-resistant plastic and preparation method thereof
CN206659381U (en) * 2017-03-29 2017-11-24 苏州佑嘉塑胶科技有限公司 A kind of pearl bullet type bump structure form of a stroke or a combination of strokes lipstick
CN206729488U (en) * 2017-05-03 2017-12-12 比优特(苏州)塑胶科技有限公司 A kind of sub warhead lipstick
CN107556677A (en) * 2017-10-09 2018-01-09 浙江卫星新材料科技有限公司 A kind of super absorbent resin of high antibiotic property and high-salt tolerance and preparation method and application
CN109090806A (en) * 2018-09-14 2018-12-28 浙江正庄实业有限公司 Antiultraviolet pressure resistance square tube lipstick and its resin material preparation method
CN109770522A (en) * 2019-03-20 2019-05-21 亦臻包装科技(苏州)有限公司 A kind of lipstick tube

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10192048A (en) * 1996-12-27 1998-07-28 Kao Corp Pen type lip cosmetic applying container
CN201839988U (en) * 2010-09-08 2011-05-25 浙江阿克希龙舜华铝塑业有限公司 Lipstick tube beam core with simple structure
CN205106740U (en) * 2015-09-25 2016-03-30 浙江阿克希龙舜华铝塑业有限公司 Lipstick pipe that lotion can be used up
CN206659381U (en) * 2017-03-29 2017-11-24 苏州佑嘉塑胶科技有限公司 A kind of pearl bullet type bump structure form of a stroke or a combination of strokes lipstick
CN206729488U (en) * 2017-05-03 2017-12-12 比优特(苏州)塑胶科技有限公司 A kind of sub warhead lipstick
CN107163359A (en) * 2017-07-18 2017-09-15 合肥万之景门窗有限公司 A kind of antibacterial wear-resistant plastic and preparation method thereof
CN107556677A (en) * 2017-10-09 2018-01-09 浙江卫星新材料科技有限公司 A kind of super absorbent resin of high antibiotic property and high-salt tolerance and preparation method and application
CN109090806A (en) * 2018-09-14 2018-12-28 浙江正庄实业有限公司 Antiultraviolet pressure resistance square tube lipstick and its resin material preparation method
CN109770522A (en) * 2019-03-20 2019-05-21 亦臻包装科技(苏州)有限公司 A kind of lipstick tube

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110789842A (en) * 2019-10-25 2020-02-14 浙江正庄实业有限公司 Antibacterial high-molecular press type small spray head and preparation method thereof
CN110789842B (en) * 2019-10-25 2024-01-16 浙江正庄实业有限公司 Antibacterial polymer pressing type small spray head and preparation method thereof

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